CN108424696A - A kind of water-and acrylate water-proof heat-insulating paint and preparation method thereof - Google Patents
A kind of water-and acrylate water-proof heat-insulating paint and preparation method thereof Download PDFInfo
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- CN108424696A CN108424696A CN201810344715.7A CN201810344715A CN108424696A CN 108424696 A CN108424696 A CN 108424696A CN 201810344715 A CN201810344715 A CN 201810344715A CN 108424696 A CN108424696 A CN 108424696A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- Engineering & Computer Science (AREA)
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Abstract
A kind of water-and acrylate water-proof heat-insulating paint of the present invention and preparation method thereof, raw material include following components by weight：80 120 parts of acrylic acid ester emulsion, 8 12 parts of hollow ceramic microspheres, 36 parts of nano far infrared ceramic powder, 36 parts of hollow glass microbead, 30 50 parts of white cement, 20 30 parts of calcium carbonate, 10 15 parts of quartz sand, 8 12 parts of titanium dioxide, 23 parts of water-reducing agent, 0.2 0.5 parts of fungicide, 0.5 0.8 parts of antifoaming agent, 0.2 0.5 parts of levelling agent, 30 50 parts of deionized water.The coating application is complete smooth, hydrophobicity, self-cleaning property are good, with lower thermal coefficient, reflective insulation excellent performance advantage, thus room temperature High tailored coating be temperature with high efficiency, thin layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, acid and alkali-resistance, anti-corrosion in one novel normal-temperature cooling energy-saving long-life coating.
Description
Technical field
The present invention relates to a kind of water-proof heat-insulating paints, and in particular to a kind of water-and acrylate water-proof heat-insulating paint and its system
Preparation Method.
Background technology
Water-proof heat-insulating paint and heat-reflecting heat-insulating it is good material composition, coating be collection reflection, radiation it is heat-insulated with cenosphere
With the novel High tailored coating of one.Coating can carry out high reflection to the solar infrared and ultraviolet light of 400nm--2500nm ranges,
The heat of the sun is not allowed to carry out accumulation heating in body surface, and can automatic will Sheng board water-proof heat-insulating paint progress heat radiation
Radiating and cooling is radiated the heat of body surface in space, reduces the temperature of object, even if in cloudy day and night coating
Energy radiations heat energy reduces temperature, while the transmission of the extremely low cenosphere isolation thermal energy of thermal coefficient is put into coating, even if
It can also be conducted to interior of articles every firmly outside heat when atmospheric temperature is very high, three large effects ensure that the object drop of brushing paint
Temperature, it is ensured that interior of articles space can keep the state of lasting constant temperature.ZS-221 heat insulation coatings are in sunlight strong, coating
20 DEG C of body surface temperature or more can be reduced, cloudy day and night can cool down at 3 DEG C or more or be reduced to and atmospheric temperature
Unanimously.Object for brushing tiny crackle has good waterproof, antiseep effect, and there are many coating, and color is available,
Can according to different colours require brushing different colours room temperature High tailored coating, in addition coating application is complete smooth, hydrophobicity, from
Clean performance is good, thus room temperature High tailored coating be temperature with high efficiency, it is thin layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, resistance to
Soda acid, anti-corrosion are in the novel normal-temperature cooling energy-saving long-life coating of one.Room temperature High tailored coating can be widely used for building, chemical industry,
Cool down in the industries such as oil, electric power, metallurgy, ship, light textile, storage, traffic, space flight, it is energy saving, create comfortable mankind's life
Living, working environment.
Invention content
It is an object of the invention to provide a kind of water-and acrylate water-proof heat-insulating paint and preparation method thereof, a kind of water
Property acrylate flood coat insulating moulding coating using acrylic acid ester emulsion as film forming matter, addition with heat-proof quality and water resistance
The materials such as hollow glass microbead, white cement, calcium carbonate, quartz sand, titanium dioxide, water-reducing agent, and part of auxiliary is added, it is prepared
A kind of water-and acrylate water-proof heat-insulating paint.This kind of water-and acrylate water-proof heat-insulating paint coating application is complete smooth flat
Whole, hydrophobicity, self-cleaning property are good, have lower thermal coefficient, reflective insulation excellent performance advantage, so room temperature High tailored coating is
Temperature with high efficiency, thin layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, acid and alkali-resistance, anti-corrosion are dropped in the novel normal-temperature of one
Warm durable energy saving orders coating.Room temperature High tailored coating can be widely used for building, chemical industry, oil, electric power, metallurgy, ship, light textile, storage
It deposits, traffic, cool down in the industries such as space flight, it is energy saving, create comfortable human lives, working environment.
Above-mentioned purpose to realize the present invention, a kind of water-and acrylate water-proof heat-insulating paint of the present invention use following technical side
Case：A kind of water-and acrylate water-proof heat-insulating paint, raw material include following components by weight：Acrylic acid ester emulsion 80-120
Part, 8-12 parts of hollow ceramic microspheres, 3-6 parts of nano far infrared ceramic powder, 3-6 parts of hollow glass microbead, 30-50 parts of white cement,
20-30 parts of calcium carbonate, 10-15 parts of quartz sand, 8-12 parts of titanium dioxide, 2-3 parts of water-reducing agent, 0.2-0.5 parts of fungicide, antifoaming agent
0.5-0.8 parts, 0.2-0.5 parts of levelling agent, 30-50 parts of deionized water.
Further, the hollow glass microbead is the hollow beads of 50~150 μm of grain size.
Further, the calcium carbonate is powdered whiting.
Further, the titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
Further, the water-reducing agent is polycarboxylic-acid.
Further, the antifoaming agent is modified polyether ester.
Further, preparation method includes the following steps：
S10, required various materials are weighed；
S11, acrylic acid ester emulsion, antifoaming agent, fungicide that step S10 is weighed are put into beaker, in the machinery of 500r/min
Under stirring, 5-10min is stirred, liquid material is prepared into；
S12, by hollow ceramic microspheres, nano far infrared ceramic powder, hollow glass microbead, white cement, calcium carbonate, quartz sand, titanium
White powder, water-reducing agent are put into according to the number claimed in BJ-100 type mixers, are mixed 5-10min, are prepared into powder；
S13, the powder that the step S12 liquid materials being prepared into and step S13 are prepared into is mixed and is added levelling agent, deionized water,
Under the mechanical agitation of 500-1000r/min, 5-10min is stirred, that is, this kind of water-and acrylate waterproof and heat-insulating is prepared and applies
Material.
It is compared with the prior art, the invention has the advantages that：
1, it is closed hollow ball using hollow glass micropearl in the present invention, inside is vacuum either N2, CO2 gas, is had
Sound insulation, heat-insulated, insulation characterisitic, its ball shape can provide more preferable than sheet, needle-shaped and irregular shape filler particle
Mobility, make coating have isotropism, so that stress is uniformly dispersed, coating can be reduced because the stress for generation of expanding with heat and contract with cold is opened
It splits.Wherein hollow glass micropearl has lower thermal coefficient, and hollow glass micropearl is added in coating and plays reflective insulation
Effect；
2, it is that a kind of heat preservation and insulation is excellent, environment that the insulating moulding coating obtained by the preparation of hollow glass micropearl is added in the present invention
Friendly heat insulation function coating, by the research to the heat insulating coatings coating heat insulation, with vacuum glass microballoon etc.
It is strong for the heat insulating coatings performance stabilization of color stuffing preparation, heat insulating function, it is used as insulating layer of external wall of building, being one kind has
The power-economizing method of effect, especially when the grain size of hollow glass microballoon is 58 μm or so, insulating moulding coating has suitable thermal conductivity,
Thermal conductivity than the hollow glass microballoon insulating moulding coating of other grain sizes is low 6-28%；When hollow glass microballoon content is less than 10%,
Heat reflectivity is dramatically increased with the increase of hollow glass microbead content；After hollow glass microbead content reaches 10%, coating
The increase reduced rate of heat reflectivity, when hollow glass microbead content reaches 12%, the heat reflectivity value highest of coating continues
Increase the content of coating hollow glass microbead, heat reflectivity almost no longer increases.Therefore hollow glass microbead content is 10%-12%
When, coating has best heat reflectivity；
3, a kind of water-and acrylate water-proof heat-insulating paint coating of the invention is not only good with antibacterial and mouldproof effect, low temperature is soft
Property, impermeability, the strong feature beauty non-toxic to humans, environmentally friendly of high-decoration decorative effect, also have UV resistant
The advantages that irradiation, caking ability are greatly, tensile strength and elongation at break are good, waterproof anti seismic efficiency is good, heat-proof quality is good；
4, a kind of water-and acrylate water-proof heat-insulating paint coating application of the present invention is complete smooth, and hydrophobicity, self-cleaning property are good,
With lower thermal coefficient, reflective insulation excellent performance advantage, so room temperature High tailored coating be temperature with high efficiency, thin layer, decoration, from
Clean, waterproof, moisture-proof, antiultraviolet aging, acid and alkali-resistance, anti-corrosion are in the novel normal-temperature cooling energy-saving long-life coating of one.Room temperature
High tailored coating can be widely used for dropping in the industries such as building, chemical industry, oil, electric power, metallurgy, ship, light textile, storage, traffic, space flight
Temperature, it is energy saving, create comfortable human lives, working environment.
Specific implementation mode
In order to make the content of the present invention more clearly understood, below according to specific embodiments of the present invention, to this
Invention is described in further detail.
Embodiment 1
A kind of water-and acrylate water-proof heat-insulating paint, raw material include following components by weight：80 parts of acrylic acid ester emulsion,
8 parts of hollow ceramic microspheres, 3 parts of nano far infrared ceramic powder, 3 parts of hollow glass microbead, 30 parts of white cement, 20 parts of calcium carbonate, stone
10 parts of sand, 8 parts of titanium dioxide, 2 parts of water-reducing agent, 0.2 part of fungicide, 0.5 part of antifoaming agent, 0.2 part of levelling agent, deionized water 30
Part.
The hollow glass microbead is the hollow beads of 50 μm of grain size.
The calcium carbonate is powdered whiting.
The titanium dioxide is rutile type titanium white, and grain size is 100 μm.
The water-reducing agent is polycarboxylic-acid.
The antifoaming agent is modified polyether ester.
Preparation method includes the following steps：
S10, required various materials are weighed；
S11, acrylic acid ester emulsion, antifoaming agent, fungicide that step S10 is weighed are put into beaker, in the machinery of 500r/min
Under stirring, 5min is stirred, liquid material is prepared into；
S12, by hollow ceramic microspheres, nano far infrared ceramic powder, hollow glass microbead, white cement, calcium carbonate, quartz sand, titanium
White powder, water-reducing agent are put into according to the number claimed in BJ-100 type mixers, are mixed 5min, are prepared into powder；
S13, the powder that the step S12 liquid materials being prepared into and step S13 are prepared into is mixed and is added levelling agent, deionized water,
Under the mechanical agitation of 500r/min, 5min is stirred, that is, this kind of water-and acrylate water-proof heat-insulating paint is prepared.
Embodiment 2
A kind of water-and acrylate water-proof heat-insulating paint, raw material include following components by weight：Acrylic acid ester emulsion 120
Part, 12 parts of hollow ceramic microspheres, 6 parts of nano far infrared ceramic powder, 6 parts of hollow glass microbead, 50 parts of white cement, calcium carbonate 30
Part, 15 parts of quartz sand, 12 parts of titanium dioxide, 3 parts of water-reducing agent, 0.5 part of fungicide, 0.8 part of antifoaming agent, 0.5 part of levelling agent, deionization
50 parts of water.
The hollow glass microbead is the hollow beads of 150 μm of grain size.
The calcium carbonate is powdered whiting.
The titanium dioxide is rutile type titanium white, and grain size is 150 μm.
The water-reducing agent is polycarboxylic-acid.
The antifoaming agent is modified polyether ester.
Preparation method includes the following steps：
S10, required various materials are weighed；
S11, acrylic acid ester emulsion, antifoaming agent, fungicide that step S10 is weighed are put into beaker, in the machinery of 500r/min
Under stirring, 10min is stirred, liquid material is prepared into；
S12, by hollow ceramic microspheres, nano far infrared ceramic powder, hollow glass microbead, white cement, calcium carbonate, quartz sand, titanium
White powder, water-reducing agent are put into according to the number claimed in BJ-100 type mixers, are mixed 10min, are prepared into powder；
S13, the powder that the step S12 liquid materials being prepared into and step S13 are prepared into is mixed and is added levelling agent, deionized water,
Under the mechanical agitation of 1000r/min, 10min is stirred, that is, this kind of water-and acrylate water-proof heat-insulating paint is prepared.
Embodiment 3
A kind of water-and acrylate water-proof heat-insulating paint, raw material include following components by weight：Acrylic acid ester emulsion 100
Part, 9 parts of hollow ceramic microspheres, 5 parts of nano far infrared ceramic powder, 5 parts of hollow glass microbead, 40 parts of white cement, 25 parts of calcium carbonate,
12 parts of quartz sand, 9 parts of titanium dioxide, 2.5 parts of water-reducing agent, 0.3 part of fungicide, 0.6 part of antifoaming agent, 0.3 part of levelling agent, deionized water
40 parts.
The hollow glass microbead is the hollow beads of 58 μm of grain size.
The calcium carbonate is powdered whiting.
The titanium dioxide is rutile type titanium white, and grain size is 120 μm.
The water-reducing agent is polycarboxylic-acid.
The antifoaming agent is modified polyether ester.
Preparation method includes the following steps：
S10, required various materials are weighed；
S11, acrylic acid ester emulsion, antifoaming agent, fungicide that step S10 is weighed are put into beaker, in the machinery of 500r/min
Under stirring, 8min is stirred, liquid material is prepared into；
S12, by hollow ceramic microspheres, nano far infrared ceramic powder, hollow glass microbead, white cement, calcium carbonate, quartz sand, titanium
White powder, water-reducing agent are put into according to the number claimed in BJ-100 type mixers, are mixed 8min, are prepared into powder；
S13, the powder that the step S12 liquid materials being prepared into and step S13 are prepared into is mixed and is added levelling agent, deionized water,
Under the mechanical agitation of 600r/min, 8min is stirred, that is, this kind of water-and acrylate water-proof heat-insulating paint is prepared.
Above said content is only the basic explanation under present inventive concept, and is appointed made by technical solution according to the present invention
What equivalent transformation, is within the scope of protection of the invention.
Claims (7)
1. a kind of water-and acrylate water-proof heat-insulating paint, which is characterized in that its raw material includes following components by weight：Propylene
80-120 parts of acid esters lotion, 8-12 parts of hollow ceramic microspheres, 3-6 parts of nano far infrared ceramic powder, 3-6 parts of hollow glass microbead,
30-50 parts of white cement, 20-30 parts of calcium carbonate, 10-15 parts of quartz sand, 8-12 parts of titanium dioxide, 2-3 parts of water-reducing agent, fungicide 0.2-
0.5 part, 0.5-0.8 parts of antifoaming agent, 0.2-0.5 parts of levelling agent, 30-50 parts of deionized water.
2. a kind of water-and acrylate water-proof heat-insulating paint according to claim 1, which is characterized in that the hollow glass
Glass microballon is the hollow beads of 50~150 μm of grain size.
3. a kind of water-and acrylate water-proof heat-insulating paint according to claim 1, which is characterized in that the calcium carbonate is
Powdered whiting.
4. a kind of water-and acrylate water-proof heat-insulating paint according to claim 1, which is characterized in that the titanium dioxide
For rutile type titanium white, grain size is 100~150 μm.
5. a kind of water-and acrylate water-proof heat-insulating paint according to claim 1, which is characterized in that the water-reducing agent is
Polycarboxylic-acid.
6. a kind of water-and acrylate water-proof heat-insulating paint according to claim 1, which is characterized in that the antifoaming agent
For modified polyether ester.
7. a kind of water-and acrylate water-proof heat-insulating paint according to claim 1, which is characterized in that preparation method packet
Include following steps：
S10, required various materials are weighed；
S11, acrylic acid ester emulsion, antifoaming agent, fungicide that step S10 is weighed are put into beaker, in the machinery of 500r/min
Under stirring, 5-10min is stirred, liquid material is prepared into；
S12, by hollow ceramic microspheres, nano far infrared ceramic powder, hollow glass microbead, white cement, calcium carbonate, quartz sand, titanium
White powder, water-reducing agent are put into according to the number claimed in BJ-100 type mixers, are mixed 5-10min, are prepared into powder；
S13, the powder that the step S12 liquid materials being prepared into and step S13 are prepared into is mixed and is added levelling agent, deionized water,
Under the mechanical agitation of 500-1000r/min, 5-10min is stirred, that is, this kind of water-and acrylate waterproof and heat-insulating is prepared and applies
Material.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810344715.7A CN108424696A (en) | 2018-04-17 | 2018-04-17 | A kind of water-and acrylate water-proof heat-insulating paint and preparation method thereof |
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| CN201810344715.7A CN108424696A (en) | 2018-04-17 | 2018-04-17 | A kind of water-and acrylate water-proof heat-insulating paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958049A (en) * | 2022-07-14 | 2022-08-30 | 江西春木建筑防水工程有限公司 | Weather-resistant roof waterproof coating with heat insulation and heat preservation functions |
-
2018
- 2018-04-17 CN CN201810344715.7A patent/CN108424696A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114958049A (en) * | 2022-07-14 | 2022-08-30 | 江西春木建筑防水工程有限公司 | Weather-resistant roof waterproof coating with heat insulation and heat preservation functions |
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Application publication date: 20180821 |