CN108467632A - A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating - Google Patents
A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating Download PDFInfo
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- CN108467632A CN108467632A CN201810345439.6A CN201810345439A CN108467632A CN 108467632 A CN108467632 A CN 108467632A CN 201810345439 A CN201810345439 A CN 201810345439A CN 108467632 A CN108467632 A CN 108467632A
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- vinyl acetate
- acrylic acid
- insulating coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
A kind of acrylic acid modified ethylene-vinyl acetate building waterproof heat-insulating coating of the present invention, raw material include following components by weight：80 120 parts of ethylene-vinyl acetate lotion, 10 30 parts of propylene acetic acid latex, 8 12 parts of hollow ceramic microspheres, 36 parts of nano far infrared ceramic powder, 36 parts of hollow glass microbead, 5 20 parts of silicate, 5 20 parts of bentonite, 20 30 parts of calcium carbonate, 10 15 parts of quartz sand, 8 12 parts of titanium dioxide, 23 parts of water-reducing agent, 36 parts of plasticizer, 13 parts of emulsifier, 0.5 0.8 parts of antifoaming agent, 0.2 0.5 parts of levelling agent, 13 parts of antifreezing agent, 0.2 0.5 parts of mould inhibitor, 0.8 1.5 parts of dispersant.The paint brush is complete smooth, hydrophobicity, self-cleaning property are good, with lower thermal coefficient, reflective insulation excellent performance advantage, so room temperature High tailored coating is temperature with high efficiency, thin layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, acid and alkali-resistance, anti-corrosion novel energy-conserving long-life coating.
Description
Technical field
The present invention relates to a kind of water-proof heat-insulating paints, and in particular to a kind of acrylic acid modified ethene-vinyl acetate building is anti-
Water insulating moulding coating.
Background technology
Water-proof heat-insulating paint and heat-reflecting heat-insulating it is good material composition, coating be collection reflection, radiation it is heat-insulated with cenosphere
With the novel High tailored coating of one.Coating can carry out high reflection to the solar infrared and ultraviolet light of 400nm--2500nm ranges,
The heat of the sun is not allowed to carry out accumulation heating in body surface, and can automatic will Sheng board water-proof heat-insulating paint progress heat radiation
Radiating and cooling is radiated the heat of body surface in space, reduces the temperature of object, even if in cloudy day and night coating
Energy radiations heat energy reduces temperature, while the transmission of the extremely low cenosphere isolation thermal energy of thermal coefficient is put into coating, even if
It can also be conducted to interior of articles every firmly outside heat when atmospheric temperature is very high, three large effects ensure that the object drop of brushing paint
Temperature, it is ensured that interior of articles space can keep the state of lasting constant temperature.ZS-221 heat insulation coatings are in sunlight strong, coating
20 DEG C of body surface temperature or more can be reduced, cloudy day and night can cool down at 3 DEG C or more or be reduced to and atmospheric temperature
Unanimously.Object for brushing tiny crackle has good waterproof, antiseep effect, and there are many coating, and color is available,
Can according to different colours require brushing different colours room temperature High tailored coating, in addition coating application is complete smooth, hydrophobicity, from
Clean performance is good, thus room temperature High tailored coating be temperature with high efficiency, it is thin layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, resistance to
Soda acid, anti-corrosion are in the novel normal-temperature cooling energy-saving long-life coating of one.Room temperature High tailored coating can be widely used for building, chemical industry,
Cool down in the industries such as oil, electric power, metallurgy, ship, light textile, storage, traffic, space flight, it is energy saving, create comfortable mankind's life
Living, working environment.
Invention content
It is an object of the invention to provide a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating, this one
Plant acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating is with ethene-vinyl acetate lotion and propylene acetic acid latex
Film forming matter, hollow ceramic microspheres, nano far infrared ceramic powder, the hollow glass with heat-proof quality and water resistance of addition
The materials such as microballon, silicate, bentonite, calcium carbonate, quartz sand, titanium dioxide, water-reducing agent, and part of auxiliary is added, it is prepared
A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating.A kind of this kind of acrylic acid modified ethene-vinyl acetate
Building waterproof heat-insulating paint brush is complete smooth, and hydrophobicity, self-cleaning property are good, has lower thermal coefficient, reflective insulation
Can good advantage, so room temperature High tailored coating be temperature with high efficiency, it is thin layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, resistance to
Soda acid, anti-corrosion are in the novel normal-temperature cooling energy-saving long-life coating of one.Room temperature High tailored coating can be widely used for building, chemical industry,
Cool down in the industries such as oil, electric power, metallurgy, ship, light textile, storage, traffic, space flight, it is energy saving, create comfortable mankind's life
Living, working environment.
Above-mentioned purpose to realize the present invention, a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating of the present invention apply
Material uses following technical scheme：A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating, raw material is by weight
Including following components：80-120 parts of ethene-vinyl acetate lotion, 10-30 parts of propylene acetic acid latex, hollow ceramic microspheres 8-12
Part, 3-6 parts of nano far infrared ceramic powder, 3-6 parts of hollow glass microbead, 5-20 parts of silicate, 5-20 parts of bentonite, calcium carbonate
20-30 parts, 10-15 parts of quartz sand, 8-12 parts of titanium dioxide, 2-3 parts of water-reducing agent, 3-6 parts of plasticizer, 1-3 parts of emulsifier, antifoaming agent
0.5-0.8 parts, 0.2-0.5 parts of levelling agent, 1-3 parts of antifreezing agent, 0.2-0.5 parts of mould inhibitor, 0.8-1.5 parts of dispersant.
Further, the hollow glass microbead is the hollow beads of 50~150 μm of grain size.
Further, the calcium carbonate is powdered whiting.
Further, the titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
Further, the water-reducing agent is polycarboxylic-acid.
Further, the antifoaming agent is modified polyether ester.
Further, the antifreezing agent is ethylene glycol.
It is compared with the prior art, the invention has the advantages that：
1, it is close using hollow glass micropearl in a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating of the present invention
Close hollow ball, inside is vacuum either N2, CO2 gas, has sound insulation, a heat-insulated, insulation characterisitic, its ball shape can be with
Mobility more better than sheet, needle-shaped and irregular shape filler particle is provided, makes coating that there is isotropism, makes stress point
It dissipates uniformly, stress cracking of the coating because of generation of expanding with heat and contract with cold can be reduced.Wherein hollow glass micropearl has lower thermal coefficient,
Hollow glass micropearl is added in coating and plays the role of reflective insulation；
2, the system of hollow glass micropearl is added in a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating of the present invention
The insulating moulding coating of standby gained is the heat insulation function coating that a kind of heat preservation and insulation is excellent, environmental-friendly, by heat-insulated to this
The research of thermal insulation coatings coating heat insulation is that heat insulating coatings performance prepared by color stuffing is steady with vacuum glass microballoon etc.
Calmly, heat insulating function is strong, is used as insulating layer of external wall of building, is a kind of effective power-economizing method, especially micro- in hollow glass
When the grain size of ball is 58 μm or so, insulating moulding coating has suitable thermal conductivity, painting more heat-insulated than the hollow glass microballoon of other grain sizes
The low 6-28% of thermal conductivity of material；When hollow glass microballoon content be less than 10% when, heat reflectivity with hollow glass microbead content increasing
Add and dramatically increases；After hollow glass microbead content reaches 10%, the increase reduced rate of coating heat reflectivity, when hollow
When glass microballoon content reaches 12%, the heat reflectivity value highest of coating continues growing the content of coating hollow glass microbead, heat
Reflectivity almost no longer increases.Therefore hollow glass microbead content be 10%-12% when, coating have best heat reflectivity；
3, a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating of the invention not only has antibacterial and mouldproof effect
Good, low temperature flexibility, impermeability, the strong feature beauty non-toxic to humans, environmentally friendly of high-decoration decorative effect, also has
UV resistant irradiation, that caking ability is big, tensile strength and elongation at break are good, waterproof anti seismic efficiency is good, heat-proof quality is good etc. is excellent
Point；
4, a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating of the present invention in coating due to having blended branch
Type modifying agent after film is solid, forms trisquare and interlocks the rubber and plastic body of network-like structure, film is made to have good elastoplasticity, and
Moderate cost, application effect are also good.When coating application, ambient air temperature is generally suitable in 5-36 degree.Before coating is coated with surface drying,
It should avoid rain drop erosion；
5, a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating paint brush of the present invention is complete smooth, hydrophobicity, from
Clean performance is good, have lower thermal coefficient, reflective insulation excellent performance advantage, thus room temperature High tailored coating be temperature with high efficiency, it is thin
Layer, decoration, self-cleaning, waterproof, moisture-proof, antiultraviolet aging, acid and alkali-resistance, anti-corrosion are in the novel normal-temperature cooling energy-saving long-life of one
Coating.Room temperature High tailored coating can be widely used for building, chemical industry, oil, electric power, metallurgy, ship, light textile, storage, traffic, space flight
Etc. cool down in industries, it is energy saving, create comfortable human lives, working environment.
Specific implementation mode
In order to make the content of the present invention more clearly understood, below according to specific embodiments of the present invention, to this
Invention is described in further detail.
Embodiment 1
A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating, raw material include following components by weight：Second
It is 80 parts of alkene-acetate emulsion, 10 parts of propylene acetic acid latex, 8 parts of hollow ceramic microspheres, 3 parts of nano far infrared ceramic powder, hollow
3 parts of glass microballoon, 5 parts of bentonite, 20 parts of calcium carbonate, 10 parts of quartz sand, 8 parts of titanium dioxide, 2 parts of water-reducing agent, increases 5 parts of silicate
Mould 3 parts of agent, 1 part of emulsifier, 0.5 part of antifoaming agent, 0.2 part of levelling agent, 1 part of antifreezing agent, 0.2 part of mould inhibitor, 0.8 part of dispersant.
The hollow glass microbead is the hollow beads of 50 μm of grain size.
The calcium carbonate is powdered whiting.
The titanium dioxide is rutile type titanium white, and grain size is 100 μm.
The water-reducing agent is polycarboxylic-acid.
The antifoaming agent is modified polyether ester.
The antifreezing agent is ethylene glycol.
Embodiment 2
A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating, raw material include following components by weight：Second
120 parts of alkene-acetate emulsion, 30 parts of propylene acetic acid latex, 12 parts of hollow ceramic microspheres, 6 parts of nano far infrared ceramic powder,
6 parts of hollow glass microbead, 20 parts of silicate, 20 parts of bentonite, 30 parts of calcium carbonate, 15 parts of quartz sand, 12 parts of titanium dioxide, water-reducing agent
3 parts, 6 parts of plasticizer, 3 parts of emulsifier, 0.8 part of antifoaming agent, 0.5 part of levelling agent, 3 parts of antifreezing agent, 0.5 part of mould inhibitor, dispersant
1.5 part.
The hollow glass microbead is the hollow beads of 150 μm of grain size.
The calcium carbonate is powdered whiting.
The titanium dioxide is rutile type titanium white, and grain size is 150 μm.
The water-reducing agent is polycarboxylic-acid.
The antifoaming agent is modified polyether ester.
The antifreezing agent is ethylene glycol.
Embodiment 3
A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating, raw material include following components by weight：Second
100 parts of alkene-acetate emulsion, 20 parts of propylene acetic acid latex, 10 parts of hollow ceramic microspheres, 5 parts of nano far infrared ceramic powder,
5 parts of hollow glass microbead, 12 parts of silicate, 12 parts of bentonite, 25 parts of calcium carbonate, 12 parts of quartz sand, 10 parts of titanium dioxide, water-reducing agent
2.5 parts, 5 parts of plasticizer, 2 parts of emulsifier, 0.6 part of antifoaming agent, 0.3 part of levelling agent, 2 parts of antifreezing agent, 0.3 part of mould inhibitor, dispersion
1.2 parts of agent.
The hollow glass microbead is the hollow beads of 58 μm of grain size.
The calcium carbonate is powdered whiting.
The titanium dioxide is rutile type titanium white, and grain size is 110 μm.
The water-reducing agent is polycarboxylic-acid.
The antifoaming agent is modified polyether ester.
The antifreezing agent is ethylene glycol.
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, every to utilize this hair
Equivalent structure or equivalent flow shift made by bright description is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (7)
1. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating, which is characterized in that its raw material wraps by weight
Include following components：80-120 parts of ethene-vinyl acetate lotion, 10-30 parts of propylene acetic acid latex, 8-12 parts of hollow ceramic microspheres,
3-6 parts of nano far infrared ceramic powder, 3-6 parts of hollow glass microbead, 5-20 parts of silicate, 5-20 parts of bentonite, calcium carbonate 20-30
Part, 10-15 parts of quartz sand, 8-12 parts of titanium dioxide, 2-3 parts of water-reducing agent, 3-6 parts of plasticizer, 1-3 parts of emulsifier, antifoaming agent 0.5-
0.8 part, 0.2-0.5 parts of levelling agent, 1-3 parts of antifreezing agent, 0.2-0.5 parts of mould inhibitor, 0.8-1.5 parts of dispersant.
2. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating according to claim 1, feature
It is, the hollow glass microbead is the hollow beads of 50~150 μm of grain size.
3. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating according to claim 1, feature exist
In the calcium carbonate is powdered whiting.
4. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating according to claim 1, feature
It is, the titanium dioxide is rutile type titanium white, and grain size is 100~150 μm.
5. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating according to claim 1, feature exist
In the water-reducing agent is polycarboxylic-acid.
6. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating according to claim 1, feature exist
In the antifoaming agent is modified polyether ester.
7. a kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating according to claim 1, feature exist
In the antifreezing agent is ethylene glycol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810345439.6A CN108467632A (en) | 2018-04-17 | 2018-04-17 | A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810345439.6A CN108467632A (en) | 2018-04-17 | 2018-04-17 | A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating |
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| CN108467632A true CN108467632A (en) | 2018-08-31 |
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| CN201810345439.6A Pending CN108467632A (en) | 2018-04-17 | 2018-04-17 | A kind of acrylic acid modified ethene-vinyl acetate building waterproof heat-insulating coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113321975A (en) * | 2021-06-11 | 2021-08-31 | 天津涂天下装饰材料有限公司 | Liquid antifouling layer and preparation method thereof |
| CN114656842A (en) * | 2022-04-27 | 2022-06-24 | 广东家实多集团有限公司 | Bridge waterproof coating |
-
2018
- 2018-04-17 CN CN201810345439.6A patent/CN108467632A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113321975A (en) * | 2021-06-11 | 2021-08-31 | 天津涂天下装饰材料有限公司 | Liquid antifouling layer and preparation method thereof |
| CN114656842A (en) * | 2022-04-27 | 2022-06-24 | 广东家实多集团有限公司 | Bridge waterproof coating |
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Application publication date: 20180831 |
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