CN109054630A - A kind of insulating moulding coating for glass - Google Patents

A kind of insulating moulding coating for glass Download PDF

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Publication number
CN109054630A
CN109054630A CN201810909124.XA CN201810909124A CN109054630A CN 109054630 A CN109054630 A CN 109054630A CN 201810909124 A CN201810909124 A CN 201810909124A CN 109054630 A CN109054630 A CN 109054630A
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CN
China
Prior art keywords
parts
glass
agent
insulating moulding
moulding coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810909124.XA
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Chinese (zh)
Inventor
徐靖
徐再
陆磊
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Five Lakes New Material Technology Development Corp Ltd Of Zhangjagang City
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Five Lakes New Material Technology Development Corp Ltd Of Zhangjagang City
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Priority to CN201810909124.XA priority Critical patent/CN109054630A/en
Publication of CN109054630A publication Critical patent/CN109054630A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04Polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of insulating moulding coatings for glass, it is formed according to parts by weight are as follows: 50~80 parts of organic siliconresin, 50~80 parts of silicon dioxide gel, 20~50 parts of silicone acrylic emulsion, 1~5 part of hollow glass micropearl, 5~15 parts of composition silicate, 2~5 parts of titanium dioxide, 2~6 parts of powdered whiting, 3~8 parts of titanium dioxide, 1~3 part of curing agent, 0.5~1.5 part of dispersing agent, 0.5~1.5 part of thickener, 0.3~0.8 part of defoaming agent, 0.2~0.6 part of levelling agent, 1~3 part of coalescing agent, 15~25 parts of deionized water.Insulating moulding coating in the present invention has preferable heat-proof quality, and light transmittance is high, has broad application prospects in the use aspect of building glass or vehicle glass.

Description

A kind of insulating moulding coating for glass
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of insulating moulding coating for glass.
Background technique
The aggravation of World Environment fuel factor, energy-saving and emission-reduction are the universal problems faceds of world architecture industry.Saving In Buildings Can, it is exactly that building is reduced for the energy consumption of heating and cooling under the conditions of guaranteeing that indoor temperature is comfortable.Glass is used extensively Make building glass window, glass door, glass curtain wall, motor-vehicle glass window etc., the heat radiation of sunlight heats interior through glass. People are that can effectively prevent heat transfer in recent years, the temperature of surface covering and internal environment are reduced, to reach reduction energy consumption Purpose.Studies have shown that the heat transfer coefficient of simple glass is 3.2 times of wall, it is 5 times of roof.Further, since simple glass The transparency, allow light directly from the side of glass reach the other side so that the space of glass inner side is by sun The irradiation of light and heat up.It can be seen that the heat insulation and preservation effect for improving windowpane is the important link in building energy-saving emission reduction.
For this reason, it is necessary to be able to solve the prior art in view of the above-mentioned problems, propose a kind of insulating moulding coating for glass The problem of.
Summary of the invention
The purpose of the present invention is to provide a kind of insulating moulding coatings for glass, to overcome deficiency in the prior art.
To achieve the above object, the invention provides the following technical scheme:
A kind of insulating moulding coating for glass, forms according to parts by weight are as follows: 50~80 parts of organic siliconresin, silica is molten 50~80 parts of glue, 20~50 parts of silicone acrylic emulsion, 1~5 part of hollow glass micropearl, 5~15 parts of composition silicate, titanium dioxide 2~5 Part, 2~6 parts of powdered whiting, 3~8 parts of titanium dioxide, 1~3 part of curing agent, 0.5~1.5 part of dispersing agent, thickener 0.5~ 1.5 parts, 0.3~0.8 part of defoaming agent, 0.2~0.6 part of levelling agent, 1~3 part of coalescing agent, 15~25 parts of deionized water.
Preferably, it is formed according to parts by weight are as follows: 60~80 parts of organic siliconresin, 60~80 parts of silicon dioxide gel, silicon third 30~50 parts of lotion, 2.5~5 parts of hollow glass micropearl, 8~15 parts of composition silicate, 3~5 parts of titanium dioxide, powdered whiting 3.5~6 parts, 4.5~8 parts of titanium dioxide, 1.5~3 parts of curing agent, 0.8~1.5 part of dispersing agent, 0.8~1.5 part of thickener, disappear 0.5~0.8 part of infusion, 0.35~0.6 part of levelling agent, 1.8~3 parts of coalescing agent, 18~25 parts of deionized water.
Preferably, it is formed according to parts by weight are as follows: 70~80 parts of organic siliconresin, 70~80 parts of silicon dioxide gel, silicon third 40~50 parts of lotion, 4~5 parts of hollow glass micropearl, 12~15 parts of composition silicate, 4~5 parts of titanium dioxide, powdered whiting 5 ~6 parts, 6~8 parts of titanium dioxide, 2.2~3 parts of curing agent, 1.1~1.5 parts of dispersing agent, 1.2~1.5 parts of thickener, defoaming agent 0.6~0.8 part, 0.5~0.6 part of levelling agent, 2.5~3 parts of coalescing agent, 22~25 parts of deionized water.
Preferably, the organic siliconresin is selected from poly- alkyl organic resin.
Preferably, the composition silicate is the compound of calcium silicates and magnesium silicate.
Preferably, the weight ratio of the calcium silicates and liter water magnesium silicate is 1:1.5.
Preferably, the dispersing agent is sodium tripolyphosphate or calgon.
Preferably, the thickener is sodium carboxymethylcellulose or lauryl sodium sulfate.
Compared with the prior art, the advantages of the present invention are as follows: the insulating moulding coating in the present invention has preferable thermal insulation property, And light transmittance is high, has broad application prospects in the use aspect of building glass or vehicle glass.
Specific embodiment
The present invention is described further by the following example: according to following embodiments, the present invention may be better understood. However, as it will be easily appreciated by one skilled in the art that specific material ratio, process conditions and its result described in embodiment are only used In illustrating the present invention, without the present invention described in detail in claims should will not be limited.
The present invention discloses a kind of insulating moulding coating for glass, forms according to parts by weight are as follows: and 50~80 parts of organic siliconresin, 50~80 parts of silicon dioxide gel, 20~50 parts of silicone acrylic emulsion, 1~5 part of hollow glass micropearl, 5~15 parts of composition silicate, two 2~5 parts of titanium oxide, 2~6 parts of powdered whiting, 3~8 parts of titanium dioxide, 1~3 part of curing agent, 0.5~1.5 part of dispersing agent, increase Thick dose 0.5~1.5 part, 0.3~0.8 part of defoaming agent, 0.2~0.6 part of levelling agent, 1~3 part of coalescing agent, deionized water 15~ 25 parts.
Wherein, the organic siliconresin is selected from poly- alkyl organic resin;The composition silicate is calcium silicates and silicic acid The compound of magnesium, further, the calcium silicates and the weight ratio for rising water magnesium silicate are 1:1.5;The dispersing agent is trimerization Sodium phosphate or calgon;The thickener is sodium carboxymethylcellulose or lauryl sodium sulfate.
Following insulating moulding coatings for glass being illustrated with specifically embodiment in the present invention.
Embodiment 1
It is formed according to parts by weight are as follows: 50 parts of organic siliconresin, 50 parts of silicon dioxide gel, 20 parts of silicone acrylic emulsion, hollow glass 1 part of glass microballon, 5 parts of composition silicate, 2 parts of titanium dioxide, 2 parts of powdered whiting, 3 parts of titanium dioxide, 1 part of curing agent, dispersion 0.5 part of agent, 0.5 part of thickener, 0.3 part of defoaming agent, 0.2 part of levelling agent, 1 part of coalescing agent, 15 parts of deionized water.
Embodiment 2
It is formed according to parts by weight are as follows: 60 parts of organic siliconresin, 60 parts of silicon dioxide gel, 30 parts of silicone acrylic emulsion, hollow glass 2.5 parts of glass microballon, 8 parts of composition silicate, 3 parts of titanium dioxide, 3.5 parts of powdered whiting, 4.5 parts of titanium dioxide, curing agent 1.5 Part, 0.8 part of dispersing agent, 0.8 part of thickener, 0.5 part of defoaming agent, 0.35 part of levelling agent, 1.8 parts of coalescing agent, deionized water 18 Part.
Embodiment 3
It is formed according to parts by weight are as follows: 70 parts of organic siliconresin, 70 parts of silicon dioxide gel, 40 parts of silicone acrylic emulsion, hollow glass 4 parts of glass microballon, 12 parts of composition silicate, 4 parts of titanium dioxide, 5 parts of powdered whiting, 6 parts of titanium dioxide, 2.2 parts of curing agent, point 1.1 parts of powder, 1.2 parts of thickener, 0.6 part of defoaming agent, 0.5 part of levelling agent, 2.5 parts of coalescing agent, 22 parts of deionized water.
Embodiment 4
It is formed according to parts by weight are as follows: 80 parts of organic siliconresin, 80 parts of silicon dioxide gel, 50 parts of silicone acrylic emulsion, hollow glass 5 parts of glass microballon, 15 parts of composition silicate, 5 parts of titanium dioxide, 6 parts of powdered whiting, 8 parts of titanium dioxide, 3 parts of curing agent, dispersion 1.5 parts of agent, 1.5 parts of thickener, 0.8 part of defoaming agent, 0.6 part of levelling agent, 3 parts of coalescing agent, 25 parts of deionized water.
Applying coating will be obtained in above-described embodiment 1~4 carries out heat resistance experiment in vehicle glass surface, the results showed that, For the applying coating that formula according to the above embodiments obtains behind vehicle glass surface, internal-external temperature difference can reach 8~10 DEG C, Therefore there is preferable heat-proof quality, have broad application prospects in the use aspect of building glass or vehicle glass.
Finally, it is to be noted that, the terms "include", "comprise" or its any other variant be intended to it is non-exclusive Property include so that include a series of elements process, method, article or equipment not only include those elements, but also Further include other elements that are not explicitly listed, or further include for this process, method, article or equipment it is intrinsic Element.

Claims (8)

1. a kind of insulating moulding coating for glass, which is characterized in that formed according to parts by weight are as follows: 50~80 parts of organic siliconresin, 50~80 parts of silicon dioxide gel, 20~50 parts of silicone acrylic emulsion, 1~5 part of hollow glass micropearl, 5~15 parts of composition silicate, two 2~5 parts of titanium oxide, 2~6 parts of powdered whiting, 3~8 parts of titanium dioxide, 1~3 part of curing agent, 0.5~1.5 part of dispersing agent, increase Thick dose 0.5~1.5 part, 0.3~0.8 part of defoaming agent, 0.2~0.6 part of levelling agent, 1~3 part of coalescing agent, deionized water 15~ 25 parts.
2. the insulating moulding coating according to claim 1 for glass, which is characterized in that formed according to parts by weight are as follows: organic It is 60~80 parts of silicone resin, 60~80 parts of silicon dioxide gel, 30~50 parts of silicone acrylic emulsion, 2.5~5 parts of hollow glass micropearl, multiple 8~15 parts of silicate of conjunction, 3~5 parts of titanium dioxide, 3.5~6 parts of powdered whiting, 4.5~8 parts of titanium dioxide, curing agent 1.5 ~3 parts, 0.8~1.5 part of dispersing agent, 0.8~1.5 part of thickener, 0.5~0.8 part of defoaming agent, 0.35~0.6 part of levelling agent, at 1.8~3 parts of film auxiliary agent, 18~25 parts of deionized water.
3. the insulating moulding coating according to claim 2 for glass, which is characterized in that formed according to parts by weight are as follows: organic It is 70~80 parts of silicone resin, 70~80 parts of silicon dioxide gel, 40~50 parts of silicone acrylic emulsion, 4~5 parts of hollow glass micropearl, compound 12~15 parts of silicate, 4~5 parts of titanium dioxide, 5~6 parts of powdered whiting, 6~8 parts of titanium dioxide, 2.2~3 parts of curing agent, 1.1~1.5 parts of dispersing agent, 1.2~1.5 parts of thickener, 0.6~0.8 part of defoaming agent, 0.5~0.6 part of levelling agent, coalescing agent 2.5~3 parts, 22~25 parts of deionized water.
4. the insulating moulding coating according to claim 1 for glass, which is characterized in that the organic siliconresin is selected from poly- alkane Base organic siliconresin.
5. the insulating moulding coating according to claim 1 for glass, which is characterized in that the composition silicate is calcium silicates With the compound of magnesium silicate.
6. the insulating moulding coating according to claim 5 for glass, which is characterized in that the calcium silicates and liter water magnesium silicate Weight ratio be 1:1.5.
7. the insulating moulding coating according to claim 1 for glass, which is characterized in that the dispersing agent is sodium tripolyphosphate Or calgon.
8. the insulating moulding coating according to claim 1 for glass, which is characterized in that the thickener is carboxymethyl cellulose Plain sodium or lauryl sodium sulfate.
CN201810909124.XA 2018-08-10 2018-08-10 A kind of insulating moulding coating for glass Withdrawn CN109054630A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112029411A (en) * 2020-08-04 2020-12-04 珠海展辰新材料股份有限公司 Fireproof water-based inorganic coating and preparation method and application thereof
CN112175422A (en) * 2020-08-25 2021-01-05 浙江巨化技术中心有限公司 Coating composition for automobile glass
CN115637084A (en) * 2021-07-20 2023-01-24 山东鲁阳节能材料股份有限公司 Temperature-resistant heat-insulating coating for metal surface

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002105385A (en) * 2000-09-28 2002-04-10 Nisshin Sangyo:Kk Application type thermally insulative material
CN101531851A (en) * 2009-04-14 2009-09-16 湖北中科博策新材料研究院 Nano water-borne heat-insulating transparent coating and preparation method thereof
CN101531854A (en) * 2009-04-13 2009-09-16 江门市威其五金化工实业有限公司 Nanometer glass heat-insulating film and manufacturing method thereof
CN102086329A (en) * 2009-12-07 2011-06-08 杨卓卫 Transparent glass thermal-insulation and heat-preservation coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002105385A (en) * 2000-09-28 2002-04-10 Nisshin Sangyo:Kk Application type thermally insulative material
CN101531854A (en) * 2009-04-13 2009-09-16 江门市威其五金化工实业有限公司 Nanometer glass heat-insulating film and manufacturing method thereof
CN101531851A (en) * 2009-04-14 2009-09-16 湖北中科博策新材料研究院 Nano water-borne heat-insulating transparent coating and preparation method thereof
CN102086329A (en) * 2009-12-07 2011-06-08 杨卓卫 Transparent glass thermal-insulation and heat-preservation coating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112029411A (en) * 2020-08-04 2020-12-04 珠海展辰新材料股份有限公司 Fireproof water-based inorganic coating and preparation method and application thereof
CN112175422A (en) * 2020-08-25 2021-01-05 浙江巨化技术中心有限公司 Coating composition for automobile glass
CN112175422B (en) * 2020-08-25 2021-10-22 浙江巨化技术中心有限公司 Coating composition for automobile glass
CN115637084A (en) * 2021-07-20 2023-01-24 山东鲁阳节能材料股份有限公司 Temperature-resistant heat-insulating coating for metal surface

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