CN107674524A - A kind of heat insulating coatings and preparation method thereof - Google Patents

A kind of heat insulating coatings and preparation method thereof Download PDF

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Publication number
CN107674524A
CN107674524A CN201711045763.8A CN201711045763A CN107674524A CN 107674524 A CN107674524 A CN 107674524A CN 201711045763 A CN201711045763 A CN 201711045763A CN 107674524 A CN107674524 A CN 107674524A
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parts
heat insulating
insulating coatings
indium
graphite
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CN201711045763.8A
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Chinese (zh)
Inventor
崔大宏
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Guangxi Environmental Protection Technology Co Ltd Is Located
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Guangxi Environmental Protection Technology Co Ltd Is Located
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Priority to CN201711045763.8A priority Critical patent/CN107674524A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2231Oxides; Hydroxides of metals of tin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of heat insulating coatings and preparation method thereof.A kind of heat insulating coatings, including following parts by weight of component:350 450 parts of cross-linking type acrylic acid emulsion, 80 120 parts of hollow ceramic microballon, 60 110 parts of indium-tin oxide powder, 100 200 parts of titanium dioxide, 20 50 parts of aerosil, 10 25 parts, 1 15 parts of graphite, 3 15 parts of manganese sesquioxide managnic oxide, 13 parts of hydroxyethyl cellulose, 5 20 parts of Sodium Polyacrylate, 10 20 parts of ammoniacal liquor, 80 120 parts of soft water, 1~10 part of acrylic resin.Heat insulating coatings of the present invention can be coated on various base materials, have each side advantages such as heat-insulation and heat-preservation, fire prevention, waterproof, anticracking, noise control.The cooling of the metal surfaces such as application and Petroleum Storage Tank pipeline suitable for exterior wall, roof, interior wall etc., reduce water drenching etc..

Description

A kind of heat insulating coatings and preparation method thereof
Technical field
The invention belongs to new energy and environmental protection and energy saving technical field, more particularly to a kind of heat insulating coatings and its preparation side Method.
Background technology
Building energy conservation occupies main positions in being saved in the whole nation, and the material such as the polyphenyl class that uses at present, extrusion molding class passes through patch Dress is thermally shielded insulation to building with construction technologies such as parcels, although these materials can also play thermal insulation function, The shortcomings of easy firing, pollution environment, complicated construction technique, short service life be present in these materials.Therefore, need to develop in industry The building coating low to solar radiative absorption rate can be reduced and be coated on body surface, surface caused by reduce due to shining upon Temperature raises, and reaches the effect of hot light reflective insulation energy conservation.
The content of the invention
In view of the problems of prior art, the present invention provides heat insulating coatings and preparation method thereof, has enhancing Reflecting properties of the exterior wall to sunlight heat, reduce the absorption that exterior wall radiates to sunlight heat, so as to reduce building Table temperature, the advantages of having reached heat-insulating and energy-saving.
The technical scheme that the present invention solves above-mentioned technical problem is as follows:A kind of heat insulating coatings, including following parts by weight Component:Cross-linking type acrylic acid emulsion 100-200 parts, hollow ceramic microballon 25-60 parts, indium-tin oxide powder 15-30 parts, titanium dioxide 50-100 parts, aerosil 5-15 parts, graphite 3-10 parts, manganese sesquioxide managnic oxide 1-5 parts, hydroxyethyl cellulose 1-3 parts, gather PAA 10-30 parts, ammoniacal liquor 20-40 parts, soft water 30-80 parts, 1~5 part of acrylic resin.
On the basis of above-mentioned technical proposal, the present invention can also do following improvement.
Further, the heat insulating coatings, including following parts by weight of component:100 parts of cross-linking type acrylic acid emulsions, 25 Part hollow ceramic microballon, 15 parts of indium-tin oxide powders, 50 parts of titanium dioxides, 5 parts of aerosils, 3 parts of graphite, 1 part of three oxidation Two manganese, 1 part of hydroxyethyl cellulose, 10 parts of Sodium Polyacrylates, 20 parts of ammoniacal liquor, 30 parts of soft water, 1 part of acrylic resin.
Further, the heat insulating coatings include following parts by weight of component:200 parts of cross-linking type acrylic acid emulsions, 60 Part hollow ceramic microballon, 30 parts of indium-tin oxide powders, 100 parts of titanium dioxides, 15 parts of aerosils, 10 parts of graphite, 5 part of three oxygen Change two manganese, 3 parts of hydroxyethyl celluloses, 30 parts of Sodium Polyacrylates, 40 parts of ammoniacal liquor, 80 parts of soft water, 5 parts of acrylic resins.
Further, the heat insulating coatings include following parts by weight of component:150 parts of cross-linking type acrylic acid emulsions, 40 Part hollow ceramic microballon, 20 parts of indium-tin oxide powders, 75 parts of titanium dioxides, 10 parts of aerosils, 7 parts of graphite, 3 part of three oxidation Two manganese, 2 parts of hydroxyethyl celluloses, 20 parts of Sodium Polyacrylates, 30 parts of ammoniacal liquor, 60 parts of soft water, 3 parts of acrylic resins.
Present invention also offers a kind of preparation method of heat insulating coatings, comprise the following steps:Weigh following parts by weight Component:Cross-linking type acrylic acid emulsion 100-200 parts, hollow ceramic microballon 25-60 parts, indium-tin oxide powder 15-30 parts, titanium dioxide 50-100 parts, aerosil 5-15 parts, graphite 3-10 parts, manganese sesquioxide managnic oxide 1-5 parts, hydroxyethyl cellulose 1-3 parts, gather PAA 10-30 parts, ammoniacal liquor 20-40 parts, soft water 30-80 parts, 1~5 part of acrylic resin, then it is well mixed, in 1000- Under 1200 revs/min of rotating speed, disperse 5-10min at a high speed.
Embodiment
The principles and features of the present invention are described below, and the given examples are served only to explain the present invention, is not intended to limit Determine the scope of the present invention.
The invention provides a kind of heat insulating coatings, including following parts by weight of component:Cross-linking type acrylic acid emulsion 100- 200 parts, hollow ceramic microballon 25-60 parts, indium-tin oxide powder 15-30 parts, titanium dioxide 50-100 parts, aerosil 5-15 Part, graphite 3-10 parts, manganese sesquioxide managnic oxide 1-5 parts, hydroxyethyl cellulose 1-3 parts, Sodium Polyacrylate 10-30 parts, ammoniacal liquor 20-40 Part, soft water 30-80 parts, 1~5 part of acrylic resin.
Inventor has carried out the screening experiment of substantial amounts of component and dosage early stage, is found surprisingly that, technology of the invention Scheme is by reasonably matching and the combination of each component, due to adding hollow ceramic microballon powder, is formed in coating a lot Microcosmic independent heat insultating cavity, the microballon has reflection, acted on scattering solar energy, while far infrared reflects adding for amylaceous substance Enter, have again and absorb too heat energy, the function of then all reflecting away, the heat effect of infrared ray can be shielded, greatly improve painting The temperature tolerance of layer, good fireproofing function is played, there is obvious heat-insulated, insulation, noise reduction after dried coating film.With it is traditional Insulating mold coating system compares, and reaches effect, and construction is very convenient.
It is introduced below by specific embodiment.
Embodiment 1
A kind of heat insulating coatings, including following parts by weight of component:100 parts of cross-linking type acrylic acid emulsions, 25 parts of hollow potteries Porcelain microballon, 15 parts of indium-tin oxide powders, 50 parts of titanium dioxides, 5 parts of aerosils, 3 parts of graphite, 1 part of manganese sesquioxide managnic oxide, 1 part Hydroxyethyl cellulose, 10 parts of Sodium Polyacrylates, 20 parts of ammoniacal liquor, 30 parts of soft water, 1 part of acrylic resin.
Embodiment 2
A kind of heat insulating coatings, including following parts by weight of component:200 parts of cross-linking type acrylic acid emulsions, 60 parts of hollow potteries Porcelain microballon, 30 parts of indium-tin oxide powders, 100 parts of titanium dioxides, 15 parts of aerosils, 10 parts of graphite, 5 parts of manganese sesquioxide managnic oxides, 3 Part 30 parts of Sodium Polyacrylates of hydroxyethyl cellulose, 40 parts of ammoniacal liquor, 80 parts of soft water, 5 parts of acrylic resins.
Embodiment 3
A kind of heat insulating coatings, including following parts by weight of component:150 parts of cross-linking type acrylic acid emulsions, 40 parts of hollow potteries Porcelain microballon, 20 parts of indium-tin oxide powders, 75 parts of titanium dioxides, 10 parts of aerosils, 7 parts of graphite, 3 parts of manganese sesquioxide managnic oxides, 2 parts Hydroxyethyl cellulose, 20 parts of Sodium Polyacrylates, 30 parts of ammoniacal liquor, 60 parts of soft water, 3 parts of acrylic resins.
Comparative example 1
Without addition hollow ceramic microballon, ammoniacal liquor, aerosil and acrylic resin in this comparative example, itself and group Divide and proportioning is identical with the technical scheme in embodiment one.
Measure of merit
The performance for determining above-described embodiment and the heat insulating coatings of comparative example preparation respectively carries out technology for detection:
Test result is as shown in table 1.
Table 1
Data in table 1, which can be seen that technical ability coating provided by the invention, has more preferable sun luminous reflectivity With heat-proof quality temperature difference, the coating so provided has superior heat-insulated, insulation, anti-acoustic capability.
Additionally, due to hollow ceramic microballon powder is added in the heat insulating coatings, its thermal conductivity factor is 0.043w/ M.k, many microcosmic independent heat insultating cavities being formed in coating, the microballon has reflection, acted on scattering solar energy, while far The addition of infrared reflection amylaceous substance, have again and absorb too heat energy, the function of then all reflecting away, infrared ray can be shielded Heat effect, greatly improve the temperature tolerance of coating, play good fireproofing function, and its chemical natural instincts, surface have anti-chemistry Corrosion, particle close-packed arrays in coating, plays good antisepsis again.Have after dried coating film obvious heat-insulated, insulation, Noise reduction.Compared with traditional insulating mold coating system, reach effect, construction is very convenient.With excellent elasticity, rise To crack resistence, water-proof function.With anticorrosion, fire-proof function.With excellent adhesive force, mould proof, anti-algae, service life length, Environmental protection, green product.
Present invention also offers a kind of preparation method of heat insulating coatings to comprise the following steps:Weigh following parts by weight Component:100 parts of cross-linking type acrylic acid emulsions, 25 parts of hollow ceramic microballons, 15 parts of indium-tin oxide powders, 50 parts of titanium dioxides, 5 parts of dioxies SiClx aeroge, 3 parts of graphite, 1 part of manganese sesquioxide managnic oxide, 1 part of hydroxyethyl cellulose, 10 parts of Sodium Polyacrylates, 20 parts of ammoniacal liquor, 30 parts Soft water, 1 part of acrylic resin, is then well mixed, and under 1000-1200 revs/min of rotating speed, disperses 5-10min at a high speed.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the invention, it is all the present invention spirit and Within principle, any modification, equivalent substitution and improvements made etc., it should be included in the scope of the protection.

Claims (5)

1. a kind of heat insulating coatings, it is characterised in that including following parts by weight of component:Cross-linking type acrylic acid emulsion 100-200 Part, hollow ceramic microballon 25-60 parts, indium-tin oxide powder 15-30 parts, titanium dioxide 50-100 parts, aerosil 5-15 parts, Graphite 3-10 parts, manganese sesquioxide managnic oxide 1-5 parts, hydroxyethyl cellulose 1-3 parts, Sodium Polyacrylate 10-30 parts, ammoniacal liquor 20-40 parts are soft Water 30-80 parts, 1~5 part of acrylic resin.
2. a kind of heat insulating coatings according to claim 1, it is characterised in that including following parts by weight of component:100 parts of friendships Connection type acrylic emulsion, 25 parts of hollow ceramic microballons, 15 parts of indium-tin oxide powders, 50 parts of titanium dioxides, 5 parts of aerosils, 3 Part graphite, 1 part of manganese sesquioxide managnic oxide, 1 part of hydroxyethyl cellulose, 10 parts of Sodium Polyacrylates, 20 parts of ammoniacal liquor, 30 parts of soft water, 1 part of propylene Acid resin.
3. a kind of heat insulating coatings according to claim 1, it is characterised in that including following parts by weight of component:200 parts of friendships Connection type acrylic emulsion, 60 parts of hollow ceramic microballons, 30 parts of indium-tin oxide powders, 100 parts of titanium dioxides, 15 parts of silica airsettings Glue, 10 parts of graphite, 5 parts of manganese sesquioxide managnic oxides, 3 parts of hydroxyethyl celluloses, 30 parts of Sodium Polyacrylates, 40 parts of ammoniacal liquor, 80 parts of soft water, 5 parts Acrylic resin.
4. a kind of heat insulating coatings according to claim 1, it is characterised in that including following parts by weight of component:150 parts of friendships Connection type acrylic emulsion, 40 parts of hollow ceramic microballons, 20 parts of indium-tin oxide powders, 75 parts of titanium dioxides, 10 parts of aerosils, 7 parts of graphite, 3 parts of manganese sesquioxide managnic oxides, 2 parts of hydroxyethyl celluloses, 20 parts of Sodium Polyacrylates, 30 parts of ammoniacal liquor, 60 parts of soft water, 3 part third Olefin(e) acid resin.
5. a kind of preparation method of heat insulating coatings, it is characterised in that comprise the following steps:Weigh the group of following parts by weight Point:Cross-linking type acrylic acid emulsion 100-200 parts, hollow ceramic microballon 25-60 parts, indium-tin oxide powder 15-30 parts, titanium dioxide 50- 100 parts, aerosil 5-15 parts, graphite 3-10 parts, manganese sesquioxide managnic oxide 1-5 parts, hydroxyethyl cellulose 1-3 parts, poly- third Olefin(e) acid sodium 10-30 parts, ammoniacal liquor 20-40 parts, soft water 30-80 parts, 1~5 part of acrylic resin, are then well mixed, in 1000- Under 1200 revs/min of rotating speed, disperse 5-10mi n at a high speed.
CN201711045763.8A 2017-10-31 2017-10-31 A kind of heat insulating coatings and preparation method thereof Pending CN107674524A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675726A (en) * 2018-07-24 2018-10-19 芜湖市棠华建材科技有限公司 A kind of waterproof insulation material and preparation method thereof
CN108864782A (en) * 2018-07-24 2018-11-23 芜湖市棠华建材科技有限公司 A kind of waterproof reflective insulation material and preparation method thereof
CN112094547A (en) * 2019-08-21 2020-12-18 合肥微晶材料科技有限公司 Far infrared reflection coating and flexible electrothermal film based on same and having single-side far infrared radiation function
CN113431370A (en) * 2021-07-02 2021-09-24 江苏省纺织产品质量监督检验研究院 Heat-insulation constant-humidity low-carbon storage transformation system for textiles

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725124A (en) * 2013-08-02 2014-04-16 太仓派欧技术咨询服务有限公司 High-radiation heat-insulated coating

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103725124A (en) * 2013-08-02 2014-04-16 太仓派欧技术咨询服务有限公司 High-radiation heat-insulated coating

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108675726A (en) * 2018-07-24 2018-10-19 芜湖市棠华建材科技有限公司 A kind of waterproof insulation material and preparation method thereof
CN108864782A (en) * 2018-07-24 2018-11-23 芜湖市棠华建材科技有限公司 A kind of waterproof reflective insulation material and preparation method thereof
CN112094547A (en) * 2019-08-21 2020-12-18 合肥微晶材料科技有限公司 Far infrared reflection coating and flexible electrothermal film based on same and having single-side far infrared radiation function
CN113431370A (en) * 2021-07-02 2021-09-24 江苏省纺织产品质量监督检验研究院 Heat-insulation constant-humidity low-carbon storage transformation system for textiles

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Application publication date: 20180209