CN105506956B - A kind of thermal insulation coat agent of decorative substrate - Google Patents

A kind of thermal insulation coat agent of decorative substrate Download PDF

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Publication number
CN105506956B
CN105506956B CN201610103068.1A CN201610103068A CN105506956B CN 105506956 B CN105506956 B CN 105506956B CN 201610103068 A CN201610103068 A CN 201610103068A CN 105506956 B CN105506956 B CN 105506956B
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parts
thermal insulation
agent
coating
decorative substrate
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CN105506956A (en
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倪海霞
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Sichuan hengzeng assembly construction technology Co., Ltd
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Sichuan Heng Zeng Building Materials Co Ltd
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
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    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D06M13/2246—Esters of unsaturated carboxylic acids
    • D—TEXTILES; PAPER
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256—Sulfonated compounds esters thereof, e.g. sultones
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
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    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/402—Amides imides, sulfamic acids
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/17—Natural resins, resinous alcohols, resinous acids, or derivatives thereof
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
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    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
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    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of thermal insulation coat agent of decorative substrate, include the component of following parts by weight：The matrix lotion of ethylene-vinyl acetate copolymer resins composition, three (2,3 dibromopropyl) fulminuric acid esters, association type aqueous polyurethane emulsion, polyacrylate dispersion, aerosil, sulfosuccinate, sulfosuccinamide, silicon-nitrogen compound, block copolymer-modified dose of ethylene oxide/propylene oxide, wood fiber powder, Aluminate.Coating agent is continuously applied in the form of foams to flat flexible parent metal, it is dried by the coating of application by infrared radiation device and/or using hot-air at a temperature of higher than 80 DEG C, cold blocking is carried out to the coating later, the preparation method overcomes the shortcomings that existing thermal insulation decorative paint coatings, provides a kind of thermal-insulation, pollution-free, good decorative property elastic thin layer thermal insulation coat finishing technique.

Description

A kind of thermal insulation coat agent of decorative substrate
Technical field
The present invention relates to a kind of thermal insulation coat agent of decorative substrate.
Background technology
The material for being used as insulation at present is broadly divided into two kinds：Low thermal conductivity light material, heat reflection material Material.Low thermal conductivity light material relies primarily on the structure of material itself and chemical property achievees the purpose that heat-insulated, main material Have：Porous light-weight material, hollow (or filling gas) material of closed pore, specialty fibers class material etc..Heat-reflecting material then relies on it Can reflection wavelength achieve the purpose that in the electromagnetic wave of infrared region it is heat-insulated, main material be some high IR heat reflectivities Metal, alloy and compound, such as ferroso-ferric oxide, metallic nickel, aluminium foil, titanium dioxide etc..
At present applied to chemical engineering industry field, especially high temperature storage tank, the heat-insulation and heat-preservation material of the pump housing, pipeline outer heat insulation Material is essentially all to wind tank body, additional galvanized iron sheet or aluminium-foil paper cladding with mineral wool class, mineral wool class.This material Only function of heat insulation does not have anti-corrosion and waterproof function, the equipment for being unfavorable for southern wet area and being imbedded in underground； And these materials on skin have very big irritation, easy incoming call respiratory tract, material to contain carcinogen, cause construction and later stage Maintenance difficulties are big；This material category highly energy-consuming trade is produced simultaneously, has been used at present by limitation in most cities.Therefore Find a kind of energy conservation and environmental protection, the heat insulating material of service life length has very important significance.
Invention content
The technical problem to be solved by the present invention is to overcome existing thermal insulation decorative paint coatings, one kind is provided Thermal-insulation, pollution-free, good decorative property elastic thin layer thermal insulation coat agent.
To achieve the goals above, the present invention adopts the following technical scheme that：A kind of thermal insulation coat of decorative substrate Agent includes the component of following parts by weight：
100 parts of the matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 10-23 parts of (2,3- dibromopropyl) fulminuric acid esters,
1-3 parts of association type aqueous polyurethane emulsion,
5-10 parts of polyacrylate dispersion,
2-4 parts of aerosil,
1-1.5 parts of sulfosuccinate,
0.3-0.8 parts of sulfosuccinamide,
6-16 parts of silicon-nitrogen compound,
5-13 parts of ethylene oxide/propylene oxide block copolymer,
12-20 parts of modifying agent；
20-35 parts of wood fiber powder；
1-10 parts of Aluminate；
The modifying agent is made from the following raw materials in parts by weight：
40-45 parts of diatomite,
4-5 parts of acrylate,
2-3 parts of tri (propylene glycol) diacrylate,
5-6 parts of zinc oxide,
4-5 parts of jade,
2-3 parts of 3- aminopropyl trimethoxysilanes,
1-2 parts of crosslinking agent TAC,
1-2 parts of zinc gluconate,
1-2 parts of zinc stearate,
0.1-0.2 parts of Rosa Damascana.
Further, the solid content of the coating agent is 30-50%, viscosity 1000-5000mpas.
The invention also discloses a kind of techniques arranged using the coating agent, and coating agent is connected in the form of foams It is continuous to be applied on flat flexible parent metal, the coating of application by infrared radiation device and/or is adopted at a temperature of higher than 80 DEG C It is dried with hot-air, cold blocking is carried out to the coating later；The layer thickness of the coating is 4-6mm；Wherein with foam The form of body applies the coating agent, and by introducing air, nitrogen, CO into the coating agent2Or their mixture As gas, to form the foams
Further, the blowing ratio control is between 1: 1.2-10.
Further, the base material is selected from the hydrophilic polymer that polyester fiber, cellulose fibre or lignin fibre are constituted Object is constituted.
Coating agent of the present invention has the beneficial effect that：It is insufficient for prior art and provide a kind of collection elasticity, thin layer, every Heat, heat preservation the advantages that in one Multifunctional partition hot coating, meanwhile, decoration of the invention is removed with coating with heat preservation and insulation Outside, also there is very strong weather resistance, to ensure that coating remains to protect in the case of relatively thin (overall thickness is less than or equal to 0.6 millimeter) Hold good heat insulation property；By configuring special elastic resin lotion, make the coating of composition that there is good elasticity, and There is reflecting effect, paint film elongation percentage may be up to 370% in very a wide range of spectrum, have to cracking caused by wall stronger Self-closed performance；And surface modifying agent protection technique is used, extend the heat preservation property of coating.
Specific implementation mode
Below by embodiment, the technical solutions of the present invention will be further described.
Embodiment one：
A kind of thermal insulation coat agent of decorative substrate, includes the component of following parts by weight：
100 parts of the matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 10 parts of (2,3- dibromopropyl) fulminuric acid esters,
1 part of association type aqueous polyurethane emulsion,
5 parts of polyacrylate dispersion,
2 parts of aerosil,
1 part of sulfosuccinate,
0.3 part of sulfosuccinamide,
6 parts of silicon-nitrogen compound,
5 parts of ethylene oxide/propylene oxide block copolymer,
12 parts of modifying agent；
20 parts of wood fiber powder；
1 part of Aluminate；
The modifying agent is made from the following raw materials in parts by weight：Diatomite 40, acrylate 4, two contract Tripropylene glycol diacrylate 2, zinc oxide 5, jade 4,3- aminopropyl trimethoxysilanes 2, crosslinking agent TAC 1, gluconic acid Zinc 1, zinc stearate 1, Rosa Damascana 0.1.The solid content of the coating agent is 30-50%, viscosity 1000-5000mpas. Blowing ratio controls between 1: 1.2-10.
Coating agent is continuously applied in the form of foams to flat flexible parent metal, will be applied at a temperature of 85 DEG C Coating be dried by infrared radiation device and/or using hot-air, cold blocking is carried out to the coating later；The coating Layer thickness be 4mm；Apply the coating agent wherein in the form of foams, and empty by being introduced into the coating agent Gas, nitrogen, CO2Or their mixture is as gas, to form the foams；Base material described in the coating agent is selected from poly- The hydrophilic polymer that ester fiber and cellulose fibre are constituted is constituted.
Embodiment two：
A kind of thermal insulation coat agent of decorative substrate, includes the component of following parts by weight：
100 parts of the matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 23 parts of (2,3- dibromopropyl) fulminuric acid esters,
3 parts of association type aqueous polyurethane emulsion,
10 parts of polyacrylate dispersion,
4 parts of aerosil,
1.5 parts of sulfosuccinate,
0.8 part of sulfosuccinamide,
16 parts of silicon-nitrogen compound,
13 parts of ethylene oxide/propylene oxide block copolymer,
20 parts of modifying agent；
35 parts of wood fiber powder；
10 parts of Aluminate；
The modifying agent is made from the following raw materials in parts by weight：Diatomite 45, acrylate 5, two contract Tripropylene glycol diacrylate 3, zinc oxide 6, jade 5,3- aminopropyl trimethoxysilanes 3, crosslinking agent TAC 2, gluconic acid Zinc 2, zinc stearate 2, Rosa Damascana 0.2.The solid content of the coating agent is 30-50%, viscosity 1000-5000mpas. Blowing ratio controls between 1: 1.2-10.
Coating agent is continuously applied in the form of foams to flat flexible parent metal, will be applied at a temperature of 98 DEG C Coating be dried by infrared radiation device and/or using hot-air, cold blocking is carried out to the coating later；The coating Layer thickness be 6mm；Apply the coating agent wherein in the form of foams, and empty by being introduced into the coating agent Gas, nitrogen, CO2Or their mixture is as gas, to form the foams；The base material is selected from polyester fiber and wood The hydrophilic polymer that quality fiber is constituted is constituted.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those skilled in the art within the technical scope disclosed by the invention, can without the variation that creative work is expected or It replaces, should be covered by the protection scope of the present invention.Therefore, protection scope of the present invention should be limited with claims Subject to fixed protection domain.

Claims (1)

1. a kind of thermal insulation coat agent of decorative substrate, it is characterised in that：Include the component of following parts by weight：
100 parts of the matrix lotion of ethene-vinyl acetate copolymer resins composition,
Three 10-23 parts of (2,3- dibromopropyl) fulminuric acid esters,
1-3 parts of association type aqueous polyurethane emulsion,
5-10 parts of polyacrylate dispersion,
2-4 parts of aerosil,
1-1.5 parts of sulfosuccinate,
0.3-0.8 parts of sulfosuccinamide,
6-16 parts of silicon-nitrogen compound,
5-13 parts of ethylene oxide/propylene oxide block copolymer,
12-20 parts of modifying agent；
20-35 parts of wood fiber powder；
1-10 parts of Aluminate；
The modifying agent is made from the following raw materials in parts by weight：
40-45 parts of diatomite,
4-5 parts of acrylate,
2-3 parts of tri (propylene glycol) diacrylate,
5-6 parts of zinc oxide,
4-5 parts of jade,
2-3 parts of 3- aminopropyl trimethoxysilanes,
1-2 parts of crosslinking agent TAC,
1-2 parts of zinc gluconate,
1-2 parts of zinc stearate,
0.1-0.2 parts of Rosa Damascana；
The solid content of the coating agent is 30-50%, viscosity 1000-5000mpas.
CN201610103068.1A 2016-02-25 2016-02-25 A kind of thermal insulation coat agent of decorative substrate Active CN105506956B (en)

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