CN107956120A - 一种抗菌棉织物的制备方法 - Google Patents

一种抗菌棉织物的制备方法 Download PDF

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CN107956120A
CN107956120A CN201711312168.6A CN201711312168A CN107956120A CN 107956120 A CN107956120 A CN 107956120A CN 201711312168 A CN201711312168 A CN 201711312168A CN 107956120 A CN107956120 A CN 107956120A
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缪百君
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Shaoxing Boke Information Technology Consulting Co Ltd
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    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
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    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
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Abstract

本发明涉及一种抗菌棉织物的制备方法,a、配置抗菌整理液,抗菌整理剂15‑20g/L,阳离子有机硅柔软剂3‑5g/L,余量为水;b、面料轧液,面料浸渍整理液中,一浸一轧,轧液率80‑100%;c、烘干,面料经150℃、45‑60s烘干,即得抗菌面料,即得抗菌面料。本发明采用季铵盐抗菌单体在改性后的纳米二氧化钛离子表面接枝的方法,增强了纳米二氧化钛的稳定分散,提高了纳米抗菌材料的稳定性及有机抗菌剂的耐热性,有效提升了抗菌剂的耐久性。

Description

一种抗菌棉织物的制备方法
技术领域
本发明涉及一种抗菌棉织物的制备方法,属于功能纺织品加工领域
背景技术
随着社会的发展、科技的进步、人们生活质量的不断提高和居住环境的改善,人们对全棉纺织产品的要求也越来越高。我国加入WTO后,也只有高技术含量和高附加值的产品才能更好的参与国际市场的竞争。人们对自身的保健及对纺织品的安全性和功能性的要求也日益增加,特别是具有持久性、安全性、抗菌防臭性好的全棉制品越来越引起人们的重视,它以健康的理念广泛的应用于医院、宾馆、家庭等场所。
发明内容
针对现有抗菌剂的不足,本发明所要解决的技术问题是提供一种抗菌棉织物的制备方法,提高棉织物抗菌的长效性和有效性。
为实现上述目的,本发明采用的技术方案为:
一种抗菌棉织物的制备方法,
a、配置抗菌整理液
抗菌整理剂15-20g/L,阳离子有机硅柔软剂3-5g/L,余量为水;
b、面料轧液
面料浸渍整理液中,一浸一轧,轧液率80-100%;
c、烘干
面料经150℃、45-60s烘干,即得抗菌面料;
所述的抗菌整理剂的制备方法,各组分以质量份计,包括以下步骤:
步骤一 将8份十二烷基二甲基氯化铵、6份烯丙基聚氧乙烯醚APEG-700、14份二甲基二烯丙基氯化铵、41份丙烯酸丁酯、12份甲基丙烯酸甲酯、6份苯乙烯、5份丙烯酸和152份去离子水加入乳化釜中,搅拌30min,成乳化液;
步骤二 向反应釜中加入8份表面改性纳米二氧化钛、1/3体积步骤一的乳化液,升温至75℃,加入0.2份过硫酸铵,保温反应30min;
步骤三 2小时内滴加剩余乳化液、0.6份过硫酸铵与20份去离水的水溶液及5份甲基丙烯酰氧基丙基三乙氧基硅烷,滴加完毕,将反应釜温度升至85℃,保温1h;
步骤四 将反应釜温度降至45~50℃,过200目筛,得抗菌整理剂。
所述表面改性纳米二氧化钛的制备方法为:
将15份纳米二氧化钛粒子加入到120份乙醇中溶解,超声分散15分钟,加入20份乙醇与2份硅烷偶联剂KH-570的混合液,加热至70℃,恒温反应3小时,经洗涤、过滤后干燥,研磨成粉体状改性纳米二氧化钛。
本发明采用季铵盐抗菌单体在改性后的纳米二氧化钛离子表面接枝的方法,增强了纳米二氧化钛的稳定分散,提高了纳米抗菌材料的稳定性及有机抗菌剂的耐热性,有效提升了抗菌剂的耐久性。
具体实施方法:
下列实施方案,仅是举例说明,不是仅有的,所以,一切在本发明范围内或是做与本发明相似的改变均包含于本发明之内。
实施例1
抗菌整理剂的制备方法,各组分以质量份计,包括以下步骤:
步骤一 将8份十二烷基二甲基氯化铵、6份烯丙基聚氧乙烯醚APEG-700、14份二甲基二烯丙基氯化铵、41份丙烯酸丁酯、12份甲基丙烯酸甲酯、6份苯乙烯、5份丙烯酸和152份去离子水加入乳化釜中,搅拌30min,成乳化液;
步骤二 向反应釜中加入8份表面改性纳米二氧化钛、1/3体积步骤一的乳化液,升温至75℃,加入0.2份过硫酸铵,保温反应30min;
步骤三 2小时内滴加剩余乳化液、0.6份过硫酸铵与20份去离水的水溶液及5份甲基丙烯酰氧基丙基三乙氧基硅烷,滴加完毕,将反应釜温度升至85℃,保温1h;
步骤四 将反应釜温度降至45~50℃,过200目筛,得抗菌整理剂。
所述表面改性纳米二氧化钛的制备方法为:
将15份纳米二氧化钛粒子加入到120份乙醇中溶解,超声分散15分钟,加入20份乙醇与2份硅烷偶联剂KH-570的混合液,加热至70℃,恒温反应3小时,经洗涤、过滤后干燥,研磨成粉体状改性纳米二氧化钛。
实施例2
一种抗菌棉织物的制备方法,
a、配置抗菌整理液
抗菌整理剂15-20g/L,阳离子有机硅柔软剂3-5g/L,余量为水;
b、面料轧液
面料浸渍整理液中,一浸一轧,轧液率80-100%;
c、烘干
面料经150℃、45-60s烘干,即得抗菌面料。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。

Claims (2)

1.一种抗菌棉织物的制备方法,
a、配置抗菌整理液
抗菌整理剂15-20g/L,
阳离子有机硅柔软剂3-5g/L,余量为水;
b、面料轧液
面料浸渍整理液中,一浸一轧,轧液率80-100%;
c、烘干
面料经150℃、45-60s烘干,即得抗菌面料;
所述的抗菌整理剂的制备方法,各组分以质量份计,包括以下步骤:
步骤一 将8份十二烷基二甲基氯化铵、6份烯丙基聚氧乙烯醚APEG-700、14份二甲基二烯丙基氯化铵、41份丙烯酸丁酯、12份甲基丙烯酸甲酯、6份苯乙烯、5份丙烯酸和152份去离子水加入乳化釜中,搅拌30min,成乳化液;
步骤二 向反应釜中加入8份表面改性纳米二氧化钛、1/3体积步骤一的乳化液,升温至75℃,加入0.2份过硫酸铵,保温反应30min;
步骤三 2小时内滴加剩余乳化液、0.6份过硫酸铵与20份去离水的水溶液及5份甲基丙烯酰氧基丙基三乙氧基硅烷,滴加完毕,将反应釜温度升至85℃,保温1h;
步骤四 将反应釜温度降至45~50℃,过200目筛,得抗菌整理剂。
2.如权利要求1所述的一种抗菌棉织物的制备方法,其特征在于:
所述表面改性纳米二氧化钛的制备方法为:
将15份纳米二氧化钛粒子加入到120份乙醇中溶解,超声分散15分钟,加入20份乙醇与2份硅烷偶联剂KH-570的混合液,加热至70℃,恒温反应3小时,经洗涤、过滤后干燥,研磨成粉体状改性纳米二氧化钛。
CN201711312168.6A 2017-11-27 2017-11-27 一种抗菌棉织物的制备方法 Pending CN107956120A (zh)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109610167A (zh) * 2018-12-19 2019-04-12 东莞亿达服装科技有限公司 一种柔软爽滑的梭织面料及其在高端女装中的应用
CN111648134A (zh) * 2020-07-20 2020-09-11 刘开江 抗静电面料及其制备方法
CN111979773A (zh) * 2020-09-07 2020-11-24 刘开江 抗静电面料及其制备方法
CN115612269A (zh) * 2022-11-04 2023-01-17 江西省萍乡市轩品塑胶制品有限公司 一种生物降解耐热吸管母粒及其制备方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109610167A (zh) * 2018-12-19 2019-04-12 东莞亿达服装科技有限公司 一种柔软爽滑的梭织面料及其在高端女装中的应用
CN109610167B (zh) * 2018-12-19 2021-06-29 东莞亿达服装科技有限公司 一种柔软爽滑的梭织面料及其在高端女装中的应用
CN111648134A (zh) * 2020-07-20 2020-09-11 刘开江 抗静电面料及其制备方法
CN111979773A (zh) * 2020-09-07 2020-11-24 刘开江 抗静电面料及其制备方法
CN111979773B (zh) * 2020-09-07 2022-11-22 江苏广昊纺织科技有限公司 抗静电面料及其制备方法
CN115612269A (zh) * 2022-11-04 2023-01-17 江西省萍乡市轩品塑胶制品有限公司 一种生物降解耐热吸管母粒及其制备方法

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