CN107956120A - 一种抗菌棉织物的制备方法 - Google Patents
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- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 28
- 239000004744 fabric Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims abstract description 15
- 229920000742 Cotton Polymers 0.000 title claims abstract description 12
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 230000003115 biocidal effect Effects 0.000 claims abstract description 6
- 239000004902 Softening Agent Substances 0.000 claims abstract description 4
- 125000002091 cationic group Chemical group 0.000 claims abstract description 4
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- 238000005096 rolling process Methods 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 15
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 9
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical class COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- PGQAXGHQYGXVDC-UHFFFAOYSA-N dodecyl(dimethyl)azanium;chloride Chemical class Cl.CCCCCCCCCCCCN(C)C PGQAXGHQYGXVDC-UHFFFAOYSA-N 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 3
- BTERVQLEXBFOIO-UHFFFAOYSA-N C(C)O[SiH](OCC)OCC.C(C=C)(=O)OCCC[SiH2]OCC Chemical compound C(C)O[SiH](OCC)OCC.C(C=C)(=O)OCCC[SiH2]OCC BTERVQLEXBFOIO-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- MLGWTHRHHANFCC-UHFFFAOYSA-N prop-2-en-1-amine;hydrochloride Chemical compound Cl.NCC=C MLGWTHRHHANFCC-UHFFFAOYSA-N 0.000 claims 1
- 238000010792 warming Methods 0.000 claims 1
- 239000003242 anti bacterial agent Substances 0.000 abstract description 4
- 230000004048 modification Effects 0.000 abstract description 4
- 238000012986 modification Methods 0.000 abstract description 4
- 230000002421 anti-septic effect Effects 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- 229940088710 antibiotic agent Drugs 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000000178 monomer Substances 0.000 abstract description 2
- -1 nano-titanium dioxide ion Chemical class 0.000 abstract description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 abstract description 2
- 238000005516 engineering process Methods 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- XDQWJFXZTAWJST-UHFFFAOYSA-N 3-triethoxysilylpropyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C=C XDQWJFXZTAWJST-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- PZNOBXVHZYGUEX-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine;hydrochloride Chemical compound Cl.C=CCNCC=C PZNOBXVHZYGUEX-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
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Abstract
本发明涉及一种抗菌棉织物的制备方法，a、配置抗菌整理液，抗菌整理剂15‑20g/L，阳离子有机硅柔软剂3‑5g/L，余量为水；b、面料轧液，面料浸渍整理液中，一浸一轧，轧液率80‑100％；c、烘干，面料经150℃、45‑60s烘干，即得抗菌面料，即得抗菌面料。本发明采用季铵盐抗菌单体在改性后的纳米二氧化钛离子表面接枝的方法，增强了纳米二氧化钛的稳定分散，提高了纳米抗菌材料的稳定性及有机抗菌剂的耐热性，有效提升了抗菌剂的耐久性。
Description
技术领域
本发明涉及一种抗菌棉织物的制备方法，属于功能纺织品加工领域
背景技术
随着社会的发展、科技的进步、人们生活质量的不断提高和居住环境的改善，人们对全棉纺织产品的要求也越来越高。我国加入WTO后，也只有高技术含量和高附加值的产品才能更好的参与国际市场的竞争。人们对自身的保健及对纺织品的安全性和功能性的要求也日益增加，特别是具有持久性、安全性、抗菌防臭性好的全棉制品越来越引起人们的重视，它以健康的理念广泛的应用于医院、宾馆、家庭等场所。
发明内容
针对现有抗菌剂的不足，本发明所要解决的技术问题是提供一种抗菌棉织物的制备方法，提高棉织物抗菌的长效性和有效性。
为实现上述目的，本发明采用的技术方案为：
一种抗菌棉织物的制备方法，
a、配置抗菌整理液
抗菌整理剂15-20g/L，阳离子有机硅柔软剂3-5g/L，余量为水；
b、面料轧液
面料浸渍整理液中，一浸一轧，轧液率80-100％；
c、烘干
面料经150℃、45-60s烘干，即得抗菌面料；
所述的抗菌整理剂的制备方法，各组分以质量份计，包括以下步骤：
步骤一 将8份十二烷基二甲基氯化铵、6份烯丙基聚氧乙烯醚APEG-700、14份二甲基二烯丙基氯化铵、41份丙烯酸丁酯、12份甲基丙烯酸甲酯、6份苯乙烯、5份丙烯酸和152份去离子水加入乳化釜中，搅拌30min，成乳化液；
步骤二 向反应釜中加入8份表面改性纳米二氧化钛、1/3体积步骤一的乳化液，升温至75℃，加入0.2份过硫酸铵，保温反应30min；
步骤三 2小时内滴加剩余乳化液、0.6份过硫酸铵与20份去离水的水溶液及5份甲基丙烯酰氧基丙基三乙氧基硅烷，滴加完毕，将反应釜温度升至85℃，保温1h；
步骤四 将反应釜温度降至45～50℃，过200目筛，得抗菌整理剂。
所述表面改性纳米二氧化钛的制备方法为：
将15份纳米二氧化钛粒子加入到120份乙醇中溶解，超声分散15分钟，加入20份乙醇与2份硅烷偶联剂KH-570的混合液，加热至70℃，恒温反应3小时，经洗涤、过滤后干燥，研磨成粉体状改性纳米二氧化钛。
本发明采用季铵盐抗菌单体在改性后的纳米二氧化钛离子表面接枝的方法，增强了纳米二氧化钛的稳定分散，提高了纳米抗菌材料的稳定性及有机抗菌剂的耐热性，有效提升了抗菌剂的耐久性。
具体实施方法：
下列实施方案，仅是举例说明，不是仅有的，所以，一切在本发明范围内或是做与本发明相似的改变均包含于本发明之内。
实施例1
抗菌整理剂的制备方法，各组分以质量份计，包括以下步骤：
步骤一 将8份十二烷基二甲基氯化铵、6份烯丙基聚氧乙烯醚APEG-700、14份二甲基二烯丙基氯化铵、41份丙烯酸丁酯、12份甲基丙烯酸甲酯、6份苯乙烯、5份丙烯酸和152份去离子水加入乳化釜中，搅拌30min，成乳化液；
步骤二 向反应釜中加入8份表面改性纳米二氧化钛、1/3体积步骤一的乳化液，升温至75℃，加入0.2份过硫酸铵，保温反应30min；
步骤三 2小时内滴加剩余乳化液、0.6份过硫酸铵与20份去离水的水溶液及5份甲基丙烯酰氧基丙基三乙氧基硅烷，滴加完毕，将反应釜温度升至85℃，保温1h；
步骤四 将反应釜温度降至45～50℃，过200目筛，得抗菌整理剂。
所述表面改性纳米二氧化钛的制备方法为：
将15份纳米二氧化钛粒子加入到120份乙醇中溶解，超声分散15分钟，加入20份乙醇与2份硅烷偶联剂KH-570的混合液，加热至70℃，恒温反应3小时，经洗涤、过滤后干燥，研磨成粉体状改性纳米二氧化钛。
实施例2
一种抗菌棉织物的制备方法，
a、配置抗菌整理液
抗菌整理剂15-20g/L，阳离子有机硅柔软剂3-5g/L，余量为水；
b、面料轧液
面料浸渍整理液中，一浸一轧，轧液率80-100％；
c、烘干
面料经150℃、45-60s烘干，即得抗菌面料。
尽管已经示出和描述了本发明的实施例，对于本领域的普通技术人员而言，可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型，本发明的范围由所附权利要求及其等同物限定。
Claims (2)
1.一种抗菌棉织物的制备方法，
a、配置抗菌整理液
抗菌整理剂15-20g/L，
阳离子有机硅柔软剂3-5g/L，余量为水；
b、面料轧液
面料浸渍整理液中，一浸一轧，轧液率80-100％；
c、烘干
面料经150℃、45-60s烘干，即得抗菌面料；
所述的抗菌整理剂的制备方法，各组分以质量份计，包括以下步骤：
步骤一 将8份十二烷基二甲基氯化铵、6份烯丙基聚氧乙烯醚APEG-700、14份二甲基二烯丙基氯化铵、41份丙烯酸丁酯、12份甲基丙烯酸甲酯、6份苯乙烯、5份丙烯酸和152份去离子水加入乳化釜中，搅拌30min，成乳化液；
步骤二 向反应釜中加入8份表面改性纳米二氧化钛、1/3体积步骤一的乳化液，升温至75℃，加入0.2份过硫酸铵，保温反应30min；
步骤三 2小时内滴加剩余乳化液、0.6份过硫酸铵与20份去离水的水溶液及5份甲基丙烯酰氧基丙基三乙氧基硅烷，滴加完毕，将反应釜温度升至85℃，保温1h；
步骤四 将反应釜温度降至45～50℃，过200目筛，得抗菌整理剂。
2.如权利要求1所述的一种抗菌棉织物的制备方法，其特征在于：
所述表面改性纳米二氧化钛的制备方法为：
将15份纳米二氧化钛粒子加入到120份乙醇中溶解，超声分散15分钟，加入20份乙醇与2份硅烷偶联剂KH-570的混合液，加热至70℃，恒温反应3小时，经洗涤、过滤后干燥，研磨成粉体状改性纳米二氧化钛。
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109610167A (zh) * | 2018-12-19 | 2019-04-12 | 东莞亿达服装科技有限公司 | 一种柔软爽滑的梭织面料及其在高端女装中的应用 |
| CN111648134A (zh) * | 2020-07-20 | 2020-09-11 | 刘开江 | 抗静电面料及其制备方法 |
| CN111979773A (zh) * | 2020-09-07 | 2020-11-24 | 刘开江 | 抗静电面料及其制备方法 |
| CN115612269A (zh) * | 2022-11-04 | 2023-01-17 | 江西省萍乡市轩品塑胶制品有限公司 | 一种生物降解耐热吸管母粒及其制备方法 |
-
2017
- 2017-11-27 CN CN201711312168.6A patent/CN107956120A/zh active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109610167A (zh) * | 2018-12-19 | 2019-04-12 | 东莞亿达服装科技有限公司 | 一种柔软爽滑的梭织面料及其在高端女装中的应用 |
| CN109610167B (zh) * | 2018-12-19 | 2021-06-29 | 东莞亿达服装科技有限公司 | 一种柔软爽滑的梭织面料及其在高端女装中的应用 |
| CN111648134A (zh) * | 2020-07-20 | 2020-09-11 | 刘开江 | 抗静电面料及其制备方法 |
| CN111979773A (zh) * | 2020-09-07 | 2020-11-24 | 刘开江 | 抗静电面料及其制备方法 |
| CN111979773B (zh) * | 2020-09-07 | 2022-11-22 | 江苏广昊纺织科技有限公司 | 抗静电面料及其制备方法 |
| CN115612269A (zh) * | 2022-11-04 | 2023-01-17 | 江西省萍乡市轩品塑胶制品有限公司 | 一种生物降解耐热吸管母粒及其制备方法 |
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