CN107513857A - 羊毛面料的抗起球整理工艺 - Google Patents

羊毛面料的抗起球整理工艺 Download PDF

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CN107513857A
CN107513857A CN201710784050.7A CN201710784050A CN107513857A CN 107513857 A CN107513857 A CN 107513857A CN 201710784050 A CN201710784050 A CN 201710784050A CN 107513857 A CN107513857 A CN 107513857A
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wool fabric
wool
solution
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dressing liquid
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赵雪琴
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TAICANG YUNYUN CHEMICAL FIBER Co Ltd
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TAICANG YUNYUN CHEMICAL FIBER Co Ltd
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Abstract

本发明公开了一种羊毛面料的抗起球整理工艺，包括步骤：前处理；酶整理；缩绒；放缩抗起球一浴法；清洗；烘干；浸轧；将浸轧过的羊毛面料进行烘干、轧光、定型整理。本发明通过在缩绒工艺之前添加酶整理工序，先通过氧化剂二硫键转变为磺酸基，破坏羊毛纤维表面类脂层的连续分布，增加羊毛纤维表面的亲水性，再用蛋白酶处理，可进一步增加羊毛表面鳞片的去除效果，保证后续的放缩抗皱一浴工艺的效果。

Description

羊毛面料的抗起球整理工艺
技术领域
本发明涉及一种面料的抗起球整理工艺，尤其是一种羊毛面料的抗起球整理工艺。
背景技术
羊毛纺织品以其良好的保暖性能以及柔软、蓬松、丰满的特性，深受消费者喜爱。但是，羊毛纤维表面有特殊结构的鳞片层。在日常着装中，由于外力的摩擦作用，鳞片层产生定向移动，发生毡缩现象，对人体有刺痒感。因此，羊毛织物必须通过整理加工，以达到国际羊毛局规定的机可洗标准，同时后整理加工能极大地改善羊毛纺织品的手感(如柔软、平滑等)，从而提高其服用性能和产品附加值。长期以来，国内的毛衫后整理企业大都是采用含氯氧化剂对羊毛纤维进行改性，其效果好，能使羊毛织物达到良好的防毡缩效果，并可为后续的柔软整理创造出有利的表面特性。但是，含氯氧化剂在毛衫后整理加工过程中，会产生大量的AOX(可吸附的有机卤化物)，严重污染环境，对人体造成伤害；工艺相对复杂，操作流程长，能源消耗大，而且会给羊毛纺织品带来严重的泛黄现象。
为解决上述问题，提供一种面料柔软又环保的整理方法是目前需要攻克的难题之一。
发明内容
发明目的：本发明的目的是克服现有技术的不足，提供羊毛面料的抗起球整理工艺。
技术方案：为了解决上述技术问题，本发明所述的一种羊毛面料的抗起球整理工艺，包括步骤：
(1)前处理：采用精梳纱织造羊毛面料，对羊毛面料进行清洗、烘干前处理；
(2)酶整理：将前处理后的羊毛面料浸入整理液中，浸入整理液的先后顺序为：第一步：在浓度为40ml/L，温度为50℃的双氧水中浸40-50min；第二步：将浸过双氧水的羊毛面料浸入含壳聚糖2g/L的溶液中整理1.5-2h，溶液温度为40℃；第三步：将浸入过壳聚糖溶液的羊毛面料浸入含有蛋白酶3％(owf)的溶液中，浴比：1∶30，溶液温度60℃，浸渍时间为35-38min；
(3)缩绒：将经过酶整理的羊毛面料放入超声波清洗仪的缩绒整理液内，开启超声波发生器，超声波频率50kHz，所述缩绒整理液中含：缩绒剂20910-12g/L，缩绒时间15-18min，缩绒温度为25-30℃，pH值为6.5～7.0，通过醋酸调节溶液PH值。
(4)放缩抗起球一浴法：将缩绒后的羊毛面料浸入整理液中，所述整理液包含无氯整理剂5-8g/L，复合蛋白酶B2-2.5g/L，防缩剂3-5g/L，水性聚氨酯5-6g/L，有机硅树脂6-8g/L，浴比为1∶30，处理温度为50℃，处理时间为45-55min；
(5)清洗：将经过防缩抗起球整理的羊毛面料在流动清水中冲洗10-15min；
(6)烘干：将清洗后的羊毛面料放入烘干机中进行烘干处理，烘干温度为85-90℃，机车速为10-13m/min；
(7)浸轧：将烘干后的羊毛面料放入浸轧工作液中通过轧车进行一浸一轧处理，浸轧工作液的温度25-30℃，pH为5.6-6.2，一浸一轧时轧车的转速为10-13r/min，轧余率85-90％，所述浸轧工作液包含以下重量：
抗菌剂：0.8-2.2/L；
渗透剂JFC：1.5-2.5g/L；
活性炭：0.5-1g/L；
柠檬酸：0.6-0.8g/L；
甘油一硬脂酸酯：1.3-1.8g/L；
醇醚磷酸盐：1.5-1.8g/L；
(8)将浸轧过的羊毛面料进行烘干、轧光、定型整理。
所述的抗菌剂为纳米氧化银。
所述的防缩剂为防缩剂DM-3501。
所述的无氯整理剂为2D树脂。
有益效果：本发明与现有技术相比，本发明的优点在于：
1.本发明通过在缩绒工艺之前添加酶整理工序，先通过氧化剂二硫键转变为磺酸基，破坏羊毛纤维表面类脂层的连续分布，增加羊毛纤维表面的亲水性，再用蛋白酶处理，可进一步增加羊毛表面鳞片的去除效果，保证后续的放缩抗皱一浴工艺的效果。
2.本发明通过将放缩抗皱合成一浴法，可有效提高羊毛面料的加工效率。
3.本发明添加的浸轧工序，可进一步保证羊毛面料的柔软性，溶液中添加的活性炭可有效去除羊毛固有的气味，提高穿着舒适性。
具体实施方式
下面结合实施例对本发明作进一步的详细说明，应理解这些实施例仅用于说明本发明而不用于限制本发明的范围。
实施例1：
一种羊毛面料的抗起球整理工艺，包括步骤：
(1)前处理：采用精梳纱织造羊毛面料，对羊毛面料进行清洗、烘干前处理；
(2)酶整理：将前处理后的羊毛面料浸入整理液中，浸入整理液的先后顺序为：第一步：在浓度为40ml/L，温度为50℃的双氧水中浸40min；第二步：将浸过双氧水的羊毛面料浸入含壳聚糖2g/L的溶液中整理1.5h，溶液温度为40℃；第三步：将浸入过壳聚糖溶液的羊毛面料浸入含有蛋白酶3％(owf)的溶液中，浴比：1∶30，溶液温度60℃，浸渍时间为38min；
(3)缩绒：将经过酶整理的羊毛面料放入超声波清洗仪的缩绒整理液内，开启超声波发生器，超声波频率50kHz，所述缩绒整理液中含：缩绒剂20910g/L，缩绒时间15min，缩绒温度为25℃，pH值为6.5，通过醋酸调节溶液PH值。
(4)放缩抗起球一浴法：将缩绒后的羊毛面料浸入整理液中，所述整理液包含2D树脂5g/L，复合蛋白酶B 2g/L，防缩剂DM-35013g/L，水性聚氨酯5g/L，有机硅树脂6g/L，浴比为1∶30，处理温度为50℃，处理时间为45min；
(5)清洗：将经过防缩抗起球整理的羊毛面料在流动清水中冲洗10min；
(6)烘干：将清洗后的羊毛面料放入烘干机中进行烘干处理，烘干温度为85℃，机车速为10m/min；
(7)浸轧：将烘干后的羊毛面料放入浸轧工作液中通过轧车进行一浸一轧处理，浸轧工作液的温度25℃，pH为5.6，一浸一轧时轧车的转速为10r/min，轧余率85％，所述浸轧工作液包含以下重量：
纳米氧化银：0.8/L；
渗透剂JFC：1.5g/L；
活性炭：0.5g/L；
柠檬酸：0.6g/L；
甘油一硬脂酸酯：1.3g/L；
醇醚磷酸盐：1.5g/L；
(8)将浸轧过的羊毛面料进行烘干、轧光、定型整理。
实施例2：
一种羊毛面料的抗起球整理工艺，包括步骤：
(1)前处理：采用精梳纱织造羊毛面料，对羊毛面料进行清洗、烘干前处理；
(2)酶整理：将前处理后的羊毛面料浸入整理液中，浸入整理液的先后顺序为：第一步：在浓度为40ml/L，温度为50℃的双氧水中浸44min；第二步：将浸过双氧水的羊毛面料浸入含壳聚糖2eg/L的溶液中整理1.8h，溶液温度为40℃；第三步：将浸入过壳聚糖溶液的羊毛面料浸入含有蛋白酶3％(owf)的溶液中，浴比：1∶30，溶液温度60℃，浸渍时间为37min；
(3)缩绒：将经过酶整理的羊毛面料放入超声波清洗仪的缩绒整理液内，开启超声波发生器，超声波频率50kHz，所述缩绒整理液中含：缩绒剂20911g/L，缩绒时间16min，缩绒温度为28℃，pH值为6.7，通过醋酸调节溶液PH值。
(4)放缩抗起球一浴法：将缩绒后的羊毛面料浸入整理液中，所述整理液包含2D树脂5.8g/L，复合蛋白酶B 2.3g/L，防缩剂DM-35014g/L，水性聚氨酯5.5g/L，有机硅树脂7.2g/L，浴比为1∶30，处理温度为50℃，处理时间为52min；
(5)清洗：将经过防缩抗起球整理的羊毛面料在流动清水中冲洗15min；
(6)烘干：将清洗后的羊毛面料放入烘干机中进行烘干处理，烘干温度为88℃，机车速为10m/min；
(7)浸轧：将烘干后的羊毛面料放入浸轧工作液中通过轧车进行一浸一轧处理，浸轧工作液的温度28℃，pH为6.1，一浸一轧时轧车的转速为12r/min，轧余率87％，所述浸轧工作液包含以下重量：
纳米氧化银：1.8/L；
渗透剂JFC：2.2g/L；
活性炭：0.8g/L；
柠檬酸：0.7g/L；
甘油一硬脂酸酯：1.5g/L；
醇醚磷酸盐：1.6g/L；
(8)将浸轧过的羊毛面料进行烘干、轧光、定型整理。
实施例3
一种羊毛面料的抗起球整理工艺，包括步骤：
(1)前处理：采用精梳纱织造羊毛面料，对羊毛面料进行清洗、烘干前处理；
(2)酶整理：将前处理后的羊毛面料浸入整理液中，浸入整理液的先后顺序为：第一步：在浓度为40ml/L，温度为50℃的双氧水中浸50min；第二步：将浸过双氧水的羊毛面料浸入含壳聚糖2g/L的溶液中整理2h，溶液温度为40℃；第三步：将浸入过壳聚糖溶液的羊毛面料浸入含有蛋白酶3％(owf)的溶液中，浴比：1∶30，溶液温度60℃，浸渍时间为38min；
(3)缩绒：将经过酶整理的羊毛面料放入超声波清洗仪的缩绒整理液内，开启超声波发生器，超声波频率50kHz，所述缩绒整理液中含：缩绒剂20912g/L，缩绒时间15-18min，缩绒温度为30℃，pH值为7.0，通过醋酸调节溶液PH值。
(4)放缩抗起球一浴法：将缩绒后的羊毛面料浸入整理液中，所述整理液包含2D树脂8g/L，复合蛋白酶B 2.5g/L，防缩剂DM-35015g/L，水性聚氨酯6g/L，有机硅树脂8g/L，浴比为1∶30，处理温度为50℃，处理时间为55min；
(5)清洗：将经过防缩抗起球整理的羊毛面料在流动清水中冲洗15min；
(6)烘干：将清洗后的羊毛面料放入烘干机中进行烘干处理，烘干温度为90℃，机车速为13m/min；
(7)浸轧：将烘干后的羊毛面料放入浸轧工作液中通过轧车进行一浸一轧处理，浸轧工作液的温度30℃，pH为6.2，一浸一轧时轧车的转速为13r/min，轧余率90％，所述浸轧工作液包含以下重量：
纳米氧化银：2.2/L；
渗透剂JFC：2.5g/L；
活性炭：1g/L；
柠檬酸：0.8g/L；
甘油一硬脂酸酯：1.8g/L；
醇醚磷酸盐：1.8g/L；
(8)将浸轧过的羊毛面料进行烘干、轧光、定型整理。

Claims (4)

1.一种羊毛面料的抗起球整理工艺，其特征在于：包括步骤：
(1)前处理：采用精梳纱织造羊毛面料，对羊毛面料进行清洗、烘干前处理；
(2)酶整理：将前处理后的羊毛面料浸入整理液中，浸入整理液的先后顺序为：第一步：在浓度为40ml/L，温度为50℃的双氧水中浸40-50min；第二步：将浸过双氧水的羊毛面料浸入含壳聚糖2g/L的溶液中整理1.5-2h，溶液温度为40℃；第三步：将浸入过壳聚糖溶液的羊毛面料浸入含有蛋白酶3％(owf)的溶液中，浴比：1：30，溶液温度60℃，浸渍时间为35-38min；
(3)缩绒：将经过酶整理的羊毛面料放入超声波清洗仪的缩绒整理液内，开启超声波发生器，超声波频率50kHz，所述缩绒整理液中含：缩绒剂20910-12g/L，缩绒时间15-18min，缩绒温度为25-30℃，pH值为6.5～7.0，通过醋酸调节溶液PH值。
(4)放缩抗起球一浴法：将缩绒后的羊毛面料浸入整理液中，所述整理液包含无氯整理剂5-8g/L，复合蛋白酶B 2-2.5g/L，防缩剂3-5g/L，水性聚氨酯5-6g/L，有机硅树脂6-8g/L，浴比为1∶30，处理温度为50℃，处理时间为45-55min；
(5)清洗：将经过防缩抗起球整理的羊毛面料在流动清水中冲洗10-15min；
(6)烘干：将清洗后的羊毛面料放入烘干机中进行烘干处理，烘干温度为85-90℃，机车速为10-13m/min；
(7)浸轧：将烘干后的羊毛面料放入浸轧工作液中通过轧车进行一浸一轧处理，浸轧工作液的温度25-30℃，pH为5.6-6.2，一浸一轧时轧车的转速为10-13r/min，轧余率85-90％，所述浸轧工作液包含以下重量：
抗菌剂：0.8-2.2/L；
渗透剂JFC：1.5-2.5g/L；
活性炭：0.5-1g/L；
柠檬酸：0.6-0.8g/L；
甘油一硬脂酸酯：1.3-1.8g/L；
醇醚磷酸盐：1.5-1.8g/L；
(8)将浸轧过的羊毛面料进行烘干、轧光、定型整理。
2.根据权利要求1所述的羊毛面料的抗起球整理工艺，其特征在于：所述的抗菌剂为纳米氧化银。
3.根据权利要求1所述的羊毛面料的抗起球整理工艺，其特征在于：所述的防缩剂为防缩剂DM-3501。
4.根据权利要求1所述的羊毛面料的抗起球整理工艺，其特征在于：所述的无氯整理剂为2D树脂。
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CN108560268A (zh) * 2018-04-23 2018-09-21 嘉兴市锦福缩染有限公司 羊毛衫的缩绒工艺
CN109750530A (zh) * 2019-01-11 2019-05-14 南通金仕达超微阻燃材料有限公司 抗起球性能高的天丝型宽幅机织物的生产方法
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CN108560268B (zh) * 2018-04-23 2020-08-21 嘉兴市锦福缩染有限公司 羊毛衫的缩绒工艺
CN109750530A (zh) * 2019-01-11 2019-05-14 南通金仕达超微阻燃材料有限公司 抗起球性能高的天丝型宽幅机织物的生产方法
WO2020186950A1 (zh) * 2019-03-15 2020-09-24 江南大学 一种利用蛋白酶k对羊毛织物进行防毡缩整理的方法
CN110306348A (zh) * 2019-07-12 2019-10-08 常熟市新光毛条处理有限公司 一种毛条防缩防粘混合处理方法
CN113123137A (zh) * 2019-12-31 2021-07-16 张家港保税区宇联羊毛工业有限公司 一种羊毛条快速防缩处理方法
CN112252028A (zh) * 2020-10-16 2021-01-22 江苏阳光集团有限公司 一种纳米银抗菌抗皱西服的生产工艺
CN114108151A (zh) * 2021-12-03 2022-03-01 王文俊 一种抗静电柔顺羊毛面料及其制备方法
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