A kind of pearl toner of thickening certainly and preparation method thereof
Technical field
The present invention relates to a kind of from thickening pearl toner and preparation method thereof, belong to cosmetic field.
Background technology
At present, the common toner for having various states on the market, such as transparent lotions, milky milk water, is suspended with pearl
Mating plate or particle or petal water, upper strata be oil phase or emulsion and lower floor be aqueous phase Double-layer water.Common above-mentioned toner glues
Degree all than relatively low, change that its denseness in use will not be over time and change.Commercially available common cosmetics simultaneously
In, added hydrolyzed pearl extract as whitening composition, Yin Qiyi causes product to turn yellow, causes it to add in the product limited
System.
Patent CN106551879A provides a kind of bird's nest toner and its manufacture method, by Denatonium Benzoate, butanediol, sea
Algae sugar, propane diols, glycerine, ethanol, hydroxyethyl cellulose, dimethyl silicone polymer, potassium sorbate, sorbic acid, ethylhexyl are sweet
Oil, hyaluronic acid, PEG-8, glycerine heteroside, ascorbic acid phosphoric acid esters and solvent are placed in container, are heated to 90 DEG C simultaneously
Stirring and dissolving;42 DEG C are cooled to after insulation 15min;Add light rain birds nest extract, brewer's yeast fungus extract, hydrolyzed pearl and
Essence, stir 3-10min;Add lemon acid for adjusting pH;Defoaming is stood, is cooled to normal temperature, filling is finished product.The bird's nest toner
In contain hydrolyzed pearl extract, be a common moisturizing astringent, do not possess from thickening effect.
The content of the invention
Problems to be solved by the invention
It is an object of the invention to provide a kind of from thickening pearl toner and preparation method thereof.Certainly the thickening pearlization
Adornment water has and can slowly risen from thickening function, viscosity, while has moisturizing, whitening and anti-acne multiple effect, moisten skin,
It is soft and soft, strengthen skin barrier function.
The solution used to solve the problem
The present invention provides a kind of thickening pearl toner certainly, with described from the weight percent for thickening pearl toner gross weight
Than meter, including following components:
Film forming agent:0.01-1.0%;
Pearl:0.05-5%;
Polyalcohol:3-20%;
Skin conditioning agent:0.0001-0.005%;
Moisturizing additive:0.01-3.0%;
Acidity regulator:0.001-0.05%;
Water:71-95%.
According to the present invention from thickening pearl toner, with described from the percentage by weight for thickening pearl toner gross weight
Meter,
The addition of the film forming agent is 0.1-0.8%, preferably 0.15-0.5%;
The addition of the pearl is 0.05-4%, preferably 0.5-2.5%;
The addition of the polyalcohol is 5-18%, preferably 8-15%;
The addition of the skin conditioning agent is 0.0003-0.005%, preferably 0.0008-0.005%;
The addition of the moisturizing additive is 0.05-2.8%, preferably 0.1-2.5%;
The addition of the acidity regulator is 0.002-0.05%;Preferably 0.005-0.03%;
The addition of the water is 75-93%, preferably 80-91%.
Included according to the present invention from thickening pearl toner, the film forming agent in carragheen, gellan gum and sodium alginate
One or more kinds of combinations.
According to the present invention from thickening pearl toner, the pearl is pearl particles or pearl powder.
1,3-PD, methyl propanediol, dipropyl are included from thickening pearl toner, the polyalcohol according to the present invention
It is more than one or both of glycol, 1,2- pentanediols, 1,3 butylene glycol, glycerine and hexylene glycol;Preferably include methyl propanediol,
Combination more than one or both of DPG, 1,2- pentanediols and 1,3 butylene glycol.
One kind in quaternary ammonium salt -73, kojic acid is included from thickening pearl toner, the skin conditioning agent according to the present invention
Or two kinds of combination.
Trehalose, pulullan polysaccharide, malt are included from thickening pearl toner, the moisturizing additive according to the present invention
Combination more than one or both of sugar alcohol, antierythrite, urea and glycine betaine.
Citric acid, lactic acid, butanedioic acid and plant are included from thickening pearl toner, the acidity regulator according to the present invention
Combination more than one or both of sour sodium.
According to the present invention from thickening pearl toner, the pH value from thickening pearl toner is between 4-6.
The present invention also provides a kind of preparation method for thickening pearl toner certainly according to the present invention, including will be described from increasing
The step of each component mixing of thick pearl toner.
The effect of invention
The present invention from thickening pearl toner there is slow thickening effect, viscosity can slowly rise, at the same have moisturizing,
Whitening and anti-acne effect, and without additionally adding cosmetics Common Preservatives, help to lift the barrier and maintenance energy of skin
Power, gentle safety are adapted to long-term use.
Embodiment
It will be detailed below various exemplary embodiments, feature and the aspect of the disclosure.Special word " example herein
Property " mean " being used as example, embodiment or illustrative ".Any embodiment here as illustrated by " exemplary " should not necessarily be construed as
Preferred or advantageous over other embodiments.
In addition, in order to which the disclosure is better described, numerous details is given in embodiment below.
It will be appreciated by those skilled in the art that without some details, the disclosure can equally be implemented.In other example,
It is not described in detail for method well known to those skilled in the art, means, equipment and step, in order to highlight the master of the disclosure
Purport.
The present invention provides a kind of thickening pearl toner certainly, with described from the weight percent for thickening pearl toner gross weight
Than meter, including following components:
Film forming agent:0.01-1.0%;
Pearl:0.05-5%;
Polyalcohol:3-20%;
Skin conditioning agent:0.0001-0.005%;
Moisturizing additive:0.01-3.0%;
Acidity regulator:0.001-0.05%;
Water:71-95%.
Film forming agent from thickening pearl toner, can play moist, soft, fine and smooth and without glutinous soapy feeling in the present invention
Film forming water retention.In the present invention, the film forming agent include one or both of carragheen, gellan gum and sodium alginate with
On combination.
Carragheen, also known as carrageenan, deer horn phycocolloid, Irish green moss glue, it is by galactolipin and Anhydrogalactose institute group
Into carry sulfuric ester biological polyoses quasi-molecule.Due to the difference of wherein sulfuric ester combining form, the κ-type typically mainly used,
Three kinds of ι-type, λ-type carragheens.The colloidal sol of low viscosity is formed when the concentration of carragheen is low, close to Newtonian fluid, there is thickening effect
Fruit.Wherein, ι-type carragheen can be formed with more preferable thixotropic gel with calcium binding.The present invention's is precious from thickening
Film forming agent in pearl toner is preferably carragheen, more preferably ι-type carragheen.
Gellan gum main component is the film forming agent that glucose, rhamnose and glucuronic acid combine.In natural Gao Yi
With the presence of acetyl group and glycerine acidic group in acyl structure, they are all located on same glucosyl group, and each average repetition is tied
Structure has a glycerine acidic group, and each two repetitive structure has an acetyl group.In the presence of calcium ion, it can be formed harder crisp
Gel.
Sodium alginate is by guluronic acid (being designated as G sections) and its two kinds of stereoisomer mannuronic acid (being designated as M sections)
The sodium salt that construction unit is formed, both construction units (MM sections, GG sections and MG sections) in a manner of three kinds pass through α-Isosorbide-5-Nitrae glycosidic bond chain
Connect, so as to form a kind of unbranched linear block copolymers.Sodium ion is easy to replace with calcium ion in sodium alginate,
Form gel.Moreover, with gentle sol-gel process, good biocompatibility and very strong water holding capacity.
In the present invention, by described from terms of the percentage by weight of thickening pearl toner gross weight, the addition of film forming agent
Between 0.01-1.0%, preferably between 0.1-0.8%, more preferably in 0.15-0.5%.The addition of film forming agent is in 0.01-
When between 1.0%, it is added into toner, skin can be made moist, soft, fine and smooth and not glutinous greasy, in skin surface shape
Into one layer of moisturizing water lock film.
In addition, preferably do not include such as in the film forming agent of the present invention:Hydroxyethyl cellulose, xanthans, agar, Scleroglucan,
Hydroxy-ethyl acrylate/sodium acryloyldimethyl taurate copolymers, AVC etc. have phase
Like the thickener of function.But on the premise of the film forming agent containing the application, it can include from thickening in pearl toner
Appropriate above-mentioned thickener.
In general, the inorganic constituents of pearl is mainly calcium carbonate, magnesium carbonate.Also containing L-aminobutanedioic acid, threonine, silk ammonia
Acid, glutamic acid, glycine, alanine, cystine, valine, methionine, isoleucine, leucine, tyrosine, phenylalanine,
17 kinds of amino acid such as histidine, arginine, proline, in addition, also containing 30 various trace elements, taurine, the life of abundant dimension
Element, peptides.Pearl is added in the present invention, can be produced from the effect of thickening, and can supplement several amino acids and Wei Sheng
Element etc., to enable the skin to realize the effect of whitening oil-control etc..
In the present invention, the pearl is pearl particles or pearl powder;Preferably pearl particles.Added when by pearl particles
To the present invention from thickening pearl toner, so as to discharge and provide bivalent cation, it can be in contact with it with slow mechanism dissolved
Film forming agent forms gel, the local aqua viscosity increase of pearl particles.Under extraneous physical force each time, such as make toppling over
With from when thickening pearl toner, the dilution of gel around pearl particles can be accelerated to diffuse in whole bottle aqua.
With the access times increase from thickening pearl toner, should can slowly increase from the denseness of thickening pearl toner
Add, viscosity will slowly rise, that is, be produced from thickening effect.When the pearl in water is not redissolved, thickening pearl toner is viscous certainly
Degree then keeps certain limit no longer to fluctuate.At this from during thickening pearl toner use, what can be brought to consumer is
The usage experience of more textured sense and entertaining sense.Pearl itself soluble organic matter is caused preferably to be dissolved in this from increasing simultaneously
In thick pearl toner, use effect of product is enriched.
In addition, when from pearl powder, it can also realize that thickening speed is compared to when using pearl particles from thickening effect
It hurry up, can be in a kind of state of viscosity stabilization faster from thickening pearl toner.Also, pearl itself solubility is organic
Material can be similarly dissolved in toner.
The pearl particles and pearl powder of the present invention are preferably fresh water pearl particle or fresh water pearl powder.
In the present invention, by described from terms of the percentage by weight of thickening pearl toner gross weight, the addition of the pearl
Amount is between 0.05-5%, preferably between 0.05-4%, more preferably between 0.5-2.5%.When the addition of pearl exists
When between 0.05-5%, the effect of thickening can be produced from, and several amino acids and vitamin etc. can be supplemented, to cause skin
Skin can realize the effect of whitening oil-control etc..
The polyalcohol of the present invention includes 1,3- propane diols, methyl propanediol, DPG, 1,2- pentanediols, 1,3- fourths two
It is more than one or both of alcohol, glycerine and hexylene glycol.Wherein, 1,3-PD is natural products, will not cause skin irritatin
Or allergy, product performance of keeping humidity can be strengthened.1,3 butylene glycol is small molecule moisturizing ingredient.DPG is small to skin irritation
NMF.Methyl propanediol has good moistening effect, while provides salubrious skin sense.Glycerine has strong hygroscopicity, can
To allow the speed that distributes of the moisture on skin to slow down, and suitably can be absorbed water from air.1,2- pentanediols are good
NMF, additionally it is possible to so that in cosmetics reduce preservative usage amount, and effectively reduce protective system excitant, be adapted to
Nursing for sensitive tender and lovely skin and aging dry skin.
Preferably, polyalcohol of the invention is included in methyl propanediol, DPG, 1,2- pentanediols and 1,3-BDO
One or more kinds of combinations.
In the present invention, by described from terms of the percentage by weight of thickening pearl toner gross weight, the polyalcohol adds
Enter amount between 3-20%, preferably between 5-18%, more preferably between 8-15%.
The skin conditioning agent of the present invention includes the combination of one or both of quaternary ammonium salt -73, kojic acid.
Quaternary ammonium salt -73 is a kind of yellow solid or crystal, has antibacterial activity, can reduce the generation of acne, acne, from
And cause the present invention's there is certain acne-removal function from thickening pearl toner.In addition, quaternary ammonium salt -73 may be used also in the present invention
To play certain antisepsis, there is certain killing ability to bacterium, staphylococcus, Escherichia coli etc..Therefore, it is of the invention
In can not add extra preservative, such as Phenoxyethanol, methyl hydroxybenzoate etc. can be added without.
In the present invention, by described from terms of the percentage by weight of thickening pearl toner gross weight, the skin conditioning agent
Addition between 0.0001-0.005%, preferably between 0.0003-0.005%, more preferably in 0.0008-0.005%
Between.
The moisturizing additive of the present invention includes trehalose, pulullan polysaccharide, maltitol, antierythrite, urea and beet
One or more kinds of combinations of alkali.
Trehalose has efficient moisture-keeping functions, can be under the mal-conditions such as high temperature, high and cold and dry dehydration in cell
Surface forms special diaphragm, effectively protects biomolecular structure in skin cell not to be destroyed, and further lifts skin and fits
Answer environment capacity and oxidation resistance.
Pulullan polysaccharide is more by the water-soluble vitamins of the similar glucan of Aureobasidium pullulans fermenting and producing, xanthans
Sugar.The straight-chain that the polysaccharide is polymerized by the maltotriose repeat unit of α -1,4- glucosides key connections through α -1,6- glycosidic bonds is more
Sugar.Pulullan polysaccharide has good moisturizing moisturizing effect.
Maltitol can have a Starch Hydrolysis and a kind of sugar alcohol that hydrofining forms.It is resistance to good hygroscopicity
Heat and acid-resistant stability.Maltitol can be effectively improved the pliability of skin while moisturizing.
Antierythrite is by a kind of fermented obtained white crystal of glucose, is good natural moisture preserving agent, can be significantly
Increase moisture of skin, keep the barrier function of skin, lift skin pliability and flexibility.
Urea (cosmetics-stage) helps to reduce skin water loss, and itself is present among the cuticula of skin, category
In the main component of skin NMF.Urea has outstanding moisturizing and soft cutin effect, and skin care is simultaneously
Lift the penetrating power of other compositions.
Glycine betaine helps to maintain Premeabilisation of cells pressure, can provide large quantity of moisture for skin, be a kind of good NMF.
In the present invention, by described from terms of the percentage by weight of thickening pearl toner gross weight, the moisturizing additive
Addition between 0.01-3.0%, preferably between 0.05-2.8%, more preferably between 0.1-2.5%.The moisturizing
It when the addition of additive is between 0.01-3.0%, can bring that silk is sliding, moist and instant moisturizing effect to skin, lift flesh
Skin water conservation and barrier ability.
In the present invention, the acidity regulator include one or both of citric acid, lactic acid, butanedioic acid and sodium phytate with
On combination.By adding acidity regulator so that pH value of the present invention can fluctuate within the specific limits, be made up from pearl is thickened
Water is in faintly acid, and skin will not be damaged, and is advantageous to the dissolving of pearl particles or pearl powder.In view of to skin
Mildness etc., acidity regulator of the invention are preferably citric acid.
In the present invention, by described from terms of the percentage by weight of thickening pearl toner gross weight, the acidity regulator
Addition is between 0.001-0.05%, preferably between 0.002-0.05%;More preferably between 0.005-0.03%.
In general, the pH value of thickening pearl toner can be made between 4.0-6.0.
In addition, the present invention from thickening pearl toner in, preferably be free of just like:CaCl2, the inorganic salts ingredients such as NaCl.
In the present invention, used water is preferably deionized water.With described from the weight for thickening pearl toner gross weight
Percentages, the addition of the water is 71-95%;Preferably 75-93%, more preferably 80-91%.
It is of the invention that a kind of preparation method according to the pearl toner of thickening certainly of the present invention is also provided, including by described in certainly
The step of thickening each component mixing of pearl toner.
Specifically, the preparation method comprises the following steps:
A:Deionized water is added into reactor, stirs the good film forming agent of lower addition disperse polyol, fully dissolving is equal
It is even;80-85 DEG C is heated to, after being incubated 15-25min, is cooled to 40-50 DEG C.
B:Then moisturizing additive is added and is evenly stirred until dissolving into above-mentioned emulsification pot;Add with polyalcohol solubilising
Skin conditioning agent, stir.
C:Acidity regulator is added, toner base-material is obtained after filtering and discharging after regulation pH is 4.0-6.0.
D:Detect it is qualified after, into each Packaging Bottle add through deionized water clean and 75% ethanol disinfection pearl
Grain, it is filling, obtain from thickening pearl toner.
Embodiment
Embodiment of the present invention is described in detail below in conjunction with embodiment, but those skilled in the art will
Understand, the following example is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.It is unreceipted specific in embodiment
Condition person, the condition suggested according to normal condition or manufacturer are carried out.Agents useful for same or the unreceipted production firm person of instrument, it is
The conventional products of acquisition purchased in market can be passed through.
Embodiment 1-10
After weight percentage according to each component in table 1 below -2 weighs, it is prepared according to following step precious from thickening
Pearl toner.
It is as follows from the preparation method of thickening pearl toner:
A:Deionized water is added into emulsification pot, the good film forming agent of lower addition disperse polyol is stirred, makes fully to dissolve
Uniformly;85 DEG C are then heated to, after being incubated 20min, is cooled to 45 DEG C.
B:Then moisturizing additive is added and is evenly stirred until dissolving into above-mentioned emulsification pot;Add with polyalcohol solubilising
Skin conditioning agent, stir.
C:Acidity regulator is added, toner base-material is obtained after filtering and discharging after regulation pH is 4.0-6.0.
D:Detect it is qualified after, into each Packaging Bottle add through deionized water clean and 75% ethanol disinfection pearl
Grain, it is filling.
E:Packaging, obtain from thickening pearl toner I, toner II, toner III ..., toner X.
Table 1
Table 2
Comparative example
According to the content (%) of each component of comparative example in table 3 below, and it is prepared according to the step identical with embodiment
Toner XI, toner XII, toner XIII ..., toner XVII.
Table 3
Experimental effect analysis
Pigment is tested
After Melan- α cells after tested sample treatment, melanin generation situation analysis is carried out.Exponential phase will be in
Melan- α cells, adjustment density be 3 × 104It is inoculated in after individual/mL in 9 orifice plates, per hole 2mL, at 37 DEG C and 5%CO2Under incubate
Educate 24h.After abandoning nutrient solution, the toner III of extraction embodiment 3, the toner V of embodiment 5, embodiment 7 toner VII,
The toner VIII of embodiment 8, the toner XII of comparative example 2, the toner XVII of comparative example 7 and 30 μ g/mL placebo materials
Each 3mL, continue to be incubated 72h, remove supernatant, after PBS 2 times, add and digested through 0.2% trypsase 1mL/ holes, added
Enter 1mL nutrient solutions and stop digestion, cell suspension is made.
Cell is collected into centrifuge tube, supernatant is removed in centrifugation, and 100 μ L concentration of addition are 1mol/L NaOH, 37 DEG C of water-baths
1.5h, cell lysis and dissolving melanin granule.The dilution of 300 μ L distilled waters is added, takes 100 μ L/ holes to add to 96 orifice plates after mixing,
Every group set 3 it is parallel, the melanin absorbance dissolved in 490nm wavelength measurement 1mol/L NaOH, be converted into various total proteins
Quality, it is as shown in table 4 below that each component melanin inhibiting rate is calculated.
The inhibiting rate that 4. each toner of table generates to melanin
(n=3, p<0.01)
From the test result of table 4, compared with negative control group, find toner III, toner V, toner VII
There is obvious inhibitory action to melanin generation with toner VIII, inhibiting rate is respectively 55.3%, 62.1%, 54% and
82.4%, and inhibition is substantially better than or suitable with placebo;Simultaneously also superior to comparative example toner XII, toner XVII
The generation inhibiting rate of melanin be respectively 51.7%, 22.2%.
Moisture content of skin is tested
Randomly select 25 tested volunteers, wherein male 12, women 13.Subject elder generation wash hands forearm,
Sit quietly 30min under constant wet temp (25 DEG C, RH43%) environment, then using subject's left and right arm both sides subregion as pair
According to each region is 3cm × 3cm, phase homogenous quantities 30mg sample is smeared to fully absorbing, with Corneometer CM825 instrument
Device tests the moisture (Corneometer Unit, C.U.) of corresponding Test sites, and experimental data is repeated 8 times respectively, is drawn
The average value tested every time, 25 volunteers are calculated and contain in different time spaced points 0h, 2h, 4h, 6h mean skin moisture
Amount is as shown in table 5, the toner I of comparing embodiment 1, the toner II of embodiment 2, the toner III of embodiment 3, comparative example 1
Toner XI, the toner XVI and blank district skin moisture content size of comparative example 6.
The skin moisture content data summarization of table 5. different time, 25 subjects
In table 5, conspicuousness:"+" represents significant difference (p<0.05);"-" represents non-limiting difference (p>0.05).
From the data in table 5, it can be seen that compared with blank district, comparative example 1 and 6, the toner I of the embodiment of the present invention, make up
Water II and toner III is considerably higher using the skin moisture content in 6h, namely with preferably moisturizing immediately and long-acting
Moistening effect.
Suppress propionibacterium acnes growth
By 5 × 105Individual/μ l of mL propionibacterium acneses (ATCC11827) suspension 100 are coated in agar plate, each culture
Toner I of the ware respectively containing 10% final concentration embodiment 1, the toner IV of embodiment 4, the toner VII of embodiment 7, reality
Apply the toner VIII of example 8, the toner IX of embodiment 9 and comparative example 7 toner XVII.Each test sample 3 is parallel.
Plate is cultivated in 37 DEG C of oxygen-free environments.Observe the 2nd day and the 4th day each plate in colony growth situation it is as shown in table 6.
Influence of the toner of table 6. to propionibacterium acnes growing state
In table 6:"-" indicates no colony growth;"+" represents a small number of colony growths;" ++ " represents many colony growths;“++
+ " represent that bacterium colony dense growth is vigorous.
As shown in Table 6, the toner I of embodiment, toner IV, toner VIII and toner IX are to propionibacterium acnes
Growth play good inhibitory action, the toner XVII of the obvious comparative example 7 of inhibition;The toner VII of embodiment 7
In, the skin conditioning agent used has certain inhibitory action to propionibacterium acnes for kojic acid in its short time;And comparative example 7
Growth effect very littles of the toner XVII to propionibacterium acnes.
4th, physicochemical property test and analysis
The toner IV of toner I, embodiment 4 to embodiment 1, the toner X, comparative example 1 of embodiment 10 cosmetic
Water XI, the toner XIII of comparative example 3, the toner XIV of comparative example 4, the toner XV of comparative example 5 and comparative example 7 cosmetic
Water XVII physicochemical property test and analysis, to viscosity (the BROOKFIELD brand HBDV-II+Pro viscosity of its different time sections
Meter, 25 DEG C, 3#, 20rpm), the pH value under 10 times of dilution and transparency investigated, as a result as shown in table 7.
The physicochemical property of table 7. is tested and analysis
In table 7, (-) represents:Viscosity is≤500mPa.S, and mobility is very good, and pearl does not stick wall;(+) represents:Viscosity
For 500-1000mPa.S, good fluidity, a small number of pearls stick wall;(++) represents:Viscosity is 1000-3000mPa.S mobility one
As, most of pearl sticks wall;(+++) represents:Viscosity is 3000-8000mPa.S, can be with mobility, the glutinous wall of pearl;(++++)
Represent:Viscosity is >=8000mPa.S, the jelly gel of flowable, and Suspended Pearl is flowable in toner;(+++ ++) table
Show:Form solid gel not flow, pearl is static to be suspended in gel.
Can by being investigated in table 7 to embodiment 1,4 and 10 and comparative example 1,3-5, the physicochemical property of 7 toner and transparency
Know, over time, slow rising occurs in toner I, IV and X of embodiment 1,4 and 10 pH value, while has very
Significantly slowly from thickening effect, and keep very high transparency.And comparative example 1 toner XI formula with embodiment 1,4 and
10 compare, and due to a lack of film forming agent, the continuous dissolution of pearl soluble component, so as to cause the increase of product sediment, outward appearance is impermeable
It is bright, it is unable to reach and possesses from thickening effect.
The toner XIII of comparative example 3 is compared with embodiment, and because the selection of macromolecule film former is different, product appearance is not yet
Together, do not possess from thickening effect simultaneously, transparency is elapsing because turbid phenomenon can occur for calcium ion dissolution over time.
For the toner XIV of comparative example 4 although the very high grade of transparency can be kept, its pH value and viscosity are more stable, are a
Common toner formula system, it is impossible to reach the present invention from thickening effect, while the water solubility of its whitening effect and pearl
Active matter is weaker than the effect of the toner of embodiment 1,4 and 10.
The toner XV of comparative example 5 can keep the very high grade of transparency, because not adding acidity regulator, its pH value of toner XV
Will not be changed with viscosity, the water-soluble active thing and calcium ion of pearl can not dissolutions, it is impossible to reach the present invention from thickening
Effect, whitening effect are also weaker than the effect of the toner of embodiment 1,4 and 10.
From the toner XVII of comparative example 7 viscosity and pH value and apparent condition data, its usage experience and effect
Fruit can not show a candle to the toner in the embodiment of the present invention 1,4,10.
Described above, the only embodiment of the disclosure, but the protection domain of the disclosure is not limited thereto is any
Those familiar with the art can readily occur in change or replacement in the technical scope that the disclosure discloses, and should all contain
Cover within the protection domain of the disclosure.Therefore, the protection domain of the disclosure should be based on the protection scope of the described claims.