CN107466289B - 用于产生烯属不饱和羧酸或羧酸酯的工艺 - Google Patents

用于产生烯属不饱和羧酸或羧酸酯的工艺 Download PDF

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Publication number
CN107466289B
CN107466289B CN201680022311.5A CN201680022311A CN107466289B CN 107466289 B CN107466289 B CN 107466289B CN 201680022311 A CN201680022311 A CN 201680022311A CN 107466289 B CN107466289 B CN 107466289B
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Prior art keywords
formaldehyde
methyl
reaction
carbonate
carboxylic acid
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Chinese (zh)
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CN107466289A (zh
Inventor
格雷厄姆·罗纳德·伊斯特汉
大卫·威廉·约翰逊
马克·沃
乔纳森·安斯利·伊戈
迈克尔·博蒙特
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Mitsubishi Chemical UK Ltd
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Lucite International UK Ltd
Mitsubishi Chemical UK Ltd
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54—Acrylic acid esters; Methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/16—Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20—Carbon compounds
    • C07C2527/232—Carbonates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201680022311.5A 2015-04-14 2016-04-12 用于产生烯属不饱和羧酸或羧酸酯的工艺 Active CN107466289B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562147347P 2015-04-14 2015-04-14
US62/147,347 2015-04-14
GBGB1506308.4A GB201506308D0 (en) 2015-04-14 2015-04-14 A process for the production of ethylenically unsaturated carboxylic acids or esters
GB1506308.4 2015-04-14
PCT/GB2016/051026 WO2016166525A1 (en) 2015-04-14 2016-04-12 A process for the production of ethylenically unsaturated carboxylic acids or esters

Publications (2)

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CN107466289A CN107466289A (zh) 2017-12-12
CN107466289B true CN107466289B (zh) 2021-09-17

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Country Link
US (1) US10464875B2 (enExample)
EP (1) EP3283456B1 (enExample)
JP (1) JP6925978B2 (enExample)
KR (1) KR102658340B1 (enExample)
CN (1) CN107466289B (enExample)
AU (1) AU2016250204A1 (enExample)
BR (1) BR112017021960B1 (enExample)
CA (1) CA2982395C (enExample)
EA (1) EA036539B1 (enExample)
ES (1) ES2886902T3 (enExample)
GB (1) GB201506308D0 (enExample)
MX (1) MX2017013164A (enExample)
MY (1) MY188189A (enExample)
SG (1) SG11201708390XA (enExample)
TW (1) TWI780025B (enExample)
WO (1) WO2016166525A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201617534D0 (en) 2016-10-14 2016-11-30 Lucite International Uk Limited A process for the production of Ethylenically unsaturated carboxylic acid esters and a catalyst therefor
EP3587390A1 (de) 2018-06-26 2020-01-01 Röhm GmbH Verfahren zur herstellung von mma in hohen ausbeuten
GB201903452D0 (en) * 2019-03-13 2019-04-24 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters
CN114478244A (zh) * 2020-10-27 2022-05-13 中国石油化工股份有限公司 一种丙烯酸甲酯合成的方法、催化剂及应用
CN114436834A (zh) * 2021-12-16 2022-05-06 江苏阿尔法药业股份有限公司 一种利用连续流微通道反应器合成瑞舒伐他汀钙中间体的方法
CN116924909A (zh) * 2023-07-25 2023-10-24 广州天赐高新材料股份有限公司 3-甲氧基丙酸甲酯、3-甲氧基-n，n-二甲基丙酰胺的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2313501A (en) * 1939-08-15 1943-03-09 Eastman Kodak Co Process for preparing methylene dialkyl malonates
GB1418451A (en) * 1973-05-09 1975-12-17 Snam Progetti Process for producing itaconic acid and derivatives thereof
JPH0648977A (ja) * 1992-07-29 1994-02-22 Daicel Chem Ind Ltd メタクリル酸又はメタクリル酸誘導体の製造方法
WO1998029379A1 (en) * 1997-01-03 1998-07-09 Eastman Chemical Company Preparation of alpha, beta-unsaturated carboxylic acids and esters in the presence of an oxide of niobium as catalyst
CN1312791A (zh) * 1998-08-11 2001-09-12 克诺尔有限公司 阿托酸乙酯的制备方法
CN103551148A (zh) * 2013-10-29 2014-02-05 西南化工研究设计院有限公司 一种用于羟醛缩合的耐水性催化剂及其制备方法和应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2212506A (en) * 1939-08-15 1940-08-27 Eastman Kodak Co Preparation of methylene dialkyl malonates
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
JP2002540201A (ja) 1999-03-30 2002-11-26 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー α‐メチレンラクトンおよびα‐置換ハイドロカルビリデンラクトンの製造方法
GB201200551D0 (en) 2012-01-13 2012-02-29 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2313501A (en) * 1939-08-15 1943-03-09 Eastman Kodak Co Process for preparing methylene dialkyl malonates
GB1418451A (en) * 1973-05-09 1975-12-17 Snam Progetti Process for producing itaconic acid and derivatives thereof
JPH0648977A (ja) * 1992-07-29 1994-02-22 Daicel Chem Ind Ltd メタクリル酸又はメタクリル酸誘導体の製造方法
WO1998029379A1 (en) * 1997-01-03 1998-07-09 Eastman Chemical Company Preparation of alpha, beta-unsaturated carboxylic acids and esters in the presence of an oxide of niobium as catalyst
CN1312791A (zh) * 1998-08-11 2001-09-12 克诺尔有限公司 阿托酸乙酯的制备方法
CN103551148A (zh) * 2013-10-29 2014-02-05 西南化工研究设计院有限公司 一种用于羟醛缩合的耐水性催化剂及其制备方法和应用

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Rhodium(III)-Catalyzed Direct C-H Allylation of Electron-Deficient Alkenes with Allyl Acetates;Chao Feng et al.;《Chemical communications》;20141105;第51卷(第2期);342-345 *

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Publication number Publication date
EP3283456A1 (en) 2018-02-21
EP3283456B1 (en) 2021-06-23
SG11201708390XA (en) 2017-11-29
WO2016166525A1 (en) 2016-10-20
KR20170137182A (ko) 2017-12-12
KR102658340B1 (ko) 2024-04-18
CA2982395C (en) 2024-03-12
MY188189A (en) 2021-11-24
MX2017013164A (es) 2018-05-22
EA201792279A1 (ru) 2018-04-30
TWI780025B (zh) 2022-10-11
ES2886902T3 (es) 2021-12-21
AU2016250204A1 (en) 2017-11-02
CA2982395A1 (en) 2016-10-20
US10464875B2 (en) 2019-11-05
EA036539B1 (ru) 2020-11-20
GB201506308D0 (en) 2015-05-27
US20180093937A1 (en) 2018-04-05
TW201636321A (zh) 2016-10-16
JP2018511636A (ja) 2018-04-26
JP6925978B2 (ja) 2021-08-25
BR112017021960A2 (pt) 2018-07-10
CN107466289A (zh) 2017-12-12
BR112017021960B1 (pt) 2021-07-13

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