KR102658340B1 - 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 - Google Patents
에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 Download PDFInfo
- Publication number
- KR102658340B1 KR102658340B1 KR1020177032837A KR20177032837A KR102658340B1 KR 102658340 B1 KR102658340 B1 KR 102658340B1 KR 1020177032837 A KR1020177032837 A KR 1020177032837A KR 20177032837 A KR20177032837 A KR 20177032837A KR 102658340 B1 KR102658340 B1 KR 102658340B1
- Authority
- KR
- South Korea
- Prior art keywords
- formaldehyde
- methyl
- carbonate
- reaction
- cesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/353—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
- C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
- C07C57/03—Monocarboxylic acids
- C07C57/04—Acrylic acid; Methacrylic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
- C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
- C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/14—Phosphorus; Compounds thereof
- C07C2527/16—Phosphorus; Compounds thereof containing oxygen
- C07C2527/167—Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/20—Carbon compounds
- C07C2527/232—Carbonates
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562147347P | 2015-04-14 | 2015-04-14 | |
| GBGB1506308.4A GB201506308D0 (en) | 2015-04-14 | 2015-04-14 | A process for the production of ethylenically unsaturated carboxylic acids or esters |
| GB1506308.4 | 2015-04-14 | ||
| US62/147,347 | 2015-04-14 | ||
| PCT/GB2016/051026 WO2016166525A1 (en) | 2015-04-14 | 2016-04-12 | A process for the production of ethylenically unsaturated carboxylic acids or esters |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20170137182A KR20170137182A (ko) | 2017-12-12 |
| KR102658340B1 true KR102658340B1 (ko) | 2024-04-18 |
Family
ID=53333750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020177032837A Active KR102658340B1 (ko) | 2015-04-14 | 2016-04-12 | 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US10464875B2 (enExample) |
| EP (1) | EP3283456B1 (enExample) |
| JP (1) | JP6925978B2 (enExample) |
| KR (1) | KR102658340B1 (enExample) |
| CN (1) | CN107466289B (enExample) |
| AU (1) | AU2016250204A1 (enExample) |
| BR (1) | BR112017021960B1 (enExample) |
| CA (1) | CA2982395C (enExample) |
| EA (1) | EA036539B1 (enExample) |
| ES (1) | ES2886902T3 (enExample) |
| GB (1) | GB201506308D0 (enExample) |
| MX (1) | MX2017013164A (enExample) |
| MY (1) | MY188189A (enExample) |
| SG (1) | SG11201708390XA (enExample) |
| TW (1) | TWI780025B (enExample) |
| WO (1) | WO2016166525A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB201617534D0 (en) | 2016-10-14 | 2016-11-30 | Lucite International Uk Limited | A process for the production of Ethylenically unsaturated carboxylic acid esters and a catalyst therefor |
| EP3587390A1 (de) | 2018-06-26 | 2020-01-01 | Röhm GmbH | Verfahren zur herstellung von mma in hohen ausbeuten |
| GB201903452D0 (en) * | 2019-03-13 | 2019-04-24 | Lucite Int Uk Ltd | A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters |
| CN114478244A (zh) * | 2020-10-27 | 2022-05-13 | 中国石油化工股份有限公司 | 一种丙烯酸甲酯合成的方法、催化剂及应用 |
| CN114436834A (zh) * | 2021-12-16 | 2022-05-06 | 江苏阿尔法药业股份有限公司 | 一种利用连续流微通道反应器合成瑞舒伐他汀钙中间体的方法 |
| CN116924909A (zh) * | 2023-07-25 | 2023-10-24 | 广州天赐高新材料股份有限公司 | 3-甲氧基丙酸甲酯、3-甲氧基-n，n-二甲基丙酰胺的制备方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2313501A (en) * | 1939-08-15 | 1943-03-09 | Eastman Kodak Co | Process for preparing methylene dialkyl malonates |
| US2212506A (en) * | 1939-08-15 | 1940-08-27 | Eastman Kodak Co | Preparation of methylene dialkyl malonates |
| IT987221B (it) * | 1973-05-09 | 1975-02-20 | Snam Progetti | Processo per la preparazione dell acido itaconico e di suoi derivati |
| JP3202802B2 (ja) * | 1992-07-29 | 2001-08-27 | ダイセル化学工業株式会社 | メタクリル酸又はメタクリル酸誘導体の製造方法 |
| US5808148A (en) * | 1997-01-03 | 1998-09-15 | Eastman Chemical Company | Preparation of α,β-unsaturated carboxylic acids and esters |
| GB9807498D0 (en) | 1998-04-08 | 1998-06-10 | Ici Plc | Production of unsaturated acids therfore and catalysts therfor |
| DE19836222A1 (de) * | 1998-08-11 | 2000-02-17 | Knoll Ag | Verfahren zur Herstellung von Atropasäureethylester |
| DE60015944T2 (de) | 1999-03-30 | 2005-11-03 | E.I. Du Pont De Nemours And Co., Wilmington | Verfahren zur herstellung von alpha-methylenelactonen und alpha-substitutierten hydrocarbyliden-lactonen |
| GB201200551D0 (en) | 2012-01-13 | 2012-02-29 | Lucite Int Uk Ltd | A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor |
| CN103551148B (zh) * | 2013-10-29 | 2015-08-05 | 西南化工研究设计院有限公司 | 一种用于羟醛缩合的耐水性催化剂及其制备方法和应用 |
-
2015
- 2015-04-14 GB GBGB1506308.4A patent/GB201506308D0/en not_active Ceased
-
2016
- 2016-04-07 TW TW105110894A patent/TWI780025B/zh not_active IP Right Cessation
- 2016-04-12 CN CN201680022311.5A patent/CN107466289B/zh active Active
- 2016-04-12 WO PCT/GB2016/051026 patent/WO2016166525A1/en not_active Ceased
- 2016-04-12 AU AU2016250204A patent/AU2016250204A1/en not_active Abandoned
- 2016-04-12 MY MYPI2017703834A patent/MY188189A/en unknown
- 2016-04-12 EA EA201792279A patent/EA036539B1/ru not_active IP Right Cessation
- 2016-04-12 SG SG11201708390XA patent/SG11201708390XA/en unknown
- 2016-04-12 BR BR112017021960-3A patent/BR112017021960B1/pt active IP Right Grant
- 2016-04-12 MX MX2017013164A patent/MX2017013164A/es unknown
- 2016-04-12 ES ES16716668T patent/ES2886902T3/es active Active
- 2016-04-12 CA CA2982395A patent/CA2982395C/en active Active
- 2016-04-12 JP JP2017553997A patent/JP6925978B2/ja not_active Expired - Fee Related
- 2016-04-12 EP EP16716668.5A patent/EP3283456B1/en active Active
- 2016-04-12 KR KR1020177032837A patent/KR102658340B1/ko active Active
- 2016-04-12 US US15/566,082 patent/US10464875B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MY188189A (en) | 2021-11-24 |
| BR112017021960B1 (pt) | 2021-07-13 |
| EA036539B1 (ru) | 2020-11-20 |
| ES2886902T3 (es) | 2021-12-21 |
| GB201506308D0 (en) | 2015-05-27 |
| CN107466289B (zh) | 2021-09-17 |
| AU2016250204A1 (en) | 2017-11-02 |
| KR20170137182A (ko) | 2017-12-12 |
| JP6925978B2 (ja) | 2021-08-25 |
| US20180093937A1 (en) | 2018-04-05 |
| SG11201708390XA (en) | 2017-11-29 |
| BR112017021960A2 (pt) | 2018-07-10 |
| EA201792279A1 (ru) | 2018-04-30 |
| CA2982395A1 (en) | 2016-10-20 |
| TW201636321A (zh) | 2016-10-16 |
| MX2017013164A (es) | 2018-05-22 |
| JP2018511636A (ja) | 2018-04-26 |
| CN107466289A (zh) | 2017-12-12 |
| WO2016166525A1 (en) | 2016-10-20 |
| EP3283456A1 (en) | 2018-02-21 |
| EP3283456B1 (en) | 2021-06-23 |
| US10464875B2 (en) | 2019-11-05 |
| CA2982395C (en) | 2024-03-12 |
| TWI780025B (zh) | 2022-10-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102658340B1 (ko) | 에틸렌성 불포화 카르복실산 또는 에스테르의 제조 방법 | |
| Rand et al. | Reactions catalyzed by potassium fluoride. III. The Knoevenagel reaction | |
| EP1352892B1 (en) | Processes for producing fluorinated ester, fluorinated acyl fluoride, and fluorinated vinyl ether | |
| Ugarte et al. | Antimony (V) catalyzed acetalisation of aldehydes: An efficient, solvent-free, and recyclable process | |
| ES2371063T3 (es) | Método para producir 2-(alquil)cicloalquenona. | |
| US20140135512A1 (en) | Method for producing glycidol | |
| US20230322655A1 (en) | Process for the conversion of furfuryl alcohol into a levulinate ester | |
| JPS6121534B2 (enExample) | ||
| US10683255B2 (en) | Process for the production of ethylenically unsaturated carboxylic acid esters and a catalyst therefor | |
| JPH04198144A (ja) | アルキルビニルエーテルの製造方法 | |
| Jayaraman et al. | An Efficient Bifunctional Ionic Liquid [BIL] as Solvent and Catalyst System for O-Alkylation of Phenols Under Solvent-Free Conditions: An Environmental Benign Approach | |
| JP7223445B2 (ja) | 脱離基を有する有機化合物と有機ケイ素化合物とのカップリング体の製造方法 | |
| KR101148995B1 (ko) | 글리세롤의 기상 탈수화 반응을 통한 아크롤레인 및 이의 제조방법 | |
| EA040930B1 (ru) | Способ получения эфиров этиленненасыщенных карбоновых кислот и его катализаторы | |
| US2844622A (en) | Ketene reactions | |
| JPS6366295B2 (enExample) | ||
| JP2017222598A (ja) | カルボン酸エステルの製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PA0105 | International application |
St.27 status event code: A-0-1-A10-A15-nap-PA0105 |
|
| PG1501 | Laying open of application |
St.27 status event code: A-1-1-Q10-Q12-nap-PG1501 |
|
| PN2301 | Change of applicant |
St.27 status event code: A-3-3-R10-R13-asn-PN2301 St.27 status event code: A-3-3-R10-R11-asn-PN2301 |
|
| A201 | Request for examination | ||
| PA0201 | Request for examination |
St.27 status event code: A-1-2-D10-D11-exm-PA0201 |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
| E13-X000 | Pre-grant limitation requested |
St.27 status event code: A-2-3-E10-E13-lim-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| E902 | Notification of reason for refusal | ||
| PE0902 | Notice of grounds for rejection |
St.27 status event code: A-1-2-D10-D21-exm-PE0902 |
|
| E13-X000 | Pre-grant limitation requested |
St.27 status event code: A-2-3-E10-E13-lim-X000 |
|
| P11-X000 | Amendment of application requested |
St.27 status event code: A-2-2-P10-P11-nap-X000 |
|
| P13-X000 | Application amended |
St.27 status event code: A-2-2-P10-P13-nap-X000 |
|
| E701 | Decision to grant or registration of patent right | ||
| PE0701 | Decision of registration |
St.27 status event code: A-1-2-D10-D22-exm-PE0701 |
|
| PR0701 | Registration of establishment |
St.27 status event code: A-2-4-F10-F11-exm-PR0701 |
|
| PR1002 | Payment of registration fee |
St.27 status event code: A-2-2-U10-U12-oth-PR1002 Fee payment year number: 1 |
|
| PG1601 | Publication of registration |
St.27 status event code: A-4-4-Q10-Q13-nap-PG1601 |