AU2016250204A1 - A process for the production of ethylenically unsaturated carboxylic acids or esters - Google Patents

A process for the production of ethylenically unsaturated carboxylic acids or esters Download PDF

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Publication number
AU2016250204A1
AU2016250204A1 AU2016250204A AU2016250204A AU2016250204A1 AU 2016250204 A1 AU2016250204 A1 AU 2016250204A1 AU 2016250204 A AU2016250204 A AU 2016250204A AU 2016250204 A AU2016250204 A AU 2016250204A AU 2016250204 A1 AU2016250204 A1 AU 2016250204A1
Authority
AU
Australia
Prior art keywords
formaldehyde
carboxylic acid
methyl
reaction
carbonate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2016250204A
Other languages
English (en)
Inventor
Michael BEAUMONT
Graham Ronald Eastham
Jonathan Ainsley IGGO
David William Johnson
Mark Waugh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical UK Ltd
Original Assignee
Lucite International UK Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite International UK Ltd filed Critical Lucite International UK Ltd
Publication of AU2016250204A1 publication Critical patent/AU2016250204A1/en
Abandoned legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/353Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by isomerisation; by change of size of the carbon skeleton
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/30Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
    • C07C69/533Monocarboxylic acid esters having only one carbon-to-carbon double bond
    • C07C69/54Acrylic acid esters; Methacrylic acid esters
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14Phosphorus; Compounds thereof
    • C07C2527/16Phosphorus; Compounds thereof containing oxygen
    • C07C2527/167Phosphates or other compounds comprising the anion (PnO3n+1)(n+2)-
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/20Carbon compounds
    • C07C2527/232Carbonates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
AU2016250204A 2015-04-14 2016-04-12 A process for the production of ethylenically unsaturated carboxylic acids or esters Abandoned AU2016250204A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201562147347P 2015-04-14 2015-04-14
US62/147,347 2015-04-14
GBGB1506308.4A GB201506308D0 (en) 2015-04-14 2015-04-14 A process for the production of ethylenically unsaturated carboxylic acids or esters
GB1506308.4 2015-04-14
PCT/GB2016/051026 WO2016166525A1 (en) 2015-04-14 2016-04-12 A process for the production of ethylenically unsaturated carboxylic acids or esters

Publications (1)

Publication Number Publication Date
AU2016250204A1 true AU2016250204A1 (en) 2017-11-02

Family

ID=53333750

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2016250204A Abandoned AU2016250204A1 (en) 2015-04-14 2016-04-12 A process for the production of ethylenically unsaturated carboxylic acids or esters

Country Status (16)

Country Link
US (1) US10464875B2 (enExample)
EP (1) EP3283456B1 (enExample)
JP (1) JP6925978B2 (enExample)
KR (1) KR102658340B1 (enExample)
CN (1) CN107466289B (enExample)
AU (1) AU2016250204A1 (enExample)
BR (1) BR112017021960B1 (enExample)
CA (1) CA2982395C (enExample)
EA (1) EA036539B1 (enExample)
ES (1) ES2886902T3 (enExample)
GB (1) GB201506308D0 (enExample)
MX (1) MX2017013164A (enExample)
MY (1) MY188189A (enExample)
SG (1) SG11201708390XA (enExample)
TW (1) TWI780025B (enExample)
WO (1) WO2016166525A1 (enExample)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB201617534D0 (en) 2016-10-14 2016-11-30 Lucite International Uk Limited A process for the production of Ethylenically unsaturated carboxylic acid esters and a catalyst therefor
EP3587390A1 (de) 2018-06-26 2020-01-01 Röhm GmbH Verfahren zur herstellung von mma in hohen ausbeuten
GB201903452D0 (en) * 2019-03-13 2019-04-24 Lucite Int Uk Ltd A catalyst and a process for the production of ethylenically unsaturated carboxylic acids for esters
CN114478244A (zh) * 2020-10-27 2022-05-13 中国石油化工股份有限公司 一种丙烯酸甲酯合成的方法、催化剂及应用
CN114436834A (zh) * 2021-12-16 2022-05-06 江苏阿尔法药业股份有限公司 一种利用连续流微通道反应器合成瑞舒伐他汀钙中间体的方法
CN116924909A (zh) * 2023-07-25 2023-10-24 广州天赐高新材料股份有限公司 3-甲氧基丙酸甲酯、3-甲氧基-n,n-二甲基丙酰胺的制备方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2313501A (en) * 1939-08-15 1943-03-09 Eastman Kodak Co Process for preparing methylene dialkyl malonates
US2212506A (en) * 1939-08-15 1940-08-27 Eastman Kodak Co Preparation of methylene dialkyl malonates
IT987221B (it) * 1973-05-09 1975-02-20 Snam Progetti Processo per la preparazione dell acido itaconico e di suoi derivati
JP3202802B2 (ja) * 1992-07-29 2001-08-27 ダイセル化学工業株式会社 メタクリル酸又はメタクリル酸誘導体の製造方法
US5808148A (en) * 1997-01-03 1998-09-15 Eastman Chemical Company Preparation of α,β-unsaturated carboxylic acids and esters
GB9807498D0 (en) 1998-04-08 1998-06-10 Ici Plc Production of unsaturated acids therfore and catalysts therfor
DE19836222A1 (de) * 1998-08-11 2000-02-17 Knoll Ag Verfahren zur Herstellung von Atropasäureethylester
JP2002540201A (ja) 1999-03-30 2002-11-26 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー α‐メチレンラクトンおよびα‐置換ハイドロカルビリデンラクトンの製造方法
GB201200551D0 (en) 2012-01-13 2012-02-29 Lucite Int Uk Ltd A process for the production of ethylenically unsaturated carboxylic acids or esters and a catalyst therefor
CN103551148B (zh) * 2013-10-29 2015-08-05 西南化工研究设计院有限公司 一种用于羟醛缩合的耐水性催化剂及其制备方法和应用

Also Published As

Publication number Publication date
EP3283456A1 (en) 2018-02-21
EP3283456B1 (en) 2021-06-23
SG11201708390XA (en) 2017-11-29
WO2016166525A1 (en) 2016-10-20
KR20170137182A (ko) 2017-12-12
KR102658340B1 (ko) 2024-04-18
CA2982395C (en) 2024-03-12
MY188189A (en) 2021-11-24
MX2017013164A (es) 2018-05-22
EA201792279A1 (ru) 2018-04-30
TWI780025B (zh) 2022-10-11
ES2886902T3 (es) 2021-12-21
CA2982395A1 (en) 2016-10-20
US10464875B2 (en) 2019-11-05
EA036539B1 (ru) 2020-11-20
GB201506308D0 (en) 2015-05-27
US20180093937A1 (en) 2018-04-05
TW201636321A (zh) 2016-10-16
JP2018511636A (ja) 2018-04-26
JP6925978B2 (ja) 2021-08-25
CN107466289B (zh) 2021-09-17
BR112017021960A2 (pt) 2018-07-10
CN107466289A (zh) 2017-12-12
BR112017021960B1 (pt) 2021-07-13

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Legal Events

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MK4 Application lapsed section 142(2)(d) - no continuation fee paid for the application