CN107405289B - 化妆品 - Google Patents
化妆品 Download PDFInfo
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- CN107405289B CN107405289B CN201680011968.1A CN201680011968A CN107405289B CN 107405289 B CN107405289 B CN 107405289B CN 201680011968 A CN201680011968 A CN 201680011968A CN 107405289 B CN107405289 B CN 107405289B
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title description 2
- 239000000178 monomer Substances 0.000 claims abstract description 75
- 229920000642 polymer Polymers 0.000 claims abstract description 37
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 33
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 24
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 21
- 229910052731 fluorine Inorganic materials 0.000 claims abstract description 19
- 125000001153 fluoro group Chemical group F* 0.000 claims abstract description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 17
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 23
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 14
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims description 14
- 229960003237 betaine Drugs 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 14
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 9
- 239000003431 cross linking reagent Substances 0.000 claims description 7
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 77
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 57
- 239000003921 oil Substances 0.000 description 42
- 235000019198 oils Nutrition 0.000 description 42
- 210000002374 sebum Anatomy 0.000 description 29
- -1 2-ethylhexyl Chemical group 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 17
- 238000003786 synthesis reaction Methods 0.000 description 17
- ZQMHJBXHRFJKOT-UHFFFAOYSA-N methyl 2-[(1-methoxy-2-methyl-1-oxopropan-2-yl)diazenyl]-2-methylpropanoate Chemical compound COC(=O)C(C)(C)N=NC(C)(C)C(=O)OC ZQMHJBXHRFJKOT-UHFFFAOYSA-N 0.000 description 15
- 229910052757 nitrogen Inorganic materials 0.000 description 15
- 238000010992 reflux Methods 0.000 description 14
- 229920002125 Sokalan® Polymers 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 11
- 230000000475 sunscreen effect Effects 0.000 description 11
- 239000000516 sunscreening agent Substances 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 10
- 239000006071 cream Substances 0.000 description 10
- 239000002904 solvent Substances 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 9
- 238000009472 formulation Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 9
- 239000002304 perfume Substances 0.000 description 9
- 239000003505 polymerization initiator Substances 0.000 description 9
- 239000008213 purified water Substances 0.000 description 9
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 229960001484 edetic acid Drugs 0.000 description 8
- 239000011261 inert gas Substances 0.000 description 8
- 239000004615 ingredient Substances 0.000 description 8
- YBGZDTIWKVFICR-JLHYYAGUSA-N Octyl 4-methoxycinnamic acid Chemical compound CCCCC(CC)COC(=O)\C=C\C1=CC=C(OC)C=C1 YBGZDTIWKVFICR-JLHYYAGUSA-N 0.000 description 7
- 239000007877 V-601 Substances 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 6
- OBETXYAYXDNJHR-UHFFFAOYSA-N 2-Ethylhexanoic acid Chemical compound CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000008266 hair spray Substances 0.000 description 6
- 239000000230 xanthan gum Substances 0.000 description 6
- 229920001285 xanthan gum Polymers 0.000 description 6
- 229940082509 xanthan gum Drugs 0.000 description 6
- 235000010493 xanthan gum Nutrition 0.000 description 6
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 5
- FJKROLUGYXJWQN-UHFFFAOYSA-M 4-hydroxybenzoate Chemical compound OC1=CC=C(C([O-])=O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-M 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 5
- 229960001631 carbomer Drugs 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 description 5
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000839 emulsion Substances 0.000 description 5
- 210000004709 eyebrow Anatomy 0.000 description 5
- 210000004209 hair Anatomy 0.000 description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 229920002050 silicone resin Polymers 0.000 description 5
- FWFUWXVFYKCSQA-UHFFFAOYSA-M sodium;2-methyl-2-(prop-2-enoylamino)propane-1-sulfonate Chemical compound [Na+].[O-]S(=O)(=O)CC(C)(C)NC(=O)C=C FWFUWXVFYKCSQA-UHFFFAOYSA-M 0.000 description 5
- 230000002194 synthesizing effect Effects 0.000 description 5
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 4
- QZKRHPLGUJDVAR-UHFFFAOYSA-K EDTA trisodium salt Chemical compound [Na+].[Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O QZKRHPLGUJDVAR-UHFFFAOYSA-K 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 4
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 4
- 235000019437 butane-1,3-diol Nutrition 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 4
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000010445 mica Substances 0.000 description 4
- 229910052618 mica group Inorganic materials 0.000 description 4
- 230000003472 neutralizing effect Effects 0.000 description 4
- 229960005323 phenoxyethanol Drugs 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 3
- 240000000912 Macadamia tetraphylla Species 0.000 description 3
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- 239000000443 aerosol Substances 0.000 description 3
- 239000008346 aqueous phase Substances 0.000 description 3
- XNEFYCZVKIDDMS-UHFFFAOYSA-N avobenzone Chemical compound C1=CC(OC)=CC=C1C(=O)CC(=O)C1=CC=C(C(C)(C)C)C=C1 XNEFYCZVKIDDMS-UHFFFAOYSA-N 0.000 description 3
- 239000004359 castor oil Substances 0.000 description 3
- 235000019438 castor oil Nutrition 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 3
- 229940075507 glyceryl monostearate Drugs 0.000 description 3
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 3
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 3
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000010466 nut oil Substances 0.000 description 3
- 239000007764 o/w emulsion Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
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- 229940042596 viscoat Drugs 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 description 2
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- HCLJOFJIQIJXHS-UHFFFAOYSA-N 2-[2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOCCOC(=O)C=C HCLJOFJIQIJXHS-UHFFFAOYSA-N 0.000 description 2
- LTHJXDSHSVNJKG-UHFFFAOYSA-N 2-[2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOCCOC(=O)C(C)=C LTHJXDSHSVNJKG-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- MOMKYJPSVWEWPM-UHFFFAOYSA-N 4-(chloromethyl)-2-(4-methylphenyl)-1,3-thiazole Chemical compound C1=CC(C)=CC=C1C1=NC(CCl)=CS1 MOMKYJPSVWEWPM-UHFFFAOYSA-N 0.000 description 2
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
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- ZAKOWWREFLAJOT-CEFNRUSXSA-N D-alpha-tocopherylacetate Chemical compound CC(=O)OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C ZAKOWWREFLAJOT-CEFNRUSXSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
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- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
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- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
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- IWWCATWBROCMCW-UHFFFAOYSA-N batyl alcohol Natural products CCCCCCCCCCCCCCCCCCOC(O)CO IWWCATWBROCMCW-UHFFFAOYSA-N 0.000 description 2
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- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
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- YWIVKILSMZOHHF-QJZPQSOGSA-N sodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4r,5s,6r)-3-acetamido-2-[(2s,3s,4r,5r,6r)-6-[(2r,3r,4r,5s,6r)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2- Chemical compound [Na+].CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 YWIVKILSMZOHHF-QJZPQSOGSA-N 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
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- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
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- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
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- XFHJDMUEHUHAJW-UHFFFAOYSA-N n-tert-butylprop-2-enamide Chemical compound CC(C)(C)NC(=O)C=C XFHJDMUEHUHAJW-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
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- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
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- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
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- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 description 1
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- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
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- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UUJLHYCIMQOUKC-UHFFFAOYSA-N trimethyl-[oxo(trimethylsilylperoxy)silyl]peroxysilane Chemical compound C[Si](C)(C)OO[Si](=O)OO[Si](C)(C)C UUJLHYCIMQOUKC-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8123—Compositions of homopolymers or copolymers of compounds having one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers, e.g. PVC, PTFE
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Abstract
一种化妆品,其特征在于,含有使如下单体成分聚合而成的聚合物,所述单体成分含有:式(I)(式中,R1表示氢原子或甲基,R2表示氢原子或氟原子,m表示0或1~4的整数,n表示1~12的整数)所示的含氟原子单体;(B)式(II)(式中,R3表示氢原子或甲基,R4及R5各自独立地表示氢原子或碳数1~4的烷基,p表示1~4的整数,q表示1~4的整数)所示的甜菜碱单体;及(C)式(III)(式中,R6表示氢原子或甲基,R7表示碳数8~22的烷基)所示的(甲基)丙烯酸烷基酯。
Description
技术领域
本发明涉及化妆品。更详细而言,本发明涉及兼具拒水性及拒油性、耐水性及耐皮脂性优异的化妆品。
背景技术
对于化妆品、尤其是彩妆化妆品,期望防止经时的颜色暗淡及提高妆容持久性,对于防晒化妆品,期望提高妆容持久性。对于头发定型化妆品,期望提高定型力的持续性。为了对化妆品赋予这些性质,必须对化妆品赋予拒水性、拒油性及防止二次附着功能。
以往,为了对化妆品赋予拒水性、拒油性及防止二次附着功能,研究了通过提高化妆品中的油分的含有率来提高耐水性,通过降低化妆品中的油分的含有率来提高耐油性,对化妆品中使用的颜料实施疏水化处理(例如参照专利文献1)。
但是,前述化妆品均不仅防止经时的颜色暗淡效果或妆容持久性的效果不充分而且不兼具耐水性及耐油性,因此,近年来,期望开发出兼具拒水性及拒油性、耐水性及耐皮脂性优异的化妆品。
现有技术文献
专利文献
专利文献1:日本特开2005-232279号公报
发明内容
发明要解决的问题
本发明是鉴于前述现有技术而作成的,其课题在于,提供兼具拒水性及拒油性、耐水性及耐皮脂性优异的化妆品。
用于解决问题的方案
本发明涉及:
(1)一种化妆品,其特征在于,含有使下述单体成分聚合而成的聚合物,所述单体成分含有:(A)式(I)所示的含氟原子单体、(B)式(II)所示的甜菜碱单体、及(C)式(III)所示的(甲基)丙烯酸烷基酯,
(式(I)中,R1表示氢原子或甲基,R2表示氢原子或氟原子,m表示0或1~4的整数,n表示1~12的整数)
(式(II)中,R3表示氢原子或甲基,R4及R5各自独立地表示氢原子或碳数1~4的烷基,p表示1~4的整数,q表示1~4的整数)
(式(III)中,R6表示氢原子或甲基,R7表示碳数8~22的烷基);
(2)根据前述(1)所述的化妆品,其中,单体成分还含有具有磺酸基或磺酸盐基的单体;及
(3)根据前述(1)或(2)所述的化妆品,其中,单体成分还含有式(IV)所示的交联剂,
(式(IV)中,R8及R9各自独立地表示氢原子或甲基,R10表示碳数2或3的亚烷基,r表示1~40的整数)。
本发明中,“(甲基)丙烯酸酯”是指“丙烯酸酯”或“甲基丙烯酸酯”。
发明的效果
根据本发明,可提供兼具拒水性及拒油性、并且耐水性及耐皮脂性优异的化妆品。
具体实施方式
本发明的化妆品如前所述,其特征在于,含有使下述单体成分聚合而成的聚合物,所述单体成分含有:(A)式(I)所示的含氟原子单体、(B)式(II)所示的甜菜碱单体、及(C)式(III)所示的(甲基)丙烯酸烷基酯,
(式(I)中,R1表示氢原子或甲基,R2表示氢原子或氟原子,m表示0或1~4的整数,n表示1~12的整数)
(式(II)中,R3表示氢原子或甲基,R4及R5各自独立地表示氢原子或碳数1~4的烷基,p表示1~4的整数,q表示1~4的整数)
(式(III)中,R6表示氢原子或甲基,R7表示碳数8~22的烷基)。
在式(I)所示的含氟原子单体中,R1为氢原子或甲基,R2为氢原子或氟原子,m为0或1~4的整数,n为1~12的整数。
m为0或1~4的整数,从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为1~4的整数、更优选为2~4的整数。n为1~12的整数,从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为2~10的整数、更优选为4~8的整数。
作为式(I)所示的含氟原子单体,例如可列举出2-全氟己基-2-乙基丙烯酸酯等,但本发明不仅限定于所述例示。式(I)所示的含氟原子单体可以为商业上容易获得的单体,作为其例子,可列举出:在式(I)中,R1为氢原子,R2为氟原子,m为2、n为6的含氟原子单体〔例如,大阪有机化学工业株式会社制、商品名:Viscoat 13F等〕;R1为氢原子、R2为氢原子、m为1、n为1的含氟原子单体〔例如,大阪有机化学工业株式会社制、商品名:Viscoat 4F等〕;R1为甲基、R2为氢原子、m为1、n为3的含氟原子单体〔例如,大阪有机化学工业株式会社制、商品名:Viscoat 8FM等〕等,但本发明不仅限定于所述例示。
对于单体成分中的式(I)所示的含氟原子单体的含有率,从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为1~30质量%、更优选为1~25质量%、进一步优选为2~20质量%。
式(II)所示的甜菜碱单体中,R3为氢原子或甲基,R4及R5各自独立地为氢原子或碳数1~4的烷基,p为1~4的整数,q为1~4的整数。
作为式(II)所示的甜菜碱单体,例如可列举出:N-(甲基)丙烯酰氧基甲基-N,N-二甲基铵-α-N-甲基羧基甜菜碱、N-(甲基)丙烯酰氧基乙基-N,N-二甲基铵-α-N-甲基羧基甜菜碱、N-(甲基)丙烯酰氧基丙基-N,N-二甲基铵-α-N-甲基羧基甜菜碱、N-(甲基)丙烯酰氧基甲基-N,N-二乙基铵-α-N-甲基羧基甜菜碱、N-(甲基)丙烯酰氧基乙基-N,N-二乙基铵-α-N-甲基羧基甜菜碱、N-(甲基)丙烯酰氧基丙基-N,N-二乙基铵-α-N-甲基羧基甜菜碱等,但本发明不仅限定于所述例示。这些甜菜碱单体可以分别单独使用,也可以组合使用2种以上。
式(II)所示的甜菜碱单体可以通过例如日本特开平9-95474号公报、日本特开平9-95586号公报、日本特开平11-222470号公报等中记载的方法容易地制备。
对于式(II)所示的甜菜碱单体,例如可以作为大阪有机化学工业株式会社制、商品名:GLBT等容易地从商业上获得。
式(II)所示的甜菜碱单体中,从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选N-甲基丙烯酰氧基乙基-N,N-二甲基铵-α-N-甲基羧基甜菜碱。
对于单体成分中的式(II)所示的甜菜碱单体的含有率,从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为3~80质量%、更优选为3~75质量%、进一步优选为5~70质量%。
式(III)所示的(甲基)丙烯酸烷基酯中,R6为氢原子或甲基,R7为碳数8~22的烷基。
作为式(III)所示的(甲基)丙烯酸烷基酯,例如可列举出(甲基)丙烯酸-2-乙基己酯、(甲基)丙烯酸正辛酯、(甲基)丙烯酸异辛酯、(甲基)丙烯酸正壬酯、(甲基)丙烯酸异壬酯、(甲基)丙烯酸-2-乙基己酯、(甲基)丙烯酸癸酯、(甲基)丙烯酸月桂酯、(甲基)丙烯酸十三烷基酯、(甲基)丙烯酸十四烷基酯、(甲基)丙烯酸十六烷基酯、(甲基)丙烯酸十八烷基酯、(甲基)丙烯酸异硬脂基酯、(甲基)丙烯酸二十烷基酯等构成酯的烷基的碳数为8~22的(甲基)丙烯酸烷基酯等,但本发明不仅限定于所述例示。这些(甲基)丙烯酸烷基酯可以分别单独使用,也可以组合使用2种以上。
对于单体成分中的式(III)所示的(甲基)丙烯酸烷基酯的含有率,从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为10~80质量%、更优选为15~75质量%、进一步优选为20~70质量%。
从提高拒油性的观点出发,优选单体成分中含有具有磺酸基或磺酸盐基的单体。
作为具有磺酸基的单体,例如可列举出:丙烯酰基二甲基牛磺酸钠、甲基丙烯酰基二甲基牛磺酸钠、2-丙烯酰胺-2-甲基丙烷磺酸、2-甲基丙烯酰胺-2-甲基丙烷磺酸、2-丙烯酰胺-2-乙基丙烷磺酸、2-甲基丙烯酰胺-2-乙基丙烷磺酸、2-丙烯酰胺-2-丙基丙烷磺酸、2-甲基丙烯酰胺-2-丙基丙烷磺酸等,但本发明不仅限定于所述例示。这些含磺酸基单体可以分别单独使用,也可以组合使用2种以上。
具有磺酸盐基的单体从提高拒油性的观点出发是优选的。具有磺酸盐基的单体的磺酸盐基例如可以通过用三乙醇胺等中和剂将含磺酸基单体中和来形成。含磺酸基单体所具有的磺酸基的中和可以在该含磺酸基单体的阶段进行,也可以对通过使单体成分聚合而得到的聚合物进行。
对于单体成分中的具有磺酸基或磺酸盐基的单体的含有率,从提高拒油性的观点出发,优选为0质量%以上、更优选为1质量%以上、进一步优选为3质量%以上、更进一步优选为5质量%以上;从提高拒水性的观点出发,优选为40质量%以下、更优选为35质量%以下、进一步优选为30质量%以下。
单体成分中在不阻碍本发明的目的的范围内可以含有其他单体。
作为其他单体,例如可列举出丙烯酸、甲基丙烯酸、衣康酸、马来酸酐等脂肪族单羧酸;丙烯酸-2-羟基乙酯、甲基丙烯酸-2-羟基乙酯、丙烯酸羟基丙酯、甲基丙烯酸羟基丙酯、丙烯酸羟基丁酯、甲基丙烯酸羟基丁酯等(甲基)丙烯酸羟基烷基酯;丙烯酸环己酯、甲基丙烯酸环己酯等(甲基)丙烯酸环烷基酯;丙烯酸苄酯、甲基丙烯酸苄酯等(甲基)丙烯酸芳基酯;丙烯酸甲氧基乙基酯、甲基丙烯酸甲氧基乙基酯、丙烯酸甲氧基丁酯、甲基丙烯酸甲氧基丁基酯等(甲基)丙烯酸烷氧基烷基酯;乙基卡必醇丙烯酸酯、乙基卡必醇甲基丙烯酸酯等烷基卡必醇(甲基)丙烯酸酯;N-甲基丙烯酰胺、N-甲基甲基丙烯酰胺、N-乙基丙烯酰胺、N-乙基甲基丙烯酰胺、N-丙基丙烯酰胺、N-丙基甲基丙烯酰胺、N-异丙基丙烯酰胺、N-异丙基甲基丙烯酰胺、N-叔丁基丙烯酰胺、N-叔丁基甲基丙烯酰胺、N-辛基丙烯酰胺、N-辛基甲基丙烯酰胺、N,N-二甲基丙烯酰胺、N,N-二甲基甲基丙烯酰胺、N,N-二乙基丙烯酰胺、N,N-二乙基甲基丙烯酰胺等烷基(甲基)丙烯酰胺;N-丁氧基甲基丙烯酰胺、N-丁氧基甲基甲基丙烯酰胺等烷氧基(甲基)丙烯酰胺;丙烯酰基吗啉、甲基丙烯酰基吗啉等(甲基)丙烯酰基吗啉;双丙酮丙烯酰胺、双丙酮甲基丙烯酰胺等双丙酮(甲基)丙烯酰胺;苯乙烯、甲基苯乙烯等苯乙烯系单体;衣康酸甲酯、衣康酸乙酯等除(甲基)丙烯酸烷基酯以外的烷基的碳数为1~4的脂肪酸烷基酯;乙酸乙烯酯、丙酸乙烯酯等脂肪酸乙烯基酯;N-乙烯基吡咯烷酮、N-乙烯基己内酰胺等含氮原子单体等单官能单体等,但本发明不仅限定于所述例示。这些其他单体可以分别单独使用,也可以组合使用2种以上。
从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选单体成分中含有式(IV)所示的交联剂,
(式(IV)中,R8及R9各自独立地表示氢原子或甲基,R10表示碳数2或3的亚烷基,r表示1~40的整数)。
式(IV)中,R8及R9各自独立地为氢原子或甲基,R10为碳数2或3的亚烷基,r为1~40的整数。从赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,r优选为1~20的整数、更优选为2~18的整数。
作为式(IV)所示的交联剂,例如可列举出乙二醇二丙烯酸酯、乙二醇二甲基丙烯酸酯、二乙二醇二丙烯酸酯、二乙二醇二甲基丙烯酸酯、三乙二醇二丙烯酸酯、三乙二醇二甲基丙烯酸酯、四乙二醇二丙烯酸酯、四乙二醇二甲基丙烯酸酯、除前述以外的聚乙二醇二丙烯酸酯、除前述以外的聚乙二醇二甲基丙烯酸酯等(聚)乙二醇二(甲基)丙烯酸酯;丙二醇二丙烯酸酯、丙二醇二甲基丙烯酸酯、二丙二醇二丙烯酸酯、二丙二醇二甲基丙烯酸酯、三丙二醇二丙烯酸酯、三丙二醇二甲基丙烯酸酯、四丙二醇二丙烯酸酯、四丙二醇二甲基丙烯酸酯、除前述以外的聚丙二醇二丙烯酸酯、除前述以外的聚丙二醇二甲基丙烯酸酯等(聚)丙二醇二(甲基)丙烯酸酯等,但本发明不仅限定于所述例示。这些交联剂可以分别单独使用,也可以组合使用2种以上。
对于单体成分中的交联剂的含有率,从提高拒水性、拒油性及拒油持续性、并且赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为0.3~15质量%、更优选为0.5~15质量%、进一步优选为1~10质量%。
使单体成分聚合时,为了调整要得到的聚合物的分子量,可以使用链转移剂。作为链转移剂,例如可列举出月桂基硫醇、十二烷基硫醇、硫代甘油等具有硫醇基的化合物、次磷酸钠、亚硫酸氢钠等无机盐等,但本发明不仅限定于所述例示。每100质量份单体成分的链转移剂的量优选为0.01~10质量份左右。
单体成分的聚合可以通过例如均相溶液聚合法、不均相溶液聚合法、乳液聚合法、反相乳液聚合法、本体聚合法、悬浮聚合法、沉淀聚合法等聚合法进行。
通过溶液聚合法使单体成分聚合时,可以使用溶剂。作为前述溶剂,例如可列举出甲醇、乙醇、丙醇、异丙醇、丁醇等醇系溶剂;己烷、庚烷、辛烷、异辛烷、癸烷、液体石蜡等烃系溶剂;甲醚、乙醚、四氢呋喃等醚系溶剂;丙酮、甲乙酮等酮系溶剂;乙酸甲酯、乙酸乙酯、乙酸丁酯等酯系溶剂;二氯甲烷、氯仿、四氯化碳等氯化物系溶剂;二甲基甲酰胺、二乙基甲酰胺、二甲基亚砜、二恶烷等,但本发明不仅限定于所述例示。这些溶剂可以分别单独使用,也可以组合使用2种以上。溶剂的量根据该溶剂的种类而异,因此不能一概地限定,通常优选每100质量份单体成分为100~1000质量份左右。
使单体成分聚合时,可以使用聚合引发剂。作为聚合引发剂,例如可列举出热聚合引发剂、光聚合引发剂等。
作为热聚合引发剂,例如可列举出二甲基-2,2’-偶氮双(2-甲基丙酸酯)、偶氮异丁腈、偶氮异丁酸甲酯、偶氮双(二甲基戊腈)等偶氮系聚合引发剂、过氧化苯甲酰、过硫酸钾、过硫酸铵等过氧化物系聚合引发剂等,但本发明不仅限定于所述例示。这些聚合引发剂可以分别单独使用,也可以组合使用2种以上。
作为光聚合引发剂,例如可列举出2-氧代戊二酸、1-羟基环己基苯基酮、2-羟基-2-甲基-1-苯基丙烷-1-酮、2-甲基[4-(甲硫基)苯基]-2-吗啉代丙烷-1-酮、2,2-二甲氧基-1,2-二苯基乙烷-1-酮、二苯甲酮、1-[4-(2-羟基乙氧基)苯基]-2-羟基-2-甲基1-丙烷-1-酮、2-苄基-2-二甲基氨基-1-(4-吗啉代苯基)丁烷-1-酮、双(2,6-二甲氧基苯甲酰基)-2,4,4-三甲基戊基氧化膦等,但本发明不仅限定于所述例示。这些聚合引发剂可以分别单独使用,也可以组合使用2种以上。
聚合引发剂的量根据该聚合引发剂的种类等而异,因此不能一概地决定,通常优选每100质量份单体成分为0.01~10质量份左右。
对使单体成分聚合时的气氛没有特别限定,可以为大气,或者也可以为氮气、氩气等非活性气体。
对单体成分的聚合温度没有特别限定,通常优选为5~80℃左右的温度。单体成分的聚合所需的时间根据聚合条件而异,因此不能一概地决定,故为任意的。聚合反应通常可以在残留的单体的量变为10质量%以下的时刻任意结束。残留的单体的量例如可以通过使单体的双键加成碘、测定双键含量来决定。
通过以上那样操作使单体成分聚合从而得到聚合物。对前述聚合物的重均分子量没有特别限制,优选为3000~10万左右。前述聚合物的重均分子量为通过凝胶渗透色谱法(GPC)测定时的值。单体成分中含有交联剂的情况下,得到的聚合物具有交联结构,因此难以测定聚合物的重均分子量。
前述聚合物根据需要可以如前所述那样进行中和。作为中和剂,例如可列举出三乙醇胺、二甲基乙醇胺、二乙基乙醇胺、吗啉、氨水、氢氧化钠等,但本发明不仅限定于所述例示。这些中和剂可以分别单独使用,也可以组合使用2种以上。
前述聚合物根据其用途等可以以其原样的状态使用,但为了将溶剂、未反应单体等去除,根据需要可以通过例如蒸馏、提取等纯化方法进行纯化。
本发明的化妆品的特征在于,含有前述聚合物。本发明的化妆品可以通过在化妆品的处方中配混前述聚合物来制备。对于本发明的化妆品中的前述聚合物的含有率,从具有期望的处方并且赋予拒水性及拒油性、提高耐水性及耐皮脂性的观点出发,优选为1~95质量%、更优选为5~95质量%。
本发明的化妆品除了含有前述聚合物以外,还可以在不阻碍本发明的效果的范围内含有通常化妆品中使用的成分例如水、油剂、表面活性剂、粘剂、防腐剂、香料、紫外线吸收剂、保湿剂、生理活性成分、盐类、抗氧化剂、螯合剂、中和剂、pH调节剂等。
如以上那样操作而得到的本发明的化妆品具有拒水性及拒油性,耐水性及耐皮脂性优异,因此可以适当地用于各种化妆品。
作为本发明的化妆品的剂型,例如可列举出粉底、底妆、白粉、口红、眼影、腮红、眉毛膏、眼线笔等彩妆化妆品、防晒剂、防晒霜、隔离霜、发膏、乳液、啫喱、眉毛膏、喷发剂、发蜡、外涂剂等,但本发明不仅限定于所述例示。
实施例
接着,基于实施例更详细地对本发明进行说明,但本发明并不仅限定于所述实施例。
合成例1
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入2-全氟己基-2-乙基丙烯酸酯10g、N-甲基丙烯酰氧基乙基-N,N-二甲基铵-N-α-甲基羧基甜菜碱5g、丙烯酰基二甲基牛磺酸钠10g、丙烯酸-2-乙基己酯70g、十三烷基乙二醇二甲基丙烯酸酯5g及乙醇2340g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入至烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
合成例2
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入2-全氟己基-2-乙基丙烯酸酯10g、N-甲基丙烯酰氧基乙基-N,N-二甲基铵-N-α-甲基羧基甜菜碱5g、丙烯酰基二甲基牛磺酸钠10g、丙烯酸-2-乙基己酯70g、四乙二醇二甲基丙烯酸酯5g及乙醇234.0g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
合成例3
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入2-全氟己基-2-乙基丙烯酸酯10g、N-甲基丙烯酰氧基乙基-N,N-二甲基铵-N-α-甲基羧基甜菜碱5g、丙烯酰基二甲基牛磺酸钠10g、丙烯酸-2-乙基己酯65g、三丙二醇二丙烯酸酯10g及乙醇2340g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
比较合成例1
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入N-甲基丙烯酰氧基乙基-N,N-二甲基铵-N-α-甲基羧基甜菜碱20g、丙烯酸-2-乙基己酯80g及乙醇234.0g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
比较合成例2
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入2-全氟己基-2-乙基丙烯酸酯10g、丙烯酸-2-乙基己酯90g及乙醇2340g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
比较合成例3
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入2-全氟己基-2-乙基丙烯酸酯20g、N-甲基丙烯酰氧基乙基-N,N-二甲基铵-N-α-甲基羧基甜菜碱80g及乙醇234.0g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
比较合成例4
向安装有搅拌装置、非活性气体导入口、回流冷凝管及温度计的500mL容量的5口烧瓶内加入2-全氟己基-2-乙基丙烯酸酯10g、N-甲基丙烯酰氧基乙基-N,N-二甲基铵-N-α-甲基羧基甜菜碱20g、丙烯酸丁酯70g及乙醇2340g。将烧瓶的内容物升温至75℃后,将二甲基-2,2’-偶氮双(2-甲基丙酸酯)〔和光纯药工业株式会社制、型号:V-601〕0.6g加入烧瓶内,边在回流条件下搅拌8小时边进行聚合反应,由此合成聚合物。
实施例1~5及比较例1~6
通过将表1或表2所示的成分1~6混合来制备水相。接着,向前述得到的水相中添加表1或表2所示的成分7~15,由此得到化妆品。需要说明的是,成分7作为成分8~15的溶剂而使用。
实施例6~10及比较例7~12
通过将表3或表4所示的成分1~7混合来制备水相。接着,向前述中得到的水相中添加表3或表4所示的成分8~16,接着添加由成分17~22形成的油相并进行乳化,由此得到化妆品。需要说明的是,成分8作为成分9~16的溶剂而使用。
接着,对于前述中得到的化妆品的物性,基于以下的方法对接触角、耐水性及耐皮脂性进行评价。将其结果记载于各表。
〔接触角〕
用刮刀将各实施例或各比较例中得到的化妆品的乙醇溶液(聚合物的含有率:20质量%)涂布在玻璃基板上并使其在室温下充分干燥。
接着,使用接触角测定装置〔协和界面科学(株式会社)制、型号:DM-501〕,在前述测定试样上各自以2μL的量滴加水或液态油(澳洲坚果油),各1滴滴加后经过1秒钟时测量接触角。
〔耐水性〕
由20名专家组成员目视观察将各实施例或各比较例中得到的化妆品20μL分别涂布到前腕部的3cm×3cm的范围内并均匀地涂开后、在室温下充分干燥后用流水清洗涂布部时的各化妆品的脱落情况,基于以下的评价基准对耐水性进行评价。
(评价基准)
A:回答化妆品“未脱落”或“不易脱落”的人数为16人以上
B:回答化妆品“未脱落”或“不易脱落”的人数为10~15人
C:回答化妆品“未脱落”或“不易脱落”的人数为9人以下
〔耐皮脂性〕
将各实施例或各比较例中得到的化妆品20μL分别涂布到前腕部的3cm×3cm的范围内并均匀地涂开后,在室温下充分干燥后,在涂布部适量地涂布液态油(澳洲坚果油)并充分涂匀。然后,由20名专家组成员目视观察用纸巾擦拭液态油时的各化妆品的脱落情况,基于以下的评价基准对耐皮脂性进行评价。
(评价基准)
A:回答化妆品“未脱落”或“不易脱落”的人数为16人以上
B:回答化妆品“未脱落”或“不易脱落”的人数为10~15人
C:回答化妆品“未脱落”或“不易脱落”的人数为9人以下
[表1]
(注)
“依地酸”:乙二胺四乙酸
“卡波姆”:羧基乙烯基聚合物
[表2]
(注)
“依地酸”:乙二胺四乙酸
“卡波姆”:羧基乙烯基聚合物
[表3]
(注)
“依地酸”:乙二胺四乙酸
“卡波姆”:羧基乙烯基聚合物
[表4]
(注)
“依地酸”:乙二胺四乙酸
“卡波姆”:羧基乙烯基聚合物
根据表1~4所示的结果可知,各实施例中得到的化妆品的水及液态油的接触角非常高,而且耐水性及耐皮脂优异。与此相对,可知各比较例中得到的化妆品的水及液态油的接触角低,耐水性及耐皮脂性差。
接着,以下记载本发明的化妆品的处方例,但本发明不仅限定于所述例示。
处方例1〔防晒霜〕
将以下各成分混合,由此制备防晒霜。确认到了所得防晒霜具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 8质量份
(3)二甲基聚硅氧烷 5质量份
(4)十甲基环五硅氧烷 25质量份
(5)三甲基硅烷氧基硅酸酯 5质量份
(6)聚氧乙烯-甲基聚硅氧烷共聚物 2质量份
(7)二丙二醇 5质量份
(7)细颗粒氧化锌 15质量份
(8)对羟基苯甲酸酯 适量
(9)苯氧基乙醇 适量
(10)乙二胺四乙酸三钠盐 适量
(11)对甲氧基肉桂酸2-乙基己酯 7.5质量份
(12)二甲基二硬脂基铵锂蒙脱石 0.5质量份
(13)球状聚丙烯酸烷基酯粉末 5质量份
(14)香料 适量
(15)纯化水 余量
处方例2〔防晒乳液〕
将以下各成分以总量成为100质量份的方式混合,由此制备防晒乳液。确认到了所得防晒乳液具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 8质量份
(3)凡士林 1质量份
(4)二甲基聚硅氧烷 3质量份
(5)甲基苯基聚硅氧烷 3质量份
(6)硬脂醇 0.5质量份
(7)甘油 7质量份
(8)二丙二醇 3质量份
(9)1,3-丁二醇 7质量份
(10)木糖醇 3质量份
(11)角鲨烷 1质量份
(12)异硬脂酸 0.5质量份
(13)硬脂酸 0.5质量份
(14)单硬脂酸聚氧乙烯甘油酯 1质量份
(15)单硬脂酸甘油酯 2质量份
(16)氢氧化钾 0.05质量份
(17)磷酸L-抗坏血酸镁 0.1质量份
(18)生育酚乙酸酯 0.1质量份
(19)乙酰化透明质酸钠 0.1质量份
(20)乙二胺四乙酸三钠盐 0.05质量份
(21)4-叔丁基-4'-甲氧基二苯甲酰基甲烷 2质量份(22)对甲氧基肉桂酸2-乙基己酯 5质量份
(23)羧基乙烯基聚合物 0.1质量份
(24)苯氧基乙醇 适量
(25)香料 适量
(26)纯化水 余量
处方例3〔防晒啫喱〕
将以下各成分以总量成为100质量份的方式混合,由此制备防晒啫喱。确认到了所得防晒啫喱具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 15质量份
(3)丁二醇 5质量份
(4)三乙醇胺 0.1质量份
(5)苯氧基乙醇 适量
(6)乙二胺四乙酸二钠盐 适量
(7)PEGPPG-19/19聚二甲基硅氧烷 4质量份
(8)PEG-60甘油异硬脂酸酯 0.1质量份
(9)甲氧基肉桂酸乙基己酯 5质量份
(10)奥克立林 2质量份
(11)双-乙基己氧苯酚甲氧苯基三嗪 3质量份
(12)黄原胶 0.1质量份
(13)丙烯酸-丙烯酸烷基酯(烷基的碳数:10-30)共聚合物 0.1质量份
(14)卡波姆 0.1质量份
(15)香料 适量
(16)氨甲环酸 2质量份
(17)滑石 3质量份
(18)氧苯酮 1质量份
(19)纯化水 余量
处方例4〔眉毛膏〕
将以下各成分以总量成为100质量份的方式混合,由此制备眉毛膏。确认到了所得眉毛膏具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)甲基聚硅氧烷乳液 适量
(3)乙醇 8质量份
(4)异丙醇 3质量份
(5)甘油 3质量份
(6)1,3-丁二醇 5质量份
(7)无水硅酸 1质量份
(8)氧化铁红被覆云母钛(珠光剂) 9质量份
(9)强氨水 0.1质量份
(10)偏磷酸钠 0.1质量份
(11)水解小麦蛋白 0.1质量份
(12)对羟基苯甲酸酯 适量
(13)脱氢乙酸钠 适量
(14)黑氧化铁(颜料) 1质量份
(15)黄原胶 1质量份
(16)硅酸铝镁 2质量份
(17)羧甲基纤维素钠 1质量份
(18)丙烯酸烷基系树脂乳液 10质量份
(19)纯化水 余量
处方例5〔粉底〕
将以下各成分以总量成为100质量份的方式混合,由此粉底制备。确认到了所得粉底具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 8质量份
(3)二甲基聚硅氧烷 8质量份
(4)山萮醇 0.5质量份
(5)鲨肝醇 0.5质量份
(6)1,3-丁二醇 5质量份
(7)澳洲坚果油 0.1质量份
(8)异硬脂酸 1.5质量份
(9)硬脂酸 1质量份
(10)山萮酸 0.5质量份
(11)2-乙基己酸鲸蜡酯 5质量份
(12)单硬脂酸聚氧乙烯甘油酯 1质量份
(13)自乳化型单硬脂酸甘油酯 1质量份
(14)黄氧化铁被覆云母钛 2质量份
(15)氧化钛 4质量份
(16)滑石 0.5质量份
(17)高岭土 3质量份
(18)合成金云母 0.1质量份
(19)交联型有机硅粉末 0.1质量份
(20)无水硅酸 5质量份
(21)氢氧化钾 0.2质量份
(22)三乙醇胺 0.8质量份
(23)乙酸DL-α-生育酚 0.1质量份
(24)透明质酸钠 0.1质量份
(25)对羟基苯甲酸酯 适量
(26)对甲氧基肉桂酸2-乙基己酯 1质量份(27)氧化铁红 适量
(28)黄氧化铁 适量
(29)黑氧化铁 适量
(30)黄原胶 0.1质量份
(31)膨润土 1质量份
(32)羧甲基纤维素钠 0.1质量份
(33)香料 适量
(34)纯化水 余量
处方例6〔水包油型乳液粉底〕
将以下各成分以总量成为100质量份的方式混合,由此制备水包油型乳液粉底。确认到了所得水包油型乳液粉底具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)烷基改性有机硅树脂被覆氧化钛 9质量份
(3)烷基改性有机硅树脂被覆超细颗粒氧化钛 5质量份
(4)烷基改性有机硅树脂被覆氧化铁(红) 0.5质量份
(5)烷基改性有机硅树脂被覆氧化铁(黄) 1.5质量份
(6)烷基改性有机硅树脂被覆氧化铁(黑) 0.2质量份
(7)聚氧亚烷基改性有机聚硅氧烷 0.5质量份
(8)十甲基环五硅氧烷 5质量份
(9)对甲氧基肉桂酸辛酯 5质量份
(10)丙烯酸类有机硅 4质量份
(11)PEG-100氢化蓖麻油 2质量份
(12)达纳炸药用甘油 6质量份
(13)黄原胶 适量
(14)羧甲基纤维素 适量
(15)丙烯酰基二甲基牛磺酸钠/丙烯酸羟基乙酯共聚物 0.5质量份
(16)乙醇 8质量份
(17)离子交换水 余量
处方例7〔底妆〕
将以下各成分以总量成为100质量份的方式混合,由此底妆制备。确认到了所得底妆具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 8质量份
(3)α-烯烃低聚物 10质量份
(4)二甲基聚硅氧烷 5质量份
(5)山萮醇 0.5质量份
(6)鲨肝醇 0.5质量份
(7)1,3-丁二醇 5质量份
(8)异硬脂酸 1质量份
(9)硬脂酸 1质量份
(10)山萮酸 1质量份
(11)2-乙基己酸鲸蜡酯 2质量份
(12)N-月桂酰基-L-谷氨酸二(植物甾醇·2-辛基十二烷基)酯 0.1质量份
(13)单硬脂酸聚氧乙烯甘油酯 2质量份
(14)自乳化型单硬脂酸甘油酯 0.5质量份
(15)滑石 0.5质量份
(16)云母钛 0.5质量份
(17)黑氧化铁被覆云母钛 0.1质量份
(18)氢氧化钾 0.2质量份
(19)偏磷酸钠 0.5质量份
(20)生育酚乙酸酯 0.1质量份
(21)对羟基苯甲酸酯 适量
(22)对甲氧基肉桂酸2-乙基己酯 3质量份
(23)有色颜料 适量
(24)黄原胶 0.1质量份
(25)膨润土 1质量份
(26)羧甲基纤维素钠 0.1质量份
(27)球状聚丙烯酸烷基粉末 0.1质量份
(28)球状无水硅酸 5质量份
(29)氧化钛 5质量份
(30)香料 适量
(31)纯化水 余量
处方例8〔喷发剂〕
将以下各成分以总量成为100质量份的方式混合,由此制备喷发剂的原液。将所得喷发剂的原液92质量份及喷射剂(液化石油气体)8质量份以填充压成为0.43MPa的方式填充至气雾剂容器内,由此制作气雾剂制品。由所得气雾剂制品喷射喷发剂后,确认到了该喷发剂具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 8质量份
(3)两性离子性聚合物〔三菱化学株式会社制、商品名:Yukaformer SM〕
12质量份
(4)乙烯基吡咯烷酮-N,N-二甲基氨基乙基甲基丙烯酸酯共聚物 5质量份
(5)2-烷基-N-羧甲基-N-羟基乙基米唑鎓甜菜碱1质量份
(6)聚氧乙烯氢化蓖麻油(氧化乙烯基的加成摩尔数:60摩尔) 0.5质量份
(7)氯化烷基三甲基铵 0.2质量份
(8)对甲氧基苯甲酸酯 适量
(9)香料 适量
(10)纯化水 余量
处方例9〔发蜡〕
将以下各成分以总量成为100质量份的方式混合,由此制备发蜡。确认到了所得发蜡具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)合成例1中得到的聚合物 2质量份
(2)乙醇 8质量份
(3)聚乙二醇(平均分子量:400) 3质量份
(4)2-乙基己酸鲸蜡酯 0.5质量份
(5)聚氧乙烯氢化蓖麻油 0.15质量份
(6)氢氧化钠 0.1质量份
(7)对羟基苯甲酸酯 适量
(8)乙二胺四乙酸三钠盐 适量
(9)凝胶多糖 0.6质量份
(10)黄原胶 0.1质量份
(11)甜菜碱聚合物〔三菱化学株式会社制、商品名:Yukaformer 301〕10质量份
(12)羧基乙烯基聚合物 0.5质量份
(13)香料 适量
(14)纯化水 余量
处方例10〔外涂剂〕
将以下各成分以总量成为100质量份的方式混合,由此制备外涂剂。确认到了所得外涂剂具有拒水性及拒油性,耐水性及耐皮脂性优异。
(1)乙二胺四乙酸三钠盐 0.1质量份
(2)甘油 5质量份
(3)二丙二醇 5质量份
(4)苯氧基乙醇 0.5质量份
(5)(二甲基丙烯酰胺/丙烯酰基二甲基牛磺酸钠)交联聚合物 0.4质量份
(6)乙醇 8质量份
(7)合成例1中得到的聚合物 2质量份
(8)香料 适量
(9)纯化水 余量
Claims (3)
2.根据权利要求1所述的化妆品,其中,单体成分还含有具有磺酸基或磺酸盐基的单体。
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