CN107384556A - 一种环境容许型生物基润滑油及其制备方法 - Google Patents

一种环境容许型生物基润滑油及其制备方法 Download PDF

Info

Publication number
CN107384556A
CN107384556A CN201710687642.7A CN201710687642A CN107384556A CN 107384556 A CN107384556 A CN 107384556A CN 201710687642 A CN201710687642 A CN 201710687642A CN 107384556 A CN107384556 A CN 107384556A
Authority
CN
China
Prior art keywords
parts
lubricating oil
oil
wear
bio
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201710687642.7A
Other languages
English (en)
Inventor
朱剑
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WUJIANG HUAWEI SPECIAL OIL Co Ltd
Original Assignee
WUJIANG HUAWEI SPECIAL OIL Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by WUJIANG HUAWEI SPECIAL OIL Co Ltd filed Critical WUJIANG HUAWEI SPECIAL OIL Co Ltd
Priority to CN201710687642.7A priority Critical patent/CN107384556A/zh
Publication of CN107384556A publication Critical patent/CN107384556A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06—Metal compounds
    • C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C10M2207/2835—Esters of polyhydroxy compounds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/286—Esters of polymerised unsaturated acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/401—Fatty vegetable or animal oils used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40—Fatty vegetable or animal oils
    • C10M2207/402—Castor oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/086—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type polycarboxylic, e.g. maleic acid
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08—Halogenated waxes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/08—Amides
    • C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C10M2215/224—Imidazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/28—Amides; Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
    • C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
    • C10M2219/066—Thiocarbamic type compounds
    • C10M2219/068—Thiocarbamate metal salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00—Metal present as such or in compounds
    • C10N2010/12—Groups 6 or 16
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明公开了一种环境容许型生物基润滑油，其由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯10~20份、降凝剂1~3份、极压抗磨助剂3~6份、十七烯基咪唑啉0.1~0.5份、氯化石蜡5~8份、乙酸冰片酯2~5份、烷醇酰胺0.1~0.3份、二烷基二苯胺0.1~0.3份、气相二氧化钛1~3份、单聚异丁烯丁二酞亚胺1~4份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为5~7：2~4:1。本发明避免了矿物基基础油的添加，最大限度的避免了润滑油的使用对环境造成的影响，所得润滑油综合润滑性能良好，具有较高的经济价值和社会价值，同时适合工业化生产和使用。

Description

一种环境容许型生物基润滑油及其制备方法
技术领域
本发明涉及润滑油技术领域，具体涉及一种环境容许型生物基润滑油及其制备方法。
背景技术
随着人们的环境危机意识日益增强，人们普遍认识到大量润滑油在生产、使用和排放过程中由于渗透、泄漏、溢出和处理不当，而造成的环境污染问题越来越严重，从社会发展的趋势来看，环境容许型润滑油及其添加剂将逐步取代现有的润滑油。
环境容许型润滑油是指在较短的时间内可被活性微生物分解为水和二氧化碳的润滑油，其具有以下特点：具有良好的润滑性能，可通过节约能耗来减少环境污染；产品自身对环境无毒害、影响小；产品能被生物降解，可以分解为简单的CO2和水而被环境吸收而无危害。
生物基润滑油主要以植物油为主，与传统矿物润滑油相比，植物油天然的可再生和可生物降解性能可提供明显的环境和经济可持续发展的好处，而且植物油同时具有挥发性低、闪点高、粘度指数高以及润滑性优异等优势。因此，以植物油为主要来源的生物基润滑油就成为了环保润滑油的主要力量。然而，如何克服植物油氧化稳定性差、低温流动性差和水解安定性差的问题成为了限制生物基润滑油发展的主要障碍。
发明内容
针对现有技术不足，本发明提供了一种使用性能良好的环境容许型生物基润滑油及其制备方法。
本发明解决上述技术问题采用的技术方案为：一种环境容许型生物基润滑油，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯10~20份、降凝剂1~3份、极压抗磨助剂3~6份、十七烯基咪唑啉0.1~0.5份、氯化石蜡5~8份、乙酸冰片酯2~5份、烷醇酰胺0.1~0.3份、二烷基二苯胺0.1~0.3份、气相二氧化钛1~3份、单聚异丁烯丁二酞亚胺1~4份；
所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为5~7：2~4:1。
进一步地，所述的耐磨合成酯为二聚亚油酸乙二醇酯、季戊四醇四油酸酯、棕榈酸异辛酯、三羟甲基丙烷油酸酯中的一种或几种。
进一步地，所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂。
进一步地，所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为1:1~3。
所述的一种环境容许型生物基润滑油的制备方法，包括以下步骤：
（1）按照所述质量份数备取原料；
（2）将生物基复合基础油、耐磨合成酯、降凝剂、十七烯基咪唑啉、烷醇酰胺、二烷基二苯胺和单聚异丁烯丁二酞亚胺于55~65℃下充分搅拌混合均匀，为预混液一；
（3）将极压抗磨助剂、氯化石蜡和气相二氧化钛于60~70℃下充分搅拌混合均匀，为预混液二；
（4）将步骤（2）和步骤（3）所得的预混液一和预混液二混合均匀后于70~80℃条件下滴加乙酸冰片酯，然后保温中速搅拌30~60min，冷却、过滤得到本发明的润滑油。
硼酸酯类极压抗磨助剂的使用可以提高润滑油的热稳定性和阻燃性，而且具有无毒环保、可抑制可燃性气体生成和成本低的特点，在燃点高温下硼化合物分解，可在材料表面覆盖形成玻璃状焦化层，隔绝空气中氧的渗入，继而起到阻燃的作用。而且硼酸酯类添加剂具有较好的抗菌防腐性能和缓蚀性能，可大大提高润滑油的综合性能，与二烷基二硫代氨基甲酸钼的复合可以产生优良的极压抗磨作用，且与胺类抗氧剂表现出良好的抗氧协同作用；十七烯基咪唑啉极性较强，可优先吸附于金属表面或与表面发生化学反应生成保护膜，抑制氧及水和金属接触，起到防锈作用，单聚异丁烯丁二酞亚胺可以起到良好的体系分散作用，且与其他组成成分协同起效，经实验测试证明具备良好的润滑效果和较强的环境适应性。
本发明避免了矿物基基础油的添加，最大限度的避免了润滑油的使用对环境造成的影响，所得润滑油综合润滑性能良好，具有较高的经济价值和社会价值，同时适合工业化生产和使用。
具体实施方式
下面结合具体实施例对本发明做进一步的说明，但下述的实施例并不构成对本发明权利的限制。
实施例1：一种环境容许型生物基润滑油，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯15份、降凝剂2份、极压抗磨助剂5份、十七烯基咪唑啉0.3份、氯化石蜡6份、乙酸冰片酯3份、烷醇酰胺0.2份、二烷基二苯胺0.2份、气相二氧化钛2份、单聚异丁烯丁二酞亚胺3份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为6:3:1。
进一步地，所述的耐磨合成酯为二聚亚油酸乙二醇酯和三羟甲基丙烷油酸酯；所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂；所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为1:2。
所述的一种环境容许型生物基润滑油的制备方法，包括以下步骤：
（1）按照所述质量份数备取原料；
（2）将生物基复合基础油、耐磨合成酯、降凝剂、十七烯基咪唑啉、烷醇酰胺、二烷基二苯胺和单聚异丁烯丁二酞亚胺于60℃下充分搅拌混合均匀，为预混液一；
（3）将极压抗磨助剂、氯化石蜡和气相二氧化钛于65℃下充分搅拌混合均匀，为预混液二；
（4）将步骤（2）和步骤（3）所得的预混液一和预混液二混合均匀后于75℃条件下滴加乙酸冰片酯，然后保温中速搅拌45min，冷却、过滤得到本发明的润滑油。
实施例2：一种环境容许型生物基润滑油，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯10份、降凝剂1份、极压抗磨助剂3份、十七烯基咪唑啉0.1份、氯化石蜡5份、乙酸冰片酯2份、烷醇酰胺0.1份、二烷基二苯胺0.1份、气相二氧化钛1份、单聚异丁烯丁二酞亚胺1份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为7:4:1。
进一步地，所述的耐磨合成酯为季戊四醇四油酸酯；所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂；所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为1: 3。
所述的一种环境容许型生物基润滑油的制备方法，包括以下步骤：
（1）按照所述质量份数备取原料；
（2）将生物基复合基础油、耐磨合成酯、降凝剂、十七烯基咪唑啉、烷醇酰胺、二烷基二苯胺和单聚异丁烯丁二酞亚胺于55℃下充分搅拌混合均匀，为预混液一；
（3）将极压抗磨助剂、氯化石蜡和气相二氧化钛于60℃下充分搅拌混合均匀，为预混液二；
（4）将步骤（2）和步骤（3）所得的预混液一和预混液二混合均匀后于70℃条件下滴加乙酸冰片酯，然后保温中速搅拌60min，冷却、过滤得到本发明的润滑油。
实施例3：一种环境容许型生物基润滑油，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯20份、降凝剂3份、极压抗磨助剂6份、十七烯基咪唑啉0.5份、氯化石蜡8份、乙酸冰片酯5份、烷醇酰胺0.3份、二烷基二苯胺0.3份、气相二氧化钛3份、单聚异丁烯丁二酞亚胺4份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为5:2:1。
进一步地，所述的耐磨合成酯为二聚亚油酸乙二醇酯、季戊四醇四油酸酯、棕榈酸异辛酯和三羟甲基丙烷油酸酯的混合；所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂；所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为1:1。
所述的一种环境容许型生物基润滑油的制备方法，包括以下步骤：
（1）按照所述质量份数备取原料；
（2）将生物基复合基础油、耐磨合成酯、降凝剂、十七烯基咪唑啉、烷醇酰胺、二烷基二苯胺和单聚异丁烯丁二酞亚胺于65℃下充分搅拌混合均匀，为预混液一；
（3）将极压抗磨助剂、氯化石蜡和气相二氧化钛于70℃下充分搅拌混合均匀，为预混液二；
（4）将步骤（2）和步骤（3）所得的预混液一和预混液二混合均匀后于80℃条件下滴加乙酸冰片酯，然后保温中速搅拌30min，冷却、过滤得到本发明的润滑油。
实施例4：一种环境容许型生物基润滑油，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯10份、降凝剂3份、极压抗磨助剂3份、十七烯基咪唑啉0.5份、氯化石蜡5份、乙酸冰片酯5份、烷醇酰胺0.1份、二烷基二苯胺0.3份、气相二氧化钛1份、单聚异丁烯丁二酞亚胺4份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为5:4:1。
进一步地，所述的耐磨合成酯为二聚亚油酸乙二醇酯和棕榈酸异辛酯；所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂；所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为2: 3。
所述的一种环境容许型生物基润滑油的制备方法，其具体步骤同实施例1。
实施例5：一种环境容许型生物基润滑油，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯12份、降凝剂2份、极压抗磨助剂4份、十七烯基咪唑啉0.2份、氯化石蜡7份、乙酸冰片酯4份、烷醇酰胺0.3份、二烷基二苯胺0.2份、气相二氧化钛2份、单聚异丁烯丁二酞亚胺3份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为12:7:2。
进一步地，所述的耐磨合成酯为棕榈酸异辛酯；所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂；所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为2:5。
所述的一种环境容许型生物基润滑油的制备方法，其具体步骤同实施例1。
对比例1：一种环境容许型生物基润滑油，由以下质量份数的原料组成：基础油100份、耐磨合成酯15份、降凝剂2份、极压抗磨助剂5份、十七烯基咪唑啉0.3份、氯化石蜡6份、乙酸冰片酯3份、烷醇酰胺0.2份、二烷基二苯胺0.2份、气相二氧化钛2份、单聚异丁烯丁二酞亚胺3份；所述基础油为按API分类的I类润滑油基础油。
进一步地，所述的耐磨合成酯为二聚亚油酸乙二醇酯和三羟甲基丙烷油酸酯；所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂；所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为1:2。
所述的一种环境容许型生物基润滑油的制备方法，包括以下步骤：
（1）按照所述质量份数备取原料；
（2）将基础油、耐磨合成酯、降凝剂、十七烯基咪唑啉、烷醇酰胺、二烷基二苯胺和单聚异丁烯丁二酞亚胺于60℃下充分搅拌混合均匀，为预混液一；
（3）将极压抗磨助剂、氯化石蜡和气相二氧化钛于65℃下充分搅拌混合均匀，为预混液二；
（4）将步骤（2）和步骤（3）所得的预混液一和预混液二混合均匀后于75℃条件下滴加乙酸冰片酯，然后保温中速搅拌45min，冷却、过滤得到本发明的润滑油。
对比例2：质量份比为6:3:1的精炼大豆油、季戊四醇酯和氢化蓖麻油的混合。
取相同量的上述实施例1-5及对比例1-2的润滑油在相同条件下做性能测试，结果如下表所示：
性能 实施例1 实施例2 实施例3 实施例4 实施例5 对比例1 对比例2 标准
粘度指数 103 92 108 99 102 91 88 GB/T265-88
摩擦系数 0.078 0.084 0.086 0.082 0.077 0.099 0.108 SH/T 0762
四球试验 PB,N 1223 1130 1107 1178 1254 1041 454 GB/T 3142
测试结果显示，本发明的润滑油不仅在润滑性能上较为突出，同时，本发明的润滑油具备较好的环保性，具有较高的经济价值和社会价值。

Claims (6)

1.一种环境容许型生物基润滑油，其特征在于，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯10~20份、降凝剂1~3份、极压抗磨助剂3~6份、十七烯基咪唑啉0.1~0.5份、氯化石蜡5~8份、乙酸冰片酯2~5份、烷醇酰胺0.1~0.3份、二烷基二苯胺0.1~0.3份、气相二氧化钛1~3份、单聚异丁烯丁二酞亚胺1~4份；
所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为5~7：2~4:1。
2.根据权利要求1所述的一种环境容许型生物基润滑油，其特征在于，由以下质量份数的原料组成：生物基复合基础油100份、耐磨合成酯15份、降凝剂2份、极压抗磨助剂5份、十七烯基咪唑啉0.3份、氯化石蜡6份、乙酸冰片酯3份、烷醇酰胺0.2份、二烷基二苯胺0.2份、气相二氧化钛2份、单聚异丁烯丁二酞亚胺3份；所述生物基复合基础油为精炼大豆油、季戊四醇酯和氢化蓖麻油，其质量份比为6:3:1。
3.根据权利要求1或2所述的一种环境容许型生物基润滑油，其特征在于：所述的耐磨合成酯为二聚亚油酸乙二醇酯、季戊四醇四油酸酯、棕榈酸异辛酯、三羟甲基丙烷油酸酯中的一种或几种。
4.根据权利要求1或2所述的一种环境容许型生物基润滑油，其特征在于：所述的降凝剂为丙烯酸酯-苯乙烯-马来酸酐三元共聚物降凝剂。
5.根据权利要求1或2所述的一种环境容许型生物基润滑油，其特征在于：所述极压抗磨助剂为蓖麻油烷醇酰胺硼酸酯和二烷基二硫代氨基甲酸钼的复合物，其质量份比为1:1~3。
6.权利要求1或2所述的一种环境容许型生物基润滑油的制备方法，其特征在于，包括以下步骤：
（1）按照所述质量份数备取原料；
（2）将生物基复合基础油、耐磨合成酯、降凝剂、十七烯基咪唑啉、烷醇酰胺、二烷基二苯胺和单聚异丁烯丁二酞亚胺于55~65℃下充分搅拌混合均匀，为预混液一；
（3）将极压抗磨助剂、氯化石蜡和气相二氧化钛于60~70℃下充分搅拌混合均匀，为预混液二；
（4）将步骤（2）和步骤（3）所得的预混液一和预混液二混合均匀后于70~80℃条件下滴加乙酸冰片酯，然后保温中速搅拌30~60min，冷却、过滤得到本发明的润滑油。
CN201710687642.7A 2017-08-11 2017-08-11 一种环境容许型生物基润滑油及其制备方法 Withdrawn CN107384556A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710687642.7A CN107384556A (zh) 2017-08-11 2017-08-11 一种环境容许型生物基润滑油及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710687642.7A CN107384556A (zh) 2017-08-11 2017-08-11 一种环境容许型生物基润滑油及其制备方法

Publications (1)

Publication Number Publication Date
CN107384556A true CN107384556A (zh) 2017-11-24

Family

ID=60354630

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710687642.7A Withdrawn CN107384556A (zh) 2017-08-11 2017-08-11 一种环境容许型生物基润滑油及其制备方法

Country Status (1)

Country Link
CN (1) CN107384556A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085116A (zh) * 2017-12-28 2018-05-29 长沙无道工业设计有限公司 汽车用润滑油机油

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102408939A (zh) * 2011-10-11 2012-04-11 中国石油化工股份有限公司 可生物降解润滑油组合物及其制备方法
CN102585983A (zh) * 2012-02-14 2012-07-18 上海金兆节能科技有限公司 一种齿轮加工微量润滑油及其制备方法和应用
CN104099160A (zh) * 2014-07-29 2014-10-15 马思特（上海）化学有限公司 一种低气味钛合金加工油及其制备方法
CN105482880A (zh) * 2015-12-28 2016-04-13 芜湖市创源新材料有限公司 一种添加油溶性纳米二氧化钛的可降解液压油
CN105542923A (zh) * 2016-02-18 2016-05-04 苏州永创达电子有限公司 一种绿色环保型润滑油
CN105861120A (zh) * 2016-04-08 2016-08-17 于迎春 一种可降解的高性能润滑油组合物

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102408939A (zh) * 2011-10-11 2012-04-11 中国石油化工股份有限公司 可生物降解润滑油组合物及其制备方法
CN102585983A (zh) * 2012-02-14 2012-07-18 上海金兆节能科技有限公司 一种齿轮加工微量润滑油及其制备方法和应用
CN104099160A (zh) * 2014-07-29 2014-10-15 马思特（上海）化学有限公司 一种低气味钛合金加工油及其制备方法
CN105482880A (zh) * 2015-12-28 2016-04-13 芜湖市创源新材料有限公司 一种添加油溶性纳米二氧化钛的可降解液压油
CN105542923A (zh) * 2016-02-18 2016-05-04 苏州永创达电子有限公司 一种绿色环保型润滑油
CN105861120A (zh) * 2016-04-08 2016-08-17 于迎春 一种可降解的高性能润滑油组合物

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108085116A (zh) * 2017-12-28 2018-05-29 长沙无道工业设计有限公司 汽车用润滑油机油

Similar Documents

Publication Publication Date Title
JP5943479B2 (ja) グリース組成物
CN102277224B (zh) 一种风电设备传动系统润滑剂组合物
CN103396865B (zh) 一种环境友好高抗磨润滑油及其制备方法
CN104498164A (zh) 一种抗腐蚀防变色环保型水基镁合金切削液
CN103525529A (zh) 高性能环保型水溶性冲压油
CN110157531B (zh) 一种可生物降解润滑油及其制备方法
TW408172B (en) Biodegradable grease compositions
JP2008169371A (ja) バイオディーゼル生産時に生成される蒸留残余物を利用した水溶性金属加工油の組成物
CN104830491A (zh) 一种防锈润滑剂及其制备方法
CN107384556A (zh) 一种环境容许型生物基润滑油及其制备方法
CN103642563B (zh) 一种节能型的全合成自动变速器传动液及其合成方法
CN108865339A (zh) 一种高速动车组轴箱轴承润滑脂组合物及其制备方法
CN110734804B (zh) 一种纳米切削油及其制备方法和应用
EP1944352B1 (en) Biodegradable grease composition using distillation residue generated in production of biodiesel
CN107446675A (zh) 一种改性蓖麻油为基础油的生物基润滑油
CN109233965A (zh) 一种钢帘线湿拉润滑剂及其制备方法
CN107488489A (zh) 一种自清净环保润滑油及其制备方法
US4956109A (en) Lubricating oil
CN103266007B (zh) 一种水基润滑油及其制备工艺
CN107033996A (zh) 一种润滑油组合物
CN107384555A (zh) 一种改善低温流动性的环保润滑油
CN106544099A (zh) 一种耐磨润滑油
CN107474910A (zh) 一种改性蓖麻油基环保润滑脂及其制备工艺
CN112300853A (zh) 一种环保型齿轮润滑油及其制备方法
CN107488488A (zh) 一种耐高温低碳清净型润滑油

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20171124