CN107373115A - A kind of ruminant domestic animal feed addictive based on APG and its preparation method and application - Google Patents

A kind of ruminant domestic animal feed addictive based on APG and its preparation method and application Download PDF

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Publication number
CN107373115A
CN107373115A CN201710695981.XA CN201710695981A CN107373115A CN 107373115 A CN107373115 A CN 107373115A CN 201710695981 A CN201710695981 A CN 201710695981A CN 107373115 A CN107373115 A CN 107373115A
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apg
domestic animal
feed addictive
ruminant domestic
additive
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CN107373115B (en
Inventor
汤少勋
韩雪峰
王敏
周传社
谭支良
颜琼娴
康劲翮
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Guangxi Rocky Desertification Control Industry Technology Research Institute Co.,Ltd.
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Institute of Subtropical Agriculture of CAS
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K50/00Feeding-stuffs specially adapted for particular animals
    • A23K50/10Feeding-stuffs specially adapted for particular animals for ruminants
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/10Organic substances
    • A23K20/163Sugars; Polysaccharides
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/10Organic substances
    • A23K20/174Vitamins
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/28Silicates, e.g. perlites, zeolites or bentonites
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23KFODDER
    • A23K20/00Accessory food factors for animal feeding-stuffs
    • A23K20/20Inorganic substances, e.g. oligoelements
    • A23K20/30Oligoelements

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Animal Husbandry (AREA)
  • Zoology (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Birds (AREA)
  • Fodder In General (AREA)
  • Feed For Specific Animals (AREA)

Abstract

The invention discloses a kind of ruminant domestic animal feed addictive based on APG and its preparation method and application.Preparation method of the present invention is:It is 150~500 by weight ratio:480~830 APG is uniformly mixed with sepiolite,In 65 DEG C of drying,Then crush and cross 40 mesh sieves,Obtain APG sepiolite pre-composition,Then in certain part by weight ratio by APG sepiolite pre-composition,Ferrous sulfate monohydrate,Cupric sulfate pentahydrate,Manganese sulfate monohydrate,Monohydrate zinc sulphate,Se content is 1wt% additive,Content of iodine is 1wt% additive,Cobalt content is 1wt% additive,Vitamin A,Vitamin E crushes after being stirred and crosses 40 mesh sieves,Obtain the ruminant domestic animal feed addictive,Antibiotic is free of in the feedstuff additive product of the present invention,As ruminant domestic animal feed addictive,Ruminant domestic animal gastrointestinal tract environment can be improved,Improve feed digestibility,And then improve the production performance of ruminant domestic animal,Development to ruminant domestic animal aquaculture has great significance.

Description

A kind of ruminant domestic animal feed addictive based on APG and preparation method thereof and Using
Technical field
The invention belongs to field of feed, and in particular to a kind of ruminant domestic animal suitable for beef cattle, mutton sheep and milk cow is supported Grow with feed addictive and its preparation method and application.
Background technology
Stalk is crop by-product the abundantest, has the characteristics that volume is big, crude fiber content is high, is adapted to feeding anti- Hay domestic animal, have the function that to improve lactating mammal butterfat percnetage.So agricultural crop straw is made full use of on ruminant, not only Culture benefit can be improved, also has the function that to reduce environmental pollution.But because stalk cane is thick and stiff and when alimentary canal stops Between it is longer, influence palatability and the feed intake of domestic animal;Stalk nitrogen content is low simultaneously, and crude fiber content is high, and cellulose and wood Quality is firmly combined with, and animal is difficult to digestibility and utilization.In general, ruminant is only 20-30% to the digestive utilization ratio of stalk. For this kind of feature of stalk feed, people are carried out in terms of improving straw utilization rate and increasing its nutritive value for a long time A large amount of in-depth studies, and obtain preferable effect.
Improve ruminant mainly includes two aspects to the approach of the utilization rate of roughage, first, being processed place to stalk Reason, second, feeding additive to improve Rumen Internal Environment.It is applied to the ruminant feed addition of regulation and control Rumen Internal Environment at present Agent mainly have methane inhibitor, antibiotic, protease, deaminizating inhibitor, go protozoon agent, microbial enzyme, fat or aliphatic acid, Buffer or artificial saliva, ionophore, probiotic and non-bacterial direct microorganism fodder.By add outer source pollution come It is mode more common at present to improve roughage utilization rate, but exogenous enzymes have loss of activity during production, preservation, so that In not reaching preferable using effect.There is research to confirm that nonionic surfactant (NIS) improves to anaerobe in cud The activity of fibre composition degraded has a significant positive effect, and NIS can be by improving the active of Ruminal Fibre element enzyme and stably Property and improve the microorganism speed of growth, and then promote fiber feedstuff degraded utilize.At present, NIS grinding in ruminant domestic animal Study carefully and using also extremely limited, and research is concentrated mainly in the influence that single NIS ferments to roughage in cud.Alkyl polysaccharide Glycosides (APG) is a kind of typical nonionic surfactant, by cornstarch glucose and the reaction generation of natural fatty alcohol.Cause It has good biological degradability and hypotoxicity and is widely used in the industries such as bathing, beauty and food processing.Therefore, this hair Bright plan is tested by a series of In Vitro Fermentations and zoopery, determines the species that APG can utilize in ruminant domestic animal And broiler diets, provide scientific basis to the utilization rate of roughage to improve ruminant domestic animal rumen microorganism.
The content of the invention
It is an object of the invention to overcome existing nonionic surfactant addition theoretical foundation deficiency, it is therefore an objective to be to carry A kind of ruminant domestic animal feed addictive based on APG is supplied, under the pitch-based sphere of the present invention, APG is fitted When reducing rumen fluid surface tension, by improving microbial cell membrane permeability, and the secretion capacity of microbial enzyme, with being added Other mineral elements synergy added, and then improve the digestibility of feed and the production performance of ruminant domestic animal.
In order to solve the above problems, the technical scheme that the present invention takes is:
A kind of ruminant domestic animal feed addictive based on APG, in parts by weight, the original of the feed addictive Material composition includes:
Preferably, in parts by weight, the raw material composition of the feed addictive includes:
It is furthermore preferred that in parts by weight, the raw material composition of the feed addictive includes:
Wherein, the preparation method of APG and the sepiolite pre-composition is:By weight 150~500:480~ 830 take APG and sepiolite to be mixed and stirred for uniformly respectively, afterwards by the above-mentioned mixture to stir in 65 DEG C of bakings It is dry, then crush and 40 mesh sieves excessively produce APG and the sepiolite pre-composition.
The APG is C8-C16 fatty alcohol glucoside, and the hydrophily of APG is 14-16, and alkyl is more Glucosides is weight than the thick liquid for 50%.
The ruminant domestic animal is milk cow, beef cattle, goat or sheep.
In addition, the preparation side of the ruminant domestic animal feed addictive based on APG is also claimed in the present invention Method, specifically comprise the following steps:
(1) by weight 150~500:480~830 take APG and sepiolite to be mixed and stirred for uniformly respectively, it The above-mentioned mixture to stir is dried at 65 DEG C afterwards, then crushes and 40 mesh sieves excessively produces the APG and Hai Pao Stone pre-composition;
(2) APG and sepiolite pre-composition obtained by step (1) are taken by weight, then weigh corresponding parts by weight Several ferrous sulfate monohydrates, cupric sulfate pentahydrate, manganese sulfate monohydrate, monohydrate zinc sulphate, the mass content of selenium are 1% additive, The mass content of iodine is 1% additive, and the mass content of cobalt is 1% additive, vitamin A, and vitamin E crushes and crosses 40 Mesh sieve, then it is mixed evenly.
The ruminant domestic animal feed based on APG being prepared by the preparation method is also claimed in the present invention Additive.
And a kind of ruminant domestic animal total mixed feed is also claimed, with the addition of above-mentioned feed in the total mixed feed adds Add agent, and the quality adding proportion of feed addictive is 2%.
Ruminant domestic animal feed addictive provided by the invention in APG, added with conventional ruminant domestic animal feed Agent is compared, and has following obvious beneficial effect:
The present invention relative to prior art main improvement in additive simultaneously used APG with And several kinds of mineral elements;Compared with not adding APG group, under the APG pitch-based sphere of the present invention, rumen fluid Surface tension be reduced to 43mN/m from 55mN/m, microbial cell membrane permeability brings up to 46% from 42%, rumen microorganism The vigor of carboxymethylcelluloenzyme enzyme improves 9.09%, and the vigor of xylan cellulase improves 9.58%.APG and institute Other mineral elements synergy of addition, makes rumen microbial protein synthetic ratio improve 11.6%.In addition, by the way that alkyl is more Glucosides is pre-mixed with sepiolite, then dries pulverizing, makes APG more convenient as the use of feed.
Embodiment
, below will be in the embodiment of the present invention to make the purpose, technical scheme and advantage of the embodiment of the present invention clearer Technical scheme be clearly and completely described.
Embodiment 1
In the present embodiment, the raw material composition of the ruminant domestic animal feed addictive based on APG, by weight:Alkane 98.18 parts of alkyl polyglucosides and sepiolite pre-composition, 0.153 part of ferrous sulfate monohydrate, 0.08 part of cupric sulfate pentahydrate, manganese sulfate monohydrate 0.3 part, 0.5 part of monohydrate zinc sulphate, the mass content of selenium is 1% 0.046 part of additive, and the mass content of iodine is 1% to add Add 0.306 part of agent, the mass content of cobalt is 1% 0.074 part of additive, 0.025 part of vitamin A, 0.336 part of vitamin E.
Wherein, the mass percentage content of the moisture of APG is less than 50%.
The preparation method of the ruminant domestic animal feed addictive based on APG of the present embodiment, specifically includes following step Suddenly:
(1) according to 150 parts of APG, the part by weight that 830 parts of sepiolite weighs above-mentioned substance, and by alkyl polysaccharide Glycosides is uniformly mixed with sepiolite, afterwards in 65 DEG C of drying;
(2) according to 98.18 parts of APG and sepiolite pre-composition, 0.153 part of ferrous sulfate monohydrate, cupric sulfate pentahydrate 0.08 part, 0.3 part of manganese sulfate monohydrate, 0.5 part of monohydrate zinc sulphate, the mass content of selenium is 1% 0.046 part of additive, iodine Mass content is 1% 0.306 part of additive, and the mass content of cobalt is 1% 0.074 part of additive, 0.025 part of vitamin A, And the part by weight of 0.336 part of vitamin E weighs above-mentioned substance;
Then, respectively by APG and sepiolite premix, ferrous sulfate monohydrate, cupric sulfate pentahydrate, a water sulphur Sour manganese, monohydrate zinc sulphate, the additive that the mass content of selenium is 1%, the additive that the mass content of iodine is 1%, the quality of cobalt Additive, vitamin A and the vitamin E that content is 1% crush and cross 40 mesh sieves;
(3) APG is added into mixer successively according to step (2) formulation weight part content and sepiolite premixes Additive, the iodine that thing, ferrous sulfate monohydrate, cupric sulfate pentahydrate, manganese sulfate monohydrate, monohydrate zinc sulphate, the mass content of selenium are 1% Mass content be 1% additive, the mass content of cobalt be 1% additive, vitamin A and vitamin E, be stirred It is even.
Embodiment 2
In the present embodiment, the ruminant domestic animal feed addictive based on APG includes by weight:APG With 98.18 parts of sepiolite pre-composition, 0.153 part of ferrous sulfate monohydrate, 0.08 part of cupric sulfate pentahydrate, 0.3 part of manganese sulfate monohydrate, one 0.5 part of water zinc sulphate, the mass content of selenium are 1% 0.046 part of additive, and the mass content of iodine is 1% additive 0.306 Part, the mass content of cobalt is 1% 0.074 part of additive, 0.025 part of vitamin A, 0.336 part of vitamin E.
Wherein, the mass percentage content of the moisture of APG is less than 50%.
The manufacture craft of the ruminant domestic animal feed addictive based on APG of the present embodiment, including:
(1) according to 300 parts of APG, the part by weight that 680 part of sepiolite weighs above-mentioned substance, and by alkyl polysaccharide Glycosides is uniformly mixed with sepiolite, in 65 DEG C of drying;
(2) according to 98.18 parts of APG and sepiolite premix, 0.153 part of ferrous sulfate monohydrate, five water sulfuric acid 0.08 part of copper, 0.3 part of manganese sulfate monohydrate, 0.5 part of monohydrate zinc sulphate, the mass content of selenium are 1% 0.046 part of additive, iodine Mass content be 1% 0.306 part of additive, the mass content of cobalt is 1% 0.074 part of additive, vitamin A 0.025 Part, and the part by weight weighing above-mentioned substance of 0.336 part of vitamin E;
Then, respectively by APG and sepiolite premix, ferrous sulfate monohydrate, cupric sulfate pentahydrate, a water sulphur Sour manganese, monohydrate zinc sulphate, the additive that the mass content of selenium is 1%, the additive that the mass content of iodine is 1%, the quality of cobalt Additive, vitamin A and the vitamin E that content is 1% crush and cross 40 mesh sieves;
(3) APG is added into mixer successively according to step (2) formulation weight part content and sepiolite premixes Additive, the iodine that thing, ferrous sulfate monohydrate, cupric sulfate pentahydrate, manganese sulfate monohydrate, monohydrate zinc sulphate, the mass content of selenium are 1% Mass content be 1% additive, the mass content of cobalt be 1% additive, vitamin A and vitamin E, be stirred It is even.
Embodiment 3
In the present embodiment, the ruminant domestic animal feed addictive based on APG includes by weight:APG With 98.18 parts of sepiolite premix, 0.153 part of ferrous sulfate monohydrate, 0.08 part of cupric sulfate pentahydrate, 0.3 part of manganese sulfate monohydrate, 0.5 part of monohydrate zinc sulphate, the mass content of selenium are 1% 0.046 part of additive, and the mass content of iodine is 1% additive 0.306 part, the mass content of cobalt is 1% 0.074 part of additive, 0.025 part of vitamin A, 0.336 part of vitamin E.
Wherein, the mass percentage content of the moisture of APG is less than 50%.
The manufacture craft of the ruminant domestic animal feed addictive based on APG of the present embodiment, including:
(1) according to 500 parts of APG, the part by weight that 480 part of sepiolite weighs above-mentioned substance, and by alkyl polysaccharide Glycosides is uniformly mixed with sepiolite, in 65 DEG C of drying;
(2) according to 98.18 parts of APG and sepiolite premix, 0.153 part of ferrous sulfate monohydrate, five water sulfuric acid 0.08 part of copper, 0.3 part of manganese sulfate monohydrate, 0.5 part of monohydrate zinc sulphate, the mass content of selenium are 1% 0.046 part of additive, iodine Mass content be 1% 0.306 part of additive, the mass content of cobalt is 1% 0.074 part of additive, vitamin A 0.025 Part, and the part by weight weighing above-mentioned substance of 0.336 part of vitamin E;
Then, respectively by APG and sepiolite premix, ferrous sulfate monohydrate, cupric sulfate pentahydrate, a water sulphur Sour manganese, monohydrate zinc sulphate, the additive that the mass content of selenium is 1%, the additive that the mass content of iodine is 1%, the quality of cobalt Additive, vitamin A and the vitamin E that content is 1% crush and cross 40 mesh sieves;
(3) APG is added into mixer successively according to step (2) formulation weight part content and sepiolite premixes Additive, the iodine that thing, ferrous sulfate monohydrate, cupric sulfate pentahydrate, manganese sulfate monohydrate, monohydrate zinc sulphate, the mass content of selenium are 1% Mass content be 1% additive, the mass content of cobalt be 1% additive, vitamin A and vitamin E, be stirred It is even.
Comparative example 1
The raw material composition of ruminant domestic animal feed addictive in this comparative example, by weight:98.18 parts of sepiolite, one 0.153 part of aqueous ferrous sulfate, 0.08 part of cupric sulfate pentahydrate, 0.3 part of manganese sulfate monohydrate, 0.5 part of monohydrate zinc sulphate, the quality of selenium contains Measure 0.046 part of the additive for 1%, the mass content of iodine is 1% 0.306 part of additive, and the mass content of cobalt is 1% to add Add 0.074 part of agent, 0.025 part of vitamin A, 0.336 part of vitamin E.
The preparation method of the ruminant domestic animal feed addictive of this comparative example, specifically includes following steps:
(1) according to 98.18 parts of sepiolite, 0.153 part of ferrous sulfate monohydrate, 0.08 part of cupric sulfate pentahydrate, manganese sulfate monohydrate 0.3 part, 0.5 part of monohydrate zinc sulphate, the mass content of selenium is 1% 0.046 part of additive, and the mass content of iodine is 1% to add Add 0.306 part of agent, the mass content of cobalt is 1% 0.074 part of additive, 0.025 part of vitamin A, and vitamin E 0.336 The part by weight of part weighs above-mentioned substance;
Then, respectively by sepiolite, ferrous sulfate monohydrate, cupric sulfate pentahydrate, manganese sulfate monohydrate, monohydrate zinc sulphate, selenium Additive that additive that mass content is 1%, the additive that the mass content of iodine is 1%, the mass content of cobalt are 1%, dimension Raw plain A and vitamin E are crushed and are crossed 40 mesh sieves;
(2) sepiolite, ferrous sulfate monohydrate, five are added into mixer successively according to step (1) formulation weight part content Brochanite, manganese sulfate monohydrate, monohydrate zinc sulphate, the additive that the mass content of selenium is 1%, the mass content of iodine are 1% Additive, vitamin A and the vitamin E that additive, the mass content of cobalt are 1%, are uniformly mixed.
Effect experiment is carried out to the ruminant domestic animal feed addictive prepared by the embodiment of the present invention and comparative example 1 below:
APG of the present invention is commercially available by market, using single-factor completely randomized design, select the age, parity, The lactation moon, the output of milk and china holstein cowses 18 similar in body condition, 1,2 group of control group and experiment are divided at random, it is right The ruminant domestic animal feed addictive of comparative example 1 is added in basal diet fine fodder according to the milk cow of group;1,2 group of experiment is in basal diet The ruminant domestic animal feed addictive of embodiment 1 is added in fine fodder, and makes content difference of the APG in TRM For 5g/kg and 10g/kg.Test ox ties raising using drylot feeding, single groove feeding in same house;Daily scale of feeding is milk cow day Grain basis fine fodder 6kg, bean dregs 15kg, maize straw 12kg, daily feeding 2 times, free water, it is other management by cattle farm provide into OK.Just trying interim, every morning and afternoon by machine milking, weigh, and record the daily output of milk.Passed through every 20 days Morning and milking in afternoon, gather 20ml every time, deepfreeze, and milk composition is determined after mixing morning and afternoon milk sample.
Influence of the APG feed addictive of table 1 to cow feeding amount, the output of milk and milk composition
Note:Significant difference (P < 0.05), butterfat correction breast=output of milk × (0.4+ are represented with different alphabetical shoulder marks in the ranks 0.15 × butterfat percnetage).
As shown in Table 1, add and feed the APG (APG) of various concentrations and the feed intake of lactation period milk is improved work With.But compared with control group, test group otherness is not notable (P > 0.05).Compared with control group, add and feed various concentrations APG is notable (P < 0.05) to the output of milk otherness of lactation period milk.Butterfat corrects newborn variation tendency and milk production variation tendency phase Together.Butterfat percnetage test group otherness compared with control group is notable (P < 0.05).Rich milk solid test group is all remarkably higher than control Group (P < 0.05).Lactoprotein, lactose and each group difference of nonfat milk solids content be not notable (P > 0.05).
Embodiments described above is part of the embodiment of the present invention, rather than whole embodiments.The reality of the present invention The detailed description for applying example is not intended to limit the scope of claimed invention, but is merely representative of the selected implementation of the present invention Example.Based on the embodiment in the present invention, what those of ordinary skill in the art were obtained under the premise of creative work is not made Every other embodiment, belongs to the scope of protection of the invention.

Claims (9)

1. a kind of ruminant domestic animal feed addictive based on APG, it is characterised in that in parts by weight, the feed adds Adding the raw material of agent to form includes:
2. the ruminant domestic animal feed addictive based on APG according to claim 1, it is characterised in that with parts by weight Meter, the raw material composition of the feed addictive include:
3. the ruminant domestic animal feed addictive based on APG according to claim 2, it is characterised in that with parts by weight Meter, the raw material composition of the feed addictive include:
4. the ruminant domestic animal feed addictive based on APG according to claim any one of 1-3, it is characterised in that The preparation method of APG and the sepiolite pre-composition is:By weight 150~500:480~830 take alkyl respectively More glucosides and sepiolite are mixed and stirred for uniformly, and the above-mentioned mixture to stir is dried at 65 DEG C afterwards, is then crushed simultaneously Cross 40 mesh sieves and produce APG and the sepiolite pre-composition.
5. the ruminant domestic animal feed addictive based on APG according to claim any one of 1-4, it is characterised in that The APG is C8-C16 fatty alcohol glucoside, and the hydrophily of APG is 14-16, and APG is weight Amount is than the thick liquid for 50%.
6. the ruminant domestic animal feed addictive based on APG according to claim any one of 1-5, it is characterised in that The ruminant domestic animal is milk cow, beef cattle, goat or sheep.
7. the preparation method of the ruminant domestic animal feed addictive based on APG according to claim any one of 1-5, It is characterised in that it includes following steps:
(1) by weight 150~500:480~830 take APG and sepiolite to be mixed and stirred for uniformly respectively, afterwards will It is pre- to produce the APG and sepiolite in 65 DEG C of drying, then crushing and 40 mesh sieves excessively for the above-mentioned mixture to stir Mixed thing;
(2) take the APG and sepiolite pre-composition obtained by step (1) by weight, and with a water of corresponding parts by weight Ferrous sulfate, cupric sulfate pentahydrate, manganese sulfate monohydrate, monohydrate zinc sulphate, Se content be 1wt% additive, content of iodine 1wt% Additive, cobalt content is 1wt% additive, and vitamin A, vitamin E crushes and cross 40 mesh sieves, be then mixed evenly .
8. the ruminant domestic animal feed addictive based on APG that preparation method described in a kind of claim 7 is prepared.
9. a kind of ruminant domestic animal total mixed feed, it is characterised in that the feeding in claim 8 is with the addition of in the total mixed feed Feed additives, and the quality adding proportion of feed addictive is 2%.
CN201710695981.XA 2017-08-15 2017-08-15 Ruminant livestock feed additive based on alkyl polyglycoside and preparation method and application thereof Active CN107373115B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108185143A (en) * 2018-03-16 2018-06-22 中国科学院亚热带农业生态研究所 A kind of ruminant domestic animal mixed feed and preparation method based on Methionine Chelated Zinc

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
YUAN,Z Q等: "Effects of dietary supplementation with alkyl polyglycoside, a nonionic surfactant, on nutrient digestion and ruminal fermentation in goats1", 《JOURNAL OF ANIMAL SCIENCE》 *
胡万川: "《养羊手册》", 31 January 2009, 河北科学技术出版社 *
袁章琴等: "烷基多糖苷添加水平对山羊瘤胃发酵特性的影响", 《动物营养学报》 *

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108185143A (en) * 2018-03-16 2018-06-22 中国科学院亚热带农业生态研究所 A kind of ruminant domestic animal mixed feed and preparation method based on Methionine Chelated Zinc

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