CN107227636A - 一种印花浆及其制备方法 - Google Patents

一种印花浆及其制备方法 Download PDF

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CN107227636A
CN107227636A CN201710460438.1A CN201710460438A CN107227636A CN 107227636 A CN107227636 A CN 107227636A CN 201710460438 A CN201710460438 A CN 201710460438A CN 107227636 A CN107227636 A CN 107227636A
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printing paste
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雷晓燕
薛洋
王维
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Changzhou Inter Ring Trade Co Ltd
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Abstract

本发明涉及一种印花浆及其制备方法,属于纺织印花技术领域。发明首先将餐厨垃圾与膨润土粉碎后发酵得到发酵产物,再将酵母粉活化后与大叶藻、山药一同发酵,经酵母粉作用可使大叶藻和山药中的有效成份溶解出来,再将有效成分、餐厨垃圾与膨润土的发酵产物喂养蚯蚓,经蚯蚓作用使混合物转化为水稳定聚体,最后再与助剂等混合即可。本发明制备的稳定型抱水印花浆稳定性能好,不易变稀分层,且抱水性能好,不易渗化,不易影响织物的美观度和质量。

Description

一种印花浆及其制备方法
技术领域
本发明涉及一种印花浆及其制备方法,属于纺织印花技术领域。
背景技术
使染料或涂料在织物上形成图案的过程为织物印花。印花是局部染色,要求有一定的染色牢度。织物花纹装饰的重要方式之一。印花之后能够很好的提高纺织品的美观度,增加纺织品的色彩。近年来,在印花行业印花浆越来越受到的推崇,这得益于其本身所具有的多样性可以变化出多种多样的印花效果,操作简单方便、易于保存、环保无污染等优点。
现在市场上的印花浆都是乳化增稠体系,由乳化糊、海藻酸钠等组成,其加入硫酸铵、粘合剂、涂料色浆制成印花浆,在使用过程中有几方面缺点:一是印浆稳定性差,易变稀分层;二是抱水性不好,易渗化。且现有的印花浆不牢固,在遇到水等物质后,容易溶解分散到介质中,造成褪色,进而很大程度上影响了纺织品的美观度。因此,迫切寻找一种稳定性能优越、抱水性好、不易渗化的印花浆。
发明内容
本发明所要解决的技术问题:针对传统的印花浆稳定性能差、抱水性不好,易渗化的问题,提供了一种抱水印花浆的制备方法。
为解决上述技术问题,本发明采用的技术方案是:
一种印花浆,其特征在于,包括以下重量份数的原料:
3~5份羧甲基纤维素、15~20份亚甲基双丙烯酰胺、8~12份衣康酸、0.3~0.5份过硫酸钠和70~80份水。
所述的原料按重量份数还包括40~50份剩余物料。
所述的剩余物料是由混合物料喂养蚯蚓后去除蚯蚓后得到的。
所述的混合物料是由干燥物与灭菌物料混合得到的。
所述的干燥物是由大叶藻和山药经发酵、离心分离、干燥得到的。
所述的灭菌物料是由餐厨垃圾和沼液经发酵、高温灭菌得到的。
所述的原料按重量份数还包括1~3份聚二甲基硅氧烷。
印花浆制备过程为:将羧甲基纤维素、亚甲基双丙烯酰胺、衣康酸、过硫酸钠和水混合后,在60~70℃搅拌反应60~90min,即得印花浆。
本发明与其他方法相比,有益技术效果是:
(1)本发明以衣康酸和亚甲基双丙烯酰胺为聚合单体,两种单体的支链多,聚合度高,使聚合产物形成三维网状结构,具有更好的抱水能力,减少毛细管效应,从而达到防渗化的效果,同时本发明中的聚二甲基硅氧烷成膜后具有防水性,可增强印花浆的防渗化作用;
(2)本发明以餐厨垃圾和膨润土混合后进行发酵,发酵过程中,餐厨垃圾产生的有机酸可将膨润土中的金属溶出,使膨润土孔隙率增大,并且在发酵过程中,产出垃圾分解的多糖可通过吸附作用粘附于膨润土表面,改变膨润土的表面性能,再将大叶藻、山药一同进行发酵,可使其中的海藻酸钠和淀粉溶解出来,再将有效成分、改性膨润土用于喂养蚯蚓,经蚯蚓的作用使混合物转化为水稳定体,且淀粉和多糖为天然高分子,对酸性和电解质耐受能力强,与聚合产物共混后,可使聚合产物具有优异的耐电解质能力及耐酸性,使印花浆不易变稀,稳定性好。
具体实施方式
首先称取1~2kg餐厨垃圾,平铺在木板上,于太阳下暴晒3~4天,取400~500g暴晒后的餐厨垃圾、1~2kg膨润土加入到粉碎机中粉碎45~55min,得到粉碎物;取800~1000g粉碎物和100~200mL沼液,搅拌混合5~10min后置于发酵罐中,于温度为35~45℃条件下密封发酵6~8天,待发酵结束,将发酵罐中的物料取出,并置于高温灭菌箱中,于温度为120~130℃条件下高温灭菌15~20min,得到灭菌产物,称取500~600g大叶藻、800~1000g山药,用水清洗3~5次,将洗净的物料置于冷冻干燥箱中,于温度为-35~-25℃条件下干燥3~5h,再将干燥后的物料置于粉碎机中粉碎,过80~100目筛,得到过筛物,称取5~8g酵母粉加入到200~300mL30~35℃温水中,搅拌混合1~3min后,静置10~15min,得到活化酵母液,将活化酵母液倒入盛有1~2L水的烧杯中,再向烧杯中加入800~1000g过筛物,搅拌混合3~5min后,用塑料薄膜密封烧杯,静置发酵5~8天,待发酵结束,再向烧杯中加入200~300mL质量分数为15%氢氧化钠溶液,搅拌反应3~4h后,将烧杯中的物料取出,并置于离心机中,以3000~4000r/min的转速离心分离10~15min,得到上层液,将上层液进行喷雾干燥,得到干燥物,取100~200g干燥物与灭菌物料混合3~5min,得到混合物料,将混合物料置于烧杯中,再向烧杯中接种混合物料质量8%的蚯蚓,并将烧杯移入恒温培养箱中,控制培养箱温度为20~25℃,对蚯蚓进行养殖12~15天,养殖期间每天向烧杯中喷洒清水,保持混合物料的含水率为40~50%,待养殖结束,分离去除蚯蚓,得到剩余物料,按重量份数计,取40~50份烧杯中的剩余物料、3~5份羧甲基纤维素、1~3份聚二甲基硅氧烷、15~20份亚甲基双丙烯酰胺、8~12份衣康酸、0.3~0.5份过硫酸钠和70~80份水加入到烧杯中,将烧杯移入数显测速恒温磁力搅拌器中,于温度为60~70℃,转速为80~100r/min的条件下搅拌反应60~90min,再将烧杯中的物料自然冷却至室温,装料,即可得到印花浆。
实例1
按重量份数计,依次称取5份羧甲基纤维素、20份亚甲基双丙烯酰胺、12份衣康酸、0.5份过硫酸钠和80份水,加入到烧杯中,将烧杯移入数显测速恒温磁力搅拌器中,于温度为70℃,转速为100r/min的条件下搅拌反应90min,再将烧杯中的物料自然冷却至室温,装料,即可得到印花浆。
实例2
首先称取2kg餐厨垃圾,平铺在木板上,于太阳下暴晒4天,取4500g暴晒后的餐厨垃圾、2kg膨润土加入到粉碎机中粉碎55min,得到粉碎物;取1000g粉碎物和200mL沼液,搅拌混合10min后置于发酵罐中,于温度为45℃条件下密封发酵8天,待发酵结束,将发酵罐中的物料取出,并置于高温灭菌箱中,于温度为130℃条件下高温灭菌20min,得到灭菌产物,称取600g大叶藻、1000g山药,用水清洗5次,将洗净的物料置于冷冻干燥箱中,于温度为-25℃条件下干燥5h,再将干燥后的物料置于粉碎机中粉碎,过100目筛,得到过筛物,称取8g酵母粉加入到300mL35℃温水中,搅拌混合3min后,静置15min,得到活化酵母液,将活化酵母液倒入盛有2L水的烧杯中,再向烧杯中加入1000g过筛物,搅拌混合5min后,用塑料薄膜密封烧杯,静置发酵8天,待发酵结束,再向烧杯中加入300mL质量分数为15%氢氧化钠溶液,搅拌反应4h后,将烧杯中的物料取出,并置于离心机中,以4000r/min的转速离心分离15min,得到上层液,将上层液进行喷雾干燥,得到干燥物,取200g干燥物与灭菌物料混合5min,得到混合物料,将混合物料置于烧杯中,再向烧杯中接种混合物料质量8%的蚯蚓,并将烧杯移入恒温培养箱中,控制培养箱温度为25℃,对蚯蚓进行养殖15天,养殖期间每天向烧杯中喷洒清水,保持混合物料的含水率为50%,待养殖结束,分离去除蚯蚓,得到剩余物料,按重量份数计,取50份烧杯中的剩余物料、5份羧甲基纤维素、20份亚甲基双丙烯酰胺、12份衣康酸、0.5份过硫酸钠和80份水加入到烧杯中,将烧杯移入数显测速恒温磁力搅拌器中,于温度为70℃,转速为100r/min的条件下搅拌反应90min,再将烧杯中的物料自然冷却至室温,装料,即可得到印花浆。
实例3
首先称取2kg餐厨垃圾,平铺在木板上,于太阳下暴晒4天,取4500g暴晒后的餐厨垃圾、2kg膨润土加入到粉碎机中粉碎55min,得到粉碎物;取1000g粉碎物和200mL沼液,搅拌混合10min后置于发酵罐中,于温度为45℃条件下密封发酵8天,待发酵结束,将发酵罐中的物料取出,并置于高温灭菌箱中,于温度为130℃条件下高温灭菌20min,得到灭菌产物,称取600g大叶藻、1000g山药,用水清洗5次,将洗净的物料置于冷冻干燥箱中,于温度为-25℃条件下干燥5h,再将干燥后的物料置于粉碎机中粉碎,过100目筛,得到过筛物,称取8g酵母粉加入到300mL35℃温水中,搅拌混合3min后,静置15min,得到活化酵母液,将活化酵母液倒入盛有2L水的烧杯中,再向烧杯中加入1000g过筛物,搅拌混合5min后,用塑料薄膜密封烧杯,静置发酵8天,待发酵结束,再向烧杯中加入300mL质量分数为15%氢氧化钠溶液,搅拌反应4h后,将烧杯中的物料取出,并置于离心机中,以4000r/min的转速离心分离15min,得到上层液,将上层液进行喷雾干燥,得到干燥物,取200g干燥物与灭菌物料混合5min,得到混合物料,将混合物料置于烧杯中,再向烧杯中接种混合物料质量8%的蚯蚓,并将烧杯移入恒温培养箱中,控制培养箱温度为25℃,对蚯蚓进行养殖15天,养殖期间每天向烧杯中喷洒清水,保持混合物料的含水率为50%,待养殖结束,分离去除蚯蚓,得到剩余物料,按重量份数计,取50份烧杯中的剩余物料、5份羧甲基纤维素、3份聚二甲基硅氧烷、20份亚甲基双丙烯酰胺、12份衣康酸、0.5份过硫酸钠和80份水加入到烧杯中,将烧杯移入数显测速恒温磁力搅拌器中,于温度为70℃,转速为100r/min的条件下搅拌反应90min,再将烧杯中的物料自然冷却至室温,装料,即可得到印花浆。
对照例:由乳化糊、海藻酸钠等组成乳化增稠体系,再加入硫酸铵、粘合剂、涂料色浆制成印花浆。
抱水性能测试:分别取30mL实例1至实例3及对照例制备的印花浆,分别加入30mL蒸馏水中,搅拌均匀后,将划有刻度的滤纸插入搅拌均与后的印花浆液中,并在30min、1h时记录水在滤纸上的上升高度,以高度表示水合性能,高度越低,水合性能越好,抱水性能越好,检测数据见表1。
渗化率:采用电脑绘制点样进行测试,测试数据见表1。
表1
从表1可看出,本发明制备的印花浆抱水性能优越,不易渗透至织物中。

Claims (8)

1.一种印花浆,其特征在于,包括以下重量份数的原料:
3~5份羧甲基纤维素、15~20份亚甲基双丙烯酰胺、8~12份衣康酸、0.3~0.5份过硫酸钠和70~80份水。
2.根据权利要求1所述的一种印花浆,其特征在于,所述的原料按重量份数还包括40~50份剩余物料。
3.根据权利要求2所述的一种印花浆,其特征在于,所述的剩余物料是由混合物料喂养蚯蚓后去除蚯蚓后得到的。
4.根据权利要求3所述的一种印花浆,其特征在于,所述的混合物料是由干燥物与灭菌物料混合得到的。
5.根据权利要求4所述的一种印花浆,其特征在于,所述的干燥物是由大叶藻和山药经发酵、离心分离、干燥得到的。
6.根据权利要求4所述的一种印花浆,其特征在于,所述的灭菌物料是由餐厨垃圾和沼液经发酵、高温灭菌得到的。
7.根据权利要求1所述的一种印花浆,其特征在于,所述的原料按重量份数还包括1~3份聚二甲基硅氧烷。
8.根据权利要求所述的一种印花浆的制备方法,其特征在于印花浆制备过程为:将羧甲基纤维素、亚甲基双丙烯酰胺、衣康酸、过硫酸钠和水混合后,在60~70℃搅拌反应60~90min,即得印花浆。
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