CN107216932A - 一种铝合金拉伸用润滑剂 - Google Patents

一种铝合金拉伸用润滑剂 Download PDF

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CN107216932A
CN107216932A CN201710282827.XA CN201710282827A CN107216932A CN 107216932 A CN107216932 A CN 107216932A CN 201710282827 A CN201710282827 A CN 201710282827A CN 107216932 A CN107216932 A CN 107216932A
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aluminum alloy
lubricator
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alloy tensile
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华兴龙
华玲玲
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HUOSHAN LONGXIN METAL PRODUCTS CO Ltd
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Abstract

本发明公开一种铝合金拉伸用润滑剂，由以下重量份的组分制成：基础油80‑85份、亚麻仁油10‑15份、丁醛肟1‑2份、聚二硫二丙烷磺酸钠4‑7份、间硝基苯磺酸钠6‑9份、枸橼酸钠2‑3份、原油降凝剂2‑4份、缓蚀剂1‑2份、抗氧化剂2‑4份、防锈剂1‑3份、消泡剂0.8‑1.0份。本发明提供的铝合金拉伸用润滑剂，润滑性能显著，可以在金属表面有很好的附着性,形成均匀分布的润滑层,并且摩擦系数小,并能形成坚固的薄膜,并能承受较大的压力，可有效的防止加工零件和模具的受损。

Description

一种铝合金拉伸用润滑剂
技术领域
本发明属于铝合金拉伸用润滑剂领域，具体涉及一种铝合金拉伸用润滑剂。
背景技术
铝合金板材拉伸过程一般分为压边阶段和板材稳定变形阶段。在压边阶段，压边圈以一定速度向下运动，而凸模保持不动，在压边圈与板材和凹模与板材之间各有一层薄的润滑膜。此时润滑膜的厚度大于工件与模具表面的粗糙度值，表现为全膜润滑。当凸模加载向下运动后，使板料开始屈服并流向凹模型腔，形成稳定的塑性变形，法兰区域板材与模具表面之间还存在完整的润滑膜，因而不发生直接接触。而在凹模圆角区域，新鲜金属向板材表面转移，活性极大的新金属表面与与模具表面发生粘结，板材与模具发生直接接触，原先的润滑膜被隔离成不完整的润滑膜。随着拉伸过程的进行，粘结现象越来越严重，最终在凹模表面产生粘结瘤，部分受力剪切脱落的金属瘤随模具在板材表面滑动，严重划伤板料，导致拉伸无法进行或板料断裂。目前市售普通的铝合金拉伸用润滑剂，冷却性较差，会造成铝合金板材局部高温，从而造成烧结、拉伤和破裂的现象，严重影响了铝合金的品质。
发明内容
为了解决现有技术的不足，本发明提供一种铝合金拉伸用润滑剂。
本发明是通过以下技术方案实现的。
一种铝合金拉伸用润滑剂，由以下重量份的组分制成：基础油80-85份、亚麻仁油10-15份、丁醛肟1-2份、聚二硫二丙烷磺酸钠4-7份、间硝基苯磺酸钠6-9份、枸橼酸钠2-3份、原油降凝剂2-4份、缓蚀剂1-2份、抗氧化剂2-4份、防锈剂1-3份、消泡剂0.8-1.0份，采用以下方法制成：将基础油、亚麻仁油、丁醛肟混合后，放入3-5℃的环境中，冷藏4-5小时后，取出，等到其温度升至20℃以上时，向其中依次加入聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠、原油降凝剂、缓蚀剂、抗氧化剂、防锈剂、消泡剂，混合搅拌均匀后，制得铝合金拉伸用润滑剂。
具体地，所述基础油为圣益润滑油公司生产的糠醛抽出油、600SN基础油、400SN基础油中的任意一种。
具体地，所述原油降凝剂为苯乙烯与马来酸酐共聚物、α-烯烃-马来酸酐共聚物中的任意一种。
具体地，所述缓蚀剂为苯并三唑、磺化木质素、喹啉、EDTA、巯基苯并噻唑中的任意一种。
具体地，所述抗氧化剂为抗氧剂697、抗氧剂264、抗氧剂502中的任意一种。
具体地，所述防锈剂为二壬基萘磺酸钡t705防锈剂。
具体地，所述消泡剂为二甲基硅油、聚丙二醇中的任意一种。
由以上的技术方案可知，本发明的有益效果是：
本发明提供的铝合金拉伸用润滑剂，润滑性能显著，可以在金属表面有很好的附着性,形成均匀分布的润滑层,并且摩擦系数小,并能形成坚固的薄膜,并能承受较大的压力，可有效的防止加工零件和模具的受损。其中，将基础油、亚麻仁油、丁醛肟混合后经过冷藏处理，可有效的提升基础油的润滑性能，能进一步提升润滑油在铝合金表面的附着力，提升润滑油分子内碳氢键和碳碳键之间的牢固性，进而提升了金属表面薄膜的坚固性，有效的保护了加工零件和模具；聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠之间协同作用后，提升了润滑剂的导热性能，可及时的将加工过程中产生的热量传走，避免了温度持续上升造成的凸、凹模之间的间隙减小,施加在铝合金材料上的应力增大，从而造成烧结、拉伤和破裂等现象。
具体实施方式
以下实施例用来说明本发明，但不能用来限制本发明的范围，实施例中采用的实施条件可以根据厂家的条件作进一步调整，未说明的实施条件通常为常规实验条件。
实施例1
一种铝合金拉伸用润滑剂，由以下重量份的组分制成：基础油80份、亚麻仁油10份、丁醛肟1份、聚二硫二丙烷磺酸钠4份、间硝基苯磺酸钠6份、枸橼酸钠2份、原油降凝剂2份、缓蚀剂1份、抗氧化剂2份、防锈剂1份、消泡剂0.8份，采用以下方法制成：将基础油、亚麻仁油、丁醛肟混合后，放入3℃的环境中，冷藏4小时后，取出，等到其温度升至20℃以上时，向其中依次加入聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠、原油降凝剂、缓蚀剂、抗氧化剂、防锈剂、消泡剂，混合搅拌均匀后，制得铝合金拉伸用润滑剂。
具体地，所述基础油为圣益润滑油公司生产的糠醛抽出油。
具体地，所述原油降凝剂为苯乙烯与马来酸酐共聚物。
具体地，所述缓蚀剂为苯并三唑。
具体地，所述抗氧化剂为抗氧剂697。
具体地，所述防锈剂为二壬基萘磺酸钡t705防锈剂。
具体地，所述消泡剂为二甲基硅油。
实施例2
一种铝合金拉伸用润滑剂，由以下重量份的组分制成：基础油83份、亚麻仁油13份、丁醛肟1份、聚二硫二丙烷磺酸钠6份、间硝基苯磺酸钠7份、枸橼酸钠2份、原油降凝剂3份、缓蚀剂1份、抗氧化剂3份、防锈剂2份、消泡剂0.9份，采用以下方法制成：将基础油、亚麻仁油、丁醛肟混合后，放入4℃的环境中，冷藏4.5小时后，取出，等到其温度升至20℃以上时，向其中依次加入聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠、原油降凝剂、缓蚀剂、抗氧化剂、防锈剂、消泡剂，混合搅拌均匀后，制得铝合金拉伸用润滑剂。
具体地，所述基础油为圣益润滑油公司生产的600SN基础油。
具体地，所述原油降凝剂为α-烯烃-马来酸酐共聚物。
具体地，所述缓蚀剂为磺化木质素。
具体地，所述抗氧化剂为抗氧剂264。
具体地，所述防锈剂为二壬基萘磺酸钡t705防锈剂。
具体地，所述消泡剂为聚丙二醇。
实施例3
一种铝合金拉伸用润滑剂，由以下重量份的组分制成：基础油85份、亚麻仁油15份、丁醛肟2份、聚二硫二丙烷磺酸钠7份、间硝基苯磺酸钠9份、枸橼酸钠3份、原油降凝剂4份、缓蚀剂2份、抗氧化剂4份、防锈剂3份、消泡剂1.0份，采用以下方法制成：将基础油、亚麻仁油、丁醛肟混合后，放入5℃的环境中，冷藏5小时后，取出，等到其温度升至20℃以上时，向其中依次加入聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠、原油降凝剂、缓蚀剂、抗氧化剂、防锈剂、消泡剂，混合搅拌均匀后，制得铝合金拉伸用润滑剂。
具体地，所述基础油为圣益润滑油公司生产的400SN基础油。
具体地，所述原油降凝剂为α-烯烃-马来酸酐共聚物。
具体地，所述缓蚀剂为巯基苯并噻唑。
具体地，所述抗氧化剂为抗氧剂502。
具体地，所述防锈剂为二壬基萘磺酸钡t705防锈剂。
具体地，所述消泡剂为二甲基硅油。
对比例1
不添加亚麻仁油、丁醛肟，且不经过冷藏处理，其余成分与实施例1完全相同。
对比例2
不添加聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠成分，其余成分与实施例2完全相同。
分别用各实施例和对比例中的提供的成分和方法制得铝合金拉伸用润滑剂，然后投入一铝合金拉伸车间使用，每种润滑剂试验时间为3个月，测得这三个月内各组铝合金拉伸工艺的成品率，测试结果如表1所示：
表1不同润滑剂对铝合金拉伸工艺成品率的影响
项目 成品率/%
实施例1 99.1
对比例1 95.6
实施例2 99.4
对比例2 93.2
实施例3 99.5
由表1可知，本发明制得的润滑剂，可以有效的提升铝合金拉伸工艺中的成品率，有效的提高了拉伸的工作效率。
最后说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技术方案进行修改或者等同替换，而不脱离本发明技术方案的宗旨和范围，其均应涵盖在本发明的权利要求范围当中。

Claims (7)

1.一种铝合金拉伸用润滑剂，其特征在于，由以下重量份的组分制成：基础油80-85份、亚麻仁油10-15份、丁醛肟1-2份、聚二硫二丙烷磺酸钠4-7份、间硝基苯磺酸钠6-9份、枸橼酸钠2-3份、原油降凝剂2-4份、缓蚀剂1-2份、抗氧化剂2-4份、防锈剂1-3份、消泡剂0.8-1.0份，采用以下方法制成：将基础油、亚麻仁油、丁醛肟混合后，放入3-5℃的环境中，冷藏4-5小时后，取出，等到其温度升至20℃以上时，向其中依次加入聚二硫二丙烷磺酸钠、间硝基苯磺酸钠、枸橼酸钠、原油降凝剂、缓蚀剂、抗氧化剂、防锈剂、消泡剂，混合搅拌均匀后，制得铝合金拉伸用润滑剂。
2.根据权利要求1中所述的一种铝合金拉伸用润滑剂，其特征在于，所述基础油为圣益润滑油公司生产的糠醛抽出油、600SN基础油、400SN基础油中的任意一种。
3.根据权利要求1中所述的一种铝合金拉伸用润滑剂，其特征在于，所述原油降凝剂为苯乙烯与马来酸酐共聚物、α-烯烃-马来酸酐共聚物中的任意一种。
4.根据权利要求1中所述的一种铝合金拉伸用润滑剂，其特征在于，所述缓蚀剂为苯并三唑、磺化木质素、喹啉、EDTA、巯基苯并噻唑中的任意一种。
5.根据权利要求1中所述的一种铝合金拉伸用润滑剂，其特征在于，所述抗氧化剂为抗氧剂697、抗氧剂264、抗氧剂502中的任意一种。
6.根据权利要求1中所述的一种铝合金拉伸用润滑剂，其特征在于，所述防锈剂为二壬基萘磺酸钡t705防锈剂。
7.根据权利要求1中所述的一种铝合金拉伸用润滑剂，其特征在于，所述消泡剂为二甲基硅油、聚丙二醇中的任意一种。
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CN103031189A (zh) * 2011-10-10 2013-04-10 洛科斯润滑油（上海）有限公司 金属拉伸油
CN104099079A (zh) * 2013-04-03 2014-10-15 中国石油天然气集团公司 一种原油降凝剂及其制备方法
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CN103031189A (zh) * 2011-10-10 2013-04-10 洛科斯润滑油（上海）有限公司 金属拉伸油
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