CN107183026A - A kind of composition pesticide and its application containing Enestroburin and fluazinam - Google Patents
A kind of composition pesticide and its application containing Enestroburin and fluazinam Download PDFInfo
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- CN107183026A CN107183026A CN201710442584.1A CN201710442584A CN107183026A CN 107183026 A CN107183026 A CN 107183026A CN 201710442584 A CN201710442584 A CN 201710442584A CN 107183026 A CN107183026 A CN 107183026A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- General Health & Medical Sciences (AREA)
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Abstract
The invention discloses a kind of composition pesticide containing Enestroburin and fluazinam, the composition pesticide includes active ingredient Enestroburin and fluazinam, and the mass ratio of the Enestroburin and fluazinam is 20:1~1:20;The invention also discloses application of the composition pesticide containing Enestroburin and fluazinam in terms of rice blast is prevented and treated.The composition pesticide of the present invention alleviates rice blast fungus respectively to Enestroburin and the potential resistance risk of fluazinam, and after Enestroburin and fluazinam combination, therebetween with obvious synergistic effect, effect is notable in terms of rice blast is prevented and treated.
Description
Technical field
The present invention relates to rice disease pesticide control, and in particular to a kind of composition pesticide containing Enestroburin and fluazinam
And its application.
Background technology
Rice blast (Rice Blast), is China as caused by rice blast fungus (Magnaporthe grisea)
Endanger one of rice disease of most serious.Rice blast, which has, propagates the spies such as fast, occurrence scope is wide, break out frequency height, catastrophe is serious
Point, has generation in China various regions, wherein being occured as with leaf portion, section portion many, the different degrees of underproduction, especially fringe can be caused after generation
Neck pest or section pest occur early and weighed, and can cause dead ears so that total crop failure.
Currently, the pesticide control of the disease mainly has carbendazim (carbendazim), thiophanate-methyl
(thiophanatemethyl), Prochloraz (prochloraz), tricyclazole (tricyclazole), kitazine (kitazine),
The medicament such as different rice blast net (iprobenfos) and kasugarnycin (kasugamycin).Carbendazim, thiophanate-methyl, kitazine and
The resistance to the action of a drug is generated after the various medicaments such as kasugarnycin, chronic administration, causes pharmacy control efficacy to reduce.Therefore, exploitation preventing and treating rice
The new medicament of seasonal febrile diseases, to ensureing that the high yield and stable yields of paddy rice have great importance.
The content of the invention
Goal of the invention:The problem of existing for the preventing and treating of rice blast in the prior art, the present invention provides a kind of oxime containing alkene
The composition pesticide of bacterium ester and fluazinam;The present invention also provides application of the composition pesticide in terms of rice blast is prevented and treated.
Technical scheme:To achieve these goals, the invention provides a kind of agricultural chemicals group containing Enestroburin and fluazinam
Compound, the composition pesticide includes active ingredient Enestroburin and fluazinam, the mass ratio of the Enestroburin and fluazinam
For 20:1~1:20.
It is preferred that, the mass ratio of the active ingredient Enestroburin and fluazinam is 10:1~1:10.
It is preferred that, fludioxonil is also included in the composition pesticide, its consumption is chlorine nalidixic bacterium ester and fluazinam gross mass
0.01-0.05 times.
It is preferred that, auxiliary agent is also included in the composition pesticide.
The auxiliary agent is filler, wetting agent, dispersant, solvent, surfactant, emulsifying agent, stabilizer, thickener, anti-
The one or more frozen in agent, antiprecipitant, defoamer.
The formulation of the composition pesticide is wettable powder (WP), suspending agent (SC), water dispersible granules (WG) or water and milk
Agent (EW).
In the composition pesticide active ingredient Enestroburin and fluazinam in the composition percentage composition be 1%~
90%.
It is of the invention finally to additionally provide the described composition pesticide containing Enestroburin and fluazinam in preventing and treating paddy rice rice blast
Application in terms of disease.
The high bactericide of Enestroburin (enestroburin) category methoxy acrylic wide sterilization spectrum, activity, has
Prevention and therapeutic action, have good to the plurality of plant diseases as caused by mastigomycetes, zygomycete, sac fungus, basidiomycetes and Fungi Imperfecti
Good prevention effect.The medicine be fungal mitochondria respiration inhibitor, its mechanism of action be by with cytochrome b c1 complexs
Combination, suppress mitochondrial electron transmission, so as to destroy the synthesis of pathogen energy, play bactericidal action.
Fluazinam (fluazinam) is 2,6- dinitroanilines, and resistance of rainwater washing against, the lasting period is long, its drug effect
Better than conventional protective fungicide, also have well to a variety of pathogens of anti-benzimidazole type and dicarboximide class biocide agent
Effect.
In addition, can also include fludioxonil in composition pesticide of the present invention, the amount of very little is used only in the raw material, can be notable
The prevention effect that increase Enestroburin and fluazinam are used in combination.
Technique effect:Compared with prior art, the pesticide combination preparation of the invention containing Enestroburin and fluazinam has
Following advantage:
(1) drug-fast generation and development are delayed:The pesticide combination that the present invention is provided is compounded by Enestroburin and fluazinam
Form, can be used with a variety of existing medicament rotations such as the carbendazim in production, thiophanate-methyl, kitazine and kasugarnycin,
Rice blast fungus development drug-fast to existing medicament is delayed with spreading;Rice blast fungus are alleviated respectively to alkene simultaneously
The potential resistance to the action of a drug of trifloxystrobin and fluazinam.
(2) medicine synergy is subtracted:It is and many between the two with obvious synergistic effect after Enestroburin and fluazinam compounding
Bacterium spirit, thiophanate-methyl, kitazine and a variety of existing medicaments such as kasugarnycin are compared can the raising pair while dosage is reduced
The prevention effect of rice blast.
Embodiment
According to following embodiments, the present invention may be better understood.However, as it will be easily appreciated by one skilled in the art that
Content described by embodiment is merely to illustrate the present invention, without should be also without limitation on described in detail in claims
The present invention.
Embodiment 1
21% Enestroburin fluazinam WP preparation:
By mass percentage, wettable powder each group distribution ratio is:20% Enestroburin, 1% fluazinam, 5% carboxylic first
Base sodium cellulosate (surfactant), 4% pull open powder (wetting agent) supplies surplus with kaolin (filler).
Preparation method:
Got the raw materials ready by said ratio and through conventional wettable powder preparation for processing, prepare 21% Enestroburin fluazinam
WP。
Embodiment 2
21% Enestroburin fluazinam SC preparation:
By mass percentage, suspending agent each component proportioning is:1% Enestroburin, 20% fluazinam, 5% sulfomethylated lignin
Sour sodium (dispersant), 5% alkylnaphthalene sulfonate (wetting agent), 0.1% polyvinyl alcohol (thickener), 0.1% ethylene glycol is (antifreeze
Agent), 0.01% organosilicon (defoamer) supplies surplus with water.
Preparation method:
Two active compound Enestroburins, fluazinam are added to the water, is stirred in stirred tank to homogeneous liquid, adds sulfomethylated lignin
Sour sodium (dispersant), alkylnaphthalene sulfonate (wetting agent) after stirring, is slowly added to use under 80~150rpm mechanical agitations
Polyvinyl alcohol (thickener) after water dilution, ethylene glycol (antifreezing agent), organosilicon (defoamer) supplies 100% content with water;Grind
Liquid material is conveyed using air compression pipe during mill, is continuously sanded using the sand mill of 4 series connection, 21% alkene oxime bacterium is made
Ester fluazinam SC.
Embodiment 3
20% Enestroburin fluazinam WP preparation:
By mass percentage, wettable powder each group distribution ratio is:10% Enestroburin, 10% fluazinam, 6% carboxylic first
Base sodium cellulosate (surfactant), 4% pull open powder (wetting agent) supplies surplus with kaolin (filler).
Preparation method:
Got the raw materials ready by said ratio and through conventional wettable powder preparation for processing, prepare 20% Enestroburin fluazinam
WP。
Embodiment 4
15% Enestroburin fluazinam SC preparation:
By mass percentage, suspending agent each component proportioning is:10% Enestroburin, 5% fluazinam, 10% sulfomethylated lignin
Sour sodium (dispersant), 10% alkylnaphthalene sulfonate (wetting agent), 5% polyvinyl alcohol (thickener), 5% ethylene glycol (antifreezing agent),
2% organosilicon (defoamer), surplus is supplied with water.
Preparation method:
Two active compound Enestroburins, fluazinam are added to the water, is stirred in stirred tank to homogeneous liquid, adds sulfomethylated lignin
Sour sodium (dispersant), alkylnaphthalene sulfonate (wetting agent) after stirring, is slowly added to use under 80~150rpm mechanical agitations
Polyvinyl alcohol (thickener) after water dilution, ethylene glycol (antifreezing agent), organosilicon (defoamer) supplies 100% with water;During grinding
Liquid material is conveyed using air compression pipe, is continuously sanded using the sand mill of 4 series connection, 15% Enestroburin fluorine is made
Pyridine amine SC.
Embodiment 5
15% Enestroburin fluazinam SC preparation:
By mass percentage, suspending agent each component proportioning is:5% Enestroburin, 10% fluazinam, 5% sulfomethylated lignin
Sour sodium (dispersant), 5% alkylnaphthalene sulfonate (wetting agent), 0.1% polyvinyl alcohol (thickener), 0.1% ethylene glycol is (antifreeze
Agent), 0.01% organosilicon (defoamer) supplies surplus with water.
Preparation method:
Two active compound Enestroburins, fluazinam are added to the water, is stirred in stirred tank to homogeneous liquid, adds sulfomethylated lignin
Sour sodium (dispersant), alkylnaphthalene sulfonate (wetting agent) after stirring, is slowly added to use under 80~150rpm mechanical agitations
Polyvinyl alcohol (thickener) after water dilution, ethylene glycol (antifreezing agent), organosilicon (defoamer) supplies 100% with water;During grinding
Liquid material is conveyed using air compression pipe, is continuously sanded using the sand mill of 4 series connection, 15% Enestroburin fluorine is made
Pyridine amine SC.
Embodiment 6
11% Enestroburin fluazinam WS preparation:
By mass percentage, wettable powder each group distribution ratio is:1% Enestroburin, 10% fluazinam, 10% alkyl
Phenol polyethenoxy ether (wetting agent), 10% sodium lignin sulfonate (dispersant), 3% sodium carboxymethylcellulose (thickener), 4% second
Glycol (antifreezing agent), 2% organosilicon (defoamer), surplus is supplied with water.
Preparation method:
Two active compound Enestroburins, fluazinam are added to the water, is stirred in stirred tank to homogeneous liquid, adds sulfomethylated lignin
Sour sodium (dispersant), APES (wetting agent) delays after stirring under 80~130rpm/min mechanical agitations
Slow sodium carboxymethylcellulose (thickener), ethylene glycol (antifreezing agent) and the organosilicon (defoamer) added after being diluted with water, finally
100% content is supplied with water;Feed liquid is conveyed using air compressed pipe during grinding, continuous sand is carried out using the sand mill of 4 series connection
Mill, is made 11% Enestroburin fluazinam WS.
Embodiment 7
10% Enestroburin fluazinam EW preparation:
By mass percentage, aqueous emulsion each group distribution ratio is:6% Enestroburin, 4% fluazinam, 18% dimethylbenzene (has
Machine solvent), 6% Tween-40 (emulsifying agent), 4% ethylene glycol (antifreezing agent), 1% organosilicon (defoamer) supplies surplus with water.
Preparation method:
First add water in stirred tank, then sequentially add antifreezing agent and defoamer, start high shear mixers mixing
After 20-30 minutes, the oil phase liquid being well mixed by Enestroburin, fluazinam, organic solvent and emulsifying agent is slowly added to, it is high
10% Enestroburin fluazinam EW is made after 1.5 hours in fast stir about.
Embodiment 8
20% Enestroburin fluazinam WP preparation:
By mass percentage, wettable powder each group distribution ratio is:10% Enestroburin, 10% fluazinam, 0.6% coughs up
Bacterium nitrile 0.03 times of fluazinam gross mass (Enestroburin and), 6% sodium carboxymethylcellulose (surfactant), 4% pull open powder
(wetting agent), surplus is supplied with kaolin (filler).
Preparation method:
Got the raw materials ready by said ratio and through conventional wettable powder preparation for processing, prepare 20% Enestroburin fluazinam
WP.The preparation method is similar to Example 3, and difference is in preparation process to add Enestroburin and fluazinam gross mass
0.03 times of fludioxonil.
Embodiment 9
20% Enestroburin fluazinam WP preparation:It is substantially the same manner as Example 8, it the difference is that only and preparing
0.2% fludioxonil 0.01 times of fluazinam gross mass (Enestroburin and) is added in journey.
Embodiment 10
20% Enestroburin fluazinam WP preparation:It is substantially the same manner as Example 8, it the difference is that only and preparing
1% fludioxonil 0.05 times of fluazinam gross mass (Enestroburin and) is added in journey.
Test example 1
Bacteriostatic activity of the single dose and built agent of Enestroburin and fluazinam to rice blast fungus:
(1) strains tested:Rice blast fungus (Magnaporthe grisea), pick up from Jurong City of Jiangsu Province rice terrace,
Separated by Zhenjiang City,Agriculture Science Research Institute plant protection research department, identify and save backup.Bacterial strain is stored in potato sucrose agar
(PSA) (4 DEG C) on inclined-plane.
(2) reagent agent:90% Enestroburin (enestroburin) active compound, is carried by Shenyang Sciencreat Chemicals Co., Ltd.
For;97% fluazinam (fluazinam) active compound, is provided by Jiangsu Weier Chemical Co., Ltd.
(3) test method:Reference《Pesticide bioassay test rule NY/T1156.2-2006》, using mycelial growth speed
Rate method carries out the Toxicity Determination of reagent agent single dose and different ratio built agent to rice blast fungus.
(4) data analysis:Using DPS13.0 professional version data handling systems, medicament single dose and different ratio compounding are calculated
Agent is to the growth inhibiting regression equation of rice blast mycelia, EC50And its 95% confidence limit.
According to Wadley methods, coefficient of synergism (SR) is calculated.The synergy of pharmacy mix is evaluated according to coefficient of synergism (SR)
Type, i.e. SR<0.5 is antagonism, and 0.5≤SR≤1.5 are summation action, SR>1.5 be synergistic effect.SR=EC50(Eth)/
EC50(Eob), EC50(Eth)=(a+b)/[(a/EC50A)+(b/EC50B)].Wherein, A, B are respectively medicament single dose, and a, b are phase
Answer ratio of the single dose in mixture, EC50(Eth) it is mixture EC50Theoretical value, EC50(Eob) it is mixture EC50Measured value.
(5) result and analysis:
The Enestroburin of table 1, fluazinam and its built agent are to rice blast fungus bioactivity (virulence) measurement result
Indoor measurement result shows, Enestroburin and fluazinam suppress the EC of rice blast fungus mycelial growth50Value difference
For 0.4913 and 0.3175 μ g/mL.Enestroburin and fluazinam compounding, ratio is between 20: 1~1: 20, built agent pair
The antibacterial coefficient of synergism of rice blast fungus is between 1.61~9.36, with synergistic effect;Ratio is 10: 1~1: 10
Between when, the built agent coefficient of synergism antibacterial to rice blast fungus is all higher than between 2.0, with more preferable synergistic effect (table
1).Therefore Enestroburin and the optimum ratio of fluazinam compounding are set in 10: 1~1:Between 10.
Test example 2
By 20% Enestroburin fluazinam WP obtained by embodiment 3, and respectively by Enestroburin and fluazinam by implementation
The method preparation 20% Enestroburin WP and 20% fluazinam WP that example 3 prepares wettable powder does single dose contrast, while with 75%
Tricyclazole WP (Jiangsu Changqing Agricultural Chemistry Co., Ltd.) carries out the field efficacy examination of preventing and treating rice blast as comparison medicament
Test.
Test process method:Test site is located at the agricultural technology renovation of Jiangsu Hilly Ground Zhenjiang Agriculture Science Research Institute
Experimental plot in the garden of center, soil is horse liver soil, middle fertility, the content of organic matter 1.75%.Rice varieties are town 18, examination
Field management conventional during testing.Experiment sets 6 processing, is respectively:20% Enestroburin fluazinam WP 600 and 900g/
hm2, 20% Enestroburin WP 900g/hm2, 20% fluazinam WP 900g/hm2, 75% tricyclazole WP 300g/hm2(recommend agent
Amount) and clear water blank control.Each processing is repeated 3 times, totally 18 cells, and plot area is 30m2, cell set protection row and with
Machine district's groups are arranged.In paddy rice cut phase (on September 5th, 2016), WBD-16 is produced using Zhengzhou Lv Di farm machineries Co., Ltd
Type power spraye, sprays, spouting liquid is 750L/hm in rice leaf and fringe portion2, blank district sprays equivalent clear water.Examination
Other bactericide are no longer sprayed during testing, field management is routinely carried out.In 28d after medicine (on October 3rd, 2016), jumped with parallel
Jump Sample Method Survey spike of rice pest incidence, and each cell investigates 20 caves, and calculates disease index and prevention effect.Disease index
It is respectively with prevention effect calculation formula:Disease index=[Σ (sick spike numbers at different levels × corresponding sick value of series)/total spike number of investigation ×
Highest typical value] × 100;Prevention effect=[(control disease index-processing disease index)/control disease index] ×
100%.
Result of the test shows, 20% Enestroburin fluazinam WP 900g/hm2To the preventive effect highest of rice blast,
20% fluazinam WP 900g/hm2Preventive effect to rice blast is minimum.5 chemicals treatments to the preventive effect of rice blast from high to low
It is followed successively by 20% Enestroburin fluazinam WP 900g/hm2, 20% Enestroburin fluazinam WP 600g/hm2, 20% alkene oxime
Bacterium ester WP 900g/hm2, 75% tricyclazole WP 300g/hm2With 20% fluazinam WP 900g/hm2, preventive effect is respectively
89.60%th, 82.29%, 75.24%, 68.53% and 63.54%.20% Enestroburin fluazinam WP 600 and 900g/hm2
Preventive effect to rice blast is above the Enestroburin WP of single dose 20% and 20% fluazinam WP 900g/hm2And comparison medicament 75%
Tricyclazole WP 300g/hm2Preventive effect and significant difference (table 2).This shows, the pesticide combination pair containing Enestroburin and fluazinam
Preferably, also synergy is obvious for field efficacy compared with single dose for the preventive effect of rice blast;Preventive effect when being applied under doses is significantly excellent
The preventive effect applied in conventional dose tricyclazole under recommended dose.
Field efficacies of the Enestroburin fluazinam WP of table 2 20% to rice blast
Note:Significant difference (P is represented with different lowercase persons are indicated after column data<0.05).
Test example 3
With test example 2, difference is that the composition pesticide of the present invention applied is embodiment 3 and the gained medicine of embodiment 8
Agent, investigates the difference to rice blast field efficacy after addition auxiliary material fludioxonil, as a result as follows:
Result of the test shows, 20% Enestroburin fluazinam WP 600g/hm2Preventive effect to rice blast is
84.69%, 0.6% fludioxonil of addition 0.03 times of fluazinam gross mass (Enestroburin and), 20% Enestroburin fluazinam afterwards
WP 600g/hm2Preventive effect to rice blast is 90.54%, both preventive effect significant differences;20% Enestroburin fluazinam
WP 900g/hm2Preventive effect to rice blast is 90.76%, adds 0.6% fludioxonil (Enestroburin and fluazinam gross mass
0.03 times) 20% Enestroburin fluazinam WP 900g/hm afterwards2Preventive effect to rice blast is 94.51%, Liang Zhefang
Imitate difference also notable (table 3).This shows, adds that reagent is supplied after auxiliary material fludioxonil in the pesticide combination of Enestroburin and fluazinam
Agent is combined has obvious synergistic effect to the field efficacy of rice blast.
Field efficacy (drug effect ratios addition fludioxonil after of the Enestroburin fluazinam WP of table 3 20% to rice blast
Compared with)
Note:Significant difference (P is represented with different lowercase persons are indicated after column data<0.05).
Claims (8)
1. a kind of composition pesticide containing Enestroburin and fluazinam, it is characterised in that the composition pesticide include effectively into
Divide Enestroburin and fluazinam, the mass ratio of the Enestroburin and fluazinam is 20:1~1:20.
2. the composition pesticide according to claim 1 containing Enestroburin and fluazinam, it is characterised in that it is described effectively into
The mass ratio for dividing Enestroburin and fluazinam is 10:1~1:10.
3. the composition pesticide according to claim 1 containing Enestroburin and fluazinam, it is characterised in that the agricultural chemicals group
Also include fludioxonil in compound, its consumption is 0.01-0.05 times of chlorine nalidixic bacterium ester and fluazinam gross mass.
4. the composition pesticide according to claim 1 containing Enestroburin and fluazinam, it is characterised in that the agricultural chemicals group
Also include auxiliary agent in compound.
5. the composition pesticide according to claim 4 containing Enestroburin and fluazinam, it is characterised in that the auxiliary agent is
Filler, wetting agent, dispersant, solvent, surfactant, emulsifying agent, stabilizer, thickener, antifreezing agent, antiprecipitant, froth breaking
One or more in agent.
6. the composition pesticide according to claim 1 containing Enestroburin and fluazinam, it is characterised in that the agricultural chemicals group
The formulation of compound is wettable powder (WP), suspending agent (SC), water dispersible granules (WG) or aqueous emulsion (EW).
7. the composition pesticide according to claim 1 containing Enestroburin and fluazinam, it is characterised in that the agricultural chemicals group
Percentage composition is 1%~90% in the composition for active ingredient Enestroburin and fluazinam in compound.
8. the composition pesticide containing Enestroburin and fluazinam described in claim any one of 1-7 is in preventing and treating rice blast side
The application in face.
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CN103109814A (en) * | 2013-03-04 | 2013-05-22 | 中化蓝天集团有限公司 | Disease-preventing suspended seed coating containing fludioxonil and fluazinam |
CN105265434A (en) * | 2014-07-18 | 2016-01-27 | 中化农化有限公司 | Pesticide composition containing fludioxonil |
CN105409961A (en) * | 2016-01-08 | 2016-03-23 | 深圳诺普信农化股份有限公司 | Sterilization composition containing fluazinam and application thereof |
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