CN107075430A - 具有洗涤活性基质的重垢型洗衣用清洁剂擦 - Google Patents
具有洗涤活性基质的重垢型洗衣用清洁剂擦 Download PDFInfo
- Publication number
- CN107075430A CN107075430A CN201580057091.5A CN201580057091A CN107075430A CN 107075430 A CN107075430 A CN 107075430A CN 201580057091 A CN201580057091 A CN 201580057091A CN 107075430 A CN107075430 A CN 107075430A
- Authority
- CN
- China
- Prior art keywords
- detergent
- matrix
- laundry detergent
- phase
- wiped
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 58
- 239000011159 matrix material Substances 0.000 title claims abstract description 37
- 239000007787 solid Substances 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 claims abstract description 14
- 238000009826 distribution Methods 0.000 claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000010457 zeolite Substances 0.000 claims abstract description 9
- 239000007844 bleaching agent Substances 0.000 claims abstract description 6
- 238000009994 optical bleaching Methods 0.000 claims abstract description 6
- 229910052615 phyllosilicate Inorganic materials 0.000 claims abstract description 6
- 238000007306 functionalization reaction Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 14
- 238000002803 maceration Methods 0.000 claims description 9
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 230000002209 hydrophobic effect Effects 0.000 claims description 4
- 238000002386 leaching Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000012209 synthetic fiber Substances 0.000 claims 2
- 229920002994 synthetic fiber Polymers 0.000 claims 2
- 239000002198 insoluble material Substances 0.000 claims 1
- 239000012459 cleaning agent Substances 0.000 description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 8
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 102000004190 Enzymes Human genes 0.000 description 5
- 108090000790 Enzymes Proteins 0.000 description 5
- 239000000470 constituent Substances 0.000 description 5
- 230000036541 health Effects 0.000 description 5
- -1 polypropylene Polymers 0.000 description 5
- 229920001202 Inulin Polymers 0.000 description 4
- 239000011149 active material Substances 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 229910021538 borax Inorganic materials 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 description 4
- 229940029339 inulin Drugs 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 239000003002 pH adjusting agent Substances 0.000 description 4
- 239000003755 preservative agent Substances 0.000 description 4
- 230000002335 preservative effect Effects 0.000 description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 4
- 239000000344 soap Substances 0.000 description 4
- 235000010339 sodium tetraborate Nutrition 0.000 description 4
- 239000004328 sodium tetraborate Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- NSFKBZXCXCJZDQ-UHFFFAOYSA-N cumene;sodium Chemical compound [Na].CC(C)C1=CC=CC=C1 NSFKBZXCXCJZDQ-UHFFFAOYSA-N 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012052 hydrophilic carrier Substances 0.000 description 1
- 239000012051 hydrophobic carrier Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000006386 memory function Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了均质三相洗衣用清洁剂擦和用于制造所述洗衣用清洁剂擦的方法，其中将不溶于水和环境温度下为固体的洗涤活性物质掺合入环境温度下为固体的基质，以使得在掺合之后所述物质跨所述基质均质分布，并且其中用浸渍液体浸渍因此功能化的所述基质。掺合入所述擦的物质可为沸石和/或层状硅酸盐和/或光学增白剂。
Description
发明领域
本发明涉及用于清洁纺织品的重垢型洗衣用清洁剂擦，并且具体而言涉及其中基质包括均质分布的洗涤活性组分的重垢型洗衣用清洁剂擦，并且涉及用于制造所述洗衣用清洁剂擦的方法。
背景技术
人类一直存在对卫生的追求。最终卫生成为日常生活的重要方面。卫生方法主要在于维持健康。除了一般的清洗效果外，由于其扩展的应用可能性，逐渐重视原材料组合物的气味和改善的清洗能力。清洗能力的优化尤其以提升卫生清洗水平的能力和清洗程度的改进为特征。
现在卫生可以分为身体、表面和纺织品卫生领域。后者还根据纺织品材料和有色(color)划分应用。至少从20世纪90年代初以来，消费者已经意识到生态清洁概念。在这一点上，理想的是一方面维持传统的清洁剂优势，另一方面寻求进一步创新和生态可行性产品方案。
工业生产的初期，洗衣用清洁剂以粉末出现。如今，粉末状洗衣用清洁剂由不同洗涤活性物质的混合物组成。
随着洗衣用清洁剂酶剂的发展进程，其他新表面活性物组合物也进入该市场领域。如今，除了清洗必需物质以外，还添加了大量的填充材料。相应的，不必改变消费者定量使用习惯。第一次尝试不使用填充材料，导致由于用户习惯的应用而过量加入表面活性剂。
液体清洁剂因可无残留定量加料而作为洗衣用清洁剂固体的混合物的物理替代品引入。然而，至今液体清洁剂不能实现重垢洗衣用清洁剂(即固体混合物)的清洗水平。这是由于液体清洁剂受限于液体成分或水溶解性好的成分。液体清洁剂中缺失的关键物质是沸石。沸石在使用时，支持吸附污垢以及增白(brightening)/固定颜色。
现有产品的趋势是分配清洁剂的简化方式。一方面，这可通过将液态清洁剂包裹于小聚合物囊(pouch)中来实现。清洁剂的另一物理改良方法在于将清洁剂与脂肪醇混合以获得所需形式。DE10 2010 060 126 A1公开，提供了一种洗衣用清洁剂擦形式的两相产品，其特征在于将亲水性载体材料和浸渍液组合。
与此相对，DE 10 2013 014 015公开了一种三相产品，其中将分散体施加至在环境温度为固体的基质。由于首次使用分散体，可实现具有粉末状洗涤清洁剂(沸石、层状硅酸盐)的特征的清洁力。已使用了主要疏水性的载体基质，因为洗衣用清洁剂分散体由于与两相体系相比更大量的洗涤活性物质而所致的亲水性特征。DE 10 2014 004 915公开了洗涤活性物质更均质分布的进一步改进三相产品和用于制造所述三相产品的方法。
因此，本发明的目的在于提供洗衣用清洁剂擦，其具有基质上洗涤活性物质和分散体固体组分的各自均质分布，以便实现活性物质进一步改进的分布和因此洗衣用清洁剂擦的更好性能。
发明内容
本发明的目的在于提供三相洗衣用清洁剂擦，其显示出基质上洗涤活性物质和分散体固体组分的各自更均匀、具体而言均质的分布。本发明的另一目的在于提供用于制造所述洗衣用清洁剂擦的方法。
此目的已通过根据权利要求1的用于制造均质三相洗衣用清洁剂擦的方法来实现，所述方法的特征在于以下步骤：(a)将不溶于水和环境温度下为固体的洗涤活性物质掺合入环境温度下为固体的基质，以使得在掺合之后所述物质在基质之上均质分布，(b)用浸渍液浸渍因此功能化的基质。
此目的还已通过根据权利要求6的三相洗衣用清洁剂擦来实现，所述洗衣用清洁剂擦包括环境温度下为固体并用浸渍液浸渍的基质，其特征在于不溶于水和环境温度下为固体的洗涤活性物质已被掺合入基质，以使得所述物质在基质之上均质分布。
本发明的三相洗衣用清洁剂擦和其制造方法较佳的实施方案公开于从属权利要求中。
具体实施方案
大体上，在基质上洗涤活性物质和分散体固体组分的各自分布并不均质。具有洗涤活性物质和固体组分各自均质分布的本发明三相洗衣用清洁剂擦可通过在基质的制造过程期间——即在应用浸渍液之前，将至今已为应用于基质的分散体组分的次级增洁剂(沸石和/或层状硅酸盐和/或光学增白剂)掺合在环境温度下为固体的基质中来实现。固体水不溶性添加剂可在基质固化之前通过水浴来添加。或者，沸石和/或层状硅酸盐可在基质制造期间经由悬浮分散体(例如，添加剂/水)喷涂至基质上。
掺合固体水不溶性和洗涤活性物质(此处：沸石和/或层状硅酸盐和/或光学增白剂)导致具有组分的基质活化，这提供了具有重垢型洗衣用清洁剂特征的三相最终产物。在掺合固体之后，利用为液体清洁剂的浸渍液浸渍因此功能化的基质。功能化基质的浸渍可通过浸于浸浴中、将液体清洁剂喷涂至活化基质上或者使用一个或多个湿润杆用液体清洁剂湿润基质来获得。
在应用浸渍液之前将水不溶性固体掺合入基质的方法具有以下优点：
a)更大颗粒适用性
b)洗涤活性和水不溶性固体跨整个基质深度分布(均质分布)
c)掺合入基质的功能性固体的储存功能导致洗涤过程期间颗粒更持久扩散，以使得颗粒可在更长时段内利用。
来自长丝纤维(连续长丝)、具体而言来自以下材料的无纺布适合用于基质：
-聚丙烯
-聚乙烯
-粘胶
-聚酯
-聚酰胺
-和这些原料的多种混合物。
上述用于基质的原料可为(一种或多种长丝纤维的)纤维混合物以及接合纤维(套芯或并列)。上述组分为疏水的并且因此具有吸附亲水洗涤水中的疏水纺织颜色的有利特征。
本发明可用于所有种类的洗衣用清洁剂。例如，使用以下洗衣用洗涤液：
重垢型洗衣用清洁剂擦(通用)：
| 阴离子表面活性剂 |
| 非离子表面活性剂 |
| 膦酸酯/复合增洁剂(complex builder) |
| C10-C18脂肪酸盐 |
| 光学增白剂 |
| 酶 |
| 稳定剂(丙二醇、甘油、硼砂、菊粉) |
| 香料(scent) |
| 防腐剂 |
| 去污聚合物 |
| pH调节剂 |
彩色洗衣用清洁剂擦(彩色)：
| 阴离子表面活性剂 |
| 非离子表面活性剂 |
| 膦酸酯/复合增洁剂 |
| C10-C18脂肪酸盐 |
| 着色剂 |
| 色彩转移保护 |
| 助水溶物(异丙苯磺酸钠) |
| 酶 |
| 稳定剂(丙二醇、甘油、硼砂、菊粉) |
| 香水 |
| 防腐剂 |
| 去污聚合物 |
| pH调节剂 |
黑色洗衣用清洁剂擦(黑色)：
白色洗衣用清洁剂擦(白色)：
| 阴离子表面活性剂 |
| 非离子表面活性剂 |
| C10-C18脂肪酸盐 |
| 光学增白剂 |
| 去污聚合物 |
| 色彩转移保护 |
| 酶 |
| 稳定剂(丙二醇、甘油、硼砂、菊粉) |
| 着色剂 |
| 遮光剂 |
| 香料 |
| 防腐剂 |
| pH调节剂 |
精细洗衣用清洁剂擦：
| 阴离子表面活性剂 |
| 非离子表面活性剂 |
| C10-C18脂肪酸盐 |
| 膦酸酯/复合增洁剂 |
| 色彩转移保护 |
| 酶 |
| 稳定剂(丙二醇、甘油、硼砂、菊粉) |
| 香料 |
| 消泡剂 |
| 防腐剂 |
| pH调节剂 |
羊毛洗衣用清洁剂擦：
浸渍液的液体洗涤清洁剂可具有大于500mPas的粘度。此外，可包括重垢型洗衣用清洁剂的所有已知组分。
Claims (10)
1.一种用于制造均质三相洗衣用清洁剂擦的方法，其特征在于以下步骤：
(a)将不溶于水和环境温度下为固体的洗涤活性物质掺合入环境温度下为固体的基质，以使得在掺合之后所述物质在所述基质之上均质分布，(b)用浸渍液浸渍因此功能化的所述基质。
2.根据权利要求1所述的用于制造均质三相洗衣用清洁剂擦的方法，其特征在于所述洗涤活性水不溶性物质包括沸石和/或层状硅酸盐和/或光学增白剂。
3.根据权利要求1或2所述的用于制造均质三相洗衣用清洁剂擦的方法，其特征在于所述基质由至少一种连续长丝或接合纤维组成。
4.根据权利要求1-3中任一项所述的用于制造均质三相洗衣用清洁剂擦的方法，其特征在于所述基质由至少一种疏水合成纤维组成以使得它提供颜色吸附。
5.根据权利要求1-4中任一项所述的用于制造均质三相洗衣用清洁剂擦的方法，其特征在于所述浸渍液为液体清洁剂。
6.一种三相重垢型洗衣用清洁剂擦，其包括环境温度下为固体并用浸渍液浸渍的基质，其特征在于不溶于水和环境温度下为固体的洗涤活性物质已被掺合入所述基质，以使得所述物质在所述基质之上均质分布。
7.根据权利要求6所述的三相重垢型洗衣用清洁剂擦，其特征在于所述洗涤活性水不溶性物质包括沸石和/或层状硅酸盐和/或光学增白剂。
8.根据权利要求6或7中任一项所述的三相重垢型洗衣用清洁剂擦，其特征在于所述基质由至少一种连续长丝或接合纤维组成。
9.根据权利要求6-8中任一项所述的三相重垢型洗衣用清洁剂擦，其特征在于所述基质由至少一种疏水合成纤维组成以使得它提供颜色吸附。
10.根据权利要求6-9中任一项所述的三相重垢型洗衣用清洁剂擦，其特征在于所述浸渍液为液体清洁剂。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102014012380.4A DE102014012380A1 (de) | 2014-08-25 | 2014-08-25 | Vollwaschmitteltuch mit waschaktivem Substrat |
| DE102014012380.4 | 2014-08-25 | ||
| PCT/DE2015/000416 WO2016029894A1 (de) | 2014-08-25 | 2015-08-20 | Vollwaschmitteltuch mit waschaktivem substrat |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107075430A true CN107075430A (zh) | 2017-08-18 |
Family
ID=54207269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580057091.5A Pending CN107075430A (zh) | 2014-08-25 | 2015-08-20 | 具有洗涤活性基质的重垢型洗衣用清洁剂擦 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US10781409B2 (zh) |
| EP (1) | EP3186351B1 (zh) |
| CN (1) | CN107075430A (zh) |
| CA (1) | CA2986159A1 (zh) |
| DE (1) | DE102014012380A1 (zh) |
| ES (1) | ES2950613T3 (zh) |
| PL (1) | PL3186351T3 (zh) |
| RU (1) | RU2726845C2 (zh) |
| WO (1) | WO2016029894A1 (zh) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102015014015A1 (de) * | 2015-10-30 | 2017-05-04 | Coin Consulting GmbH | Hochaktives Dreiphasen-Vollwaschmitteltuch und Verfahren zu dessen Herstellung |
| DE102017200139A1 (de) * | 2017-01-08 | 2018-07-12 | Coin Consulting GmbH | Waschmitteltuch mit kontrollierter Aktivierung der waschaktiven Substanzen |
| DE102021212785A1 (de) | 2021-11-13 | 2023-05-17 | Coin Consulting GmbH | Feuchttuch mit biologisch abbaubarem verbundträger |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN88100807A (zh) * | 1987-02-19 | 1988-09-28 | 普罗格特-甘布尔公司 | 可改善洗涤性能的含有洗衣洗涤剂并涂有法污聚合物的基片 |
| EP0957158A1 (en) * | 1997-01-23 | 1999-11-17 | Kao Corporation | Sheetlike article for washing |
| US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
| DE102010060126A1 (de) * | 2010-10-22 | 2012-04-26 | Albaad Deutschland Gmbh | Feuchtes Waschmitteltuch |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4938888A (en) * | 1989-01-05 | 1990-07-03 | Lever Brothers Company | Detergent sheet with alkyl polyglycoside composition |
| ES2193405T3 (es) * | 1996-12-09 | 2003-11-01 | Kao Corp | Articulo impregnado de detergente. |
| EP1869152B1 (en) * | 2005-04-13 | 2009-08-26 | Unilever N.V. | Liquid hard surface cleaning composition |
| US8066956B2 (en) * | 2006-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Delivery of an odor control agent through the use of a presaturated wipe |
| JP4982571B2 (ja) * | 2007-02-12 | 2012-07-25 | ダウ グローバル テクノロジーズ エルエルシー | 複合体 |
| WO2011131585A1 (en) * | 2010-04-20 | 2011-10-27 | Henkel Ag & Co. Kgaa | Laundry article having cleaning properties |
| US20120255129A1 (en) * | 2011-04-05 | 2012-10-11 | Akos Jankura | Method, apparatus and system for laundry cleaning |
| CN105683349A (zh) * | 2013-08-26 | 2016-06-15 | 科因咨询Ug有限责任公司 | 一种三相重垢型洗衣用洗涤剂擦及其制造方法 |
| DE102014004915A1 (de) | 2014-04-07 | 2015-10-08 | Coin Consulting Ug (Haftungsbeschränkt) | Homogenes Dreiphasen-Waschmitteltuch und Verfahren zu dessen Herstellung |
| DE102013014015A1 (de) | 2013-08-26 | 2015-02-26 | Coin Consulting Ug (Haftungsbeschränkt) | Dreiphasen-Vollwaschmitteltuch |
-
2014
- 2014-08-25 DE DE102014012380.4A patent/DE102014012380A1/de not_active Withdrawn
-
2015
- 2015-08-20 CN CN201580057091.5A patent/CN107075430A/zh active Pending
- 2015-08-20 US US15/506,112 patent/US10781409B2/en active Active
- 2015-08-20 CA CA2986159A patent/CA2986159A1/en not_active Abandoned
- 2015-08-20 EP EP15771501.2A patent/EP3186351B1/de active Active
- 2015-08-20 WO PCT/DE2015/000416 patent/WO2016029894A1/de active Application Filing
- 2015-08-20 PL PL15771501.2T patent/PL3186351T3/pl unknown
- 2015-08-20 ES ES15771501T patent/ES2950613T3/es active Active
- 2015-08-20 RU RU2017105624A patent/RU2726845C2/ru active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN88100807A (zh) * | 1987-02-19 | 1988-09-28 | 普罗格特-甘布尔公司 | 可改善洗涤性能的含有洗衣洗涤剂并涂有法污聚合物的基片 |
| US20030207630A1 (en) * | 1995-12-19 | 2003-11-06 | Newlund Laboratories, Inc. | Method of making a laundry detergent article containing detergent formulations |
| EP0957158A1 (en) * | 1997-01-23 | 1999-11-17 | Kao Corporation | Sheetlike article for washing |
| DE102010060126A1 (de) * | 2010-10-22 | 2012-04-26 | Albaad Deutschland Gmbh | Feuchtes Waschmitteltuch |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2986159A1 (en) | 2016-03-03 |
| WO2016029894A4 (de) | 2016-05-12 |
| EP3186351C0 (de) | 2023-06-07 |
| RU2017105624A (ru) | 2018-10-01 |
| US10781409B2 (en) | 2020-09-22 |
| EP3186351B1 (de) | 2023-06-07 |
| RU2726845C2 (ru) | 2020-07-16 |
| RU2017105624A3 (zh) | 2018-10-01 |
| EP3186351A1 (de) | 2017-07-05 |
| US20180216042A1 (en) | 2018-08-02 |
| WO2016029894A1 (de) | 2016-03-03 |
| DE102014012380A1 (de) | 2016-02-25 |
| ES2950613T3 (es) | 2023-10-11 |
| PL3186351T3 (pl) | 2023-11-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2020526620A (ja) | 非アルコキシル化エステルアミンを含む、洗浄組成物 | |
| CN106916659A (zh) | 一种多层洗衣片及其制备方法 | |
| JP2023507905A (ja) | 洗濯用の別個の成分を有する液体洗浄組成物およびそのキットならびに自動洗濯機用の洗浄方法 | |
| CA2974200A1 (en) | Cleaning and/or treatment compositions | |
| CH703978A2 (de) | Feuchtes Waschmitteltuch. | |
| JP2020200469A (ja) | 封入体を含む洗剤組成物 | |
| CN105683349A (zh) | 一种三相重垢型洗衣用洗涤剂擦及其制造方法 | |
| CN107075430A (zh) | 具有洗涤活性基质的重垢型洗衣用清洁剂擦 | |
| DE112018004365T5 (de) | Waschprodukte | |
| JP2020528091A (ja) | 官能化シロキサンポリマー及びそれを含む組成物 | |
| RU2687482C2 (ru) | Салфетка с усиленным моющим средством для стирки с температурно-зависимой активацией моющих активных веществ | |
| DE102017200139A1 (de) | Waschmitteltuch mit kontrollierter Aktivierung der waschaktiven Substanzen | |
| CN106661522A (zh) | 具有洗涤活性物质的受控相排放物扩散的重垢型洗衣用清洁剂擦 | |
| CN103987830A (zh) | 关于织物处理组合物的改进 | |
| WO2020081293A1 (en) | Polyethyleneimine compounds containing n-halamine and derivatives thereof | |
| WO2020081297A1 (en) | Polyethyleneimine compounds containing n-halamine and derivatives thereof | |
| CN103415237A (zh) | 负载有清洁组合物的干燥的、可洗涤的且可重复使用的表面清洁衬底 | |
| AU2019204345B2 (en) | Fabric conditioners | |
| JP7098633B2 (ja) | 効果を提供するための布地処理組成物及び方法 | |
| CN108603143B (zh) | 用于处理具有油污的织物的方法 | |
| CN109983109A (zh) | 纺织物柔软剂片及其制备方法 | |
| JP4424605B2 (ja) | 洗浄剤 | |
| EP4112709A1 (en) | Use of cyclodextrins for malodor reduction in the area of laundry care | |
| CN118792120A (zh) | 一种洗衣组合物及其制备方法 | |
| DE102021212785A1 (de) | Feuchttuch mit biologisch abbaubarem verbundträger |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: DE Ref document number: 1242726 Country of ref document: HK |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170818 |
|
| REG | Reference to a national code |
Ref country code: HK Ref legal event code: WD Ref document number: 1242726 Country of ref document: HK |