CN107056032B - 一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺 - Google Patents

一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺 Download PDF

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CN107056032B
CN107056032B CN201710409442.5A CN201710409442A CN107056032B CN 107056032 B CN107056032 B CN 107056032B CN 201710409442 A CN201710409442 A CN 201710409442A CN 107056032 B CN107056032 B CN 107056032B
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江骐全
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Hebei Ming Suntech Glass Polytron Technologies Inc
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
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    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
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    • C03B23/04Re-forming tubes or rods
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    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B25/00Annealing glass products
    • C03B25/02Annealing glass products in a discontinuous way
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    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001General methods for coating; Devices therefor
    • C03C17/003General methods for coating; Devices therefor for hollow ware, e.g. containers
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    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/008Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
    • C03C17/009Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
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    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • C03C17/25Oxides by deposition from the liquid phase
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    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/30Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
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    • G01MTESTING STATIC OR DYNAMIC BALANCE OF MACHINES OR STRUCTURES; TESTING OF STRUCTURES OR APPARATUS, NOT OTHERWISE PROVIDED FOR
    • G01M7/00Vibration-testing of structures; Shock-testing of structures
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    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • C03C2217/213SiO2
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/47Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
    • C03C2217/475Inorganic materials
    • C03C2217/478Silica
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/78Coatings specially designed to be durable, e.g. scratch-resistant
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    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/112Deposition methods from solutions or suspensions by spraying

Abstract

本发明公开了一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,包括如下步骤:将耐热玻璃管根据图纸加热选择人工和机制相结合,制成相应的产品器皿;退火去除应力;本发明提供一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,本发明具有以下几个方面的优点:避免耐热玻璃器皿破裂碎片飞溅的制造工艺,采用线膨胀系数3.3的高硼硅耐热玻璃制成器皿,然后用硅胶漆技术与之结合,用此工艺加工出来的耐热玻璃器皿,硅胶漆不粘手,既保持了耐热玻璃器皿的功能,又在摔碎时避免随便飞溅而伤到使用者,随着耐热玻璃器皿的应用在不断扩大,用的人越来越多,此工艺亟需推广应用。

Description

一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺
技术领域
本发明涉及器皿制造技术领域,具体是一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺。
背景技术
1、塑料器皿属于有机高分子材料,不能长期经受高温,故该器皿不宜蒸煮高温消毒,长期使用材料本身易老化而释放出对人体有害的物质,该材料在制造时添加增塑剂(塑化剂),因增塑剂含有邻苯二甲酸酯类塑化剂成分,其成分作用类似于人工荷尔蒙,会危害男性生殖能力并促使女性性早熟,长期大量摄取会导致肝癌。另该器皿透明度差,不利于清洗观察。
玻璃器皿目前大部分为钠钙玻璃器皿,钠钙玻璃器皿化学稳定性差,长期使用会产生脱片,会被人体吸收进入血液形成血栓,还有钙玻璃耐急热急冷能力差,不能高温蒸煮消毒或遇冷热水交替使用易爆裂;
不锈钢器皿,造价昂贵,杯口沿薄,喝水很不舒服,水长时间在杯中有金属的味道,影响水的味感。
2、根据玻璃器皿市面上的器皿材质的优缺点,我们选用了一种低膨胀率、耐高温、高强度、高硬度、高透光率和高化学稳定性的特殊玻璃材料,G3.3高硼硅玻璃的线膨胀系数是3.3士0.1×10-6/K,是以氧化钠(Na2O)、氧化硼(B2O3)、二氧化硅(SIO2)为基本成份的一种玻璃。该玻璃成分中硼硅含量较高,分别为硼:12.5~13.5%,硅:78~80%,故称此类玻璃为高硼硅玻璃。属于硼硅酸盐玻璃中的PYREX玻璃。耐酸耐碱耐水,抗腐蚀性能优越,拥有良好的热稳定性、化学稳定性和电学性能,故具有抗化学侵蚀性、抗热冲击性、机械性能好、承受高温等特性;
但是高硼硅玻璃器皿不小心摔碎,其产生的玻璃渣会飞溅,不宜打扫,会对儿童,老人造成划伤等危险;
因此如何解决用耐高温、易清洗、化学性能稳定的膨胀系数为3.3的高硼硅材制造的器皿,既健康又安全,摔碎不会碎片飞溅制造工艺领域亟需解决的问题。
发明内容
本发明的目的在于提供一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,以解决上述背景技术中提出的问题。
为实现上述目的,本发明提供如下技术方案:
一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,包括如下步骤:
(1)将耐热玻璃管根据图纸加热选择人工和机制相结合,制成相应的产品器皿;
(2)退火去除应力;将该器皿放置退火炉中,该炉分为四个区域每个区域温度依次为:390℃、480℃、590℃和550℃,转速为415±15转/分,该器皿在每个区域的时间为25分钟;
(3)耐热冲击测试依据GB/T 6579-1986实验室玻璃仪器耐热冲击试验方法:将玻璃放入烤箱中加热至170℃并保持15-30分钟,然后放入20℃恒温水中,测试标准:若有裂纹、破碎为不合格;
(4)机械冲击测试,采用重量为3oz钢球敲击杯身,测试判定标准:任何破裂和裂纹都不允许;玻璃产品放置在测试工装下,钢球在距离测试部位76mm高度处垂直跌落撞击,口部以下1英寸,外杯中部、外杯底部以上1英寸和外杯底部中心;
(5)先用稀释剂加入油漆搅拌均匀,稀释剂和油漆分别采用白电油和硅胶漆,白电油比硅胶漆为5比1;再加入专用铂金水3%搅拌均匀,用250目-300目小滤网过滤后,即可上机喷涂;用IR或在烘箱中180℃-220℃烘烤10-30分钟。
与现有技术相比,本发明的有益效果是:本发明提供一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,本发明具有以下几个方面的优点:避免耐热玻璃器皿破裂碎片飞溅的制造工艺,采用线膨胀系数3.3的高硼硅耐热玻璃制成器皿,然后用硅胶漆技术与之结合,用此工艺加工出来的耐热玻璃器皿,硅胶漆不粘手,既保持了耐热玻璃器皿的功能,又在摔碎时避免随便飞溅而伤到使用者,随着耐热玻璃器皿的应用在不断扩大,用的人越来越多,此工艺亟需推广应用。
具体实施方式
下面结合具体实施方式对本专利的技术方案作进一步详细地说明。
实施例1
一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,包括如下步骤:
(1)将耐热玻璃管根据图纸加热选择人工和机制相结合,制成相应的产品器皿;
(2)退火去除应力;将该器皿放置退火炉中,该炉分为四个区域每个区域温度依次为:390℃、480℃、590℃和550℃,转速为415±15转/分,该器皿在每个区域的时间为25分钟;
(3)耐热冲击测试依据GB/T 6579-1986实验室玻璃仪器耐热冲击试验方法:将玻璃放入烤箱中加热至170℃并保持16分钟,然后放入20℃恒温水中,测试标准:若有裂纹、破碎为不合格;
(4)机械冲击测试,采用重量为3oz钢球敲击杯身,测试判定标准:任何破裂和裂纹都不允许;玻璃产品放置在测试工装下,钢球在距离测试部位76mm高度处垂直跌落撞击,口部以下1英寸,外杯中部、外杯底部以上1英寸和外杯底部中心;
(5)先用稀释剂(白电油)加入硅胶漆搅拌均匀,(稀释剂:硅胶漆=5:1)再加入专用铂金水3%搅拌均匀,用250目-300目小滤网过滤后,即可上机喷涂;用IR或在烘箱中180℃-220℃烘烤16分钟。
实施例2
一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,包括如下步骤:
(1)将耐热玻璃管根据图纸加热选择人工和机制相结合,制成相应的产品器皿;
(2)退火去除应力;将该器皿放置退火炉中,该炉分为四个区域每个区域温度依次为:390℃、480℃、590℃和550℃,转速为415±15转/分,该器皿在每个区域的时间为25分钟;
(3)耐热冲击测试依据GB/T 6579-1986实验室玻璃仪器耐热冲击试验方法:将玻璃放入烤箱中加热至170℃并保持28分钟,然后放入20℃恒温水中,测试标准:若有裂纹、破碎为不合格;
(4)机械冲击测试,采用重量为3oz钢球敲击杯身,测试判定标准:任何破裂和裂纹都不允许;玻璃产品放置在测试工装下,钢球在距离测试部位76mm高度处垂直跌落撞击,口部以下1英寸,外杯中部、外杯底部以上1英寸和外杯底部中心;
(5)先用稀释剂(白电油)加入硅胶漆搅拌均匀,(稀释剂:硅胶漆=5:1)再加入专用铂金水3%搅拌均匀,用250目-300目小滤网过滤后,即可上机喷涂;用IR或在烘箱中180℃-220℃烘烤25分钟。
本发明的工作原理是:本发明提供一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,本发明具有以下几个方面的优点:避免耐热玻璃器皿破裂碎片飞溅的制造工艺,采用线膨胀系数3.3的高硼硅耐热玻璃制成器皿,然后用硅胶漆技术与之结合,用此工艺加工出来的耐热玻璃器皿,硅胶漆不粘手,既保持了耐热玻璃器皿的功能,又在摔碎时避免随便飞溅而伤到使用者,随着耐热玻璃器皿的应用在不断扩大,用的人越来越多,此工艺亟需推广应用。
上面对本专利的较佳实施方式作了详细说明,但是本专利并不限于上述实施方式,在本领域的普通技术人员所具备的知识范围内,还可以在不脱离本专利宗旨的前提下做出各种变化。

Claims (1)

1.一种避免耐热玻璃器皿破裂碎片飞溅的制造工艺,其特征在于,包括如下步骤:
(1)将耐热玻璃管根据图纸加热选择人工和机制相结合,制成相应的产品器皿;
(2)退火去除应力;将该器皿放置退火炉中,该炉分为四个区域每个区域温度依次为:390℃、480℃、590℃和550℃,转速为415±15转/分,该器皿在每个区域的时间为25分钟;
(3)耐热冲击测试依据GB/T 6579-1986实验室玻璃仪器耐热冲击试验方法:将玻璃放入烤箱中加热至170℃并保持15-30分钟,然后放入20℃恒温水中,测试标准:若有裂纹、破碎为不合格;
(4)机械冲击测试,采用重量为3oz钢球敲击杯身,测试判定标准:任何破裂和裂纹都不允许;玻璃产品放置在测试工装下,钢球在距离测试部位76mm高度处垂直跌落撞击,口部以下1英寸,外杯中部、外杯底部以上1英寸和外杯底部中心;
(5)先用稀释剂加入油漆搅拌均匀,稀释剂和油漆分别采用白电油和硅胶漆,白电油比硅胶漆为5比1;再加入专用铂金水3%搅拌均匀,用250目-300目小滤网过滤后,即可上机喷涂;用IR或在烘箱中180℃-220℃烘烤10-30分钟。
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