CN107027766A - A kind of Synergistic bactericidal composition for preventing and treating sclerotinia sclerotiorum - Google Patents
A kind of Synergistic bactericidal composition for preventing and treating sclerotinia sclerotiorum Download PDFInfo
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- CN107027766A CN107027766A CN201710293127.0A CN201710293127A CN107027766A CN 107027766 A CN107027766 A CN 107027766A CN 201710293127 A CN201710293127 A CN 201710293127A CN 107027766 A CN107027766 A CN 107027766A
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- Prior art keywords
- ningnanmycin
- fluorine azoles
- azoles bacterium
- bacterium aniline
- bactericidal composition
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of Synergistic bactericidal composition for preventing and treating sclerotinia sclerotiorum, active ingredient is made up of Ningnanmycin and fluorine azoles bacterium aniline, and the weight ratio of Ningnanmycin and fluorine azoles bacterium aniline is 15 1:1‑10.The Synergistic bactericidal composition that the present invention carries out rational mixture by Ningnanmycin and fluorine azoles bacterium aniline is used to prevent and treat sclerotinia sclerotiorum, synergistic function is obvious, preventive effect is significantly higher than the preventive effect of alone Ningnanmycin and fluorine azoles bacterium aniline, so as to reduce Pesticide use amount, disease is delayed to develop immunity to drugs, it is environmentally friendly and the lasting period is long.
Description
Technical field
The invention belongs to pesticides application technical field, and in particular to a kind of Synergistic sterilizing combination of preventing and treating sclerotinia sclerotiorum
Thing.
Background technology
Rape is the main oil crops of China, and sclerotinia sclerotiorum is one of important disease in Rape-seed production, long-term strain
The incidence of disease is up to 10%~30%, serious up to more than 80%；The general underproduction 10%~70% of diseased plant.Whole breeding time can be sent out
Disease, productive phase, occurs most heavy.Stem, leaf, flower, silique can be aggrieved, and stem is aggrieved most heavy.At present, because long-term single use is killed
Bacterium medicament so that pathogen is easy to develop immunity to drugs, causes drug effect to decline, disease breaks out, and then increases medication, is formed pernicious
Circulation, increases drug cost, aggravates environmental pollution, this is also a great problem of chemical prevention.Therefore by the different mechanisms of action
Rationally compounding is to overcome one of effective measures of resistance to the action of a drug generation to agricultural chemicals.
Fluorine azoles bacterium aniline, English name：Penflufen.Fluorine azoles bacterium aniline is class novel pyrazole developed in recent years
Acid amide fungicides, with the effect such as protection, treatment, interior suction, transporting.The bactericide is succinate dehydrogenase (SDH) inhibitor,
Respiratory chain electron transmission Complex II is mainly acted on, energetic supersession is blocked.Seed after treatment can in germination process
To absorb fluorine azoles bacterium aniline, and other positions of plant are transmitted to by xylem, so as to play a part of cover crop.Can
With prevent and treat kind pass, soil pass basidiomycetes and sac fungus disease, to have black scurf of potato caused by rhizoctonia and ustilagin etc.,
The diseases such as wheat sharp eyespot, rice sheath blight disease, sclerotinia sclerotiorum, loose smut of wheat, the bunt of wheat, corn southern leaf blight have
There are good prevention and control, therapeutic effect.
Ningnanmycin, is called Junkeduke, English common name ningnanmycin is that Cystosine nucleocide type of new generation resists
Raw element class wide-spectrum bactericide.Ningnanmycin is Chengdu Inst. of Biology, Chinese Academy of Sciences after the Seventh Five-Year Plan, 85,95 national science and technologies
The patented technology product tackled key problems and succeeded in developing, this bacterium is isolated in Ningnan County, Sichuan Province soil, is found first
Cystosine nucleocide type antibiotics, therefore its tunning is named as Ningnanmycin.At present in tobacco mosaic virus disease, tomato
Virosis, pepper virus disease, rice seedling blight, root rot, stripe disease, alternaria leaf spot of apple, cucumber are white
Registration is achieved in powder disease, sclerotinia sclerotiorum, peronophythora litchi is being prevented and treated in addition, it is other crop virosis, stem rot, climing withered
Also it has been widely applied in the multiple diseases such as disease.
At present the research of sclerotinia sclerotiorum is applied to using Ningnanmycin, fluorine azoles bacterium aniline as the composition of active ingredient not yet
There is relevant report.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of high-efficiency low-toxicity, environmentally friendly, preventing and treating sclerotinia sclerotiorum
Synergistic bactericidal composition.
The present invention is to be achieved through the following technical solutions：A kind of Synergistic bactericidal composition for preventing and treating sclerotinia sclerotiorum, effectively
Composition is made up of Ningnanmycin and fluorine azoles bacterium aniline, and the weight ratio of Ningnanmycin and fluorine azoles bacterium aniline is 15-1:1-10.It is preferred that
The weight ratio of ground, Ningnanmycin and fluorine azoles bacterium aniline is 5-1:1-5.
The active ingredient of the Synergistic bactericidal composition accounts for the 5-50% of Synergistic bactericidal composition gross weight, and surplus is agricultural chemicals
Upper acceptable auxiliary agent.
Described Synergistic bactericidal composition is according to method known in those skilled in the art, and adding can connect on corresponding agricultural chemicals
The formulation that the auxiliary agent received is made is wettable powder, water dispersible granules or suspending agent.
The auxiliary agent that uses of Synergistic bactericidal composition of the present invention includes dispersant, wetting agent, binding agent, disintegrant, antifreeze
Agent, defoamer, thickener, filler, solvent etc. or it is other be beneficial to active ingredient in the formulation stablize and drug effect play it is known
Material, is all the various auxiliary components commonly used in field of pesticide preparation or allow to use.
The dispersant and wetting agent are selected from calcium dodecyl benzene sulfonate, lauryl sodium sulfate, Tea Saponin, polycarboxylic acids
Salt, lignosulfonates, APES, the formaldehyde condensation products of methyl naphthalene sulfonic acid sodium, sodium hydroxyethyl cellulose, alkyl
Sodium naphthalene sulfonate, aliphatic alcohol polyoxyvinethene phosphate, AEO, sodium butylnaphthalenesulfonate, styrylphenol gather
One or more in oxygen vinethene, sldium lauryl sulfate, pull open powder.
The one kind of the binding agent in starch, polyvinyl alcohol, sodium carboxymethylcellulose.
The one kind of the disintegrant in sodium carbonate, calcium chloride, ammonium carbonate, potassium chloride, sodium sulphate.
The one kind of the antifreezing agent in ethylene glycol, propane diols, glycerine, urea.
The defoamer is selected from organic silicone oil.
The one kind of the thickener in xanthans, Arabic gum, Magnesiumaluminumsilicate.
The filler is in kaolin, precipitated calcium carbonate, attapulgite, soil powder, diatomite, bentonite, white carbon
One or more.
The solvent is deionized water.
Beneficial effects of the present invention：The present invention carries out the Synergistic sterilizing of rational mixture by Ningnanmycin and fluorine azoles bacterium aniline
Composition is used to prevent and treat sclerotinia sclerotiorum, and substantially, preventive effect is significantly higher than alone Ningnanmycin and fluorine azoles bacterium benzene to synergistic function
The preventive effect of amine, so as to reduce Pesticide use amount, delays disease to develop immunity to drugs, and the lasting period is long, environmentally friendly.
Embodiment
Technical scheme and technique effect are described further below in conjunction with specific embodiment, institute of the present invention
The percentage stated is weight percentage.
First, Toxicity Determination is tested
After determining the effective inhibition concentration scope of each medicament through prerun, each medicament is set 5 agent by active constituent content respectively
Gradient processing is measured, if clear water is compareed.Reference《Farm-chemical indoor determination test rule bactericide》Carry out, using mycelial growth speed
Rate method determines virulence of the medicament to Sclerotinia sclerotiorum.Colony diameter is measured with crossing method after 72h, each processing is calculated net raw
Long amount, mycelial growth inhibition rate.
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm value (x), with minimum
Square law tries to achieve virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.Simultaneously according to the abundant methods of Sun Yun
Co-toxicity coefficient method (CTC) evaluate the synergistic effect of pharmacy mix, i.e. CTC≤80, composition shows as antagonism, when 80
<CTC<120, composition shows as summation action, and when CTC >=120, composition shows as synergistic effect.As a result such as table 1.
The toxicity test analysis of results table of the Ningnanmycin of table 1, fluorine azoles bacterium aniline and its compounding to Sclerotinia sclerotiorum
| Reagent agent | Proportioning | Regression equation (y=a+bx) | Coefficient correlation | EC50(μg/mL) | Co-toxicity coefficient |
| Ningnanmycin (A) | / | Y=1.3244+1.9740x | 0.9910 | 72.78 | / |
| Fluorine azoles bacterium aniline (B) | / | Y=6.5001+1.5317x | 0.9813 | 0.10 | / |
| A：B | 15:1 | Y=4.7830+1.9567x | 0.9903 | 1.29 | 121.5 |
| A：B | 10:1 | Y=5.1741+1.4766x | 0.9901 | 0.76 | 142.8 |
| A：B | 8:1 | Y=5.5307+2.2011x | 0.9990 | 0.57 | 156.2 |
| A：B | 5:1 | Y=5.8008+1.6954x | 0.9944 | 0.34 | 175.3 |
| A：B | 1:1 | Y=6.6153+1.6544x | 0.9805 | 0.11 | 181.6 |
| A：B | 1:5 | Y=6.5258+1.3387x | 0.9627 | 0.07 | 171.4 |
| A：B | 1:8 | Y=6.5077+1.4067x | 0.9815 | 0.08 | 140.6 |
| A：B | 1:10 | Y=6.5228+1.4869x | 0.9887 | 0.09 | 122.2 |
| A：B | 1:15 | Y=6.5290+1.6866x | 0.9724 | 0.12 | 88.9 |
| A：B | 25:1 | Y=4.1381+1.4820x | 0.9623 | 3.82 | 65.8 |
As shown in Table 1, the weight ratio of Ningnanmycin and fluorine azoles bacterium aniline is in 15-1:Mixture is to rape sclerotium in the range of 1-10
Germ shows obvious synergistic effect.Wherein, when Ningnanmycin and fluorine azoles bacterium aniline weight ratio are in 5-1:Synergy is made during 1-5
With especially prominent；When Ningnanmycin and fluorine azoles bacterium aniline weight ratio are 1:When 15, composition shows as summation action；When Ningnan is mould
Element is 25 with fluorine azoles bacterium aniline weight ratio:When 1, composition shows as antagonism.
Two：Product prepares embodiment
Embodiment 1：20% Ningnanmycin fluorine azoles bacterium aniline wettable powder (1:1)
Ningnanmycin (active ingredient) 10%, fluorine azoles bacterium aniline (active ingredient) 10%, polycarboxylate (dispersant) 3%,
Negel (dispersant) 2%, lauryl sodium sulfate (wetting agent) 3.5%, white carbon (filler) 10%, kaolin
(filler) complements to 100%；Each component is mixed, 20% Ningnanmycin fluorine azoles bacterium aniline is made after air-flow crushing wettable
Property pulvis.
Embodiment 2：18% Ningnanmycin fluorine azoles bacterium aniline suspending agent (1:5)
Ningnanmycin (active ingredient) 3%, fluorine azoles bacterium aniline (active ingredient) 15%, calcium dodecyl benzene sulfonate (moistening
Agent) 3.5%, aliphatic alcohol polyoxyvinethene phosphate (dispersant) 4.5%, xanthans (thickener) 2%, propane diols (antifreezing agent)
2%th, organic silicone oil (defoamer) 0.3%, deionized water (solvent) complement to 100%；First other auxiliary agents are mixed, in cutter
Middle shear-mixed is uniform, then adds Ningnanmycin and fluorine azoles bacterium aniline, 2h is ground in ball crusher, you can 18% Ningnan is made
Mycin fluorine azoles bacterium aniline suspending agent.
Embodiment 3：33% Ningnanmycin fluorine azoles bacterium aniline suspending agent (10:1)
Ningnanmycin (active ingredient) 30%, fluorine azoles bacterium aniline (active ingredient) 3%, lauryl sodium sulfate (wetting agent)
5.5%th, aliphatic alcohol polyoxyvinethene phosphate (dispersant) 6%, Arabic gum (thickener) 2.5%, glycerine (antifreezing agent)
3%th, organic silicone oil (defoamer) 0.3%, deionized water (solvent) complement to 100%；First other auxiliary agents are mixed, in cutter
Middle shear-mixed is uniform, then adds Ningnanmycin and fluorine azoles bacterium aniline, 2h is ground in ball crusher, you can 33% Ningnan is made
Mycin fluorine azoles bacterium aniline suspending agent.
Embodiment 4：27% Ningnanmycin fluorine azoles bacterium aniline water dispersible granules (8:1)
Ningnanmycin (active ingredient) 24%, fluorine azoles bacterium aniline (active ingredient) 3%, the formaldehyde condensation of methyl naphthalene sulfonic acid sodium
Thing (dispersant) 5.5%, calcium dodecyl benzene sulfonate (wetting agent) 5%, sodium carboxymethylcellulose (binding agent) 2%, sodium carbonate
(disintegrant) 2%, kaolin (filler) complement to 100%；Each component is well mixed, after being crushed through airslide disintegrating mill, stirring
30min, is mediated, and is then added and is granulated in fluid bed, is dried after granulation is good, is sieved i.e. obtained 27% Ningnanmycin
Fluorine azoles bacterium aniline water dispersible granules.
3rd, embodiment is applied to the field medicine effect test of preventing and treating sclerotinia sclerotiorum
Test method：Reference《GB/T17980.35-2000 pesticide field efficacy medicine tests criterion (one) bactericidal agent for preventing and treating rape
Sclerotiniose》.Using conventional spray-on process, in the spray dispenser for the first time of disease early period of origination, second of spray dispenser, is applied altogether after 10 days
Medicine is twice.Experiment sets 7 processing altogether, often handles 4 repetitions, per plot area 35m2, totally 28 cells, random district's groups arrangement.
This test arrangement is in Nanning.
Investigation method：Before dispenser, 7 days after second of dispenser, disease index investigation is carried out within 14 days, per cell checkerboard type 10
Point investigation, every is investigated 5 plants, is careful not to sample in side row during investigation.Record total strain number, diseased plant number at different levels and sick series, meter
Calculate disease index and preventive effect.
Grade scale is：
0 grade：It is disease-free；
1 grade：Slight morbidity, onset area accounts for less than the 5% of stem surface area；
3 grades：Slight morbidity, onset area accounts for the 6%-15% of stem surface area；
5 grades：Medium morbidity, onset area accounts for the 16%-30% of stem surface area；
7 grades：Highly fall ill, onset area accounts for the 31%-50% of stem surface area；
9 grades：Serious morbidity, onset area accounts for more than the 50% of stem surface area.
Disease index and prevention effect computational methods：
Formula (1)：Disease index calculation formula：In formula (1)：X- disease indexs；Ni- disease at different levels
Strain number；I- is with respect to value of series；N- investigates total strain number.
Formula (2)：Prevention effect calculation formula：In formula (2)：P- prevention effects, unit
For percentage (%)；CK0Disease index before the dispenser of-blank district；CK1Disease index after the dispenser of-blank district；PT0- medicine
Disease index before agent treatment region dispenser；PT1Disease index after the dispenser of-chemicals treatment district.
The Ningnanmycin of table 2, fluorine azoles bacterium aniline and its compounding preventing and treating sclerotinia sclerotiorum test of pesticide effectiveness
It can be seen that Ningnanmycin and the Synergistic bactericidal composition of fluorine azoles bacterium aniline compounding can be prevented and treated effectively by the result of the test of table 2
Sclerotinia sclerotiorum, substantially, preventive effect is significantly higher than the preventive effect of alone Ningnanmycin and fluorine azoles bacterium aniline to synergistic function, so as to drop
Low Pesticide use amount, delays disease to develop immunity to drugs, and the lasting period is long, environmentally friendly.
Claims (4)
1. a kind of Synergistic bactericidal composition for preventing and treating sclerotinia sclerotiorum, it is characterised in that active ingredient is by Ningnanmycin and fluorine azoles
Bacterium aniline is constituted, and the weight ratio of Ningnanmycin and fluorine azoles bacterium aniline is 15-1:1-10.
2. Synergistic bactericidal composition according to claim 1, it is characterised in that the weight of Ningnanmycin and fluorine azoles bacterium aniline
Than for 5-1:1-5.
3. Synergistic bactericidal composition according to claim 1 or 2, it is characterised in that described active ingredient accounts for synergy and killed
The 5-50% of bacteria composition gross weight, surplus is acceptable auxiliary agent on agricultural chemicals.
4. the Synergistic bactericidal composition according to claim any one of 1-3, it is characterised in that described Synergistic sterilizing combination
Thing can be prepared into wettable powder, water dispersible granules or suspending agent.
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Citations (7)
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|---|---|---|---|---|
| CN103329905A (en) * | 2013-07-24 | 2013-10-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Sterilization composition containing penflufen and validamycin |
| CN103960261A (en) * | 2014-05-05 | 2014-08-06 | 深圳诺普信农化股份有限公司 | Sterilization composition |
| CN104054712A (en) * | 2014-05-28 | 2014-09-24 | 深圳诺普信农化股份有限公司 | Sterilization composition containing boscalid |
| CN104126585A (en) * | 2013-05-04 | 2014-11-05 | 陕西美邦农药有限公司 | Compound bactericidal composition containing penflufen |
| CN104396959A (en) * | 2014-10-23 | 2015-03-11 | 北京燕化永乐生物科技股份有限公司 | Bactericidal composition |
| WO2015160619A1 (en) * | 2014-04-16 | 2015-10-22 | Bayer Cropscience Lp | Compositions comprising ningnanmycin and a fungicide |
| CN105248424A (en) * | 2015-01-12 | 2016-01-20 | 四川利尔作物科学有限公司 | Sterilization composition and application thereof |
-
2017
- 2017-04-28 CN CN201710293127.0A patent/CN107027766A/en not_active Withdrawn
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104126585A (en) * | 2013-05-04 | 2014-11-05 | 陕西美邦农药有限公司 | Compound bactericidal composition containing penflufen |
| CN103329905A (en) * | 2013-07-24 | 2013-10-02 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Sterilization composition containing penflufen and validamycin |
| WO2015160619A1 (en) * | 2014-04-16 | 2015-10-22 | Bayer Cropscience Lp | Compositions comprising ningnanmycin and a fungicide |
| CN103960261A (en) * | 2014-05-05 | 2014-08-06 | 深圳诺普信农化股份有限公司 | Sterilization composition |
| CN104054712A (en) * | 2014-05-28 | 2014-09-24 | 深圳诺普信农化股份有限公司 | Sterilization composition containing boscalid |
| CN104396959A (en) * | 2014-10-23 | 2015-03-11 | 北京燕化永乐生物科技股份有限公司 | Bactericidal composition |
| CN105248424A (en) * | 2015-01-12 | 2016-01-20 | 四川利尔作物科学有限公司 | Sterilization composition and application thereof |
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Application publication date: 20170811 |