CN105935055B - A kind of granular pesticide containing probenazole and thiram - Google Patents
A kind of granular pesticide containing probenazole and thiram Download PDFInfo
- Publication number
- CN105935055B CN105935055B CN201610278297.7A CN201610278297A CN105935055B CN 105935055 B CN105935055 B CN 105935055B CN 201610278297 A CN201610278297 A CN 201610278297A CN 105935055 B CN105935055 B CN 105935055B
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- Prior art keywords
- thiram
- probenazole
- granular pesticide
- present
- pesticide containing
- Prior art date
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- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 229960002447 thiram Drugs 0.000 title claims abstract description 41
- 239000005843 Thiram Substances 0.000 title claims abstract description 40
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 239000000575 pesticide Substances 0.000 title claims abstract description 20
- 241000209094 Oryza Species 0.000 claims abstract description 18
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 17
- 235000009566 rice Nutrition 0.000 claims abstract description 17
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 2
- LJWIAZFZRNWQOL-UHFFFAOYSA-N benzene;1,3-thiazole Chemical compound C1=CSC=N1.C1=CC=CC=C1 LJWIAZFZRNWQOL-UHFFFAOYSA-N 0.000 claims description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- 125000005336 allyloxy group Chemical group 0.000 claims 1
- 150000003851 azoles Chemical class 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 241000918585 Pythium aphanidermatum Species 0.000 abstract description 10
- 239000004480 active ingredient Substances 0.000 abstract description 9
- 201000010099 disease Diseases 0.000 abstract description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 239000003814 drug Substances 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 241000813090 Rhizoctonia solani Species 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 230000000855 fungicidal effect Effects 0.000 description 3
- 239000000417 fungicide Substances 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 229940125898 compound 5 Drugs 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 241001330975 Magnaporthe oryzae Species 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- -1 Sodium alkyl sulfate Chemical class 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/26—Oxidation products of dithiocarbamic acid derivatives, e.g. thiuram sulfides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of granular pesticide containing probenazole and thiram, active ingredient is by following weight ratio into being grouped as：Probenazole 5 8%, thiram 2 5%, the weight ratio of wherein probenazole and thiram are：5‑8:2‑5.The present invention is suitable for the rice damping-off of prevention dry rice seedling, and formula synergy is notable, and absorbability is good, can effectively control disease, has time and labour saving labour-saving effect.
Description
Technical field
The present invention relates to technical field of pesticide, more particularly to a kind of granular pesticide containing probenazole and thiram.
Background technology
Probenazole, English are general entitled：Probenazole is that Japanese Meiji Seika Kaisha, Ltd. develops
A kind of inducing immunity fungicide by the way that plant is excited to realize protection effect to immune (resistance) reaction of disease in itself, leads to
Plant root absorption is crossed, and relatively rapidly infiltration is conducted to plant each section.Rice is handled by probenazole, can be promoted
Root system absorbs, and relatively quickly infiltration conduction is to plant each section, and cover crop is not by Pyricularia oryzae and rhizoctonia solani
It infects.
Thiram, English common name：Thiram, chemical name：Tetramethyl thiuram disulfide.It is a kind of protective effect
Fungicide, has a broad antifungal spectrum mainly for the treatment of seed and soil, stands the seedling stage of Cereal smut and various crop withered
Disease has preferable control effect.
The raising rice seedlings in China realize the seedling raising method from based on watery ricenursery to based on dry rice seedling substantially at present, and rice shoot is sick
Evil is still watered spray-on process with medicament and is prevented, more time-consuming.In the case of rural labour's shortage, effort-saving is prevented curing the disease
The method of insect pest is more and more concerned, and the present invention is compounded by active ingredient probenazole and thiram, is prepared into pesticide
Granula, uptake and translocation is good, and in seedling operation or seeding stage is applied, and can effectively be prevented seedling blight, be reached time saving province
The effect of work.
At present, the research of probenazole and thiram mixture be there are no into relevant report.
Invention content
The technical problem to be solved by the present invention is to provide a kind of granular pesticide containing probenazole and thiram, use
In the prevention of dry rice seedling phase rice damping-off, formula synergy is notable, and absorbability is good, can effectively control disease, has time saving province
Work labour-saving effect.
The technical solution adopted by the present invention is that：A kind of granular pesticide containing probenazole and thiram, active ingredient
It is made of probenazole and thiram, the weight ratio of wherein probenazole and thiram is：5-8:2-5, it is preferred that allyl
The weight ratio of benzene thiazole and thiram is 7:3.
Weight percent of the probenazole in granular pesticide is 5-8%, and thiram is in granular pesticide
In weight percent be 2-5%.
The adjuvant that the granular pesticide of the present invention adds in includes filler, binding agent, dispersant, wetting agent, disintegrant,
Toner, stabilizer or it is other be beneficial to active ingredient in the formulation stablize and drug effect play substance, be all field of pesticide preparation
In commonly use or allow the various composition used.
The present invention has the following advantages and significant technique effect:
(1) probenazole and thiram have double action mechanism, and mutual mixture germ is not easy to produce resistance.
(2) indoor biometrics the result shows that, probenazole and thiram according to a certain percentage mixture to rhizoctonia solani synergy
Significantly, it advantageously reduces applications of pesticide amount and reduces pesticide cost.
(3) present invention is prepared into granular pesticide, is applied during with reference to dry rice seedling operation or during seedling, alleviates farming behaviour
Make, be conducive to save labour cost.
Specific embodiment
Technical scheme of the present invention and advantageous effect are described further with reference to embodiments, of the present invention hundred
Ratio is divided to be weight percentage.
First, embodiment is prepared
Embodiment 1：(active ingredient is than 5 for 7% probenazole thiram granule:2)
Formula：Weigh probenazole 5% by weight, thiram 2%, naphthalenesulfonate formaldehyde condensation compound 2.5%, 12
Sodium alkyl sulfate 3%, polyvinyl alcohol 3.5%, bentonite complements to 100%.
Embodiment 2：(active ingredient is than 6 for 8% probenazole thiram granule:2)
Formula：Probenazole 6%, thiram 2%, naphthalenesulfonate formaldehyde condensation compound 5%, dodecane are weighed by weight
Base sodium sulphate 4.5%, polyvinyl alcohol 3%, attapulgite 15%, kaolin complements to 100%.
Embodiment 3：(active ingredient is than 7 for 10% probenazole thiram granule:3)
Formula：Probenazole 7%, thiram 3%, lauryl sodium sulfate 2.5%, carboxymethyl fibre are weighed by weight
Dimension element 3.5%, diatomite 15%, bentonite complements to 100%.
Embodiment 4：(active ingredient is than 8 for 10% probenazole thiram granule:2)
Formula：Probenazole 8%, thiram 2%, naphthalenesulfonate formaldehyde condensation compound 5%, dodecane are weighed by weight
Base sodium sulphate 2.5%, polyvinyl alcohol 5%, kaolin complements to 100%.
Preparation method：Recipe ingredient described in above-described embodiment 1-4 is uniformly mixed, is crushed, water is added fully to be stirred after soaking
It mixes uniformly, then is granulated with screw extruder pelletizer, is sieved after dry up to the granule of thiram containing probenazole.
2nd, BIOLOGICAL ACTIVITY EXAMPLES
The BIOLOGICAL ACTIVITY EXAMPLES of the present invention is divided into the experiment of indoor biometrics toxicity test and field medicine effect test.
Embodiment 1：Probenazole, thiram and compounding agent are to the Toxicity Determination of damping-off
After prerun determines the effective inhibition concentration range of each medicament, by probenazole, thiram and its mixed agent by having
Effective component content gradient series dilute 5 concentration, if clear water compares.Reference《Farm-chemical indoor determination test rule fungicide》
It carries out, virulence of the medicament to rice rice damping-off is measured using mycelial growth rate method.After 72h bacterium colony is measured with crossing method
Diameter calculates each processing net growth, mycelial growth inhibition rate.
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm (x), with minimum
Square law acquires virulence regression equation (y=a+bx), and thus calculates the EC of each medicament50Value.
The synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of the abundant methods of Sun Yun, i.e. CTC≤80 are antagonism
Effect, 80<CTC<120 be summation action, and CTC >=120 are synergistic effect.Statistical result is as shown in table 1：
| Reagent agent | Proportioning | EC50(mg/L) | Co-toxicity coefficient (CTC) |
| Probenazole (A) | / | 1.35 | / |
| Thiram (B) | / | 2.73 | / |
| A：B | 5:2 | 1.26 | 125.6 |
| A：B | 5:3 | 1.21 | 138.0 |
| A：B | 6:2 | 1.15 | 134.8 |
| A：B | 6:5 | 1.24 | 141.2 |
| A：B | 7:3 | 0.96 | 165.4 |
| A：B | 7:4 | 1.21 | 137.0 |
| A：B | 8:2 | 1.18 | 127.7 |
| A：B | 8:5 | 1.26 | 133.1 |
| A：B | 1:10 | 3.34 | 75.7 |
Measurement result shows that when the proportioning of probenazole and thiram be 5-8:During 2-5, co-toxicity coefficient (CTC) is more than
120, synergistic effect is apparent.
Embodiment 2：The preparation for preparing 3 gained of embodiment is used to prevent the field control effectiveness test of rice shoot damping-off
(1) experimental design:By 10% probenazole thiram (7:3) granule is as test group 1#, amount of application
0.1 kilogram/m2；Using 8% probenazole granule as control group 1#, amount of application is 0.2 kilogram/m2；With 10% thiram particle
Agent is control group 2#, and amount of application is 0.25 kilogram/m2, 1 blank control group is set.
(2) application method
Disease-free seedling plot is selected, the soil with rhizoctonia solani is uniformly mixed, is layered on successively i.e. by smooth seedling furrow
It will test on seedling furrow, it is desired to which the thickness of soil in spite of illness on furrow is consistent.The seed-grain for having urged bud is planted in soil, in experiment
Each 3 repetitions of processing, plot area 1m2, by experimental design by test group 1#, control group 1#, control group 2# correspondence medicament
And dosage is uniformly imposed in corresponding cell, keeps seedbed environment consistent in each cell.
(3) result of the test
It 12 days after medicine, is investigated with reference to rice shoot damping-off high-incidence season result, incidence and control effect is calculated, through statistical
Analysis, test group 1# are 87.53% to the control effect of rice shoot damping-off, and control group 1# is to the control effect of rice shoot damping-off
73.24%；Control group 2# is 68.52% to the control effect of rice shoot damping-off.Find out from experiment, probenazole is beautiful with good fortune
After double rational mixtures, mixed agent is apparent to rice shoot damping-off synergy, has not only reduced the usage amount of active ingredient, but also show and be better than
The field efficacy of single dose helps to reduce Pesticide use cost.
Claims (4)
- A kind of 1. granular pesticide containing probenazole and thiram, which is characterized in that the weight of probenazole and thiram Measuring ratio is：5-8:2-5.
- 2. the granular pesticide according to claim 1 containing probenazole and thiram, which is characterized in that phenyl allyloxy thiophene The weight ratio of azoles and thiram is 7:3.
- 3. the granular pesticide according to claim 1 or 2 containing probenazole and thiram, which is characterized in that allyl The weight percent of benzene thiazole is 5-8%, and the weight percent of thiram is 2-5%.
- 4. the granular pesticide containing probenazole and thiram described in claim 3 is used to prevent dry rice seedling rice seedling blight Purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610278297.7A CN105935055B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and thiram |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610278297.7A CN105935055B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and thiram |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105935055A CN105935055A (en) | 2016-09-14 |
| CN105935055B true CN105935055B (en) | 2018-06-19 |
Family
ID=57152543
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610278297.7A Active CN105935055B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and thiram |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105935055B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3629428A (en) * | 1967-09-07 | 1971-12-21 | Meiji Seika Kaisha | Pesticide for controlling bacterial and fungal diseases of rice plant |
| US4855311A (en) * | 1987-04-24 | 1989-08-08 | Agro-Kanesho Co., Ltd. | Benzoisothiazole oximes which are plant protection agents for control of fungi and bacteria |
| CN103238622A (en) * | 2012-02-10 | 2013-08-14 | 陕西美邦农药有限公司 | Bactericidal composition containing probenazole |
-
2016
- 2016-04-28 CN CN201610278297.7A patent/CN105935055B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3629428A (en) * | 1967-09-07 | 1971-12-21 | Meiji Seika Kaisha | Pesticide for controlling bacterial and fungal diseases of rice plant |
| US4855311A (en) * | 1987-04-24 | 1989-08-08 | Agro-Kanesho Co., Ltd. | Benzoisothiazole oximes which are plant protection agents for control of fungi and bacteria |
| CN103238622A (en) * | 2012-02-10 | 2013-08-14 | 陕西美邦农药有限公司 | Bactericidal composition containing probenazole |
Non-Patent Citations (1)
| Title |
|---|
| 新型杀菌剂8%烯丙苯噻唑颗粒剂防治水稻稻瘟病田间试验;孙柏欣 等;《辽宁农业科学》;20131231(第3期);第71-72页 * |
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| CN105935055A (en) | 2016-09-14 |
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