CN105918325B - A kind of granular pesticide containing probenazole and Metalaxyl-M - Google Patents
A kind of granular pesticide containing probenazole and Metalaxyl-M Download PDFInfo
- Publication number
- CN105918325B CN105918325B CN201610279128.5A CN201610279128A CN105918325B CN 105918325 B CN105918325 B CN 105918325B CN 201610279128 A CN201610279128 A CN 201610279128A CN 105918325 B CN105918325 B CN 105918325B
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- Prior art keywords
- metalaxyl
- probenazole
- granular pesticide
- weight ratio
- containing probenazole
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- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 title claims abstract description 40
- 239000005808 Metalaxyl-M Substances 0.000 title claims abstract description 39
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 title claims abstract description 38
- 239000000575 pesticide Substances 0.000 title claims abstract description 21
- 241000209094 Oryza Species 0.000 claims abstract description 19
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 19
- 235000009566 rice Nutrition 0.000 claims abstract description 19
- 241000918585 Pythium aphanidermatum Species 0.000 claims abstract 2
- DDSAOQMKNUBIBW-UHFFFAOYSA-N S1C=NC=C1.C(CC)C1=CC=CC=C1 Chemical compound S1C=NC=C1.C(CC)C1=CC=CC=C1 DDSAOQMKNUBIBW-UHFFFAOYSA-N 0.000 claims 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 201000010099 disease Diseases 0.000 abstract description 8
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 230000002265 prevention Effects 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 description 10
- 239000008187 granular material Substances 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- 238000000034 method Methods 0.000 description 8
- 241000233629 Phytophthora parasitica Species 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 241000196324 Embryophyta Species 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- -1 Metalaxyl-M compound Chemical class 0.000 description 4
- 241000813090 Rhizoctonia solani Species 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000820 toxicity test Toxicity 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241001330975 Magnaporthe oryzae Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 241001281805 Pseudoperonospora cubensis Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000006399 behavior Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of granular pesticide containing probenazole and Metalaxyl-M, effective component is by following weight ratio at being grouped as: probenazole 5-10%, Metalaxyl-M 0.5-3.0%, the wherein weight ratio of probenazole and Metalaxyl-M are as follows: 10-20:1-5.Granular pesticide of the invention is used for the prevention and treatment of dry rice seedling phase rice damping-off, and formula synergy is significant, and absorbability is good, can effectively control disease, has time and labour saving labour-saving effect.
Description
Technical field
The present invention relates to technical field of pesticide, more particularly to a kind of pesticide granules containing probenazole and Metalaxyl-M
Agent.
Background technique
Probenazole, English common name are as follows: probenazole is that Japanese Meiji Seika Kaisha, Ltd. develops
A kind of inducing immunity fungicide is realized protection effect to immune (resistance) reaction of disease by excitation plant itself, is led to
Plant root absorption is crossed, and relatively rapidly infiltration is conducted to plant each section.Probenazole handles rice, can promote root system
It absorbs, and relatively rapidly to plant each section, cover crop is not infected by Pyricularia oryzae and rhizoctonia solani for infiltration conduction.
Metalaxyl-M, English common name are as follows: metalaxyl-M is a kind of efficient systemic fungicide, has protection and treatment to make
With, drug effect is high, residual is low, to Pseudoperonospora cubensis, phytophthora germ, vegetables caused by rotten mildew fungus, fruit tree, tobacco, oil plant, cotton,
The crop diseases such as grain have efficient.
At this stage, raising rice seedlings realize the transformation from watery ricenursery to dry rice seedling substantially, and rice shoot disease is still watered with medicament
It is prevented and treated by spraying, it is more time-consuming.In the case where rural labour's shortage, effort-saving prevents and treats the method for pest and disease damage increasingly
Concerned, the present invention is compounded by effective component probenazole and Metalaxyl-M, and granular pesticide, uptake and translocation is made
Good, in seedling operation or seeding stage is applied, and can be effectively prevented rice seedling damping-off, be achieved the effect that time and labour saving.
Currently, probenazole there are no relevant report to the research of Metalaxyl-M mixture.
Summary of the invention
The technical problem to be solved by the present invention is to, a kind of granular pesticide containing probenazole and Metalaxyl-M is provided,
For the prevention and treatment of dry rice seedling phase rice damping-off, formula synergy is significant, and absorbability is good, can effectively control disease, has time saving
The effect to save labor.
The technical solution adopted by the present invention is that: a kind of granular pesticide containing probenazole and Metalaxyl-M, effectively at
Divide probenazole and Metalaxyl-M composition, wherein the weight ratio of probenazole and Metalaxyl-M are as follows: 10-20:1-5, preferably
, the weight ratio of probenazole and Metalaxyl-M is 15:2.
Weight percent of the probenazole in granular pesticide is 5-10%, and Metalaxyl-M is in pesticide granules
Weight percent in agent is 0.5-3.0%.
The adjuvant that granular pesticide of the invention is added includes filler, binder, dispersing agent, wetting agent, disintegrating agent, steady
Determine agent or it is other be beneficial to the effective component substance that stable and drug effect plays in the formulation, be all commonly used in field of pesticide preparation or
Allow using various composition.
The present invention has the following advantages that and significant technical effect:
(1) probenazole and Metalaxyl-M have double action mechanism, and mutually mixture germ is not easy to produce resistance.
(2) indoor biometrics the result shows that, probenazole and Metalaxyl-M compound according to a certain percentage increases rhizoctonia solani
Effect is obvious, can be reduced applications of pesticide amount and reduces pesticide cost.
(3) present invention is prepared into granular pesticide, applies when in conjunction with dry rice seedling operation or during seedling, alleviates farming behaviour
Make, more saves labor.
Specific embodiment
Technical solution of the present invention and beneficial effect are described further with reference to embodiments, of the present invention hundred
Ratio is divided to be weight percentage.
One, embodiment is prepared
Embodiment 1:5.5% probenazole Metalaxyl-M granule (effective component ratio 10:1)
Formula: weighing probenazole 5% by weight, Metalaxyl-M 0.5%, naphthalenesulfonate formaldehyde condensation compound 4%, and ten
Sodium dialkyl sulfate 3%, polyvinyl alcohol 3.5%, bentonite complements to 100%.
Embodiment 2:8.5% probenazole Metalaxyl-M granule (effective component ratio 15:2)
Formula: weighing probenazole 7.5% by weight, Metalaxyl-M 1%, naphthalenesulfonate formaldehyde condensation compound 3%, and ten
Sodium dialkyl sulfate 3.5%, polyvinyl alcohol 3%, attapulgite 12%, kaolin complements to 100%.
Embodiment 3:12.5% probenazole Metalaxyl-M granule (effective component ratio 20:5)
Formula: probenazole 10%, Metalaxyl-M 2.5%, lauryl sodium sulfate 2.5%, carboxylic are weighed by weight
Methylcellulose 3.5%, diatomite 15%, bentonite complements to 100%.
Embodiment 4:13% probenazole Metalaxyl-M granule (effective component ratio 10:3)
Formula: weighing probenazole 10% by weight, Metalaxyl-M 3%, naphthalenesulfonate formaldehyde condensation compound 5%, and ten
Sodium dialkyl sulfate 2.5%, polyvinyl alcohol 5%, kaolin complements to 100%.
Preparation method: recipe ingredient described in above-described embodiment 1-4 is uniformly mixed, and is crushed, is sufficiently stirred after wetting with water
It mixes uniformly, then is granulated with screw extruder pelletizer, is sieved after dry up to the granule of Metalaxyl-M containing probenazole.
Two, BIOLOGICAL ACTIVITY EXAMPLES
BIOLOGICAL ACTIVITY EXAMPLES of the invention is the method combined using indoor toxicity test and field trial.
Embodiment 1: the indoor toxicity test of probenazole, Metalaxyl-M and compounding agent to rice seedling blight
After prerun determines the effective inhibition concentration range of each medicament, probenazole, Metalaxyl-M and its mixed agent are pressed
Active constituent content gradient series dilute 5 concentration, if clear water compares.Referring to " farm-chemical indoor determination test rule sterilization
Agent " it carries out, using mycelial growth rate method measurement medicament to the virulence of rhizoctonia solani.Bacterium colony is measured with crossing method after 72h
Diameter calculates each processing net growth, mycelial growth inhibition rate.
Mycelial growth inhibition rate is converted into probit value (y), liquor strength (μ g/mL) is converted into logarithm (x), with minimum
Square law acquires virulence regression equation (y=a+bx), and thus calculates the EC of every kind of medicament50Value.
The synergistic effect of pharmacy mix is evaluated according to the co-toxicity coefficient method (CTC) of Sun Yunpei's Method, i.e. CTC≤80 are antagonism
Effect, 80<CTC<120 are summation action, and CTC>=120 are synergistic effect.Statistical result is as shown in table 1:
| Reagent agent | Proportion | EC50(mg/L) | Co-toxicity coefficient (CTC) |
| Probenazole (A) | / | 1.51 | / |
| Metalaxyl-M (B) | / | 2.57 | / |
| A:B | 10:1 | 1.23 | 127.6 |
| A:B | 10:3 | 1.26 | 132.1 |
| A:B | 10:5 | 1.22 | 142.8 |
| A:B | 15:1 | 1.16 | 133.4 |
| A:B | 15:2 | 0.95 | 166.9 |
| A:B | 15:5 | 1.25 | 134.6 |
| A:B | 20:1 | 1.16 | 132.6 |
| A:B | 20:3 | 1.27 | 125.8 |
| A:B | 20:5 | 1.25 | 131.6 |
| A:B | 1:9 | 3.05 | 78.6 |
Measurement result show when the proportion of probenazole and Metalaxyl-M be 10-20:1-5 when, co-toxicity coefficient (CTC)
Greater than 120, synergistic effect is obvious.
Embodiment 2: the preparation resulting preparation of embodiment 2 is used to prevent and treat the field control effectiveness test of rice seedling blight
(1) experimental design: using 8.5% probenazole Metalaxyl-M (15:2) granule as test group 1#, application
Amount is 0.1 kilogram/m2；Using 8% probenazole granule as control group 1#, amount of application is 0.15 kilogram/m2；With 12% smart first
White spirit granule is control group 2#, and amount of application is 0.15 kilogram/m2, 1 blank control group is set.
(2) application method
Disease-free seedling plot is selected, the soil with rhizoctonia solani is uniformly mixed, is successively layered on i.e. by smooth seedling furrow
It will test on seedling furrow, it is desired to which the thickness of soil in spite of illness on furrow is consistent.The seed-grain of bud will be urged to plant in soil, in test
3 repetitions of each processing, plot area 1m2, by experimental design by the correspondence medicament of test group 1#, control group 1#, control group 2#
It is uniformly imposed in corresponding cell by defined dosage, keeps seedbed environment consistent in each cell.
(3) test result
It 10 days after medicine, is investigated in conjunction with rice shoot damping-off high-incidence season result, calculates disease incidence and control efficiency, the results showed that,
Test group 1# is 91.53% to the control efficiency of rice shoot damping-off, and control group 1# is to the control efficiency of rice shoot damping-off
71.24%；Control group 2# is 74.52% to the control efficiency of rice shoot damping-off.Find out from test, probenazole and smart first
After white spirit mixture, mixed agent is obvious to rice shoot damping-off synergy, not only reduces the usage amount of effective component, but also show better than single
The field efficacy of agent helps to reduce Pesticide use cost.
Claims (4)
1. a kind of granular pesticide containing probenazole and Metalaxyl-M, which is characterized in that probenazole and Metalaxyl-M
Weight ratio are as follows: 10-20:1-5.
2. the granular pesticide according to claim 1 containing probenazole and Metalaxyl-M, which is characterized in that phenyl allyloxy
The weight ratio of thiazole and Metalaxyl-M is 15:2.
3. the granular pesticide according to claim 1 or 2 containing probenazole and Metalaxyl-M, which is characterized in that alkene
The weight percent of propyl benzene thiazole is 5-10%, and the weight percent of Metalaxyl-M is 0.5-3%.
4. the granular pesticide as claimed in claim 3 containing probenazole and Metalaxyl-M is for preventing and treating dry rice seedling rice damping-off
Purposes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610279128.5A CN105918325B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and Metalaxyl-M |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610279128.5A CN105918325B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and Metalaxyl-M |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105918325A CN105918325A (en) | 2016-09-07 |
| CN105918325B true CN105918325B (en) | 2019-01-18 |
Family
ID=56836654
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610279128.5A Active CN105918325B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and Metalaxyl-M |
Country Status (1)
| Country | Link |
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| CN (1) | CN105918325B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108013077A (en) * | 2018-01-17 | 2018-05-11 | 河南科技学院 | A kind of microbe soil fungicide |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3629428A (en) * | 1967-09-07 | 1971-12-21 | Meiji Seika Kaisha | Pesticide for controlling bacterial and fungal diseases of rice plant |
| JP2581917B2 (en) * | 1987-04-24 | 1997-02-19 | アグロカネシヨウ株式会社 | Agricultural and horticultural fungicides |
| CN105340953B (en) * | 2012-02-10 | 2017-11-21 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing probenazole |
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2016
- 2016-04-28 CN CN201610279128.5A patent/CN105918325B/en active Active
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| CN105918325A (en) | 2016-09-07 |
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Effective date of registration: 20240516 Address after: 274400 Jianglou administrative village, qinggangji Township, Cao County, Heze City, Shandong Province (New Material Industrial Park) Patentee after: Shandong Aosheng Biotechnology Co.,Ltd. Country or region after: China Address before: Room 101, 102, 107, 108, 109, Room 6, West Hall, Room E1, Wuhan Software New Town, Room 9, Huacheng Avenue, Wuhan Donghu New Technology Development Zone, Hubei Province, 430075 Patentee before: Wuhan Huanlv times ecological garden Technology Co.,Ltd. Country or region before: China |