CN105918325A - Pesticide granule containing probenazole and metalaxyl-M - Google Patents
Pesticide granule containing probenazole and metalaxyl-M Download PDFInfo
- Publication number
- CN105918325A CN105918325A CN201610279128.5A CN201610279128A CN105918325A CN 105918325 A CN105918325 A CN 105918325A CN 201610279128 A CN201610279128 A CN 201610279128A CN 105918325 A CN105918325 A CN 105918325A
- Authority
- CN
- China
- Prior art keywords
- metalaxyl
- probenazole
- pesticide granule
- pesticide
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000005808 Metalaxyl-M Substances 0.000 title claims abstract description 41
- ZQEIXNIJLIKNTD-GFCCVEGCSA-N metalaxyl-M Chemical compound COCC(=O)N([C@H](C)C(=O)OC)C1=C(C)C=CC=C1C ZQEIXNIJLIKNTD-GFCCVEGCSA-N 0.000 title claims abstract description 41
- WHHIPMZEDGBUCC-UHFFFAOYSA-N probenazole Chemical compound C1=CC=C2C(OCC=C)=NS(=O)(=O)C2=C1 WHHIPMZEDGBUCC-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000000575 pesticide Substances 0.000 title claims abstract description 23
- 239000008187 granular material Substances 0.000 title abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 18
- 241000209094 Oryza Species 0.000 claims abstract description 17
- 235000009566 rice Nutrition 0.000 claims abstract description 17
- 241000918585 Pythium aphanidermatum Species 0.000 claims 1
- DDSAOQMKNUBIBW-UHFFFAOYSA-N S1C=NC=C1.C(CC)C1=CC=CC=C1 Chemical compound S1C=NC=C1.C(CC)C1=CC=CC=C1 DDSAOQMKNUBIBW-UHFFFAOYSA-N 0.000 claims 1
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 claims 1
- 150000001336 alkenes Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 230000002265 prevention Effects 0.000 abstract description 6
- 201000010099 disease Diseases 0.000 abstract description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract description 5
- 241000607479 Yersinia pestis Species 0.000 abstract description 3
- 230000009885 systemic effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 11
- 238000012360 testing method Methods 0.000 description 10
- 239000004615 ingredient Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 241000233629 Phytophthora parasitica Species 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 4
- 241000813090 Rhizoctonia solani Species 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000000440 bentonite Substances 0.000 description 2
- 229910000278 bentonite Inorganic materials 0.000 description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 2
- 230000004071 biological effect Effects 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 230000000857 drug effect Effects 0.000 description 2
- 238000013401 experimental design Methods 0.000 description 2
- 230000009036 growth inhibition Effects 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001018 virulence Effects 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- RZYKUPXRYIOEME-UHFFFAOYSA-N CCCCCCCCCCCC[S] Chemical compound CCCCCCCCCCCC[S] RZYKUPXRYIOEME-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001330975 Magnaporthe oryzae Species 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- 241001281805 Pseudoperonospora cubensis Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- LJWIAZFZRNWQOL-UHFFFAOYSA-N benzene;1,3-thiazole Chemical compound C1=CSC=N1.C1=CC=CC=C1 LJWIAZFZRNWQOL-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229940126214 compound 3 Drugs 0.000 description 1
- 229940125898 compound 5 Drugs 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 206010025482 malaise Diseases 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229930015698 phenylpropene Natural products 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000013207 serial dilution Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000005945 translocation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Reagent agent | Proportioning | EC50(mg/L) | Co-toxicity coefficient (CTC) |
Probenazole (A) | / | 1.51 | / |
Metalaxyl-M (B) | / | 2.57 | / |
A:B | 10:1 | 1.23 | 127.6 |
A:B | 10:3 | 1.26 | 132.1 |
A:B | 10:5 | 1.22 | 142.8 |
A:B | 15:1 | 1.16 | 133.4 |
A:B | 15:2 | 0.95 | 166.9 |
A:B | 15:5 | 1.25 | 134.6 |
A:B | 20:1 | 1.16 | 132.6 |
A:B | 20:3 | 1.27 | 125.8 |
A:B | 20:5 | 1.25 | 131.6 |
A:B | 1:9 | 3.05 | 78.6 |
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610279128.5A CN105918325B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and Metalaxyl-M |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610279128.5A CN105918325B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and Metalaxyl-M |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105918325A true CN105918325A (en) | 2016-09-07 |
CN105918325B CN105918325B (en) | 2019-01-18 |
Family
ID=56836654
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610279128.5A Active CN105918325B (en) | 2016-04-28 | 2016-04-28 | A kind of granular pesticide containing probenazole and Metalaxyl-M |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105918325B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108013077A (en) * | 2018-01-17 | 2018-05-11 | 河南科技学院 | A kind of microbe soil fungicide |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3629428A (en) * | 1967-09-07 | 1971-12-21 | Meiji Seika Kaisha | Pesticide for controlling bacterial and fungal diseases of rice plant |
US4855311A (en) * | 1987-04-24 | 1989-08-08 | Agro-Kanesho Co., Ltd. | Benzoisothiazole oximes which are plant protection agents for control of fungi and bacteria |
CN103238622A (en) * | 2012-02-10 | 2013-08-14 | 陕西美邦农药有限公司 | Bactericidal composition containing probenazole |
-
2016
- 2016-04-28 CN CN201610279128.5A patent/CN105918325B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3629428A (en) * | 1967-09-07 | 1971-12-21 | Meiji Seika Kaisha | Pesticide for controlling bacterial and fungal diseases of rice plant |
US4855311A (en) * | 1987-04-24 | 1989-08-08 | Agro-Kanesho Co., Ltd. | Benzoisothiazole oximes which are plant protection agents for control of fungi and bacteria |
CN103238622A (en) * | 2012-02-10 | 2013-08-14 | 陕西美邦农药有限公司 | Bactericidal composition containing probenazole |
Non-Patent Citations (1)
Title |
---|
张一宾,徐进: "作物抗病激活剂烯丙苯噻唑的合成", 《现代农药》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108013077A (en) * | 2018-01-17 | 2018-05-11 | 河南科技学院 | A kind of microbe soil fungicide |
Also Published As
Publication number | Publication date |
---|---|
CN105918325B (en) | 2019-01-18 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20181206 Address after: 448200 Guodian Village, Jishan Town, Shayang County, Jingmen City, Hubei Province Applicant after: JINMEN LVYOU FLOWER NURSERY Co.,Ltd. Address before: 530000 room 3106, block C, hang Yang International City, No. 131, National Road, Qingxiu District, Nanning, the Guangxi Zhuang Autonomous Region. Applicant before: GUANGXI NANNING YITU BIOTECHNOLOGY Co.,Ltd. |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20191108 Address after: 430075 Hubei city Wuhan East Lake New Technology Development Zone 9 Huacheng Road 9 Wuhan software new town E1 building 101, 102, 107, 108, 109 room West Hall 6. Patentee after: Wuhan Huanlv times ecological garden Technology Co.,Ltd. Address before: 448200 Guodian Village, Jishan Town, Shayang County, Jingmen City, Hubei Province Patentee before: JINMEN LVYOU FLOWER NURSERY Co.,Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240516 Address after: 274400 Jianglou administrative village, qinggangji Township, Cao County, Heze City, Shandong Province (New Material Industrial Park) Patentee after: Shandong Aosheng Biotechnology Co.,Ltd. Country or region after: China Address before: Room 101, 102, 107, 108, 109, Room 6, West Hall, Room E1, Wuhan Software New Town, Room 9, Huacheng Avenue, Wuhan Donghu New Technology Development Zone, Hubei Province, 430075 Patentee before: Wuhan Huanlv times ecological garden Technology Co.,Ltd. Country or region before: China |