CN102119685B - Bactericidal composition containing fluazinam and validamycin and application of same - Google Patents
Bactericidal composition containing fluazinam and validamycin and application of same Download PDFInfo
- Publication number
- CN102119685B CN102119685B CN 201010017614 CN201010017614A CN102119685B CN 102119685 B CN102119685 B CN 102119685B CN 201010017614 CN201010017614 CN 201010017614 CN 201010017614 A CN201010017614 A CN 201010017614A CN 102119685 B CN102119685 B CN 102119685B
- Authority
- CN
- China
- Prior art keywords
- fluazinam
- jinggangmeisu
- bactericidal composition
- composition
- validamycin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention belongs to the field of farm chemicals and discloses a bactericidal composition containing fluazinam and validamycin and the application of the same. The fluazinam and the validamycin serve as effective components of the composition, wherein the total content of the fluazinam and the validamycin in mass percentage is 5% to 70%, and the mass ratio of the fluazinam to the validamycin is 50:1 to 1:30. The composition can be used for preventing and treating diseases such as rice blast, rice sheath blight, wheat leaf blight, wheat rust disease, peanut leaf spot, peanut net blotch, late blight of tomato and potato, gray mold, powdery mildew and anthracnose of cucumber, and apple scab caused by fungi and other pathogens of cereal crops, vegetable and fruit trees, and has the advantages of wide application range, low cost and good effect.
Description
Technical field
The invention belongs to pesticide field, relate to a kind of bactericidal composition and application thereof, be specifically related to bactericidal composition and the application thereof of a kind of containing fluazinam and jinggangmeisu.
Background technology
In recent years, because fungi, bacterium, nematode, virus and the plant disease that causes such as malnutritive are more and more heavy, the impact that causes is also increasing.
Fluazinam belongs to 2,6-dinitroanilines, is protective fungicide, is mitochondrial oxidation phosphorylated uncoupler.Suppress the course of infection in all stages by suppressing spore germination, mycelia breakthrough, growth and sporulation.The fungicidal spectrum of fluazinam is very wide, and its effect is better than the GPF (General Protection False bactericide.Interlink spore genus, Botrytis, Phytophthora, single shaft Pseudomonas, Sclerotinia and Venturia there are special efficacy, the Botrytis cinerea of anti-benzimidazole type and dicarboximide series bactericidal agent are belonged to good effect is also arranged.This medicine also has the effect that resistance of rainwater washing against, lasting period are long, have good control phytophagous mites concurrently in addition, and the club root of crucifer is also had remarkable preventive effect, and the microbial paddy rice damping off of friendly head mold is also had good control efficiency.
In China, because the fluazinam import price is high, usable floor area is confined on the high some crops of economic value added, uses area less, can not use in the crop pests control widely, and this bactericide also exists the larger defective of toxicity.
Jinggangmeisu is a kind of antibiotic of actinomycetes generation, has very strong interior suction bactericidal action, is easily absorbed by somatic cells and rapidly conduction within it, disturbs and inhibition somatic cells g and D.The crops such as suitable water paddy and wheat class, vegetables, ginseng, corn, beans, cotton and melon and fruit, to rice sheath blight disease, false smut, Wheat sheath blight, cotton, ginseng, beans and melon and fruit class damping off, corn northern and southern leaf blight has better effects.But under the condition of at present long-term single drug, the evil bacterium increases gradually to its pesticide resistance, and with other kinds series bactericidal agent cross resistance is arranged, and the agricultural chemicals single dose descends gradually to the effect of evil bacterium control.
Agriculture chemical compounding can obviously improve drug effect, and delays the generation of evil bacterium resistance.Not yet find up to now the Pesticidal combination of relevant fluazinam and jinggangmeisu.
Summary of the invention
The objective of the invention is for the problems referred to above, a kind of applied widely, containing fluazinam that cost is low, effective and the bactericidal composition of jinggangmeisu are provided.
Another object of the present invention provides this
A kind of microbicide compositions, take fluazinam and jinggangmeisu as active ingredient, wherein the mass ratio of fluazinam and jinggangmeisu is 50: 1～1: 30, preferred 30: 1～1: 20, particularly preferably 20: 1～1: 10.Wherein, the gross mass percentage composition of described fluazinam and jinggangmeisu is 5%～70%, preferred 10%～60%.
Described fluazinam and jinggangmeisu and known auxiliary agent and excipient are re-dubbed any one formulation that allows on the agricultural chemicals.Can be processed into suspending agent, dry suspending agent, wetting powder, pulvis, water dispersion granule etc. after the combination of two active components.
This bactericidal composition can be used for preparing the bactericide of preventing and treating corps diseases, be preferred for preparing the bactericide of control paddy rice, wheat, corn, cotton, vegetables or fruit crop disease, further be preferred for preparation and prevent and treat rice sheath blight disease, false smut, wheat sharp eyespot, cotton seedling blight, the bactericide of cucumber downy mildew, powdery mildew or tomato blight, the particularly preferably bactericide of preparation control cucumber downy mildew, powdery mildew or rice sheath blight disease.
Beneficial effect of the present invention: the used fluazinam of the present invention is the pyridines bactericide, and jinggangmeisu is the antibiotics bactericide, and mutually being mixed can not produce conflict, can produce significant synergistic function, can reduce dosage when using, and reduces cost.The present composition has enlarged fungicidal spectrum and has widened dispenser period, has better antibacterial and sterilization double effects, has overcome the deficiency of a certain composition of single use, has avoided plant disease to produce the risk of resistance.
Embodiment
Embodiment 1:70% fluazinam jinggangmeisu suspending agent
Fluazinam 50kg
Jinggangmeisu 20kg
Phosphoric acid esters wedding agents 6kg
Polysiloxane defoamers 0.2kg
Xanthans 0.3kg
Water complements to 100kg
Above-mentioned respectively the metering stirred by the one-level sand mill after composition mixes, behind the secondary sand mill sand milling, in modulation kettle, allocate, carry out metering, distributing, packaging after inspection by sampling is qualified and both got the suspending agent formulation products.
Embodiment 2:60% fluazinam jinggangmeisu dry suspending agent
Fluazinam 50kg
Jinggangmeisu 10kg
Sodium lignin sulfonate 8kg
Sodium phosphate trimer 3kg
Ammonium sulfate 12kg
Kaolin complements to 100kg
With various compositions mix all with, pulverizing after, mix suitable water spray granulating and drying and get the dry suspending agent formulation products.
Embodiment 3:50% fluazinam jinggangmeisu suspending agent
Fluazinam 40kg
Jinggangmeisu 10kg
Phosphoric acid esters wedding agents 6kg
Polysiloxane defoamers 0.2kg
Xanthans 0.3kg
Water complements to 100kg
Above-mentioned respectively the metering stirred by the one-level sand mill after composition mixes, behind the secondary sand mill sand milling, in modulation kettle, allocate, carry out metering, distributing, packaging after inspection by sampling is qualified and both got the suspending agent formulation products.
Embodiment 4:40% fluazinam jinggangmeisu wetting powder
Fluazinam 35kg
Jinggangmeisu 5kg
Pull open powder 3kg
Naphthalene sulfonate 2kg
White carbon 5kg
Kaolin complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the wetting powder formulation products.
Embodiment 5:20% fluazinam jinggangmeisu wetting powder
Fluazinam 15kg
Jinggangmeisu 5kg
Pull open powder 3kg
Naphthalene sulfonate 2kg
White carbon 5kg
Kaolin complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the wetting powder formulation products.
Embodiment 6:60% fluazinam jinggangmeisu water dispersion granule
Fluazinam 50kg
Jinggangmeisu 10kg
Naphthalene sulfonate 6kg
Ammonium sulfate 4kg
Kaolin complements to 100kg
To add wetting dispersing agent after the active ingredient dissolving, the rear interpolation kaolin that stirs grinds the pressure granulation after the mixing, and oven dry had both got the water dispersion granule formulation products.
Embodiment 7:10% fluazinam validamycin powder agent
Fluazinam 8kg
Jinggangmeisu 2kg
White carbon 5kg
Talcum powder complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the powder preparation product.
Embodiment 8:5% fluazinam jinggangmeisu dry suspending agent
Fluazinam 3kg
Jinggangmeisu 2kg
Sodium lignin sulfonate 3kg
Sodium phosphate trimer 2kg
Ammonium sulfate 10kg
Kaolin complements to 100kg
With various compositions mix all with, pulverizing after, mix suitable water spray granulating and drying and get the dry suspending agent formulation products.
Embodiment 9:55% fluazinam jinggangmeisu water dispersion granule
Fluazinam 50kg
Jinggangmeisu 5kg
Naphthalene sulfonate 6kg
Ammonium sulfate 4kg
Kaolin complements to 100kg
To add wetting dispersing agent after the active ingredient dissolving, the rear interpolation kaolin that stirs grinds the pressure granulation after the mixing, and oven dry had both got the water dispersion granule formulation products.
Embodiment 10:63% fluazinam jinggangmeisu wetting powder
Fluazinam 60kg
Jinggangmeisu 3kg
Pull open powder 4kg
Naphthalene sulfonate 3kg
White carbon 8kg
Kaolin complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the wetting powder formulation products.
Embodiment 11:24% fluazinam jinggangmeisu dry suspending agent
Fluazinam 4kg
Jinggangmeisu 20kg
Sodium lignin sulfonate 4kg
Sodium phosphate trimer 5kg
Ammonium sulfate 12kg
Kaolin complements to 100kg
With various compositions mix all with, pulverizing after, mix suitable water spray granulating and drying and get the dry suspending agent formulation products.
Embodiment 12:20% fluazinam validamycin powder agent
Fluazinam 2kg
Jinggangmeisu 18kg
White carbon 7kg
Talcum powder complements to 100kg
Above metering composition is mixed laggard promoting the circulation of qi stream pulverize, both got the powder preparation product.
Application example 1: the experiment of control cucumber downy mildew
1. be indoor conventional screening cucumber sense downy mildew kind for studying thing.
2. test is processed: this test medicine consumption arranges 5 concentration gradients according to the content of active ingredient, and the contrast medicament is 50% fluazinam suspending agent and 12% jinggangmeisu aqua and the contrast of blank clear water.
3. test method: from the cucumber cotyledons phase, on the cucumber leaves that 2 true leaves are arranged, the spray medicine is processed after 24 hours with downy mildew of cucurbits bacterium spore suspension spray inoculation.Check the blade disease index after 7 days, calculate co-toxicity coefficient.
4. result of the test sees the following form 1:
Table 1
| Medicament | Regression equation | EC 50(95% confidence interval) (mg/L) | Co-toxicity coefficient |
| 50% fluazinam suspending agent | Y＝0.6248+2.1104x | 55.65(45.371～84.724) | / |
| 12% jinggangmeisu aqua | Y＝0.4837+3.2451x | 168.345(83.371～177.76) | / |
| Embodiment 1 | Y＝1.9033+1.7583x | 42.494(31.643～63.856) | 184 |
| Embodiment 3 | Y＝0.5235+2.6234x | 34.143(21.657～43.453) | 218 |
| Embodiment 4 | Y＝1.2455+2.4141x | 119.65(98.341～132.43) | 125 |
From Toxicity Determination, two kinds of group of effective components are combined it and spend coefficient together greater than 100, have obvious synergistic effect.
Application example 2: prevent and treat the rice sheath blight disease field control effectiveness test
1. test is processed: this test medicine consumption is the consumption of active ingredient, different preparations are established respectively three concentration for the treatment of, and the contrast medicament is respectively commercially available agricultural chemicals 50% fluazinam suspending agent (SC) and 12% jinggangmeisu aqua (AS) and the test of blank clear water.
2. test method: each residential quarter area is 66.7m
2, repeat 3 times; Inspection drug effect method before the dispenser behind the Investigation and Prevention is: random sampling 5 points in the test treatment region, check the banded sclerotial blight occurrence degree by 10 clumps every.
3. result of the test sees Table 2:
Table 2
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Dosage in the table 2 refers to the consumption of active ingredient in each preparation.Field efficacy is the result show, 12% jinggangmeisu aqua is prevented and treated rice sheath blight disease good control efficiency in early stage, but general effect is poor, and fluazinam and validamycin composition have good control efficiency to rice sheath blight disease, and control efficiency all is better than the single dose kind.
Application example 3: prevent and treat the powdery mildew of cucumber test.
1. test is processed: this test medicine consumption is the consumption of active ingredient, different preparations are established respectively three concentration for the treatment of, and the contrast medicament is respectively commercially available agricultural chemicals 50% fluazinam suspending agent (SC) and 12% jinggangmeisu aqua (AS) and the test of blank clear water.
2. test method: each residential quarter area is 66.7m
2, repeat 3 times; Inspection drug effect method before the dispenser behind the Investigation and Prevention is: random sampling 5 points in the test treatment region, every 10 leaves check the powdery mildew occurrence degree.
3. result of the test sees Table 3:
Table 3
Annotate: a is illustrated on α=0.05 level remarkable, and b is illustrated on α=0.05 level variant, and c is illustrated on α=0.05 level not remarkable.
Dosage in the table 2 refers to the consumption of active ingredient in each preparation.Field efficacy is the result show, fluazinam and validamycin composition have good control efficiency to powdery mildew of cucumber, and control efficiency all is better than the single dose kind.
Claims (11)
1. bactericidal composition is characterized in that said composition take fluazinam and jinggangmeisu as active ingredient, and wherein the mass ratio of fluazinam and jinggangmeisu is 50: 1～1: 30.
2. bactericidal composition according to claim 1, the mass ratio that it is characterized in that described fluazinam and jinggangmeisu is 30: 1～1: 20.
3. bactericidal composition according to claim 1, the mass ratio that it is characterized in that described fluazinam and jinggangmeisu is 20: 1～1: 10.
4. according to claim 1,2 or 3 described bactericidal compositions, it is characterized in that the gross mass percentage composition of fluazinam and jinggangmeisu is 5%～70% in the described composition.
5. bactericidal composition according to claim 4 is characterized in that the gross mass percentage composition of fluazinam and jinggangmeisu is 10%～60% in the described composition.
6. bactericidal composition according to claim 1 is characterized in that this bactericidal composition is re-dubbed any one formulation that allows on the agricultural chemicals by fluazinam and jinggangmeisu and known auxiliary agent and excipient.
7. described bactericidal composition according to claim 6 is characterized in that described formulation is suspending agent, pulvis, water dispersion granule.
8. the application of bactericidal composition claimed in claim 1 in the bactericide of preparation control corps diseases.
9. the application of bactericidal composition claimed in claim 1 in the bactericide of preparation control paddy rice, wheat, corn, cotton, vegetables or fruit crop disease.
10. bactericidal composition claimed in claim 1 is prevented and treated rice sheath blight disease, false smut in preparation, wheat sharp eyespot, cotton seedling blight, the application in the bactericide of cucumber downy mildew, powdery mildew or tomato blight.
11. application according to claim 10 is characterized in that the application of bactericidal composition claimed in claim 1 in the bactericide of preparation control cucumber downy mildew, powdery mildew or rice sheath blight disease.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010017614 CN102119685B (en) | 2010-01-08 | 2010-01-08 | Bactericidal composition containing fluazinam and validamycin and application of same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010017614 CN102119685B (en) | 2010-01-08 | 2010-01-08 | Bactericidal composition containing fluazinam and validamycin and application of same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102119685A CN102119685A (en) | 2011-07-13 |
| CN102119685B true CN102119685B (en) | 2013-01-23 |
Family
ID=44248431
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010017614 Active CN102119685B (en) | 2010-01-08 | 2010-01-08 | Bactericidal composition containing fluazinam and validamycin and application of same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102119685B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102812964A (en) * | 2012-09-06 | 2012-12-12 | 中国农业大学 | Pesticide composition containing thiacloprid and validamycin |
| CN104542598A (en) * | 2015-01-15 | 2015-04-29 | 钱忠金 | Biological-chemical synergism bactericide |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101160052A (en) * | 2005-03-31 | 2008-04-09 | 三井化学株式会社 | Pesticidal composition |
| CN101208009A (en) * | 2005-07-27 | 2008-06-25 | 三井化学株式会社 | Composition for preventing and removing pest |
| EP2014167A1 (en) * | 2007-07-13 | 2009-01-14 | Bayer CropScience AG | Active compound combinations |
| CN101605461A (en) * | 2007-02-06 | 2009-12-16 | 巴斯夫欧洲公司 | Pesticide combination |
-
2010
- 2010-01-08 CN CN 201010017614 patent/CN102119685B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101160052A (en) * | 2005-03-31 | 2008-04-09 | 三井化学株式会社 | Pesticidal composition |
| CN101208009A (en) * | 2005-07-27 | 2008-06-25 | 三井化学株式会社 | Composition for preventing and removing pest |
| CN101605461A (en) * | 2007-02-06 | 2009-12-16 | 巴斯夫欧洲公司 | Pesticide combination |
| EP2014167A1 (en) * | 2007-07-13 | 2009-01-14 | Bayer CropScience AG | Active compound combinations |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102119685A (en) | 2011-07-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111296460B (en) | Compound synergistic bactericidal composition for preventing and treating main diseases of tomatoes and pears and application thereof | |
| CN101595882B (en) | Pesticide composition containing methoxyl acrylic ester bactericide | |
| CN102119693B (en) | Synergetic antibacterial composition containing fluazinam and tebuconazole and use thereof | |
| CN102119685B (en) | Bactericidal composition containing fluazinam and validamycin and application of same | |
| CN102119689B (en) | Bactericidal composition containing fluazinam and azoxystrobin and application of same | |
| CN101755779B (en) | Fungicidal composition containing bromothalonil and propineb and application thereof | |
| CN101194620B (en) | Bactericide agent composition containing tebuconazole | |
| CN102119691B (en) | Bactericidal composition containing fluazinam and difenoconazole and application of same | |
| CN103329905B (en) | Sterilization composition containing penflufen and validamycin | |
| CN102119697B (en) | Synergistic bactericidal composition containing fluazinam and carbendazim and application thereof | |
| CN102119690B (en) | Bactericidal composition containing fluazinam and epoxiconazole and application of same | |
| CN102119699B (en) | Bactericidal composition containing fluazinam and prochloraz and application thereof | |
| CN102119698A (en) | Bactericidal composition containing fluazinam and thiophanate methyl and application of same | |
| CN102119683B (en) | Bactericidal composition containing fluazinam and kasugamycin and application thereof | |
| CN102119684B (en) | Bactericidal composition containing fluazinam and dimethachlon and application of same | |
| CN105340944A (en) | Pesticide granule containing imidacloprid and azoxystrobin | |
| CN104488891A (en) | Powdery mildew control sterilization composition | |
| CN102726451B (en) | Azoxystrobin-containing bactericidal composition and its application | |
| CN102119688A (en) | Bactericidal composition containing fluazinam and cyprodinil and application of same | |
| CN102119686A (en) | Synergistic bactericidal composition containing fluazinam and chlorothalonil and application thereof | |
| CN100375597C (en) | Germicide composition containing pyraclostrobin and carbendazim and its use | |
| CN105475356A (en) | Pesticide composition containing propineb and prochloraz manganese | |
| CN105918325A (en) | Pesticide granule containing probenazole and metalaxyl-M | |
| CN102119700B (en) | Synergetic antibacterial composition containing fluazinam and iprobenfos and use thereof | |
| CN104430438A (en) | Cymoxanil-containing fungicide composition and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |