CN106948082A - 高密度仿里皮 - Google Patents
高密度仿里皮 Download PDFInfo
- Publication number
- CN106948082A CN106948082A CN201710331823.6A CN201710331823A CN106948082A CN 106948082 A CN106948082 A CN 106948082A CN 201710331823 A CN201710331823 A CN 201710331823A CN 106948082 A CN106948082 A CN 106948082A
- Authority
- CN
- China
- Prior art keywords
- parts
- high density
- cloth
- inner leather
- imitation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010985 leather Substances 0.000 title claims abstract description 27
- 239000004744 fabric Substances 0.000 claims abstract description 42
- 239000004745 nonwoven fabric Substances 0.000 claims abstract description 28
- 238000004026 adhesive bonding Methods 0.000 claims abstract description 25
- 238000005520 cutting process Methods 0.000 claims abstract description 25
- 229920000742 Cotton Polymers 0.000 claims abstract description 16
- 238000009960 carding Methods 0.000 claims abstract description 16
- 238000005406 washing Methods 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 229920000728 polyester Polymers 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 8
- 238000007731 hot pressing Methods 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 238000002156 mixing Methods 0.000 claims abstract description 8
- 230000006855 networking Effects 0.000 claims abstract description 8
- 238000003825 pressing Methods 0.000 claims abstract description 8
- 230000002787 reinforcement Effects 0.000 claims abstract description 8
- 238000004513 sizing Methods 0.000 claims abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 32
- 239000003292 glue Substances 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000011787 zinc oxide Substances 0.000 claims description 16
- 230000001070 adhesive effect Effects 0.000 claims description 11
- 239000000853 adhesive Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 10
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 10
- 229920003180 amino resin Polymers 0.000 claims description 8
- 239000002518 antifoaming agent Substances 0.000 claims description 8
- 239000002480 mineral oil Substances 0.000 claims description 8
- 235000010446 mineral oil Nutrition 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 5
- 230000006641 stabilisation Effects 0.000 claims description 5
- 238000011105 stabilization Methods 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims 1
- BEBXIKIXVLRHEM-UHFFFAOYSA-N [Na].C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=C(C=CC=C2)C2=C1S(O)(=O)=O Chemical compound [Na].C1=CC2=CC=CC=C2C(S(=O)(=O)O)=C1CC1=CC=C(C=CC=C2)C2=C1S(O)(=O)=O BEBXIKIXVLRHEM-UHFFFAOYSA-N 0.000 claims 1
- YWWOEPOBDHZQEJ-UHFFFAOYSA-N s-(4-cyclohexyl-1,3-benzothiazol-2-yl)thiohydroxylamine Chemical class C1=CC=C2SC(SN)=NC2=C1C1CCCCC1 YWWOEPOBDHZQEJ-UHFFFAOYSA-N 0.000 claims 1
- 229940124530 sulfonamide Drugs 0.000 claims 1
- 150000003456 sulfonamides Chemical class 0.000 claims 1
- 230000009286 beneficial effect Effects 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 238000004132 cross linking Methods 0.000 description 4
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 4
- LOVAOFAFMFWSKC-UHFFFAOYSA-N 4-[(4-sulfonaphthalen-1-yl)methyl]naphthalene-1-sulfonic acid Chemical compound C12=CC=CC=C2C(S(=O)(=O)O)=CC=C1CC1=CC=C(S(O)(=O)=O)C2=CC=CC=C12 LOVAOFAFMFWSKC-UHFFFAOYSA-N 0.000 description 3
- 238000001238 wet grinding Methods 0.000 description 3
- 239000005864 Sulphur Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 210000004080 milk Anatomy 0.000 description 2
- 235000013336 milk Nutrition 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- ZMESHQOXZMOOQQ-UHFFFAOYSA-N 1-(naphthalen-1-ylmethyl)naphthalene Chemical compound C1=CC=C2C(CC=3C4=CC=CC=C4C=CC=3)=CC=CC2=C1 ZMESHQOXZMOOQQ-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- IOJUPLGTWVMSFF-UHFFFAOYSA-N cyclobenzothiazole Natural products C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009415 formwork Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000012783 reinforcing fiber Substances 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/435—Polyesters
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
- D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
- D04H1/48—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation
- D04H1/485—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres in combination with at least one other method of consolidation in combination with weld-bonding
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/52—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with selenium, tellurium, polonium or their compounds; with sulfur, dithionites or compounds containing sulfur and halogens, with or without oxygen; by sulfohalogenation with chlorosulfonic acid; by sulfohalogenation with a mixture of sulfur dioxide and free halogens
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/693—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural or synthetic rubber, or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
本发明公开了一种高密度仿里皮，采用如下生产工艺制得：步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷；步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷，形成无纺布；步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感。本发明的有益效果为：该高密度仿里皮具有良好的耐磨性能。
Description
技术领域
本发明涉及无纺布，特别涉及一种高密度仿里皮。
背景技术
无纺布是由定向或随机的纤维而构成。无纺布没有经纬线，剪裁和缝纫都非常方便，而且质轻容易定型深受手工爱好者的喜爱。但是，在使用无纺布制作箱包内衬时，人们希望无纺布能够具有里皮般的质感。
公开号为CN102587037A的中国专利公开了一种仿里皮无纺布及其制备方法。该仿里皮无纺布复合粘合剂树脂，增加产品的耐磨度和柔软性。该仿里皮无纺布不仅具有无纺布的特点，又具有里皮般的质感，深受人们喜爱。
鉴于此，本发明人希望能够进一步提升仿里皮类无纺布的耐磨性能，增加其使用时间。
发明内容
本发明的目的是提供一种高密度仿里皮。该高密度仿里皮具有良好的耐磨性能。
本发明的上述技术目的是通过以下技术方案得以实现的：
一种高密度仿里皮，采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
橡胶粘合剂1900-2100份、架桥剂90-110份、消泡剂1-5份、安定剂15-25份、热敏剂1-5份；
所述架桥剂包括如下重量份数的组分：
氧化锌65-75份、橡胶促进剂10-30份、硫磺粉25-35份、分散剂10-30份、水340-360份。
通过采用上述技术方案，用硫磺粉对橡胶粘合剂进行硫化。用橡胶促进剂促进硫磺粉的活化，加快硫磺粉与橡胶粘合剂的交联反应，达到缩短硫化时间和降低硫化温度的效果。而氧化锌不仅能够加快硫化速度，而且能够提高交联度，减少橡胶促进剂用量。分散剂能够促进各组分之间充分混合，从而提高各组分之间的相互作用。利用架桥剂促进橡胶粘合剂的交联，而当无纺布经过上胶池时，胶水混合物与无纺布充分接触并进入无纺布的涤纶纤维之间，从而在橡胶粘合剂进行交联的同时促进涤纶纤维之间的相互结合，从而增强无纺布的耐磨性能。
本发明进一步设置为：所述氧化锌为片状氧化锌。
通过采用上述技术方案，相比于粉末状氧化锌，片状氧化锌在加快硫化速度时，片状氧化锌的面积大，内部连接强度高，从而能够增强纤维之间的连接强度。
本发明进一步设置为：所述橡胶促进剂选用N-环己基-2-苯并噻唑次磺酰胺、N-叔丁基-2-苯并噻唑次磺酰胺、N-氧联二亚乙基-2-苯并噻唑次磺酰胺、N，N′-二环己基-2-苯并噻唑次磺酰胺中的一种。
通过采用上述技术方案，N-环己基-2-苯并噻唑次磺酰胺、N-叔丁基-2-苯并噻唑次磺酰胺、N-氧联二亚乙基-2-苯并噻唑次磺酰胺、N，N′-二环己基-2-苯并噻唑次磺酰胺均属于次磺酰胺类橡胶促进剂。次磺酰胺类促进剂能够在氧化锌作用下进一步提升硫化效果。
本发明进一步设置为：所述分散剂选用亚甲基二萘磺酸钠。
通过采用上述技术方案，亚甲基二萘磺酸钠为阴离子表面活性剂，有良好的扩散力，起泡能力低，能够与其他阴离子和非离子表面活性剂混用。
本发明进一步设置为：所述橡胶粘合剂选用丁腈胶水。
通过采用上述技术方案，丁腈胶水具有良好的耐油性、耐化学药品性、耐热性、粘接性和耐磨性。
本发明进一步设置为：所述丁腈胶水中水的质量分数为40％-60％。
通过采用上述技术方案，水的含量太高，则丁腈的粘接性能较差。水的含量太低，则丁腈胶水的流动性能差，难以进入到无纺布的纤维之间。
本发明进一步设置为：所述消泡剂为矿物油类消泡剂。
通过采用上述技术方案，矿物油类消泡剂价格较为便宜，但是消泡效果不好，适合低剪切的体系中。消泡剂的使用能够减少胶水组合物中气体的引入。
本发明进一步设置为：所述安定剂选用甲醚化氨基树脂。
通过采用上述技术方案，甲醚化氨基树脂能够增加无纺布的稳定性能，降低表面张力，防止光、热分解和氧化分解，提高无纺布的拉伸强度和耐热性、耐油性。
本发明进一步设置为：所述热敏剂选用聚醚缩醛。
通过采用上述技术方案，聚醚缩醛对热较为敏感，在常温下能够保持良好的稳定性。
综上所述，本发明具有以下有益效果：
利用架桥剂促进橡胶粘合剂的交联，而当无纺布经过上胶池时，胶水混合物与无纺布充分接触并进入无纺布的涤纶纤维之间，从而在橡胶粘合剂进行交联的同时促进涤纶纤维之间的相互结合，从而增强无纺布的耐磨性能。
具体实施方式
实施例1
一种高密度仿里皮，采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
丁腈胶水1900份、架桥剂110份、矿物油类消泡剂5份、甲醚化氨基树脂25份、聚醚缩醛3份；其中丁腈胶水中水的质量分数为40％；
所述架桥剂包括如下重量份数的组分：
片状氧化锌70份、N-环己基-2-苯并噻唑次磺酰胺20份、硫磺粉35份、亚甲基二萘磺酸钠30份、水350份。
实施例2
一种高密度仿里皮，采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
丁腈胶水2000份、架桥剂100份、矿物油类消泡剂4份、甲醚化氨基树脂20份、聚醚缩醛4份；其中丁腈胶水中水的质量分数为60％；
所述架桥剂包括如下重量份数的组分：
片状氧化锌72份、N-叔丁基-2-苯并噻唑次磺酰胺25份、硫磺粉32份、亚甲基二萘磺酸钠18份、水360份。
实施例3
一种高密度仿里皮，采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
丁腈胶水2100份、架桥剂95份、矿物油类消泡剂3份、甲醚化氨基树脂15份、聚醚缩醛5份；其中丁腈胶水中水的质量分数为50％；
所述架桥剂包括如下重量份数的组分：
片状氧化锌75份、N-氧联二亚乙基-2-苯并噻唑次磺酰胺15份、硫磺粉30份、亚甲基二萘磺酸钠12份、水340份。
实施例4
一种高密度仿里皮，采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
丁腈胶水1950份、架桥剂90份、矿物油类消泡剂2份、甲醚化氨基树脂18份、聚醚缩醛1份；其中丁腈胶水中水的质量分数为55％；
所述架桥剂包括如下重量份数的组分：
片状氧化锌68份、N，N′-二环己基-2-苯并噻唑次磺酰胺10份、硫磺粉28份、亚甲基二萘磺酸钠15份、水355份。
实施例5
一种高密度仿里皮，采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
丁腈胶水2050份、架桥剂105份、矿物油类消泡剂1份、甲醚化氨基树脂22份、聚醚缩醛2份；其中丁腈胶水中水的质量分数为45％；
所述架桥剂包括如下重量份数的组分：
片状氧化锌65份、N-环己基-2-苯并噻唑次磺酰胺30份、硫磺粉25份、亚甲基二萘磺酸钠10份、水345份。
对比例1
选用公开号为CN102587037A的中国专利的实施例作为对比例1。
耐磨性能试验
Step1：按照5cm*5cm的面积大小分别取实施例1-5和对比例1的制作的仿里皮，平放在湿磨机上固定，取白色平纹里布5cm*5cm面积大小布块，套在被摩擦的圆柱模具上。启动湿磨机，对仿里皮进行摩擦，当发现布料出现颜色变化时，停止湿磨机，记录此时的摩擦次数；
Step2：重复Step1五次，将五次得到的摩擦次数取平均值，即为湿磨情况下的耐磨系数；
表1实施例1-5和对比例的湿磨耐磨性能记录表
从表1可以看出，相比于对比例1，本发明具有良好的耐磨性能。
本具体实施例仅仅是对本发明的解释，其并不是对本发明的限制，本领域技术人员在阅读完本说明书后可以根据需要对本实施例做出没有创造性贡献的修改，但只要在本发明的权利要求范围内都受到专利法的保护。
Claims (9)
1.一种高密度仿里皮，其特征是：采用如下生产工艺制得：
步骤1：涤纶纤维依次经过混棉机混合、开松机松散后进入棉箱、梳理机梳棉、成网机进行成网；
步骤2：依次经过针刺机针刺加固、开边机剪裁多余的棉网、热压三辊机压合，切刀成卷，形成无纺布；
步骤3：置于放布架进行放布，依次经过上胶池上胶、红外定型、洗槽水洗、烘箱加热、切刀成卷；
步骤4：再次置于放布架上进行放布，切分为二，磨平布料切分后形成的表面，达到里皮般手感；
所述上胶池中的胶水组合物包括如下重量份数的组分：
橡胶粘合剂1900-2100份、架桥剂90-110份、消泡剂1-5份、安定剂15-25份、热敏剂1-5份；
所述架桥剂包括如下重量份数的组分：
氧化锌65-75份、橡胶促进剂10-30份、硫磺粉25-35份、分散剂10-30份、水340-360份。
2.根据权利要求1所述的高密度仿里皮，其特征是：所述氧化锌为片状氧化锌。
3.根据权利要求1所述的高密度仿里皮，其特征是：所述橡胶促进剂选用N- 环已基-2-苯并噻唑次磺酰胺、N- 叔丁基-2- 苯并噻唑次磺酰胺、N- 氧联二亚乙基-2- 苯并噻唑次磺酰胺、N,N'- 二环已基-2- 苯并噻唑次磺酰胺中的一种。
4.根据权利要求1所述的高密度仿里皮，其特征是：所述分散剂选用亚甲基二萘磺酸钠。
5.根据权利要求1所述的高密度仿里皮，其特征是：所述橡胶粘合剂选用丁腈胶水。
6.根据权利要求5所述的高密度仿里皮，其特征是：所述丁腈胶水中水的质量分数为40%-60%。
7.根据权利要求1所述的高密度仿里皮，其特征是：所述消泡剂为矿物油类消泡剂。
8.根据权利要求1所述的高密度仿里皮，其特征是：所述安定剂选用甲醚化氨基树脂。
9.根据权利要求1所述的高密度仿里皮，其特征是：所述热敏剂选用聚醚缩醛。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710331823.6A CN106948082B (zh) | 2017-05-11 | 2017-05-11 | 高密度仿里皮 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710331823.6A CN106948082B (zh) | 2017-05-11 | 2017-05-11 | 高密度仿里皮 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106948082A true CN106948082A (zh) | 2017-07-14 |
| CN106948082B CN106948082B (zh) | 2019-02-19 |
Family
ID=59478547
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710331823.6A Expired - Fee Related CN106948082B (zh) | 2017-05-11 | 2017-05-11 | 高密度仿里皮 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106948082B (zh) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108385365A (zh) * | 2018-02-28 | 2018-08-10 | 东莞市颖盛纤维制品有限公司 | 无纺布的制备方法及其应用 |
| CN109811467A (zh) * | 2019-01-23 | 2019-05-28 | 平阳盛兴无纺布有限公司 | 一种仿里皮 |
| CN112962215A (zh) * | 2021-01-18 | 2021-06-15 | 平阳盛兴无纺布有限公司 | 一种可降解的抗静电无纺布 |
| CN115029864A (zh) * | 2022-05-09 | 2022-09-09 | 东莞市颖盛纤维制品有限公司 | 一种耐摩擦无纺布及其制备方法与应用 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003096676A (ja) * | 2001-09-25 | 2003-04-03 | Toray Ind Inc | 皮革様シート状物の製造方法 |
| CN1637187A (zh) * | 2003-12-12 | 2005-07-13 | 可乐丽股份有限公司 | 人造革用基底、人造革以及人造革用基底的制造方法 |
| CN101454503A (zh) * | 2006-05-30 | 2009-06-10 | 可乐丽股份有限公司 | 人造皮革用基材和粒面人造皮革 |
| JP4346346B2 (ja) * | 2003-05-09 | 2009-10-21 | サカイオーベックス株式会社 | 人工皮革の製造方法 |
| CN101591860A (zh) * | 2008-05-30 | 2009-12-02 | 上海华峰超纤材料股份有限公司 | 不定岛超细纤维绒面革的耐刮处理方法 |
| CN102587037A (zh) * | 2012-02-23 | 2012-07-18 | 昆山胜昱无纺布有限公司 | 一种仿里皮无纺布及其制备方法 |
| CN202466126U (zh) * | 2012-02-23 | 2012-10-03 | 昆山胜昱无纺布有限公司 | 一种仿里皮无纺布 |
| CN106048893A (zh) * | 2016-07-15 | 2016-10-26 | 恩平市奕马企业有限公司 | 一种防虹吸不织布及其制造方法 |
-
2017
- 2017-05-11 CN CN201710331823.6A patent/CN106948082B/zh not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003096676A (ja) * | 2001-09-25 | 2003-04-03 | Toray Ind Inc | 皮革様シート状物の製造方法 |
| JP4346346B2 (ja) * | 2003-05-09 | 2009-10-21 | サカイオーベックス株式会社 | 人工皮革の製造方法 |
| CN1637187A (zh) * | 2003-12-12 | 2005-07-13 | 可乐丽股份有限公司 | 人造革用基底、人造革以及人造革用基底的制造方法 |
| CN101454503A (zh) * | 2006-05-30 | 2009-06-10 | 可乐丽股份有限公司 | 人造皮革用基材和粒面人造皮革 |
| CN101591860A (zh) * | 2008-05-30 | 2009-12-02 | 上海华峰超纤材料股份有限公司 | 不定岛超细纤维绒面革的耐刮处理方法 |
| CN102587037A (zh) * | 2012-02-23 | 2012-07-18 | 昆山胜昱无纺布有限公司 | 一种仿里皮无纺布及其制备方法 |
| CN202466126U (zh) * | 2012-02-23 | 2012-10-03 | 昆山胜昱无纺布有限公司 | 一种仿里皮无纺布 |
| CN106048893A (zh) * | 2016-07-15 | 2016-10-26 | 恩平市奕马企业有限公司 | 一种防虹吸不织布及其制造方法 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108385365A (zh) * | 2018-02-28 | 2018-08-10 | 东莞市颖盛纤维制品有限公司 | 无纺布的制备方法及其应用 |
| CN109811467A (zh) * | 2019-01-23 | 2019-05-28 | 平阳盛兴无纺布有限公司 | 一种仿里皮 |
| CN112962215A (zh) * | 2021-01-18 | 2021-06-15 | 平阳盛兴无纺布有限公司 | 一种可降解的抗静电无纺布 |
| CN112962215B (zh) * | 2021-01-18 | 2022-06-17 | 平阳盛兴无纺布有限公司 | 一种可降解的抗静电无纺布 |
| CN115029864A (zh) * | 2022-05-09 | 2022-09-09 | 东莞市颖盛纤维制品有限公司 | 一种耐摩擦无纺布及其制备方法与应用 |
| CN115029864B (zh) * | 2022-05-09 | 2024-03-19 | 东莞市颖盛纤维制品有限公司 | 一种耐摩擦无纺布及其制备方法与应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106948082B (zh) | 2019-02-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106948082A (zh) | 高密度仿里皮 | |
| CN102517923B (zh) | 超软高回弹湿式超细旦聚酰胺皮革的制造方法 | |
| CN107043477A (zh) | 石墨烯‑丁腈胶乳复合浆料及其制备方法、用途 | |
| KR101755837B1 (ko) | 통풍 시트용 인조가죽 원단 및 이의 제조방법 | |
| WO2014012979A2 (fr) | Composition de latex | |
| CN111850825A (zh) | 功能性针刺复合无纺布及其制作工艺 | |
| CN104179032B (zh) | 一种环保型的蛋白质耳机革的制备方法 | |
| CN106012571A (zh) | 一种tpu发泡革复合面料及其制备方法 | |
| CN108264754A (zh) | 一种具有密度梯度的热塑性聚氨酯弹性体发泡材料及其制备方法 | |
| CN106246774A (zh) | 一种碳纤维树脂基摩擦材料及其制备方法 | |
| CN108978246B (zh) | 一种模拟天然头层皮的超纤革的制备方法及应用 | |
| CN103450519A (zh) | 止滑橡胶及其制造方法 | |
| JP2011506643A (ja) | 空気透過性構造を持つシリコーンフォームの製造方法 | |
| CN102330166A (zh) | 一种调温纤维及其制备方法 | |
| CN103572612B (zh) | 可透湿的防火布料及其制造方法 | |
| CN110128812A (zh) | 一种粉扑用可温变海绵及其制作工艺 | |
| CN104562719B (zh) | 一种应用于合成革的基布面料的制备方法和一种合成革的制备方法 | |
| CN107189122B (zh) | 一种碳纤维基抗穿刺橡胶复合材料及其制备方法 | |
| KR20140084443A (ko) | 자동차용 플로어 카페트 | |
| CN109177394A (zh) | 一种皮革毛毡复合成型工艺 | |
| CN105774087B (zh) | 一种环保亲肤耐用型的耳机革的制备方法 | |
| CN108505348A (zh) | 一种背胶防水喷绘油画布及其生产方法 | |
| CN103726322B (zh) | 烟气过滤材料后整理用发泡涂层胶、制备方法及使用方法 | |
| CN103046348A (zh) | 耐高温水洗及抗菌的织物的制造方法及其结构 | |
| CN106120367A (zh) | 一种运动休闲鞋用无溶剂聚氨酯合成革的制造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20190219 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |