CN106947329A - A kind of large arch dam inorganic compounding exterior coating and preparation method thereof - Google Patents
A kind of large arch dam inorganic compounding exterior coating and preparation method thereof Download PDFInfo
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- CN106947329A CN106947329A CN201710109314.9A CN201710109314A CN106947329A CN 106947329 A CN106947329 A CN 106947329A CN 201710109314 A CN201710109314 A CN 201710109314A CN 106947329 A CN106947329 A CN 106947329A
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- Prior art keywords
- powder
- agent
- calcite
- arch dam
- large arch
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Abstract
The invention discloses a kind of large arch dam inorganic compounding exterior coating, mainly it is made up of following mass percent component:Water 10~15%, styrene-acrylic emulsion 13~18%, defoamer 0.3~0.5%, dispersant 0.4~0.6%, wetting agent 0.1~0.3%, pH adjusting agent 0.1~0.2%, hydroxyethyl ether cellulose 0.1~0.4%, rutile type titanium white 5~10%, talcum powder 4~6%, calcite in powder 35~50%, Ludox 10~15%, coalescents 1~1.5%, alkali swollen thickener 0.4~0.6%, preservative 0.1~0.2%, said components gross weight are 100%.The exterior coating excellent performance of the present invention, preparation method is simple, reduces working procedure, saves cost.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of large arch dam inorganic compounding exterior coating and preparation method thereof.
Background technology
With the raising and the progress of society of living standards of the people, selection of the people to building decoration coating is increasingly weighed
Depending on, especially exterior coating, not only the protection to ground and ornamental requirement are high, and require letter to the working procedure of coating
Just, efficiently.
At present common exterior coating as architectural decoration coating material in use, need to add water out during its construction dilute, and construction week
Phase is long, twice putty of typically constructing, one of priming paint and two coat finish, could External Wall play certain protection and decoration
Effect, causes working procedure cumbersome, more manpower and time cost is consumed, while the construction method has certain limitation
Property, is mainly manifested in many exterior coatings having constructed 2 years or so and starts hollowing, peeling and the phenomenon of peeling occur, and occur
The reason for this phenomenon is greatly that putty is caused.Because exterior wall putty is relatively loose, easy absorbing water powder is melted,
It is easier such case occur when leakage brush or second-rate putty occurs in exterior coating.There is provided one kind is new as can be seen here
Exterior coating is significant.
The content of the invention
In view of the defect that above-mentioned prior art is present, the purpose of the present invention is to propose to a kind of painting of large arch dam inorganic compounding exterior wall
Material.The exterior coating excellent performance, reduces working procedure, saves cost.Another object of the present invention also proposed a kind of Gao Gu
The preparation method of the exterior coating containing inorganic compounding.
The purpose of the present invention will be achieved by the following technical programs:
A kind of large arch dam inorganic compounding exterior coating, is mainly made up of following mass percent component:Water 10~15%, benzene
Acrylic emulsion 13~18%, defoamer 0.3~0.5%, dispersant 0.4~0.6%, wetting agent 0.1~0.3%, pH adjusting agent 0.1
~0.2%, hydroxyethyl ether cellulose 0.1~0.4%, rutile type titanium white 5~10%, talcum powder 4~6%, calcite in powder
35~50%, Ludox 10~15%, coalescents 1~1.5%, alkali swollen thickener 0.4~0.6%, preservative 0.1~
0.2%, said components gross weight is 100%.
A kind of above-mentioned large arch dam inorganic compounding exterior coating, is mainly made up of following mass percent component:Water 11~
14%th, styrene-acrylic emulsion 14~18%, defoamer 0.3~0.5%, dispersant 0.4~0.6%, wetting agent 0.1~0.3%, pH are adjusted
Save agent 0.1~0.2%, hydroxyethyl ether cellulose 0.1~0.3%, rutile type titanium white 5~10%, talcum powder 4~6%, side
Solve stone flour 38~50%, Ludox 10~13%, coalescents 1~1.3%, alkali swollen thickener 0.4~0.6%, preservative
0.1~0.2%, said components gross weight is 100%.
A kind of above-mentioned large arch dam inorganic compounding exterior coating, is mainly made up of following mass percent component:Water 11~
14%th, styrene-acrylic emulsion 14~18%, defoamer 0.4%, dispersant 0.5%, wetting agent 0.2%, pH adjusting agent 0.15~
0.2%th, hydroxyethyl ether cellulose 0.2%, rutile type titanium white 5~10%, talcum powder 5~6%, calcite in powder 40~
47%th, Ludox 10~12%, coalescents 1~1.2%, alkali swollen thickener 0.4~0.5%, preservative 0.2%, above-mentioned
Component weight is 100%.
A kind of above-mentioned large arch dam inorganic compounding exterior coating, the calcite in powder include 800 mesh calcite in powder and 320~
400 mesh calcite in powder, the 800 mesh calcite in powder is 1: 2~3 with the amount ratio of 320~400 mesh calcite in powder.
A kind of preparation method of large arch dam inorganic compounding exterior coating, comprises the following steps:Water and styrene-acrylic emulsion are put into
Dispersion cylinder, sequentially adds defoamer, dispersant, wetting agent, pH adjusting agent, hydroxyethyl ether cellulose while stirring;600r/min
Scattered 5 minutes to uniformly without particle, 800r/min sequentially adds rutile type titanium white, talcum powder, calcite in powder, 1200r/
Min is scattered 30 minutes;Then Ludox, coalescents, alkali swollen thickener and preservative are put into successively under 400r/min, is stirred
Mix 15 minutes, adjust viscosity, shut down discharging, produce.
A kind of preparation method of above-mentioned large arch dam inorganic compounding exterior coating, wherein, the styrene-acrylic emulsion is RS-892
Styrene-acrylic emulsion;The defoamer is mineral oil antifoam agent;The dispersant is sodium salt or ammonium salt class dispersant;The wetting agent is
CF-10 wetting agents;The pH adjusting agent is AMP-95;The coalescents are Texanol coalescents;Thickening that the alkali soluble is swollen
Agent is ASE-60 alkali swollen thickeners;Described preservative is Kathon CG.
The present invention is combined using inorganic Ludox with organic styrene-acrylic emulsion, and silica sol granule is trickle, silica during analysis glue
With higher activity, new silicate inorganic high-molecular compound can be generated with some inorganic salts, metal oxide, be formed very
Hard film;The tiny penetration to base material of particle is strong, and tiny particle can penetrate into the inside of base material by capillarity, and
Can be with the alkaline matter Ca (OH) in base material2Reaction generation calcium silicates CaSiO3, make film that there is stronger adhesive force, adhesive force
Enhancing be the infiltration of Ludox, the resultant effect that coheres of hardening, be mechanical snap and the synthesis result of chemical bonding, thus tool
There is the cohesion of the surface attachment better than general coating;Ludox is miscible with organic high molecular polymer, makes organic polymer equal
In the gap for being distributed in silicon-oxygen-silicon inorganic coating evenly, remaining hydrophilic radical in shielded inorganic coating, film is subjected to cold and hot
The contraction of coating is buffered when alternately, and makes coating that there is certain elasticity, the coating formed is with inorganic coating
With the characteristic of organic coating, both are made up not enough;Silica bodily form network structure is formed after Ludox film forming, soda acid is not afraid of, improved
Film performance;The exterior coating viscosity prepared plus the present invention is higher, and viscosity reaches 100000mPas;Gu it is reachable containing higher
To 70%, and general exterior coating is contained in 50% or so admittedly, thus the present invention exterior coating without advance plaster putty, can
Directly batch scrape on the cement mortar of exterior wall, survive for twice, you can to have filling leveling function as exterior wall putty, together
When decoration and defencive function with common exterior coating.
Compared with prior art, a kind of large arch dam inorganic compounding exterior coating that the present invention is provided and preparation method thereof, reaches
To have the technical effect that:(1) exterior coating prepared by the present invention has excellent adhesive force, and alkali resistance is good, has excellent weather resistance, into
This is low, and preparation technology is simple;(2) coating is than common traditional road working procedures of exterior coating Shao Liao tri-, saved it is artificial into
Sheet and material cost.
Below just in conjunction with the embodiments, the embodiment to the present invention is described in further detail, so that technical scheme is more
It should be readily appreciated that, grasp.
Embodiment
Below by specific embodiment, the present invention will be described, but the invention is not limited in this.In following embodiments
The experimental method, unless otherwise specified, is conventional method;The reagent and material, unless otherwise specified, can be from business
Approach is obtained, example below and the scope of the claims for being not used to the limitation present invention, all equivalence enforcements without departing from carried out by the present invention
Or change, it is intended to be limited solely by this patent protection domain.
Material:Styrene-acrylic emulsion:RS-892 styrene-acrylic emulsions;Defoamer:Mineral oil antifoam agent;Dispersant:Sodium salt or ammonium salt class
Dispersant;Wetting agent:CF-10 wetting agents;PH adjusting agent:AMP-95;Coalescents:Texanol coalescents;Thickening that alkali soluble is swollen
Agent:ASE-60 alkali swollen thickeners;Preservative:Kathon CG.
Embodiment 1
A kind of large arch dam inorganic compounding exterior coating, is mainly made up of following mass percent component:Water 12.85%;Benzene
Acrylic emulsion 14%;Defoamer 0.4%;Dispersant 0.5%;Wetting agent 0.2%;PH adjusting agent 0.15%;Hydroxyethyl ether cellulose
0.2%;Rutile type titanium white 5%;Talcum powder 6%;800 mesh calcite in powder 15%;320~400 mesh calcite in powder 32%;Silicon
Colloidal sol 12%;Coalescents 1%;Alkali swollen thickener 0.5%;Preservative 0.2%.
The preparation method of large arch dam inorganic compounding exterior coating:
By 14 parts of input dispersion cylinders of 12.85 parts of water and styrene-acrylic emulsion, 0.4 part of defoamer is sequentially added while stirring, is disperseed
0.5 part of agent, 0.2 part of wetting agent, 0.15 part of pH adjusting agent, 0.2 part of hydroxyethyl ether cellulose.600r/min middling speeds are scattered 5 minutes
To uniformly without particle;5 parts of rutile type titanium white, 6 parts of talcum powder, 800 mesh calcite in powder 15 are sequentially added under 800r/min
32 parts of part and 320~400 mesh calcite in powder, 1200r/min are scattered 30 minutes at a high speed;Then silicon is put into successively under 400r/min
0.2 part of 12 parts of colloidal sol, 1 part of coalescents, 0.5 part of alkali swollen thickener and preservative are stirred 15 minutes, and adjustment viscosity is arrived
100000mPas, shuts down discharging, produces.
Embodiment 2
A kind of large arch dam inorganic compounding exterior coating, is made up of following mass percent component:Water 11.85%;Phenylpropyl alcohol breast
Liquid 16%;Defoamer 0.4%;Dispersant 0.5%;Wetting agent 0.2%;PH adjusting agent 0.15%;Hydroxyethyl ether cellulose
0.2%;Rutile type titanium white 7%;Talcum powder 6%;800 mesh calcite in powder 13%;320~400 mesh calcite in powder 31%;Silicon
Colloidal sol 12%;Coalescents 1.1%;Alkali swollen thickener 0.4%;Preservative 0.2%.
The preparation method of large arch dam inorganic compounding exterior coating:
By 16 parts of input dispersion cylinders of 11.85 parts of water and styrene-acrylic emulsion, 0.4 part of defoamer is sequentially added while stirring, is disperseed
0.5 part of agent, 0.2 part of wetting agent, 0.15 part of pH adjusting agent, 0.2 part of hydroxyethyl ether cellulose.600r/min middling speeds are scattered 5 minutes
To uniformly without particle;7 parts of rutile type titanium white, 6 parts of talcum powder, 800 mesh calcite in powder 13 are added next time in 800r/min
31 parts of part and 320~400 mesh calcite in powder, 1200r/min are scattered 30 minutes at a high speed;Then silicon is put into successively under 400r/min
0.2 part of 12 parts of colloidal sol, 1.1 parts of coalescents, 0.4 part of alkali swollen thickener and preservative, are stirred 15 minutes, and adjustment viscosity is arrived
100000mPas, shuts down discharging, produces.
Embodiment 3
Large arch dam inorganic compounding exterior coating, is made up of following mass percent component:Water 13.7%;Styrene-acrylic emulsion
18%;Defoamer 0.4%;Dispersant 0.5%;Wetting agent 0.2%;PH adjusting agent 0.2%;Hydroxyethyl ether cellulose 0.2%;Gold
Red stone-type titanium dioxide 10%;Talcum powder 5%;800 mesh calcite in powder 10%;The Ludox of 320~400 mesh calcite in powder 30%
10%;Coalescents 1.2%;Alkali swollen thickener 0.4%;Preservative 0.2%.
The preparation method of large arch dam inorganic compounding exterior coating:
By 18 parts of input dispersion cylinders of 13.7 parts of water and styrene-acrylic emulsion, 0.4 part of defoamer, dispersant are sequentially added while stirring
0.5 part, 0.2 part of wetting agent, 0.2 part of pH adjusting agent, 0.2 part of hydroxyethyl ether cellulose.Scattered 5 minutes of 600r/min middling speeds are to equal
It is even without particle.Add 10 parts of rutile type titanium white next time in 800r/min, 5 parts of talcum powder, 800 10 parts of mesh calcite in powder and
320~400 30 parts of mesh calcite in powder, 1200r/min is scattered 30 minutes at a high speed;Then Ludox is put into successively under 400r/min
10 parts, 1.2 parts of coalescents, 0.2 part of 0.4 part of alkali swollen thickener and preservative are stirred 15 minutes, adjustment viscosity is arrived
100000mPas, shuts down discharging, produces.
Test example
The construction method of large arch dam inorganic compounding exterior coating prepared by embodiment 1-3:Large arch dam prepared by the present invention without
Machine composite exterior wall coating is directly used in exterior wall plaster twice, is polished during plaster second time.
The construction method of traditional coating:First twice of putty of plaster is filled levelling, is constructed again after putty is parched completely
A time primary coat and twice of face are applied.
Comparative example:Traditional coating (ippon room obtains precious weather-proof exterior wall latex paint),
Production batch:5/20160811/5D76;Wherein, traditional coating can also by market other conventional common coating generations
Replace;
The large arch dam inorganic compounding exterior coating that respectively prepared by embodiment 1-3, comparative example should according to above-mentioned construction method
For exterior wall, by detecting the result such as table 1 that index of correlation is drawn;
As shown in Table 1, large arch dam inorganic compounding exterior coating of the invention can directly be criticized and scraped without advance plaster putty
Above the cement mortar of exterior wall, survive for twice, easy construction, and be less prone to the phenomenons such as hollowing, peeling and peeling.
Some preferred embodiments of the present invention have shown and described in described above, but as previously described, it should be understood that the present invention
Be not limited to form disclosed herein, be not to be taken as the exclusion to other embodiment, and available for various other combinations,
Modification and environment, and above-mentioned teaching or the technology or knowledge of association area can be passed through in invention contemplated scope described herein
It is modified., then all should be in this hair and the change and change that those skilled in the art are carried out do not depart from the spirit and scope of the present invention
In the protection domain of bright appended claims.
Claims (6)
1. a kind of large arch dam inorganic compounding exterior coating, it is characterised in that be mainly made up of following mass percent component:Water 10
~15%, styrene-acrylic emulsion 13~18%, defoamer 0.3~0.5%, dispersant 0.4~0.6%, wetting agent 0.1~0.3%, pH
Conditioning agent 0.1~0.2%, hydroxyethyl ether cellulose 0.1~0.4%, rutile type titanium white 5~10%, talcum powder 4~6%,
Calcite in powder 35~50%, Ludox 10~15%, coalescents 1~1.5%, alkali swollen thickener 0.4~0.6%, anti-corrosion
Agent 0.1~0.2%, said components gross weight is 100%.
2. according to a kind of large arch dam inorganic compounding exterior coatings of claim 1 Suo Shu Qie, it is characterised in that mainly by following quality
Percent composition is constituted:Water 11~14%, styrene-acrylic emulsion 14~18%, defoamer 0.3~0.5%, dispersant 0.4~0.6%,
Wetting agent 0.1~0.3%, pH adjusting agent 0.1~0.2%, hydroxyethyl ether cellulose 0.1~0.3%, rutile type titanium white 5
~10%, talcum powder 4~6%, calcite in powder 38~50%, Ludox 10~13%, coalescents 1~1.3%, alkali soluble is swollen increase
Thick dose 0.4~0.6%, preservative 0.1~0.2%, said components gross weight are 100%.
3. according to a kind of large arch dam inorganic compounding exterior coatings of claim 1 Suo Shu Qie, it is characterised in that mainly by following quality
Percent composition is constituted:Water 11~14%, styrene-acrylic emulsion 14~18%, defoamer 0.4%, dispersant 0.5%, wetting agent
0.2%th, pH adjusting agent 0.15~0.2%, hydroxyethyl ether cellulose 0.2%, rutile type titanium white 5~10%, talcum powder 5~
6%th, calcite in powder 40~47%, Ludox 10~12%, coalescents 1~1.2%, alkali swollen thickener 0.4~0.5%,
Preservative 0.2%, said components gross weight is 100%.
4. according to a kind of large arch dam inorganic compounding exterior coatings of any one of claim 1-3 Suo Shu Qie, it is characterised in that the side
Solving stone flour includes 800 mesh calcite in powder and 320~400 mesh calcite in powder, the 800 mesh calcite in powder and 320~400 mesh
Calcite Fen Qie amount ratios are 1:2~3.
5. one kind is according to any one of claim 1-4 Suo Shu Qie large arch dam inorganic compounding Wai wall Tu Liao Qie preparation methods, its feature
It is to comprise the following steps:By water and styrene-acrylic emulsion input dispersion cylinder, defoamer, dispersant, moistening are sequentially added while stirring
Agent, pH adjusting agent, hydroxyethyl ether cellulose;600r/min disperses 5 minutes to uniformly without particle, 800r/min sequentially adds golden red
Stone-type titanium dioxide, talcum powder, calcite in powder, 1200r/min is scattered 30 minutes;Then silicon is put into successively under 400r/min molten
Glue, coalescents, alkali swollen thickener and preservative, are stirred 15 minutes, adjust viscosity, are shut down discharging, are produced.
6. according to a kind of large arch dam inorganic compounding Wai walls Tu Liao Qie preparation methods of claim 5 Suo Shu Qie, it is characterised in that described
Styrene-acrylic emulsion is RS-892 styrene-acrylic emulsions;The defoamer is mineral oil antifoam agent;The dispersant is sodium salt or ammonium salt class point
Powder;The wetting agent is CF-10 wetting agents;The pH adjusting agent is AMP-95;The coalescents help for Texanol film forming
Agent;The alkali swollen thickener is ASE-60 alkali swollen thickeners;Suo Shu Qie preservatives are Kathon CG.
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CN111454628A (en) * | 2020-04-30 | 2020-07-28 | 安徽雅圆建材科技有限公司 | Composite base coat with sealing, leveling and intermediate coloring functions |
CN111875998A (en) * | 2020-08-31 | 2020-11-03 | 三棵树涂料股份有限公司 | Water-based magnetic inorganic interior wall coating |
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Address after: 511401 Room 820, No. 96 Wanhui Road, Nancun Town, Panyu District, Guangzhou City, Guangdong Province Applicant after: Guangdong Fanzhu Waterborne Coatings Co., Ltd. Address before: 511401 Room 820, No. 96 Wanhui Road, Nancun Town, Panyu District, Guangzhou City, Guangdong Province Applicant before: Guangzhou Pu bamboo water coating Co., Ltd. |
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RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170714 |