CN106783217B - 高效率制备氮掺杂石墨烯碳纳米管薄膜的方法 - Google Patents
高效率制备氮掺杂石墨烯碳纳米管薄膜的方法 Download PDFInfo
- Publication number
- CN106783217B CN106783217B CN201611097195.1A CN201611097195A CN106783217B CN 106783217 B CN106783217 B CN 106783217B CN 201611097195 A CN201611097195 A CN 201611097195A CN 106783217 B CN106783217 B CN 106783217B
- Authority
- CN
- China
- Prior art keywords
- graphene carbon
- nitrogen
- ethanol solution
- carbon nanotube
- tube film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 67
- 239000002238 carbon nanotube film Substances 0.000 title claims abstract description 32
- 238000000034 method Methods 0.000 title claims abstract description 18
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 82
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 54
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 27
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 12
- 239000002243 precursor Substances 0.000 claims abstract description 10
- 229930192474 thiophene Natural products 0.000 claims abstract description 8
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000243 solution Substances 0.000 claims description 33
- 235000019441 ethanol Nutrition 0.000 claims description 27
- 239000002041 carbon nanotube Substances 0.000 claims description 13
- 229910021393 carbon nanotube Inorganic materials 0.000 claims description 13
- 150000003233 pyrroles Chemical class 0.000 claims description 12
- 238000002347 injection Methods 0.000 claims description 8
- 239000007924 injection Substances 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 3
- 208000006735 Periostitis Diseases 0.000 claims 1
- 210000003460 periosteum Anatomy 0.000 claims 1
- 238000007667 floating Methods 0.000 abstract description 6
- 238000005336 cracking Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 5
- 230000008569 process Effects 0.000 abstract description 4
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000001132 ultrasonic dispersion Methods 0.000 abstract 1
- 239000003990 capacitor Substances 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 239000006193 liquid solution Substances 0.000 description 3
- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- -1 graphene carbon nanotube compound Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000002071 nanotube Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 238000005411 Van der Waals force Methods 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 210000000038 chest Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000006250 one-dimensional material Substances 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010408 sweeping Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
- H01G11/36—Nanostructures, e.g. nanofibres, nanotubes or fullerenes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/13—Energy storage using capacitors
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Power Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611097195.1A CN106783217B (zh) | 2017-01-16 | 2017-01-16 | 高效率制备氮掺杂石墨烯碳纳米管薄膜的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201611097195.1A CN106783217B (zh) | 2017-01-16 | 2017-01-16 | 高效率制备氮掺杂石墨烯碳纳米管薄膜的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106783217A CN106783217A (zh) | 2017-05-31 |
CN106783217B true CN106783217B (zh) | 2018-07-13 |
Family
ID=58883268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201611097195.1A Active CN106783217B (zh) | 2017-01-16 | 2017-01-16 | 高效率制备氮掺杂石墨烯碳纳米管薄膜的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN106783217B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107555553A (zh) * | 2017-08-04 | 2018-01-09 | 天津大学 | 一种用于电容去离子的氮掺杂碳纳米管薄膜的制备方法 |
KR102177472B1 (ko) * | 2017-09-29 | 2020-11-11 | 주식회사 테스 | 그래핀 옥사이드 증착용 소스 및 이를 이용한 그래핀 옥사이드 박막 형성 방법 |
CN110858535A (zh) * | 2018-08-23 | 2020-03-03 | 天津大学 | 硼氮共掺的碳纳米管薄膜及其制备方法和应用 |
CN109704310A (zh) * | 2019-03-04 | 2019-05-03 | 无锡远稳烯科技有限公司 | 一种石墨烯碳纳米管薄膜的制作工艺 |
CN110316720B (zh) * | 2019-06-27 | 2021-03-30 | 沈健民 | 硫、氮双掺杂碳纳米管薄膜及其制备方法 |
CN111747767B (zh) * | 2020-07-20 | 2021-12-03 | 天津大学 | 石墨烯增强的树脂基全碳复合材料及其制备方法 |
CN115079338A (zh) * | 2022-07-08 | 2022-09-20 | 湖北工业大学 | 氮掺杂碳纳米管的微纳光纤、及包含其的气体传感器 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103151101A (zh) * | 2013-04-02 | 2013-06-12 | 重庆绿色智能技术研究院 | 掺杂石墨烯柔性透明电极及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103153843B (zh) * | 2010-12-30 | 2014-04-02 | 海洋王照明科技股份有限公司 | 石墨烯衍生物-碳纳米管复合材料及其制备方法 |
CN103407982B (zh) * | 2013-07-16 | 2016-02-10 | 清华大学 | 一种氮掺杂的碳纳米管阵列和石墨烯的杂化物及其制备方法 |
-
2017
- 2017-01-16 CN CN201611097195.1A patent/CN106783217B/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103151101A (zh) * | 2013-04-02 | 2013-06-12 | 重庆绿色智能技术研究院 | 掺杂石墨烯柔性透明电极及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN106783217A (zh) | 2017-05-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106783217B (zh) | 高效率制备氮掺杂石墨烯碳纳米管薄膜的方法 | |
Shi et al. | Flexible 3D carbon cloth as a high-performing electrode for energy storage and conversion | |
He et al. | Quantum dots of molybdenum nitride embedded in continuously distributed polyaniline as novel electrode material for supercapacitor | |
Zhang et al. | 3D porous silicon/N-doped carbon composite derived from bamboo charcoal as high-performance anode material for lithium-ion batteries | |
Wang et al. | Boric acid assisted reduction of graphene oxide: a promising material for sodium-ion batteries | |
CN103303912B (zh) | 一种高比表面积多孔氮掺杂石墨化纳米碳材料的制备方法 | |
Shah et al. | Heteroatom-doped carbonaceous electrode materials for high performance energy storage devices | |
CN106925330B (zh) | 一种石墨相碳化氮纳米片/ZiF-67片层结构复合材料 | |
Jin et al. | Three-dimensional interconnected porous graphitic carbon derived from rice straw for high performance supercapacitors | |
Yang et al. | Synthesis of cobalt phosphides and their application as anodes for lithium ion batteries | |
Shrestha et al. | Nanoarchitectonics of nanoporous carbon materials in supercapacitors applications | |
CN106587017A (zh) | 一种多孔石墨烯及其制备方法 | |
CN108654659B (zh) | 一种磷化钼/石墨烯复合纳米材料及其制备方法 | |
CN102992308A (zh) | 一种具有高比电容的石墨烯及其制备方法 | |
Zhang et al. | Ultrahigh capacitance of TiO2 nanotube arrays/C/MnO2 electrode for supercapacitor | |
CN104140097A (zh) | 一种磷掺杂石墨烯及其制备方法 | |
Ji et al. | 3D ordered macroporous Pt/ZnS@ ZnO core-shell heterostructure for highly effective photocatalytic hydrogen evolution | |
CN102779649A (zh) | 一种薄层石墨烯聚合物复合材料的制备方法 | |
CN104108709A (zh) | 一种多孔石墨烯及其制备方法 | |
CN103578796A (zh) | 一种不含粘合剂超级电容器电极的制备方法 | |
CN102496481A (zh) | 一种石墨烯/聚吡咯纳米管复合材料以及一种以其为电极的超级电容器及其制备方法 | |
Li et al. | Controllable preparation of nitrogen-doped graphitized carbon from molecular precursor as non-metal oxygen evolution reaction electrocatalyst | |
CN105702473A (zh) | 具有超高比电容的碳基电极材料及其复合电极材料 | |
CN107055510A (zh) | 一种金属有机配合物纳米管及其衍生多孔碳纳米管的制备方法 | |
Deng et al. | Research advance of NiCoP-based materials for high-performance supercapacitors |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP02 | Change in the address of a patent holder | ||
CP02 | Change in the address of a patent holder |
Address after: 300350 Haijing garden, Haihe Education Park, Jinnan, Tianjin, 135, Tianjin University. Patentee after: Tianjin University Address before: 300072 Tianjin City, Nankai District Wei Jin Road No. 92 Patentee before: Tianjin University |
|
CP02 | Change in the address of a patent holder | ||
CP02 | Change in the address of a patent holder |
Address after: 300452 Binhai Industrial Research Institute Campus of Tianjin University, No. 48 Jialingjiang Road, Binhai New Area, Tianjin Patentee after: Tianjin University Address before: 300350 Haijing garden, Haihe Education Park, Jinnan, Tianjin, 135, Tianjin University. Patentee before: Tianjin University |