CN106701353A - Plant detergent powder for cleaning greasy dirt - Google Patents
Plant detergent powder for cleaning greasy dirt Download PDFInfo
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- CN106701353A CN106701353A CN201610955428.0A CN201610955428A CN106701353A CN 106701353 A CN106701353 A CN 106701353A CN 201610955428 A CN201610955428 A CN 201610955428A CN 106701353 A CN106701353 A CN 106701353A
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- shrub althea
- ethanol
- althea flower
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- 239000000843 powder Substances 0.000 title claims abstract description 56
- 239000003599 detergent Substances 0.000 title abstract description 6
- 238000004140 cleaning Methods 0.000 title abstract 2
- 240000004507 Abelmoschus esculentus Species 0.000 claims abstract description 47
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000000284 extract Substances 0.000 claims abstract description 36
- 241000196324 Embryophyta Species 0.000 claims abstract description 31
- 239000000341 volatile oil Substances 0.000 claims abstract description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 143
- 244000130592 Hibiscus syriacus Species 0.000 claims description 97
- 235000018081 Hibiscus syriacus Nutrition 0.000 claims description 97
- 239000000047 product Substances 0.000 claims description 74
- 229920005989 resin Polymers 0.000 claims description 61
- 239000011347 resin Substances 0.000 claims description 61
- 238000000605 extraction Methods 0.000 claims description 50
- 102000004190 Enzymes Human genes 0.000 claims description 47
- 108090000790 Enzymes Proteins 0.000 claims description 47
- 239000004365 Protease Substances 0.000 claims description 47
- 229940088598 enzyme Drugs 0.000 claims description 47
- 235000003934 Abelmoschus esculentus Nutrition 0.000 claims description 46
- 239000006286 aqueous extract Substances 0.000 claims description 37
- 238000005406 washing Methods 0.000 claims description 33
- 238000002360 preparation method Methods 0.000 claims description 31
- 239000000287 crude extract Substances 0.000 claims description 30
- 239000012153 distilled water Substances 0.000 claims description 30
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 28
- 108091005804 Peptidases Proteins 0.000 claims description 27
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 27
- 235000019419 proteases Nutrition 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 25
- 238000005238 degreasing Methods 0.000 claims description 23
- 108010059892 Cellulase Proteins 0.000 claims description 20
- 108090000526 Papain Proteins 0.000 claims description 20
- 229940106157 cellulase Drugs 0.000 claims description 20
- 239000000706 filtrate Substances 0.000 claims description 20
- 229940055729 papain Drugs 0.000 claims description 20
- 235000019834 papain Nutrition 0.000 claims description 20
- 239000000203 mixture Substances 0.000 claims description 19
- 240000004160 Capsicum annuum Species 0.000 claims description 16
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims description 16
- 235000007862 Capsicum baccatum Nutrition 0.000 claims description 16
- 239000001728 capsicum frutescens Substances 0.000 claims description 16
- 235000013399 edible fruits Nutrition 0.000 claims description 16
- 239000004094 surface-active agent Substances 0.000 claims description 16
- 235000010443 alginic acid Nutrition 0.000 claims description 15
- 229920000615 alginic acid Polymers 0.000 claims description 15
- 150000002148 esters Chemical class 0.000 claims description 15
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 14
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 14
- 229920002678 cellulose Polymers 0.000 claims description 12
- 239000001913 cellulose Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 11
- 239000000796 flavoring agent Substances 0.000 claims description 11
- 235000019634 flavors Nutrition 0.000 claims description 11
- 238000005119 centrifugation Methods 0.000 claims description 10
- 230000007071 enzymatic hydrolysis Effects 0.000 claims description 10
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 claims description 10
- 230000007062 hydrolysis Effects 0.000 claims description 10
- 238000006460 hydrolysis reaction Methods 0.000 claims description 10
- 239000012535 impurity Substances 0.000 claims description 10
- 238000001471 micro-filtration Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 238000002390 rotary evaporation Methods 0.000 claims description 10
- 238000007873 sieving Methods 0.000 claims description 10
- 238000001179 sorption measurement Methods 0.000 claims description 10
- 238000000967 suction filtration Methods 0.000 claims description 10
- 239000006228 supernatant Substances 0.000 claims description 10
- 239000003795 chemical substances by application Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 6
- 230000001954 sterilising effect Effects 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 3
- 230000003213 activating effect Effects 0.000 claims 1
- 239000000835 fiber Substances 0.000 claims 1
- 238000004659 sterilization and disinfection Methods 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 5
- 230000000975 bioactive effect Effects 0.000 abstract description 4
- 239000004615 ingredient Substances 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract description 3
- 231100000419 toxicity Toxicity 0.000 abstract description 3
- 230000001988 toxicity Effects 0.000 abstract description 3
- 235000002566 Capsicum Nutrition 0.000 abstract 1
- 235000005206 Hibiscus Nutrition 0.000 abstract 1
- 235000007185 Hibiscus lunariifolius Nutrition 0.000 abstract 1
- 244000284380 Hibiscus rosa sinensis Species 0.000 abstract 1
- 239000006002 Pepper Substances 0.000 abstract 1
- 235000016761 Piper aduncum Nutrition 0.000 abstract 1
- 235000017804 Piper guineense Nutrition 0.000 abstract 1
- 244000203593 Piper nigrum Species 0.000 abstract 1
- 235000008184 Piper nigrum Nutrition 0.000 abstract 1
- 230000009044 synergistic interaction Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 23
- 239000002253 acid Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 10
- 241000033009 Merremia Species 0.000 description 9
- 235000019009 Merremia tuberosa Nutrition 0.000 description 9
- 235000009000 Rosa woodsii Nutrition 0.000 description 9
- 238000005374 membrane filtration Methods 0.000 description 9
- 230000010355 oscillation Effects 0.000 description 9
- 235000011705 wood rose Nutrition 0.000 description 9
- 239000006260 foam Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 5
- 241000219146 Gossypium Species 0.000 description 5
- 238000003756 stirring Methods 0.000 description 4
- 230000003115 biocidal effect Effects 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 229920000180 alkyd Polymers 0.000 description 2
- 210000000170 cell membrane Anatomy 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 241000588724 Escherichia coli Species 0.000 description 1
- 206010053759 Growth retardation Diseases 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000003385 bacteriostatic effect Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 231100000001 growth retardation Toxicity 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002503 metabolic effect Effects 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000013642 negative control Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 210000003463 organelle Anatomy 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3719—Polyamides or polyimides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention aims to provide plant detergent powder for cleaning greasy dirt. With a natural plant ingredient as a main raw material, the plant detergent powder realizes the synergistic interaction, dirt removal and antibacterial effects by the aid of rich bioactive ingredients contained in red cluster pepper essential oil, hibiscus extract products, okra enzymolysis products and distillers' grain water extracting solutions, has natural plant aroma and solves the problems that most of detergent powder produced at present has poor greasy dirt removal capability and antibacterial property and has certain toxicity.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, and in particular to a kind of degreasing plant washing powder.
Background technology
Existing washing powder all has dirt-removing power, but can not control the generation of bacterium, can not sterilizing.It is few
Number disinfectant detergent powder is generally chlorinated products, and excitant is big, long-term use meeting damaging laundry, and is unfavorable for health.
The content of the invention
It is an object of the invention to provide a kind of degreasing plant washing powder, with natural plant composition as primary raw material, lead to
Cross conical redpepper fruit essential oil, shrub althea flower extract product, gumbo enzymolysis product, in vinasse aqueous extract containing abundant bioactivity into
Point, the effect of Synergistic soil-release antibacterial is reached, it is fuel-displaced with the most of washing powder for solving existing production with natural plant fragrance
Dirty ability and antibiotic property are poor, have the problem of certain toxicity.
The present invention is by the following technical programs to realize above-mentioned purpose, a kind of degreasing plant washing powder, by following heavy
Measure the component composition of number meter：11-17 parts of shitosan amphoteric polymeric surfactant, sodium carbonate 26-37 parts, cellulose second
Alkyd 7-11 parts, enzyme 0.2-0.7 parts, propane diols acid 1-3 part of algin ester, 1-5 parts of conical redpepper fruit essential oil, shrub althea flower extraction
Product 4-9 parts, 12-18 parts of gumbo enzymolysis product, 27-43 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the degreasing plant washing powder is made up of the component of following percentage by weight meter：Shitosan both sexes
High molecular surfactant 13-16 parts, sodium carbonate 29-34 parts, glycolic cellulose 8-9 parts, enzyme 0.3-0.5 parts, the third two
1-2 parts of alkyd algin ester, 2-3 parts of conical redpepper fruit essential oil, shrub althea flower extract 5-8 parts of product, gumbo enzymolysis product 13-15
Part, 32-38 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=10-22.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
The preparation method of degreasing plant washing powder of the present invention, comprises the following steps：Shitosan two is added toward softened water
Property high molecular surfactant and propane diols acid algin ester, stir, add glycolic cellulose, sodium carbonate,
Enzyme, conical redpepper fruit essential oil, stir, and are eventually adding shrub althea flower and extract product, vinasse aqueous extract, the stirring of gumbo enzymolysis product
It is even.
Degreasing plant washing powder of the present invention is with shitosan amphoteric polymeric surfactant and propane diols acid algin
Ester is used as primary surfactant, then coordinates the composition of GEH and protease, quickly can be risen with the greasy dirt on fabric
Act on and by its effective removal, while each component is cooperateed with, stable system can extend the shelf-life of product.
In the present invention, vinasse aqueous extract, shrub althea flower extract product, in gumbo enzymolysis product rich in natural bioactive into
Point, by these bioactive ingredients by synergistic function, while can be by the collaboration of each component especially sodium carbonate
Synergy, acts on the cell membrane and cell film system of pathogenic bacteria, and the energy for depending on membrane structure integrality is destroyed directly and rapidly
Metabolism and the selective permeability to material depended on for existence of cell and organelle, make nutriment and the metabolite cannot be normal
Through cell membrane, microorganism is lost nutrition and cause its growth retardation, reach the purpose of restraining and sterilizing bacteria；Or by suppressing to cause
The respiration of germ, makes metabolic activity be obstructed, it is impossible to maintains normal dynamic membrane structure, causes the self-dissolving of cell.By hair
The groups such as the abundant hydroxyl contained in the active component in bright, easily form hydrogen bond, and then cause generation with active site in alcohol
Thank to system disorders, and then reach the effect of antibiotic and sterilizing.
The present invention is extracted product, gumbo and is digested with natural plant composition as primary raw material by conical redpepper fruit essential oil, shrub althea flower
Containing abundant bioactive ingredients in product, vinasse aqueous extract, the effect of Synergistic soil-release antibacterial is reached, with natural
Plant flavour, goes out that greasy dirt ability and antibiotic property are poor, have certain toxicity with the most of washing powder for solving the problems, such as existing production.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 15 parts of agent, 32 parts of sodium carbonate, 8 parts of glycolic cellulose, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, conical redpepper fruit
2 parts of essential oil, shrub althea flower extract 7 parts of product, 14 parts of gumbo enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=18.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Embodiment 2
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 15 parts of agent, 32 parts of sodium carbonate, 8 parts of glycolic cellulose, 0.3 part of enzyme, 1 part of propane diols acid algin ester, conical redpepper fruit
2 parts of essential oil, shrub althea flower extract 5 parts of product, 13 parts of gumbo enzymolysis product, 32 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=10.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Embodiment 3
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 15 parts of agent, 32 parts of sodium carbonate, 9 parts of glycolic cellulose, 0.5 part of enzyme, 2 parts of propane diols acid algin ester, conical redpepper fruit
3 parts of essential oil, shrub althea flower extract 8 parts of product, 15 parts of gumbo enzymolysis product, 38 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=22.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Embodiment 4
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 13 parts of agent, 29 parts of sodium carbonate, 8 parts of glycolic cellulose, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, conical redpepper fruit
2 parts of essential oil, shrub althea flower extract 7 parts of product, 14 parts of gumbo enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, the molecular formula of the shitosan amphoteric polymeric surfactant is,
Wherein n=14.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Embodiment 5
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 16 parts of agent, 34 parts of sodium carbonate, 8 parts of glycolic cellulose, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, conical redpepper fruit
2 parts of essential oil, shrub althea flower extract 7 parts of product, 14 parts of gumbo enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, further, the molecular formula of the shitosan amphoteric polymeric surfactant is, wherein n=20.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Comparative example 1
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：32 parts of sodium carbonate, cellulosic ethanol
8 parts of acid, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, 2 parts of conical redpepper fruit essential oil, shrub althea flower extract 7 parts of product, gumbo
14 parts of enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Comparative example 2
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 15 parts of agent, 8 parts of glycolic cellulose, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, 2 parts of conical redpepper fruit essential oil, the rose of Sharon
Flower extracts 7 parts of product, 14 parts of gumbo enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, further, the molecular formula of the shitosan amphoteric polymeric surfactant is, wherein n=18.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Comparative example 3
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 15 parts of agent, 32 parts of sodium carbonate, 8 parts of glycolic cellulose, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, conical redpepper fruit
2 parts of essential oil, 14 parts of gumbo enzymolysis product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the gumbo enzymolysis product is：Gumbo after stripping and slicing, the pretreatment such as blending, to expect
Liquor ratio 1: 3（m/V）Add water, soaked overnight, by the way of cellulase and papain mixed enzymolysis, enzymatic hydrolysis condition is：
The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain be respectively 1500 U/g and
1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then by micro-filtration
Obtain gumbo enzymolysis product.
Further, further, the molecular formula of the shitosan amphoteric polymeric surfactant is, wherein n=16.
Comparative example 4
A kind of degreasing plant washing powder, is made up of the component of following percentage by weight meter：Live on shitosan Amphiphatic high polymer surface
Property 15 parts of agent, 32 parts of sodium carbonate, 8 parts of glycolic cellulose, 0.4 part of enzyme, 2 parts of propane diols acid algin ester, conical redpepper fruit
2 parts of essential oil, shrub althea flower extract 7 parts of product, 35 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
Further, the preparation method of the vinasse aqueous extract is：Vinasse after taking after making wine, by 1:4 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinasse aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, further, the molecular formula of the shitosan amphoteric polymeric surfactant is, wherein n=14.
Further, the preparation method of the shrub althea flower extraction product is：By shrub althea flower clean dry, then shrub althea flower is ground
50 mesh sieves are clayed into power and cross, the shrub althea flower powder after sieving adds 70% ethanol, the quality (g) of shrub althea flower powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Wood
Rose of Sharon flower ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains shrub althea flower crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Shrub althea flower crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains shrub althea flower and extracts product after wash-out liquid condensing concentration.
Comparative example 5
This comparative example chooses prestige Lay（Guangzhou）The batch of commodity Co., Ltd production is that 20150821 Wei Lushi imitates laundry entirely
Liquid.
Comparative example 6
This comparative example is the washing powder prepared according to CMC GBs.
Measure of merit
1. detergency experiment
According to the washing powder prepared in GB ∕ T 13174-2008, testing example 1-5 and comparative example 1-6 to three kinds of soiled cottons
（JB01-carbon black soiled cotton, JB02-albumen soiled cotton and JB03-sebum soiled cotton）Detergency.Test dirty in 457nm with whiteness instrument
Cloth wash before whiteness value.Four pieces of every kind of soiled cotton（6cm×6cm）, washed at 30 DEG C.Detergency test machine rotating speed is 120rpm, stirring
20min.Then, the whiteness value after measurement washing, rinsing and drying.With same method, phase is done as with reference to sample using standard flour
With experiment.Detergency is expressed from the next：Detergency=（RAW-RBW）/（RAW R-RBW R）；
Wherein, RAWAnd RBWWhiteness value respectively before and after washing powder washing, RAW RAnd RBW RIt is respectively flat before and after standard flour washing
Equal whiteness value.
| Test group | JB01 | JB02 | JB03 |
| Embodiment 1 | 1.59 | 1.72 | 1.88 |
| Embodiment 2 | 1.5 | 1.71 | 1.87 |
| Embodiment 3 | 1.57 | 1.74 | 1.91 |
| Embodiment 4 | 1.43 | 1.78 | 1.96 |
| Embodiment 5 | 1.37 | 1.49 | 1.81 |
| Comparative example 1 | 0.59 | 0.75 | 0.31 |
| Comparative example 2 | 0.68 | 0.53 | 0.4 |
| Comparative example 3 | 0.68 | 0.91 | 0.49 |
| Comparative example 4 | 0.79 | 0.83 | 0.53 |
| Comparative example 5 | 1.15 | 1.25 | 1.11 |
| Comparative example 6 | 1.08 | 1.13 | 1.02 |
2. foaming properties
Foaming properties are according to Malaysian palm oil association（MPOB）Internalist methodology is tested.By embodiment 1-5 and comparative example 1-6
Laundry composition prepare 0.2% sample aqueous solution.30 generation foams are stirred up and down with a standard piston in graduated cylinder,
Foam height when record start and 5min is foamability, and the change of foam height turns to foam stability.
| Test group | Initial foam height（mm） | Foam height after 5 minutes（mm） |
| Embodiment 1 | 290 | 140 |
| Embodiment 2 | 275 | 130 |
| Embodiment 3 | 270 | 130 |
| Embodiment 4 | 280 | 140 |
| Embodiment 5 | 285 | 130 |
| Comparative example 1 | 195 | 65 |
| Comparative example 2 | 235 | 85 |
| Comparative example 3 | 215 | 60 |
| Comparative example 4 | 250 | 105 |
| Comparative example 5 | 260 | 110 |
| Comparative example 6 | 245 | 120 |
3. bacteriostatic test
It is 5.0 × 10 to prepare bacteria concentration respectively5-5.0×106The staphylococcus aureus bacteria suspension of cfu/ml and Escherichia coli
Bacteria suspension, takes 0.1ml bacteria suspensions and is spread evenly across Bacteria Culture primary surface, after after its natural drying, places an Oxford cup and exists
Center, light pressure is fixed.Washing powder in extraction embodiment 1-5 and comparative example 1-6（Concentration is 0.2%）0.2ml is to Oxford cup
In, 37 DEG C are cultivated 24 hours, calculate antibacterial circle diameter size.With the PBS liquid of pH 7.2 as negative control, be not added with any training
The culture medium of nutrient solution is used as aseptic blank.Every kind of liquid detergent sample is parallel to make 3 flat boards, repeats 2 times.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask and limited rather than described above, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.The ins and outs not described in detail in the present invention, can be by any in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (6)
1. a kind of degreasing plant washing powder, it is characterised in that be made up of the component of following parts by weight meter：Shitosan both sexes are high
Molecular surface active agent 11-17 parts, sodium carbonate 26-37 parts, glycolic cellulose 7-11 parts, enzyme 0.2-0.7 parts, propane diols
1-3 parts of sour algin ester, 1-5 parts of conical redpepper fruit essential oil, shrub althea flower extract 4-9 parts of product, gumbo enzymolysis product 12-18
Part, 27-43 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
2. degreasing plant washing powder according to claim 1, it is characterised in that the degreasing plant washing powder by with
The component composition of lower percentage by weight meter：13-16 parts of shitosan amphoteric polymeric surfactant, sodium carbonate 29-34 parts, fibre
Plain 8-9 part of the glycolic of dimension, enzyme 0.3-0.5 parts, sour 1-2 parts of the algin ester of propane diols, 2-3 parts of conical redpepper fruit essential oil, the rose of Sharon
Flower extracts 5-8 parts of product, 13-15 parts of gumbo enzymolysis product, 32-38 parts of vinasse aqueous extract；
Described enzyme is the composition of GEH and protease, and the weight ratio of the GEH and protease is
1:1。
3. degreasing plant washing powder according to claim 1, it is characterised in that the preparation side of the vinasse aqueous extract
Method is：Vinasse after taking after making wine, by 1:4 solid-liquid ratio（g:mL）Distilled water is added, at room temperature after the h of mechanical shaking extraction 3
Filter to get filtrate, by filtrate again by 0.22 μm of sterilised membrane filter filtration sterilization, obtain vinasse aqueous extract, protected under the conditions of 4 DEG C
Deposit standby.
4. degreasing plant washing powder according to claim 1, it is characterised in that the preparation side of the gumbo enzymolysis product
Method is：Gumbo after stripping and slicing, the pretreatment such as blending, with solid-liquid ratio 1: 3（m/V）Add water, soaked overnight, using cellulase and
The mode of papain mixed enzymolysis, enzymatic hydrolysis condition is：45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase
1500 U/g and 1300U/g are respectively with the enzyme concentration of papain；The enzyme that gone out after terminating is digested, by enzymolysis liquid at 4 DEG C
5000r/min is centrifuged 10min, takes supernatant, then obtain gumbo enzymolysis product by micro-filtration.
5. degreasing plant washing powder according to claim 1, it is characterised in that the shitosan Amphiphatic high polymer surface
The molecular formula of activating agent is, wherein n=10-22.
6. degreasing plant washing powder according to claim 1, it is characterised in that the shrub althea flower extracts the preparation of product
Method is：By shrub althea flower clean dry, then shrub althea flower grind into powder and cross 50 mesh sieves, the shrub althea flower powder after sieving
70% ethanol is added, the quality (g) of shrub althea flower powder is with the volume (mL) of ethanol than m: V=1: 13；Ultrasonic wave shakes
Swing instrument (40 DEG C, 450 W) min of assisted extraction 20；Shrub althea flower ethanol flows back through water-bath extract again, and extraction temperature is 65
DEG C, extracting 3 times, 1.5 h every time, suction filtration centrifugation (5000r/min, 15min), rotary evaporation in vacuo is returned after filtering
Ethanol is received, shrub althea flower crude extract is obtained；HPD-300 macroreticular resins are soaked into 24 h with 95% ethanol, distilled water is cleaned to nothing
20 cm × 240 special the chromatographic columns of cm macroreticular resins are put into after ethanol flavor；Shrub althea flower crude extract is with 400 BV/h (BV:
The volume of macroreticular resin) the rate of adsorption be adsorbed on HPD-300 macroreticular resins, upper column quantity be 600 BV；Adsorb
The resin distilled water of 800 BV with the impurity on the flow velocity eluted resin of 1000 BV/h, then with 1200 BV's
60% ethanol is eluted to the crude extract being attached on resin, and obtaining shrub althea flower after wash-out liquid condensing concentration extracts product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955428.0A CN106701353A (en) | 2016-11-03 | 2016-11-03 | Plant detergent powder for cleaning greasy dirt |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610955428.0A CN106701353A (en) | 2016-11-03 | 2016-11-03 | Plant detergent powder for cleaning greasy dirt |
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| Publication Number | Publication Date |
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ID=58940788
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
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| CN (1) | CN106701353A (en) |
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2016
- 2016-11-03 CN CN201610955428.0A patent/CN106701353A/en active Pending
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| WD01 | Invention patent application deemed withdrawn after publication |