CN106029859B - Fiber softener composition - Google Patents
Fiber softener composition Download PDFInfo
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- CN106029859B CN106029859B CN201580010355.1A CN201580010355A CN106029859B CN 106029859 B CN106029859 B CN 106029859B CN 201580010355 A CN201580010355 A CN 201580010355A CN 106029859 B CN106029859 B CN 106029859B
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Abstract
The present invention relates to a kind of fiber softener compositions, and it includes organic acids and vinegar, and the turbidity (NTU) of rinse water is 0.05~9 when washing.The clothing etc. crossed using fiber softener cleaning compositions of the invention, oil (greasy is not had, oily feeling), but the dry and comfortable soft feeling as drying in the sun, due to having carried out sterilization processing to smell source bacterium, therefore moist feeling is not had, and with pure and fresh fragrance.Also, the fiber softener composition is highly effective to removal laundry detergents residue.Moreover, it relates to a kind of fiber softener composition, the retentivity of transparent and stable and fragrance to the vitreous fibre softener composition containing a large amount of organic acid, fermented vinegar and fragrance is highly effective.Wherein, as solubilizer, fatty acid ethylene oxide addition product and fatty alcohol ethylene oxide adduct have been used, has eliminated the peculiar smell due to caused by the acetic acid in vinegar, has improved fragrance satisfaction.In addition, fiber softener composition of the invention using pKa by 3~5 and the organic acid with carboxyl replaces the cationic surfactant being harmful to the human body, the spot on clothing can be effectively removed.Moreover, the present invention relates to a kind of fiber softener compositions, specifically, it has used colored fermented vinegar as fiber softener, it is more outstanding to the removal effect of ammonia and methyl mercaptan compared with common vinegar.
Description
Technical field
The present invention relates to a kind of fiber softener compositions.
Background technique
Electrostatic is generated on clothing in order to prevent, and in order to assign the flexibility of fiber, fiber softener is extensive in the family
It uses, and its usage amount is the trend gradually increased.Recently, as the improvement of consumer's living standards, to hygienic and clean
Demand gradually increases, moreover, to preventing, there may be the microorganisms on clothing in order to pursue life of more comfortably wearing the clothes
Breeding, and the attention rate removed odors are gradually being promoted.
Under normal circumstances, the moist smell generated in fiber, can be by forming the organic compound ingredient of sweat odor etc.
Decompose the unsaturated lower fatty acid generated with skin normal flora and the volatile organic compounds such as ammonia react, or with wash
The residual component of clothing agent or softener reacts and generates.It is reported that especially when rainy season indoor clothing is dry, due to drying
Time-lag is influenced by peculiar smell bacterium Morxella asloensis and is more prone to produce moist smell.
It is previous to use the fiber softener composition comprising antibacterial agent in order to remove the smell etc. of this humidity, but wrap
The antibacterial agent being contained in previous fiber softener is harmful to the human body.Recently, with using synthetic antibacterial agents to be harmful to the human body
Content be reported, the use of this antibacterial agent is by public separate.
In addition, since fiber softener is since nineteen fifty, in generation, was popularized by the whole world, more than 60 years as long as always using sun
Ionic surface active agent is as submissive ingredient (KR published patent the 10-2007-0090861st).However, this in recent years
Cationic surfactant is disclosed for the harmfulness of human body, it is desirable to which the demand far from this harmful substance is gradually increasing.
Summary of the invention
Subject to be solved by the invention
It is not used the object of the present invention is to provide one kind and was included in fiber softener composition as submissive ingredient in the past
In cationic surfactant, and have outstanding deodorization and sterilization effect, anti-static effect and removal laundry detergents residual
The fiber softener composition of object effect.
In addition, the object of the present invention is to provide a kind of unused cationic surfactant, by the way that fragrance is dissolved in packet
So that its is kept transparent phase in fiber softener containing organic acid and fermented vinegar, mitigate acetic acid taste and fragrance satisfaction it is high fiber it is soft
Along agent composition.
In addition, it is 3~5 and having with carboxyl that the object of the present invention is to provide a kind of comprising pKa value (acidity coefficient)
The decontamination fiber softener composition of machine acid.
In addition, the object of the present invention is to provide a kind of in previous fiber softener using flower fermented vinegar to remove
The fiber softener composition that smelly effect is improved.
The method to solve the problem
In order to achieve the above object, the present invention provides a kind of fiber softener composition comprising organic acid and edible
Vinegar,
When using the fiber softener cleaning compositions, rinsing water turbidity (NTU) is 0.05~9.
In addition, the present invention provides a kind of fiber softener composition comprising organic acid, fermented vinegar and solubilizer,
The solubilizer includes fatty acid ethylene oxide addition product and fatty alcohol ethylene oxide adduct.
In addition, the present invention provides a kind of decontamination fiber softener composition, wherein do not include cation surface activating
Agent is 3~5 and the organic acid with carboxyl comprising pKa value.
In addition, the present invention provides a kind of fiber softener composition comprising flower fermented vinegar.It is submissive in fiber of the invention
In agent composition, flower fermented vinegar can be by will the group as composed by peach blossom, apricot flower, sophora flower, Flos Chrysanthemi, Jasmine and lotus flower
In more than one the petal selected washed and dried, and mix with vinegar and syrup post-fermentation 3~7 days and be made.
Invention effect
Using the clothing etc. of fiber softener cleaning compositions of the invention, oil (greasy, oily) is not had
Feel, but a kind of dry and comfortable soft feeling as drying in the sun, due to having carried out sterilization processing to smell source bacterium,
And then moist feeling is not had, and with pure and fresh fragrance.Also, the fiber softener composition is residual to removal laundry detergents
Stay object highly effective.
Fiber softener composition of the invention is not used cationic surfactant, but with organic acid, fermented vinegar one
It rises and has used solubilizer, therefore, maintain transparent phase, and mitigated acetic acid taste, make it have outstanding fragrance satisfaction.
In addition, fiber softener composition of the invention is by pKa value by 3~5 and the organic acid with carboxyl replaces
Therefore the cationic surfactant being harmful to the human body under the premise of harmless, uses cationic surface with previous
The fiber softener of activating agent is compared, its clean effect can also be improved.
In addition, fiber softener composition of the invention has used colored fermented vinegar, and then have to ammonia and methyl mercaptan excellent
Elegant removal effect.
Specific embodiment
The present invention relates to a kind of fiber softener composition comprising organic acid and vinegar, and use the fiber
The turbidity (NTU) of rinse water is 0.05~9 (hereinafter referred to as " the first fiber softener composition ") when softener cleaning compositions.
As described above, fiber softener composition of the invention includes organic acid and vinegar.In addition, fibre of the invention
Tie up softener composition not compositions comprising cationic surfactants.
In the present invention, organic acid plays the role of deodorant and removal laundry detergents residue.In addition, described organic
Acid can play the role of softener itself (keeping dress material soft, to improve sense of touch).
The type of organic acid is not limited by special, for example, may include by citric acid, acetic acid, tartaric acid, succinic acid,
Selected in group composed by malic acid and lactic acid more than one.
For the organic acid, acidity is higher, and its deodorizing effect is more outstanding, and pKa value is lower, the pH value of aqueous solution
Lower, therefore, the deodorizing effect of fiber softener can be improved in when organic acid lower using pKa value.The pKa of the citric acid is
3.1, the pKa of malic acid is 3.4, and the pKa of acetic acid is 4.8, therefore in the present invention, uses citric acid more advantageous as organic acid
In invention effect.Especially since the cost of the raw material of citric acid is relatively low, thus be suitable for come as organic acid using.
The content of the organic acid is not limited by special, above-mentioned relative to 100 weight % of fiber softener composition
The content of organic acid can be 7.5~20 weight %, 8~19 weight % or 9~18 weight %.It, can be in the range
Outstanding deodorizing effect is presented, and laundry detergents residue can be effectively removed.When the content of organic acid is more than 20 weight %
Still outstanding deodorizing effect can be presented, but as the content of organic acid increases, the pH value of rinse water can be reduced, therefore, excellent
Selected control system is below 20 weight %.
In the present invention, vinegar plays the role of sterilization, taste removal and removal laundry detergents residue.
The main component of vinegar is acetic acid, is in a kind of acid with micro- sweetening, containing acetic acid, citric acid with
And tens kinds of organic acids such as various amino acid, it can not only boost metabolism, assist in removing internal excreta, also act as strong
The effect of the preservative, fungicide of effect.
In the present invention, vinegar may include colored fermented vinegar, specifically can be simultaneously comprising vinegar and flower hair
Ferment vinegar.
At this point, vinegar can specifically play the role of removing laundry detergents residue.
The content of these vinegars is not limited by special, above-mentioned relative to 100 weight % of fiber softener composition
The content of vinegar can be 0.1~10 weight %, 0.5~5 weight % or 1~3 weight %.In the range, vinegar
Play the role of sterilization and removal laundry detergents residue.
In addition, flower fermented vinegar can play potent deodorization.
The colored fermented vinegar can be by washing and drying petal, and sends out after mixing with excessive vinegar and syrup
Ferment 3~7 days and be made.
The vinegar can be commercially available making vinegar, relative to 1 parts by weight of petal, it is preferable to use 5~30 parts by weight
Vinegar.In addition, the syrup may include the various carbohydrates such as glucose, granulated sugar, fructose, oligosaccharide or malt sugar.The sugar
Water plays the role of making flower extract alcoholic fermentation.Relative to 1 parts by weight of petal, the syrup of 5~30 parts by weight is preferably added.
In addition, after the colored fermented vinegar can also be by that will spend direct sterilization treatment, carry out 10 at 100~150 DEG C~
30 minutes hot water extracts, then places after the hot water extract is mixed with kind vinegar (vinegar starter) and syrup
In 20~40 DEG C of environment, it is made by fermentation in 72~96 hours.
Described kind of vinegar refers to, isolates from the free from extraneous odour manufactured by traditional approach, the making vinegar without foreign odor wild
Vinegar bacterium, and to the wild vinegar bacterium carry out proliferation fermentation and manufactured vinegar.In addition, as long as wild acetic acid bacteria-can be passed through
Kind of vinegar made of acetobacter (Acetobacter sp.) can use.At this point, relative to flower 100 weight of hot water extract
% is measured, the described kind of vinegar of 5~30 weight % can be added.When the additive amount of described kind of vinegar is lower than 5 weight %, it is not easy to induce institute
State the edible vinegar fermentation for curing flower hot water extract；When more than 30 weight %, compared with additive amount, the efficiency of vinegar fermentation is eaten
It will not sustainable growth again.
The syrup may include the various carbohydrates such as glucose, granulated sugar, fructose, oligosaccharide or malt sugar.The syrup plays
Make the effect for spending hot water extract's alcoholic fermentation.Relative to flower 100 weight % of hot water extract, it can add 5~30 weight %'s
The syrup.
The pH value of flower fermented vinegar made of the method can be 2.70~3.30, and acidity can achieve 3~7.
There is no any restrictions to the type of the flower for manufacturing the colored fermented vinegar.It is, for example, possible to use peach blossom, apricot flower,
Sophora flower, Flos Chrysanthemi, Jasmine and lotus flower etc..
The content of the fermented vinegar is not particularly limited, and relative to 100 weight % of fiber softener composition, may include
0.001~10 weight %, the fermented vinegar of 0.05~5 weight % or 0.1~2 weight %.In the range, the fermentation
Outstanding bactericidal effect is presented in vinegar, and can remove odors easily.
In the present invention, the total usage amount of vinegar relative to 100 weight % of fiber softener composition can for 0.001~
20 weight %.
When using fiber softener cleaning compositions of the invention, rinsing water turbidity (NTU) can be 0.05~9.Institute
It states in range, can be perceive intuitively that transparent rinse water by naked eyes, consumer's satisfaction can be given.Specifically,
The rinsing water turbidity can be 0.1~9 or 0.1~8.
As the experiment condition for measuring the rinsing water turbidity, the environment of Environmental Industry technology institute, South Korea can use
The experimental method of EL306 (fiber softener) in Taken authentication benchmark, sample usage amount can be 0.67mL/L.In addition, turbidity
(NTU) the 2100AN nephelometer (Turbidimeter) of HACH company can be used to measure.
In addition, the pH value of rinse water can be 4.5 or more when using fiber softener cleaning compositions of the invention.
Moreover, it relates to a kind of fiber softener composition (hereinafter referred to as " the second fiber softener composition "),
It includes organic acid, fermented vinegar and solubilizer,
The solubilizer includes fatty acid ethylene oxide addition product and fatty alcohol ethylene oxide adduct.
As described above, fiber softener composition according to the present invention includes organic acid, fermented vinegar and solubilizer.
In the present invention, organic acid plays the role of deodorization, and removal laundry detergents residue.In addition, the organic acid
Play the role of softener itself (keeping dress material soft, to improve sense of touch).The type of these organic acids is not particularly limited, for example,
It may include more than one selected in the group as composed by citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
The acidity of the organic acid is higher, and deodorizing effect is more outstanding, and since pKa value is lower, the pH value of aqueous solution is lower,
Therefore, the deodorizing effect of fiber softener can be improved when organic acid lower using pKa value.The pKa value of the citric acid is
3.1, the pKa value of malic acid is 3.4, and the pKa value of acetic acid is 4.8, therefore, citric acid is used in the present invention as organic acid more
Be conducive to invention effect, particularly because the cost of the raw material of citric acid is relatively low, so being suitable for making as organic acid
With.
The content of the organic acid is not particularly limited, and may include 1 relative to 100 weight % of fiber softener composition
~30 weight %, the organic acid of 5~20 weight % or 8~15 weight %.In the range, outstanding deodorization effect can be presented
Fruit, and laundry detergents residue can be effectively removed.It still can be presented when the content of organic acid is more than 30 weight % excellent
Elegant deodorizing effect, but as the content of organic acid increases, the pH value of rinse water can also reduce, it is therefore preferable that usage amount is 30
Weight % or less.
In the present invention, fermented vinegar can play potent deodorization.
The type of this fermented vinegar is not particularly limited, and it is, for example, possible to use flower fermented vinegars.
Fiber softener composition according to the present invention can also be potent comprising playing in addition to above-mentioned constituent
The flower fermented vinegar of deodorization.
The colored fermented vinegar can be by washing and drying petal, and sends out after mixing with excessive vinegar and syrup
Ferment 3~7 days and be made.
The vinegar can be commercially available making vinegar, relative to 1 parts by weight of petal, it is preferable to use 5~30 parts by weight
Vinegar.In addition, the syrup may include the various carbohydrates such as glucose, granulated sugar, fructose, oligosaccharide or malt sugar.The sugar
Water plays the role of making flower extract alcoholic fermentation.Relative to 1 parts by weight of petal, it is preferable to use the syrup of 5~30 parts by weight.
In addition, carrying out 10~30 at 100~150 DEG C after the colored fermented vinegar can be by that will spend direct sterilization treatment
The hot water of minute extracts, then is placed in 20~40 DEG C of environment after the hot water extract is mixed with kind vinegar and syrup,
It is made by fermentation in 72~96 hours.
Described kind of vinegar refers to, isolates from the free from extraneous odour manufactured by traditional approach, the making vinegar without foreign odor wild
Vinegar bacterium, and to the wild vinegar bacterium carry out proliferation fermentation and manufactured vinegar.In addition, as long as wild acetic acid bacteria-can be passed through
Kind of vinegar made of acetobacter (Acetobacter sp.) can use.At this point, relative to flower 100 weight of hot water extract
% is measured, the described kind of vinegar of 5~30 weight % can be added.When the additive amount of described kind of vinegar is lower than 5 weight %, it is not easy to induce institute
State the edible vinegar fermentation for curing flower hot water extract；When more than 30 weight %, compared with additive amount, the efficiency of vinegar fermentation is eaten
It will not sustainable growth again.
The syrup may include the various carbohydrates such as glucose, granulated sugar, fructose, oligosaccharide or malt sugar.The syrup plays
Make the effect for spending hot water extract's alcoholic fermentation.Relative to flower 100 weight % of hot water extract, it can add 5~30 weight %'s
The syrup.
The pH value of flower fermented vinegar made of the method can be 2.70~3.30, and acidity can achieve 3~7.
Seeds of flowering plants class for manufacturing the colored fermented vinegar is unrestricted.It is, for example, possible to use peach blossom, apricot flower, sophora flower,
Flos Chrysanthemi, Jasmine or lotus flower etc..
The content of the fermented vinegar is not particularly limited, and relative to 100 weight % of fiber softener composition, may include
0.001~10 weight %, the fermented vinegar of 0.05~5 weight % or 0.1~2 weight %.In the range, present outstanding
Bactericidal effect, and can easily remove odors.
In the present invention, solubilizer can mitigate the smell of vinegar because of generations such as fermented vinegars, and then improve the perfume (or spice) of fiber softener
Taste satisfaction.
As this solubilizer, nonionic surfactant can be used, specifically, fatty acid epoxy second can be used
Alkane addition product and fatty alcohol ethylene oxide adduct.
Contain cationic surfactant and fragrance in previous fiber softener, solubilizer is to stablize these sun
Ionic surface active agent and fragrance and use, as the solubilizer, used and be added to ethylene oxide in fatty alcohol
Nonionic surfactant.At this point, cationic surfactant, fragrance and nonionic surfactant are formed as emulsification grain
The packet structure of son keeps stability.
However, as described herein, when using organic acid and fermented vinegar to replace cationic surfactant, fiber
The liquid property of softener composition shows acidity of the pH value less than 3, therefore, if using non-ionic surface active as described above
Agent may result in the problem of fragrance component is deformed through acid catalyzed reaction, and since the peculiar smell of vinegar ingredient causes fragrance full
The reduction of meaning degree, so there may be commodity value reduction the problem of.
Therefore, in the present invention, using the mixing of fatty acid ethylene oxide addition product and fatty alcohol ethylene oxide adduct
Object is as solubilizer, to remove the peculiar smell of vinegar ingredient, to improve fragrance satisfaction, and improves the stabilization of fiber softener
Property.
As the fatty acid ethylene oxide addition product, specifically, may is that in carbon atom number be 10~20 and master
In fatty acid on chain or branch with alkyl or alkenyl, the addition nonionic surfactant of ethylene oxide, it is more specific and
Speech, can be rilanit special EO addition product.
In addition, as fatty alcohol ethylene oxide adduct, specifically, may is that carbon atom number be 10~20 and
In the fatty alcohol for having alkyl or alkenyl on main chain or branch, the addition nonionic surfactant of ethylene oxide, more
For body, polyoxyethylene alkyl ether can be.
The content of the solubilizer is not particularly limited, and may include 1 relative to 100 weight % of fiber softener composition
~10 weight %, the solubilizer of 2~8 weight % or 3~5 weight %.In the range, the removal effect of the smell of vinegar is outstanding, can
To improve fragrance satisfaction, and the stability of fiber softener can be improved.
In addition, in solubilizer, the ratio of fatty acid ethylene oxide addition product and fatty alcohol ethylene oxide adduct can be with
It is 1:0.1~1:5 or 1:0.3~1:3.
Moreover, it relates to a kind of submissive for the decontamination fiber of 3~5 and the organic acid with carboxyl comprising pKa value
Agent composition (hereinafter referred to as " third fiber softener composition ").In addition, the feature of fiber softener composition of the invention
It is, does not include cationic surfactant.
As described above, it is 3~5 and the organic acid with carboxyl that fiber softener composition of the invention, which includes pKa value,.
In the present invention, pKa value be 3~5 and with carboxyl organic acid play decontamination, deodorization and removal laundry detergents it is residual
Stay the effect of object.In addition, the organic acid can play the role of softener itself (keeping dress material soft, to improve sense of touch).These
The type of organic acid is not particularly limited, for example, may include by citric acid, acetic acid, tartaric acid, succinic acid, malic acid and
Selected in group composed by lactic acid more than one.Particularly because the cost of the raw material of citric acid is relatively low, so being suitable for
As organic acid come using.
The content of the organic acid is not particularly limited, and may include 1 relative to 100 weight % of fiber softener composition
~20 weight %, the organic acid of 5~15 weight % or 8~12 weight %.In the range, the organic acid can present excellent
Elegant clean effect.Outstanding clean effect still can be presented when the content of organic acid is more than 20 weight %, but with having
The pH value that the content of machine acid increases rinse water can reduce, it is therefore preferable that 20 weight % usage amounts below.
In fiber softener composition (second or third fiber softener composition) of the invention, food can also be added
Use vinegar.
The main component of vinegar is acetic acid, is in a kind of acid with micro- sweetening, it includes acetic acid, citric acid with
And tens kinds of organic acids such as various amino acid, it can not only boost metabolism, excreta in removing body also acts as potent anti-
Rotten agent, the effect of fungicide.In addition, vinegar can play the role of removing laundry detergents residue.
The content of the vinegar is not particularly limited, and relative to 100 weight % of fiber softener composition, may include
0.1~10 weight %, the vinegar of 0.5~5 weight % or 1~3 weight %.In the range, vinegar play sterilization with
And the effect of removal laundry detergents residue.
For fiber softener composition (third fiber softener composition) of the invention, except above-mentioned constituent
It outside, can also include the flower fermented vinegar for playing potent deodorization.The colored fermented vinegar is as described above.
Even if composition present invention as described above does not include cationic surfactant, it may have outstanding decontamination effect
Fruit, therefore conveniently used with fiber softener.
Moreover, it relates to a kind of fiber softener composition (hereinafter referred to as " the 4th fiber comprising flower fermented vinegar
Softener composition ").Fiber softener composition of the invention is characterized in that, comprising serve not only as deodorant be also used as it is soft
Along the flower fermented vinegar that ingredient works, to have outstanding deodorizing effect to ammonia and methyl mercaptan.
The colored fermented vinegar can be by washing and drying petal, and sends out after mixing with excessive vinegar and syrup
Ferment 3~7 days and be made.
The vinegar can be commercially available making vinegar, relative to 1 parts by weight of petal, it is preferable to use 5~30 parts by weight
Vinegar.In addition, the syrup may include the various carbohydrates such as glucose, granulated sugar, fructose, oligosaccharide or malt sugar.The sugar
Water plays the role of making flower extract alcoholic fermentation.Relative to 1 parts by weight of petal, it is preferable to use the syrup of 5~30 parts by weight.
Alternatively, after the colored fermented vinegar can also be by that will spend direct sterilization treatment, carry out 10 at 100~150 DEG C~
30 minutes hot water extracts, then 20~40 DEG C of environment is placed on after the hot water extract is mixed with kind vinegar and syrup
In, it is made by fermentation in 72~96 hours.
Described kind of vinegar refers to, isolates from the free from extraneous odour manufactured by traditional approach, the making vinegar without foreign odor wild
Vinegar bacterium, and to the wild vinegar bacterium carry out proliferation fermentation and manufactured vinegar.In addition, as long as wild acetic acid bacteria-can be passed through
Kind of vinegar made of acetobacter (Acetobacter sp.) can use.At this point, relative to flower 100 weight of hot water extract
% is measured, the described kind of vinegar of 5~30 weight % can be added.When the additive amount of described kind of vinegar is lower than 5 weight %, it is not easy to induce institute
State the edible vinegar fermentation for curing flower hot water extract；When more than 30 weight %, compared with additive amount, the efficiency of vinegar fermentation is eaten
It will not sustainable growth again.
The syrup may include the various carbohydrates such as glucose, granulated sugar, fructose, oligosaccharide or malt sugar.The syrup plays
Make the effect for spending hot water extract's alcoholic fermentation.Relative to flower 100 weight % of hot water extract, it can add 5~30 weight %'s
The syrup.
The pH value of flower fermented vinegar made of the method can be 2.70~3.30, and acidity can achieve 3~7.
Type for manufacturing the flower of the colored fermented vinegar is unrestricted.It is, for example, possible to use peach blossoms, apricot flower, Chinese scholartree
Flower, Flos Chrysanthemi, Jasmine and lotus flower etc..
The content of the colored fermented vinegar is not particularly limited, and relative to 100 weight % of fiber softener composition, can be wrapped
Containing 0.001~10 weight %, the fermented vinegar of 0.05~5 weight % or 0.1~2 weight %.In the range, the flower
Fermented vinegar has bactericidal effect and taste removal effect.
In addition, fiber softener composition of the invention (first, second, third or the 4th fiber softener composition)
In, it can also include ethyl alcohol for the phase stability of content.
The content of the ethyl alcohol is not particularly limited, and may include 0.1 relative to 100 weight % of fiber softener composition
~10 weight %, the ethyl alcohol of 0.5~8 weight % or 1~7 weight %.In the range, content has outstanding phase
Stability.
In addition, fiber softener composition of the invention (first, second, third or the 4th fiber softener composition)
In, fragrance can also be added.The fragrance for example may include fragrant flower (Floral) class fragrance, citrus (citrus) class fragrance
Deng.It in addition to this, as long as can be as the fragrance that fiber softener uses, in the range of not interfering effect of the present invention
To use, there is no any limitations.The content of the fragrance is not particularly limited, relative to fiber softener composition 100
Weight % may include the fragrance of 0.01~5 weight % or 0.1~3 weight %.
(first, second, third or the 4th fiber softener combination in addition, fiber softener composition according to the present invention
Object) in, fragrance solubilizer can also be added, the fragrance solubilizer is used to mitigate the acetic acid taste by generations such as fermented vinegars, thus
Improve the fragrance satisfaction of fiber softener.Its content is not particularly limited, relative to 100 weight of fiber softener composition
% is measured, may include the fragrance solubilizer of 0.1~10 weight % or 1~7 weight %.
(first, second, third or the 4th fiber softener combination in addition, fiber softener composition according to the present invention
Object), it can also include plant extracts, to improve the removal effect of the stinks such as Dichlorodiphenyl Acetate taste.The plant extracts can wrap
Containing more than one selected in the group as composed by persimmon leaf, green tea and dried orange peel.
(first, second, third or the 4th fiber softener combination in addition, fiber softener composition according to the present invention
Object), it can also include a small amount of additive within the scope of the purpose of the present invention.The additive can be to further increase and kill
In addition to this sterilization component of bacterium effect can also be pigment, preservative, antioxidant and defoaming agent etc..Additive contains
Amount is not particularly limited, and may include 0.01~5 weight % or 0.1~3 weight relative to 100 weight % of fiber softener composition
Measure the additive of %.
Each dosage form of (first, second, third or the 4th fiber softener composition) in addition, composition of the invention
In, in addition to using ingredient as described above, according to demand, use can also be mated properly into and be normally fitted to fiber softener
In oil component, water, surfactant, moisturizer, lower alcohol, thickener, chelating agent, pigment and preservative etc..It is contained
Amount is not particularly limited, and may include 55~90 weight % or 60~85 weights relative to 100 weight % of fiber softener composition
Measure the ingredient of %.
Furthermore it is possible to by methods known in the art, by composition of the invention (first, second, third or the 4th fine
Dimension softener composition) carry out powdered, granulating and use, liquid can also be made and use.
Specific embodiment
Examples 1 to 5
The fiber softener composition constituted with content (weight %) as shown in table 1 below is manufactured.
Citric acid, vinegar and flower fermented vinegar are put into after stirring 30 minutes in Purified Water first, added thereto molten
Solution stirs 30 minutes after having the solution of ethyl alcohol, fragrance, fragrance solubilizer and defoaming agent, and fiber softener composition has been made.
Vinegar has selected making vinegar (wholefood).
In addition, used colored fermented vinegar is, by drying after washing jasmine petal, then will be relative to 1 weight of petal
Amount part be 15 parts by weight vinegar and 15 parts by weight syrup mixed with the petal of the drying after, by about 7 days
Spontaneous fermentation and be made.
Comparative example 1~10
It is prepared for the fiber softener composition that there is content (weight %) as shown in table 1 below to constitute.
Table 1
Embodiment 6~7
It is prepared for the fiber softener composition that there is content (weight %) as shown in table 2 below to constitute.
Table 2
Comparative example 11
Using water instead of fiber softener composition.
Comparative example 12
Using standard fibers softener instead of fiber softener composition of the invention.
In the standard fibers softener composition, with the environmental label certification benchmark of Environmental Industry technology institute, South Korea
Standard fibers softener composition in the experimental method of EL306 (fiber softener) is identical.
Experimental example 1: experiment of the various concentration citric acid to rinsing water turbidity
To the fiber softener composition of Examples 1 to 5 and comparative example 1~10, its rinse water pH value is measured, naked eyes
Transparency and turbidity (NTU).
At this point, as the experiment condition for obtaining rinse water pH value, it then follows the environmental mark of Environmental Industry technology institute, South Korea is recognized
The experimental method of EL306 (fiber softener) in benchmark is demonstrate,proved, sample usage amount is 0.67mL/L.In addition, using HACH company
The turbidity (NTU) of 2100AN nephelometer (Turbidimeter) measurement citric acid.In addition, naked eyes transparency is carried out by naked eyes
Determine, zero is determined as when such as transparent, △ is determined as when slightly muddy, and be determined as when muddiness ×.
It will be shown in the following table 3 by the result of above-mentioned measurement.
Table 3
Table 3 as above can confirm, as the content of citric acid increases, more transparent trend is presented in rinse water.Specifically, working as
When the content of citric acid is 7.5 weight % or more, the rinse water of fiber softener composition becomes transparent, haze reduction.
Furthermore it is possible to confirm as the content of citric acid increases, the pH value of rinse water can be reduced.
Experimental example 2: laundry detergents removing residues experiment
Using the fiber softener composition of embodiment 6~7 and comparative example 11~12, laundry detergents residue (carbon is implemented
Sour calcium) removal experiment.
Washing experiment condition follows in the environmental label certification benchmark of Environmental Industry technology institute, South Korea that (fiber is submissive by EL306
Agent) experimental method, sample usage amount be 0.67mL/L.
The washing clothing used is white standard cotton (10 × 10cm) 3 (calcium carbonate content: 0ppm), and what is used washes
Clothing agent is to be easy powdered laundry detergents buy, containing calcium carbonate on the market.
Analysis after washing, rinsing to laundry detergents residue (calcium carbonate), carries out with being discussed further below: first from the washing
Point take 0.5g in washed experiment cloth under experiment condition, using hydrochloric acid, hydrofluoric acid, nitric acid and boric acid mixed liquor to its into
After row acid processing, extract within 24 hours, then be analyzed using ICP (high-frequency induction coupled plasma).
Above-mentioned experimental result is shown in Table 4.
Table 4
As shown in Table 4 above, ingredient on clothing, not soluble in water in laundry detergents i.e. laundry detergents are remained in washing process
Residue includes calcium carbonate.By this clothing for remaining calcium carbonate, after being handled using fiber softener, then to fiber
In calcium carbonate residual quantity analyzed, the result shows that, relative to there is no calcium carbonate when using previous fiber softener
Removal effect is compared, fiber softener composition of the invention has the effect of outstanding removal calcium carbonate, and citric acid contains
Amount is higher, and the removal effect of calcium carbonate is more outstanding.
Experimental example 3: detergency evaluation
Using the fiber softener composition of embodiment 6 and comparative example 11~12, detergency experiment has been carried out.
Detergency experiment is to wash experimental method progress using standard solid fabric, and according to KSM2709, and sample usage amount is
0.67mL/L。
Standard solid fabric has used Japan's washing scientific institution's wet type artificial contamination cloth having a size of 8 × 8cm (common dirty
Dye cloth), C/BC-2-060 (coffee pollution cloth), the C-BC-03 (tea pollution cloth), E-164 (grass juice factor of Dutch CFT b.v. company
Pollute cloth) and E-116 (protein contamination cloth) artificial contamination's cloth.
As detergency, pollution is measured using the Spectro colormeter SA2000 of Nippon Denshoku company
The change colour difference of cloth, difference is bigger, and detergency is more outstanding.
Above-mentioned experimental result is shown in Table 5.
Table 5
It can be confirmed from above-mentioned table 5 to of the invention according to detergency evaluation as a result, in terms of coffee, tea, grass juice factor pollution
Fiber softener composition (composition containing citric acid) clean effect it is outstanding, especially in the tea pollution side containing chlorophyll
Face, clean effect are very outstanding.This is because under the conditions of the acid of citric acid, can remove magnesium in tea pollution chlorophyll from
Son (Mg2+) reason.
Experimental example 4: deodorization power evaluation
Deodorization power evaluation experimental has been carried out using the fiber softener composition of embodiment 6 and comparative example 12.
Deodorization power is measured by 1988 experimental method of ASTM D, and using detection pipe.
As experimental sample, standard usage amount (0.67mL/L) is used and has been diluted to 2 times of standard usage amount
The liquid of (1.34mL/L).Detection pump has used the detection of Japanese GASTEC company to pump, and detection pipe has used Japanese GASTEC public
The ammonia detection pipe (No.3La) and amine detection pipe (No.180) of department.In addition, standard stink has used 1% ammonia spirit and three
Methylamine water solution.
It is measured in container in the hermetic type that capacity is 200mL, sample solution is mixed with standard stink solution and places 10
Minute, then the stink in container is drawn onto detection pipe using detection pump and is measured.
Above-mentioned measurement result is shown in following table 6.
Table 6
Table 6 as above can confirm, fiber softener composition of the invention is and previous to the deodorizing effect of ammonia and trimethylamine
Fiber softener composition (previous softener) compared to more outstanding.
Embodiment 8~14
It is prepared for the fiber softener composition that there is content (weight %) as shown in table 7 below to constitute.
Firstly, citric acid, vinegar, flower fermented vinegar and solubilizer are put into after stirring 30 minutes in Purified Water, Xiang Qi
Middle solution of the addition dissolved with ethyl alcohol, fragrance, fragrance solubilizer and defoaming agent, stirs 30 minutes and fiber softener has been made
Composition.
Vinegar has used making vinegar (wholefood).
In addition, used colored fermented vinegar is, by by after jasmine petal washing and drying, then will be relative to 1 weight of petal
Amount part was that the vinegar of 15 parts by weight and the syrup of 15 parts by weight are mixed with the petal of the drying, by oneself of about 7 days
It so ferments and is made.
Comparative example 13~18
It is prepared for the fiber softener composition that there is content (weight %) as shown in table 7 below to constitute.
Table 7
Using the fiber softener by being prepared in above-described embodiment 8~14 and comparative example 13~18, determines preservation and stablize
Property and removal acetic acid taste effect, and be shown in following table 8.
Wherein, storage stability is by visually distinguishing transparent phase and whether separate out measurement, in addition, acetic acid taste
Removal effect is measured by the sensory evaluation of the special supervisor to undergo training.
Table 8
From above-mentioned table 8 it is found that fiber is submissive when using polyoxyethylene alkyl ether and rilanit special EO addition product respectively
Agent storage stability is bad, and in the embodiment that two kinds of ingredients are mixed, the storage stability of fiber softener is outstanding.
It especially, is 80~65 weight %, rilanit special when the mixed proportion of two kinds of ingredients is polyoxyethylene alkyl ether
When EO addition product is 20~35 weight %, the storage stability of fiber softener is outstanding.
Furthermore it is possible to confirm, alkyl group becomes most effective when carbon atom number 10~20, when adding persimmon in the composition
It is effective to removal acetic acid taste when the composite vegetables extractive of subtree leaf, green tea and dried orange peel etc..
Embodiment 15~22
It is prepared for the fiber softener composition that there is content (weight %) as shown in table 9 below to constitute.
Firstly, organic acid, vinegar and flower fermented vinegar are put into after stirring 30 minutes in Purified Water, addition is pre- thereto
Solution first dissolved with ethyl alcohol, fragrance, fragrance solubilizer and defoaming agent, stirs 30 minutes and fiber softener combination has been made
Object.
In addition, being 3~5 and the organic acid with carboxyl as pKa value, citric acid (pKa 3.14), tartaric acid have been used
(pKa 3.22), malic acid (pKa 3.40), lactic acid (pKa 3.86), succinic acid (pKa 4.20) and acetic acid (pKa
4.76)。
In addition, vinegar has used making vinegar (wholefood).
In addition, used colored fermented vinegar is, by by after jasmine petal washing and drying, then will be relative to 1 weight of petal
Amount part was that the vinegar of 15 parts by weight and the syrup of 15 parts by weight are mixed with the petal of the drying, by oneself of about 7 days
It so ferments and is made.
Comparative example 19
Using water instead of fiber softener composition.
Comparative example 20
Using standard fibers softener instead of fiber softener composition of the invention.
EL306 in the standard fibers softener composition and the environmental label certification benchmark of South Korea's Environmental Industry technology institute
Standard fibers softener composition in the experimental method of (fiber softener) is identical.
Comparative example 21
It is prepared for the fiber softener composition that there is content (weight %) as shown in table 9 below to constitute.
Firstly, addition is dissolved in advance thereto after cationic surfactant is put into stirring 30 minutes in Purified Water
Ethyl alcohol, fragrance, fragrance solubilizer and defoaming agent solution, stirring 30 minutes and fiber softener composition has been made.
As cationic surfactant, used TEA Ester Quaternary (INCI Name:
Dehydrogenated palmoylethyl hydroxyethylmonium methosulfate, active 90%).
Table 9
Experimental example 5: the measurement of detergency after washing
Using through the foregoing embodiment and after the washing of fiber softener made of comparative example, detergency is had rated.
As standard solid fabric, C-BC-03 (the tea pollution of the Dutch CFT b.v. company having a size of 8 × 8cm has been used
Cloth) and E-164 (grass juice factor pollution cloth) artificial contamination's cloth.Laundry detergents used LG life health tech (Commodity
Name).
Detergency experiment is carried out using standard solid fabric, and based on KSM2709 washing experimental method, it is contemplated that washing machine
Rinsing time, set mixing time as 3 minutes, sample usage amount is 0.67mL/L.
The data of detergency are the Spectro colormeter SA2000 by using Nippon Denshoku company
The pollution cloth of measurement becomes colour difference, and the bigger clean effect of difference is more outstanding.
The measurement result of detergency is shown in Table 10.
Table 10
| It distinguishes | C-BC-03 (tea pollution cloth) | E-164 (grass juice factor pollution cloth) |
| Embodiment 15 | 1.74 | 3.03 |
| Embodiment 16 | 1.71 | 3.02 |
| Embodiment 17 | 1.70 | 3.00 |
| Embodiment 18 | 1.67 | 2.98 |
| Embodiment 19 | 1.65 | 2.98 |
| Embodiment 20 | 1.60 | 2.95 |
| Embodiment 21 | 1.76 | 3.05 |
| Embodiment 22 | 1.78 | 3.06 |
| Comparative example 19 | 0.9 | 2.75 |
| Comparative example 20 | 0.93 | 2.37 |
| Comparative example 21 | 0.90 | 2.50 |
It can confirm from above-mentioned table 10, and the comparative example 19 and comparative example 20 for using water or standard fibers softener to rinse, with
It the use of pKa value is 3~5 and having with carboxyl and compared with the case where having used comparative example 21 of cationic surfactant
The detergency that the composition of the embodiment 15~22 of machine acid pollutes grass juice factor and tea is significantly outstanding.
Embodiment 23~28 and comparative example 22~25
Be prepared for having content (weight %) as shown in table 11 below to constitute fiber softener composition (embodiment 23~
28 and comparative example 22~25).
As vinegar, natural fermented fruits vinegar (apple vinegar, the Ottogi for being easy to buy on the market have been used
Corporation), grain vinegar (brown rice vinegar, Ottogi Corporation) and Barcelona Mick vinegar (Balsamic
Vinegar, Daesang Corporation).
In addition, used colored fermented vinegar is, by drying after washing petal, then will be relative to 1 parts by weight of petal
After being mixed for the vinegar of 15 parts by weight and the syrup of 15 parts by weight with the petal of the drying, by about 7 days natures
It ferments and is made.
In order to manufacture softening agent for fibres, flower fermented vinegar is put into after being stirred 30 minutes in Purified Water, investment is preparatory thereto
Solution dissolved with ethyl alcohol, fragrance and additive stirs 30 minutes and fiber softener has been made.
As the additive, the mixture of fragrance solubilizer (5 weight %) and defoaming agent (0.5 weight %) has been used.
Table 11
Embodiment 6: deodorization power investigation
The experiment of deodorization power is carried out by detection pipe described in ASTM D 1988 and detection pump, and malodor source uses
Ammonia and methyl mercaptan.
As methyl mercaptan, the SILVER REAGENT methyl mercaptan that methyl mercaptan concentration is 0.1% in benzene solvent is used, ammonia is with 0.05%
Concentration dilution is used as malodor source in water.As gas suction pump, GV-100S air sampling is used to pump (AIR Sampling
Pump, Gastec co. (Japan)).As gas detecting tube, Gastec Detector tube No.71 (Methyl has been used
mercaptan),Gastec Detector tube No.3La(Ammonia)。
Deodorizing rate evaluation has been carried out as described below.That is, Purified Water or sample stoste are first poured into 250mL's with specified amount
After container, then stench solution investment wherein and is sealed, gas is drawn to detection pipe by using gas suction pump after ten minutes
In, it detects and records odour concentration, wherein deodorizing rate is calculated by following mathematical expressions 1:
Mathematical expression 1:
Table 12
By above-mentioned table 12 it is found that according to experimental result, the comparative example 22 without vinegar or flower fermented vinegar is to ammonia and first sulphur
Alcohol is almost without deodorizing effect, moreover, removing when using flower fermented vinegar to ammonia and methyl mercaptan compared with using common vinegar
Smelly effect is more excellent.
Claims (27)
1. a kind of fiber softener composition is comprising spend fermented vinegar, organic acid, relative to fiber softener composition 100
Weight %, the content of the colored fermented vinegar are 0.001~10 weight %, and the turbidity NTU of rinse water is 0.05~9 when washing.
2. fiber softener composition according to claim 1, wherein do not include cationic surfactant.
3. fiber softener composition according to claim 1, wherein the pH value of rinse water is 4.5 or more when washing.
4. fiber softener composition according to claim 1, wherein the organic acid is by citric acid, acetic acid, winestone
Selected in group composed by acid, succinic acid, malic acid and lactic acid more than one.
5. fiber softener composition according to claim 1, wherein relative to 100 weight of fiber softener composition
% is measured, the content of the organic acid is 7.5~20 weight %.
6. fiber softener composition according to claim 1, wherein the colored fermented vinegar is by will be by peach blossom, apricot
More than one petals selected in group composed by flower, sophora flower, Flos Chrysanthemi, Jasmine and lotus flower are washed and are dried, and
Post-fermentation is mixed with vinegar and syrup 3~7 days and obtain.
7. fiber softener composition according to claim 1, wherein also include fragrance and ethyl alcohol.
8. a kind of fiber softener composition is comprising organic acid, flower fermented vinegar and solubilizer, submissive relative to fiber
100 weight % of agent composition, the content of the colored fermented vinegar are 0.001~10 weight %, and the solubilizer includes fatty acid ring
Oxidative ethane addition product and fatty alcohol ethylene oxide adduct.
9. fiber softener composition according to claim 8, wherein do not include cationic surfactant.
10. fiber softener composition according to claim 8, wherein the organic acid is by citric acid, acetic acid, wine
Selected in group composed by stone acid, succinic acid, malic acid and lactic acid more than one.
11. fiber softener composition according to claim 8, wherein relative to 100 weight of fiber softener composition
% is measured, the content of the organic acid is 1~30 weight %.
12. fiber softener composition according to claim 8, wherein the colored fermented vinegar is by will be by peach blossom, apricot
More than one the petal selected in group composed by flower, sophora flower, Flos Chrysanthemi, Jasmine and lotus flower is washed and is dried,
And post-fermentation is mixed with vinegar and syrup 3~7 days and obtain.
13. fiber softener composition according to claim 8, wherein in the fatty acid ethylene oxide addition product,
Fatty acid is that carbon atom number is the fatty acid on 10~20 and main chain or branch with alkyl or alkenyl.
14. fiber softener composition according to claim 8, wherein in the fatty alcohol ethylene oxide adduct,
Fatty alcohol is that carbon atom number is the fatty alcohol on 10~20 and main chain or branch with alkyl or alkenyl.
15. fiber softener composition according to claim 8, wherein the content of the solubilizer is 1~10 weight
Measure %.
16. fiber softener composition according to claim 8, wherein also include plant extracts.
17. a kind of fiber softener composition is comprising flower fermented vinegar and pKa value are 3~5 and have the organic of carboxyl
Acid, relative to 100 weight % of fiber softener composition, the content of the colored fermented vinegar is 0.001~10 weight %.
18. fiber softener composition according to claim 17, wherein the pKa value is 3~5 and with carboxyl
Organic acid is more than one selected in the group as composed by citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
19. fiber softener composition according to claim 17, wherein relative to 100 weight of fiber softener composition
% is measured, the pKa value is 3~5 and the content of the organic acid with carboxyl is 1~20 weight %.
20. fiber softener composition according to claim 17, wherein the colored fermented vinegar be by will by peach blossom,
More than one the petal selected in group composed by apricot flower, sophora flower, Flos Chrysanthemi, Jasmine and lotus flower is washed and is done
It is dry, and mix with vinegar and syrup post-fermentation 3~7 days and obtain.
21. fiber softener composition according to claim 17, wherein do not include cationic surfactant.
22. the fiber softener composition according to claim 8 or 17, wherein also include vinegar.
23. fiber softener composition according to claim 22, wherein relative to 100 weight of fiber softener composition
% is measured, the content of the vinegar is 0.1~10 weight %.
24. a kind of fiber softener composition is comprising spend fermented vinegar, relative to 100 weight of fiber softener composition
% is measured, the content of the colored fermented vinegar is 0.001~10 weight %.
25. fiber softener composition according to claim 24, wherein the colored fermented vinegar be by will by peach blossom,
More than one the petal selected in group composed by apricot flower, sophora flower, Flos Chrysanthemi, Jasmine and lotus flower is washed and is done
It is dry, and mix with vinegar and syrup post-fermentation 3~7 days and obtain.
26. fiber softener composition according to claim 25, wherein relative to 1 parts by weight of petal, the vinegar
Content be 5~30 parts by weight.
27. fiber softener composition according to claim 25, wherein relative to 1 parts by weight of petal, the syrup contains
Amount is 5~30 parts by weight.
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| KR10-2014-0021928 | 2014-02-25 | ||
| KR20140021928 | 2014-02-25 | ||
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| KR10-2014-0021927 | 2014-02-25 | ||
| KR10-2014-0052639 | 2014-04-30 | ||
| KR20140052641 | 2014-04-30 | ||
| KR10-2014-0052641 | 2014-04-30 | ||
| KR20140052639 | 2014-04-30 | ||
| KR10-2014-0102215 | 2014-08-08 | ||
| KR1020140102215A KR20150125521A (en) | 2014-04-30 | 2014-08-08 | Fabric softener composition |
| KR10-2014-0102213 | 2014-08-08 | ||
| KR1020140102213A KR20150125519A (en) | 2014-04-30 | 2014-08-08 | Fabric softener composition |
| KR1020140102207A KR20150100465A (en) | 2014-02-25 | 2014-08-08 | Fabric softener composition |
| KR10-2014-0102207 | 2014-08-08 | ||
| KR10-2014-0102206 | 2014-08-08 | ||
| KR1020140102206A KR20150100464A (en) | 2014-02-25 | 2014-08-08 | Fabric softener composition |
| KR10-2015-0025432 | 2015-02-23 | ||
| KR1020150025431A KR101637473B1 (en) | 2014-02-25 | 2015-02-23 | Fabric softener composition |
| KR10-2015-0025430 | 2015-02-23 | ||
| KR10-2015-0025429 | 2015-02-23 | ||
| KR1020150025429A KR101776681B1 (en) | 2014-02-25 | 2015-02-23 | Fabric softener composition |
| KR1020150025430A KR101780249B1 (en) | 2014-02-25 | 2015-02-23 | Fabric softener composition |
| KR10-2015-0025431 | 2015-02-23 | ||
| KR1020150025432A KR102058480B1 (en) | 2014-02-25 | 2015-02-23 | Fabric softener composition |
| PCT/KR2015/001840 WO2015130084A1 (en) | 2014-02-25 | 2015-02-25 | Composition for fabric softener |
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| EP3650523A1 (en) | 2018-11-07 | 2020-05-13 | The Procter & Gamble Company | Process for treating a fabric and related compositions |
| JP7335131B2 (en) * | 2018-11-07 | 2023-08-29 | ザ プロクター アンド ギャンブル カンパニー | Low pH fabric care composition |
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| JP6629220B2 (en) | 2020-01-15 |
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