JP6833248B2 - Fiber softener composition - Google Patents
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- JP6833248B2 JP6833248B2 JP2019095118A JP2019095118A JP6833248B2 JP 6833248 B2 JP6833248 B2 JP 6833248B2 JP 2019095118 A JP2019095118 A JP 2019095118A JP 2019095118 A JP2019095118 A JP 2019095118A JP 6833248 B2 JP6833248 B2 JP 6833248B2
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- 239000000835 fiber Substances 0.000 title claims description 99
- 239000000203 mixture Substances 0.000 title claims description 96
- 239000000052 vinegar Substances 0.000 claims description 44
- 235000021419 vinegar Nutrition 0.000 claims description 44
- 150000007524 organic acids Chemical class 0.000 claims description 39
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 26
- 229920000642 polymer Polymers 0.000 claims description 21
- 238000005406 washing Methods 0.000 claims description 21
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 20
- 239000003205 fragrance Substances 0.000 claims description 18
- 239000003093 cationic surfactant Substances 0.000 claims description 15
- 235000000346 sugar Nutrition 0.000 claims description 13
- 229920006317 cationic polymer Polymers 0.000 claims description 12
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 6
- 229920006243 acrylic copolymer Polymers 0.000 claims description 5
- 235000010254 Jasminum officinale Nutrition 0.000 claims description 4
- 240000005385 Jasminum sambac Species 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- 235000015165 citric acid Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 235000005985 organic acids Nutrition 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 229920000289 Polyquaternium Polymers 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 235000011054 acetic acid Nutrition 0.000 claims description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- 239000004310 lactic acid Substances 0.000 claims description 3
- 235000014655 lactic acid Nutrition 0.000 claims description 3
- 239000001630 malic acid Substances 0.000 claims description 3
- 235000011090 malic acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 244000144730 Amygdalus persica Species 0.000 claims description 2
- 240000008886 Ceratonia siliqua Species 0.000 claims description 2
- 235000013912 Ceratonia siliqua Nutrition 0.000 claims description 2
- 240000007472 Leucaena leucocephala Species 0.000 claims description 2
- 235000010643 Leucaena leucocephala Nutrition 0.000 claims description 2
- 240000002853 Nelumbo nucifera Species 0.000 claims description 2
- 235000006508 Nelumbo nucifera Nutrition 0.000 claims description 2
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- 244000018633 Prunus armeniaca Species 0.000 claims description 2
- 235000009827 Prunus armeniaca Nutrition 0.000 claims description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 claims description 2
- 229940070641 chamomile flowers Drugs 0.000 claims description 2
- 239000002979 fabric softener Substances 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 26
- 230000000694 effects Effects 0.000 description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 229910000019 calcium carbonate Inorganic materials 0.000 description 13
- 230000008719 thickening Effects 0.000 description 13
- 239000003599 detergent Substances 0.000 description 10
- 229960000583 acetic acid Drugs 0.000 description 7
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- 230000001965 increasing effect Effects 0.000 description 6
- 238000000034 method Methods 0.000 description 6
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- 230000000052 comparative effect Effects 0.000 description 5
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- 239000003242 anti bacterial agent Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 239000002518 antifoaming agent Substances 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- -1 guagam Chemical compound 0.000 description 3
- 229940093915 gynecological organic acid Drugs 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 239000008213 purified water Substances 0.000 description 3
- 239000008237 rinsing water Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000207199 Citrus Species 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000013305 food Nutrition 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 229920001542 oligosaccharide Polymers 0.000 description 2
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- 230000035807 sensation Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
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- 150000008163 sugars Chemical class 0.000 description 2
- 239000006188 syrup Substances 0.000 description 2
- 235000020357 syrup Nutrition 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- JVTIXNMXDLQEJE-UHFFFAOYSA-N 2-decanoyloxypropyl decanoate 2-octanoyloxypropyl octanoate Chemical compound C(CCCCCCC)(=O)OCC(C)OC(CCCCCCC)=O.C(=O)(CCCCCCCCC)OCC(C)OC(=O)CCCCCCCCC JVTIXNMXDLQEJE-UHFFFAOYSA-N 0.000 description 1
- OSCJHTSDLYVCQC-UHFFFAOYSA-N 2-ethylhexyl 4-[[4-[4-(tert-butylcarbamoyl)anilino]-6-[4-(2-ethylhexoxycarbonyl)anilino]-1,3,5-triazin-2-yl]amino]benzoate Chemical compound C1=CC(C(=O)OCC(CC)CCCC)=CC=C1NC1=NC(NC=2C=CC(=CC=2)C(=O)NC(C)(C)C)=NC(NC=2C=CC(=CC=2)C(=O)OCC(CC)CCCC)=N1 OSCJHTSDLYVCQC-UHFFFAOYSA-N 0.000 description 1
- WLAMNBDJUVNPJU-UHFFFAOYSA-N 2-methylbutyric acid Chemical compound CCC(C)C(O)=O WLAMNBDJUVNPJU-UHFFFAOYSA-N 0.000 description 1
- 241000589234 Acetobacter sp. Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 235000011511 Diospyros Nutrition 0.000 description 1
- 244000236655 Diospyros kaki Species 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000010227 chenpi Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 230000003749 cleanliness Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 235000009569 green tea Nutrition 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
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- 230000004060 metabolic process Effects 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 244000005714 skin microbiome Species 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
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- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
- Fats And Perfumes (AREA)
Description
本発明は、繊維柔軟剤組成物に関する。 The present invention relates to a fiber softener composition.
繊維柔軟剤は、衣類に発生する静電気を防止し、繊維の柔軟性を付与するために家庭で広く使用しており、その使用量が次第に増加している傾向にある。最近、消費者の生活水準が向上し、衛生及び清潔に対する欲求が増加し、より快適な衣生活を追求しようとするにつれて、衣類に発生し得る微生物の増殖防止及び悪臭除去に対する関心が増えている。 Fiber softeners are widely used at home to prevent static electricity generated in clothing and to impart fiber flexibility, and the amount used tends to be gradually increasing. Recently, as consumers' living standards have improved, their desire for hygiene and cleanliness has increased, and their pursuit of a more comfortable clothing life has increased, there has been increasing interest in preventing the growth of microorganisms that can occur in clothing and eliminating malodors. ..
一般的に、繊維に発生する湿っぽい臭いは、汗の臭い等の成分である有機化合物が、皮膚常在菌が分解されて生成された不飽和低級脂肪酸及びアンモニア等の揮発性有機化合物と反応するか、洗濯洗剤または繊維柔軟剤の残留成分と反応して発生し得る。特に、梅雨時の場合、室内乾燥時に、乾燥時間が遅延されるため、悪臭菌であるＭｏｒｘｅｌｌａ ａｓｌｏｅｎｓｉｓに起因して湿っぽい臭いがさらに発生しているものと知られている。 Generally, in the moist odor generated in fibers, organic compounds that are components such as sweat odor react with unsaturated lower fatty acids and volatile organic compounds such as ammonia produced by decomposition of indigenous skin bacteria. Or it can occur by reacting with residual components of laundry detergent or fabric softener. In particular, in the case of the rainy season, it is known that a moist odor is further generated due to the malodorous bacterium Morxella asloensis because the drying time is delayed during indoor drying.
このような湿っぽい臭い等を除去するために、従来、抗菌剤を含む繊維柔軟剤組成物を使用したが、従来の繊維柔軟剤に含まれる抗菌剤は、人体に有害である。最近、合成抗菌剤の使用時に、人体に有害であるという内容が報道され、このような抗菌剤の使用が忌避されていることが現況である。 Conventionally, a fiber softener composition containing an antibacterial agent has been used in order to remove such a damp odor, but the antibacterial agent contained in the conventional fiber softener is harmful to the human body. Recently, it has been reported that the use of synthetic antibacterial agents is harmful to the human body, and the current situation is that the use of such antibacterial agents is avoided.
また、繊維柔軟剤は、１９５０年代に全世界的に商用化された後、６０年以上柔軟成分として陽イオン界面活性剤を使用している「韓国公開特許第１０−２００７−００９０８６１号」。しかし、近年、このような陽イオン界面活性剤の人体有害性が明らかにされ、これを忌避しようとする欲求が増加している。 In addition, the fiber softener is "Korean Published Patent No. 10-2007-090861" which has used a cationic surfactant as a softening ingredient for more than 60 years after being commercialized worldwide in the 1950s. However, in recent years, the harmful effects of such cationic surfactants on the human body have been clarified, and the desire to avoid them has increased.
また、繊維柔軟剤は、粘度が高ければ、洗濯水で有機酸の拡散（溶解）が遅くなって、充分に有機酸の効力を発揮できないという短所がある。 Further, the fiber softener has a disadvantage that if the viscosity is high, the diffusion (dissolution) of the organic acid is delayed in the washing water, and the effect of the organic acid cannot be sufficiently exhibited.
本発明は、従来の繊維柔軟剤組成物に柔軟成分として含まれた陽イオン界面活性剤を使用せず、有機酸を添加し、且つ、増粘用ポリマーを使用して有機酸の溶解性を向上させ、衣類内に残存する洗剤不溶性成分である炭酸カルシウムの溶解及び除去効果に優れた繊維柔軟剤組成物を提供することを目的とする。 The present invention does not use the cationic surfactant contained as a softening component in the conventional fiber softener composition, adds an organic acid, and uses a thickening polymer to improve the solubility of the organic acid. It is an object of the present invention to provide a fiber softener composition which is improved and has an excellent effect of dissolving and removing calcium carbonate, which is a detergent-insoluble component remaining in clothing.
また、本発明は、従来の繊維柔軟剤組成物に通常香キャリアとして含まれた陽イオン界面活性剤を使用せず、陽イオン性ポリマーを使用して、残香を強化させた繊維柔軟剤組成物を提供することを目的とする。 Further, the present invention does not use the cationic surfactant normally contained as a scent carrier in the conventional fiber softener composition, but uses a cationic polymer to enhance the residual scent. The purpose is to provide.
前記目的を達成するために、本発明は、有機酸と増粘用ポリマーを含み、回転用粘度計で２５℃、６０ｒｐｍで測定された粘度が１〜２５０ｃＰｓである繊維柔軟剤組成物を提供する。 In order to achieve the above object, the present invention provides a fiber softener composition containing an organic acid and a thickening polymer and having a viscosity measured at 25 ° C. and 60 rpm with a rotating viscometer of 1 to 250 cPs. ..
また、本発明は、陽イオン界面活性剤を含まず、陽イオン性ポリマーと；有機酸と；香料とを含む残香強化用繊維柔軟剤組成物を提供する。 The present invention also provides a fiber softener composition for enhancing residual aroma, which does not contain a cationic surfactant and contains a cationic polymer; an organic acid; and a fragrance.
本発明による繊維柔軟剤組成物は、有機酸を使用し、且つ、増粘用ポリマーを付加して短い洗い／すすぎ時間に有機酸の溶解性を向上させて、衣類内に残存する洗剤不溶性成分である炭酸カルシウムの溶解及び除去に非常に効果的である。 The fiber softener composition according to the present invention uses an organic acid and adds a thickening polymer to improve the solubility of the organic acid in a short wash / rinse time, and the detergent-insoluble component remaining in the clothes. It is very effective in dissolving and removing calcium carbonate.
本発明による繊維柔軟剤組成物は、通常の香キャリアとして作用して、残香に影響を与えながら、人体に有害な陽イオン界面活性剤の代わりに、陽イオン性ポリマー及び有機酸を使用して、人体に有害でなく、既存の陽イオン界面活性剤を使用した繊維柔軟剤より残香を強化させることができる。 The fiber softener composition according to the present invention uses a cationic polymer and an organic acid instead of the cationic surfactant which is harmful to the human body while acting as a normal incense carrier and affecting the residual aroma. , It is not harmful to the human body, and the residual scent can be strengthened more than the fiber softener using the existing cationic surfactant.
本発明は、有機酸と増粘用ポリマーを含み、回転用粘度計で２５℃、６０ｒｐｍで測定された粘度が１〜２５０ｃＰｓである繊維柔軟剤組成物（以下、第１繊維柔軟剤組成物という）に関する。 The present invention contains a fiber softener composition containing an organic acid and a thickening polymer, and has a viscosity of 1 to 250 cPs measured at 25 ° C. and 60 rpm with a rotating viscometer (hereinafter referred to as a first fiber softener composition). ).
粘度が高ければ、洗濯水に有機酸の拡散（溶解）が遅くなって、充分に有機酸の効力を発揮できないため、本発明の繊維柔軟剤組成物は、有機酸に増粘用ポリマーを付加して、短い洗い／すすぎ時間に有機酸の溶解性を向上させたものであることを特徴とする。 If the viscosity is high, the diffusion (dissolution) of the organic acid in the washing water becomes slow and the effect of the organic acid cannot be sufficiently exerted. Therefore, the fiber softener composition of the present invention adds a thickening polymer to the organic acid. Therefore, it is characterized in that the solubility of the organic acid is improved in a short washing / rinsing time.
本発明において有機酸は、洗剤残渣、具体的に炭酸カルシウム除去役目を行う。また、前記有機酸は、柔軟剤本然の（布を柔らかくし、触感を良好にする）役目を行う。 In the present invention, the organic acid serves to remove detergent residue, specifically calcium carbonate. In addition, the organic acid acts as a softener (softens the cloth and improves the tactile sensation).
前記有機酸は、例えば、クエン酸、酢酸、酒石酸、コハク酸、リンゴ酸または乳酸等を１つ以上使用できるが、特にこれに制限されるものではない。好ましくは、有機酸は、クエン酸であることができる。前記クエン酸は、原材料費のコストが低いため、繊維柔軟剤組成物の生産コストを節減できる。 As the organic acid, for example, one or more citric acid, acetic acid, tartaric acid, succinic acid, malic acid, lactic acid and the like can be used, but the organic acid is not particularly limited thereto. Preferably, the organic acid can be citric acid. Since the citric acid has a low raw material cost, the production cost of the fiber softener composition can be reduced.
前記有機酸の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して５〜３０重量％、さらに具体的に、１０〜２５重量％、より具体的に、１５〜２０重量％で含まれることができる。前記範囲内で優れた炭酸カルシウム除去効果を示すことができる。有機酸の含量が３０重量％を超過する場合でも、優れた炭酸カルシウム除去効果を示すが、有機酸の含量が高くなるほど、すすぎ水のｐＨが低くなるので、３０重量％以下で使用することが良い。 The content of the organic acid is not particularly limited, and is 5 to 30% by weight, more specifically 10 to 25% by weight, more specifically 15 to 20% by weight, based on 100% by weight of the fiber softener composition. Can be included in. An excellent calcium carbonate removing effect can be exhibited within the above range. Even when the content of organic acid exceeds 30% by weight, it shows an excellent calcium carbonate removing effect, but the higher the content of organic acid, the lower the pH of the rinse water, so it can be used at 30% by weight or less. good.
本発明の繊維柔軟剤組成物は、有機酸の溶解性を向上させることができるように粘度を調節できる増粘用ポリマーを含む。本発明において、前記増粘用ポリマーとして、カルシウム−カルボキシメチルセルロース、メチルセルロース／ヒドロキシプロピルメチルセルロース、ヒドロキシエチルセルロース、カーボポール９３４（ｃａｒｂｏｐｏｌ ９３４）、カーボポール９４１（ｃａｒｂｏｐｏｌ ９４１）、キサンタンガム、アルギン酸ナトリウム、グアガム、カラギナン、ペクチン、アクリル系ポリマー等を使用できる。好ましくは、アクリル酸ポリマー類及びアクリルコポリマー、アクリル化シリコン系よりなる群から選択された１つ以上のアクリル系ポリマーが良い。 The fiber softener composition of the present invention comprises a thickening polymer whose viscosity can be adjusted so as to improve the solubility of organic acids. In the present invention, the thickening polymer includes calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropyl methyl cellulose, hydroxyethyl cellulose, carbopol 934, carbopol 941, xanthan gum, sodium alginate, guagam, carrageenan, and the like. Pectin, acrylic polymer, etc. can be used. Preferably, one or more acrylic polymers selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylicized silicon-based polymers are preferable.
前記増粘用ポリマーの含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．０１〜１．２重量％、より具体的に、０．０５〜１重量％で含まれることができる。前記範囲内で有機酸の溶解性が向上し、炭酸カルシウム除去効果に優れている。 The content of the thickening polymer is not particularly limited, and is contained in an amount of 0.01 to 1.2% by weight, more specifically 0.05 to 1% by weight, based on 100% by weight of the fiber softener composition. be able to. Within the above range, the solubility of organic acids is improved, and the effect of removing calcium carbonate is excellent.
また、前記増粘用ポリマーは、本発明の繊維柔軟剤組成物の粘度を制御する要因になり、より具体的に、回転型粘度計で２５℃、６０ｒｐｍで測定する場合、粘度は、１〜２５０ｃＰｓであることができる。前記粘度が２５０ｃＰｓを超過した場合、洗い／すすぎ水内で有機酸の拡散溶解性が劣り、衣類内に残存する炭酸カルシウムの除去が容易でないことがある。 Further, the thickening polymer becomes a factor for controlling the viscosity of the fiber softener composition of the present invention, and more specifically, when measured with a rotary viscometer at 25 ° C. and 60 rpm, the viscosity is 1 to 1. It can be 250 cPs. When the viscosity exceeds 250 cPs, the diffusion solubility of the organic acid in the washing / rinsing water is inferior, and it may not be easy to remove the calcium carbonate remaining in the clothes.
本発明による組成物は、有機酸と増粘用ポリマーを使用することによって、陽イオン界面活性剤を含まなくても、洗剤残渣の除去効果に優れ、繊維柔軟剤として容易に使用できる。 By using an organic acid and a thickening polymer, the composition according to the present invention has an excellent effect of removing detergent residue even if it does not contain a cationic surfactant, and can be easily used as a fiber softener.
一具体例において、本発明による繊維柔軟剤組成物を洗い／すすぎ水に提供する場合、衣類に残存する炭酸カルシウムを完全に除去した。 In one specific example, when the fiber softener composition according to the present invention was provided in washing / rinsing water, calcium carbonate remaining on clothing was completely removed.
また、本発明は、陽イオン界面活性剤を含まず、陽イオン性ポリマーと；有機酸と；香料とを含む残香強化用繊維柔軟剤組成物（以下、第２繊維柔軟剤組成物という）に関する。 The present invention also relates to a fiber softener composition for strengthening residual aroma (hereinafter referred to as a second fiber softener composition) containing a cationic polymer, an organic acid, and a fragrance without containing a cationic surfactant. ..
本発明において陽イオン性ポリマーは、残香を強化させる役目を行う。前記陽イオン性ポリマーは、グルコース系ポリマー、アクリル系ポリマーよりなる群から選択された１つ以上あることができるが、残香強化役目をする陽イオン性ポリマーなら、本発明の効果を阻害しない範囲内で制限なしに使用され得る。前記グルコース系ポリマーは、ポリクオタニウム、グア、スターチ及びローカストビーン系よりなる群から選択された１つ以上あることができるが、これに制限されない。前記アクリル系ポリマーは、アクリル酸ポリマー、アクリルコポリマー及びアクリル化シリコンよりなる群から選択された１つ以上あることができるが、これに制限されない。 In the present invention, the cationic polymer serves to enhance the residual aroma. The cationic polymer may be one or more selected from the group consisting of a glucose-based polymer and an acrylic-based polymer, but a cationic polymer having a residual scent enhancing role does not impair the effect of the present invention. Can be used without limitation. The glucose-based polymer can be, but is not limited to, one or more selected from the group consisting of polyquaternium, gua, starch and locust bean. The acrylic polymer can be, but is not limited to, one or more selected from the group consisting of acrylic acid polymers, acrylic copolymers and acrylicized silicon.
前記陽イオン性ポリマーの含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．１〜３重量％、０．２〜２重量％または０．３〜１重量％で含まれることができる。前記範囲内で優れた残香強化役目をし、粘度上昇効果にも効率的である。 The content of the cationic polymer is not particularly limited and is contained in an amount of 0.1 to 3% by weight, 0.2 to 2% by weight or 0.3 to 1% by weight based on 100% by weight of the fiber softener composition. Can be It has an excellent residual scent enhancing role within the above range, and is also efficient in increasing the viscosity.
本発明において有機酸は、脱臭剤及び洗剤残渣の除去の役目を行う。また、前記有機酸は、柔軟剤本然の（布を柔らかくし、触感を良好にする）役目を行う。このような有機酸の種類は、特に制限されず、例えば、クエン酸、酢酸、酒石酸、コハク酸、リンゴ酸及び乳酸よりなる群から選択された１つ以上を含むことができる。特に、クエン酸は、原材料費のコストが低いため、有機酸として使用するに適している。 In the present invention, the organic acid serves to remove the deodorant and the detergent residue. In addition, the organic acid acts as a softener (softens the cloth and improves the tactile sensation). The type of such an organic acid is not particularly limited and may include, for example, one or more selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid. In particular, citric acid is suitable for use as an organic acid because of its low raw material cost.
前記有機酸の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して１〜２０重量％、５〜１５重量％または８〜１２重量％で含まれることができる。前記範囲内で優れた洗濯不溶分成分の洗剤残渣の除去効果を示すことができる。有機酸の含量が２０重量％以上でも、優れた洗濯不溶分成分の洗剤残渣の除去効果を示すが、有機酸の含量が高くなるほど、すすぎ水のｐＨが低くなるため、２０重量％以下で使用したことが良い。 The content of the organic acid is not particularly limited and may be 1 to 20% by weight, 5 to 15% by weight or 8 to 12% by weight based on 100% by weight of the fiber softener composition. Within the above range, an excellent effect of removing the detergent residue of the washing insoluble component can be exhibited. Even if the content of the organic acid is 20% by weight or more, the effect of removing the detergent residue of the washing insoluble component is excellent, but the higher the content of the organic acid, the lower the pH of the rinse water, so use it at 20% by weight or less. It's good to have done it.
本発明において香料は、例えば、フロラール系香料、シトラス系香料等を含むことができるが、そのほか、繊維柔軟剤として使用できるものなら、本発明の効果を阻害しない範囲内で制限なしに使用され得る。前記香料の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．１〜３重量％、０．２〜２重量％または０．３〜１重量％で含まれることができる。前記範囲を脱すれば、残香があまり低いか、あまり高い問題点がある。 In the present invention, the fragrance may include, for example, a floral fragrance, a citrus fragrance, etc., but other fragrances can be used without limitation as long as they can be used as a fiber softener, as long as the effects of the present invention are not impaired. .. The content of the fragrance is not particularly limited and may be contained in an amount of 0.1 to 3% by weight, 0.2 to 2% by weight or 0.3 to 1% by weight based on 100% by weight of the fiber softener composition. it can. If it goes out of the above range, there is a problem that the residual scent is too low or too high.
本発明の繊維柔軟剤組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）に、酢が追加に使用され得る。 Vinegar can be additionally used in the fiber softener composition of the present invention (first fiber softener composition or second fiber softener composition).
酢は、主成分として酢酸を含有し、酸っぱくて、少し甘味がある調味料であって、酢酸、クエン酸及び各種アミノ酸等、数十種類の有機酸が入っていて、新陳代謝を活発にさせ、体内老廃物を無くすのに役立つだけでなく、強力な防腐剤であり且つ強力な殺菌剤としての役目を行う。また、酢は、洗剤残渣の除去役目を行うことができる。 Vinegar is a seasoning that contains acetic acid as the main component and is sour and has a slight sweetness. It contains dozens of organic acids such as acetic acid, citric acid and various amino acids, and activates metabolism. Not only does it help eliminate waste products in the body, it also acts as a powerful preservative and a powerful bactericide. In addition, vinegar can serve to remove detergent residues.
前記酢の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．１〜１０重量％、０．５〜５重量％または１〜３重量％で含まれることができる。前記範囲内で殺菌効果及び洗剤残渣を除去する効果を有する。 The content of the vinegar is not particularly limited and can be contained in an amount of 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight based on 100% by weight of the fiber softener composition. It has a bactericidal effect and an effect of removing detergent residue within the above range.
本発明による繊維柔軟剤組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）は、前述した組成成分以外に、強力な脱臭の役目を担当する花発酵酢をさらに含むことができる。 The fiber softener composition according to the present invention (first fiber softener composition or second fiber softener composition) may further contain fermented flower vinegar, which is responsible for a strong deodorizing role, in addition to the above-mentioned composition components. it can.
前記花発酵酢は、花びらを水洗及び乾燥し、過量の酢及び糖水と混合し、３日〜７日間発酵させて得たものであることができる。 The flower fermented vinegar can be obtained by washing and drying the petals with water, mixing with an excess amount of vinegar and sugar water, and fermenting the petals for 3 to 7 days.
前記酢は、市販の醸造酢であることができ、花びら１重量部に対して５〜３０重量部使用することが好ましい。また、前記糖水をブドウ糖、砂糖、果糖、オリゴ糖、または水飴等各種糖を含むものであることができる。前記糖水は、花抽出物をアルコール発酵させる役目をし、花びら１重量部に対して５〜３０重量部を使用することが好ましい。 The vinegar can be a commercially available brewed vinegar, and it is preferable to use 5 to 30 parts by weight with respect to 1 part by weight of the petals. In addition, the sugar water may contain various sugars such as glucose, sugar, fructose, oligosaccharides, and starch syrup. The sugar water serves to ferment the flower extract with alcohol, and it is preferable to use 5 to 30 parts by weight with respect to 1 part by weight of the petals.
または、前記花発酵酢は、花の原物を滅菌し、１００〜１５０℃で１０〜３０分間熱水抽出した後、前記の熱水抽出物と種酢及び糖水を混合した後、２０〜４０℃で７２〜９６時間発酵過程を経て得ることができる。 Alternatively, the fermented flower vinegar is obtained by sterilizing the original flower, extracting it with hot water at 100 to 150 ° C. for 10 to 30 minutes, mixing the hot water extract with seed vinegar and sugar water, and then 20 to 40. It can be obtained through a fermentation process at ° C. for 72 to 96 hours.
前記種酢は、伝統方式で製造された異味、異臭がない醸造酢から分離した野生酢菌を増殖させて発酵させたものを言い、前記種酢は、野生酢酸菌アセトバクター菌（Ａｃｅｔｏｂａｃｔｅｒ ｓｐ．）によって製造され得るものであれば、すべて使用され得る。この際、前記種酢の添加量は、花熱水抽出物１００重量％に対して５〜３０重量％で添加され得る。前記種酢の添加量が５重量％未満の場合、前記熟成された花熱水抽出物の酢発酵を誘導しにくく、３０重量％を超過する場合、添加量に比べて、酢発酵の効率がこれ以上増加しない。 The seed vinegar refers to a product obtained by growing and fermenting wild vinegar separated from brewed vinegar that has no offensive taste or odor produced by a traditional method, and the seed vinegar refers to wild acetic acid bacterium Acetobacter sp. ) Can be used as long as it can be manufactured. At this time, the seed vinegar can be added in an amount of 5 to 30% by weight based on 100% by weight of the hot water extract. When the amount of the seed vinegar added is less than 5% by weight, it is difficult to induce vinegar fermentation of the aged flower hot water extract, and when it exceeds 30% by weight, the efficiency of vinegar fermentation is higher than that of the added amount. It will not increase any more.
前記糖水をブドウ糖、砂糖、果糖、オリゴ糖、または水飴等各種糖を含むものであることができる。前記糖水は、花熱水抽出物をアルコール発酵させる役目をし、花熱水抽出物１００重量％に対して５〜３０重量％で添加され得る。 The sugar water can contain various sugars such as glucose, sugar, fructose, oligosaccharides, and starch syrup. The sugar water serves to alcohol-ferment the hot water extract, and can be added in an amount of 5 to 30% by weight based on 100% by weight of the hot water extract.
前記方法を通じて製造された花発酵酢は、ｐＨが２．７０〜３．３０、酸度は、３〜７を有することができる。 The flower fermented vinegar produced through the above method can have a pH of 2.70 to 3.30 and an acidity of 3 to 7.
前記花発酵酢の製造に使用する花の種類は、制限なしに使用できる。一例として、桃の花、杏の花、アカシアの花、カモミールの花、ジャスミンの花または蓮の花等を使用できる。 The type of flower used for producing the fermented flower vinegar can be used without limitation. As an example, peach flowers, apricot flowers, acacia flowers, chamomile flowers, jasmine flowers, lotus flowers and the like can be used.
前記花発酵酢の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．００１〜１０重量％、０．０５〜５重量％または０．１〜２重量％で含まれることができる。前記範囲内で殺菌作用及び臭いを除去する効果を有する。 The content of the fermented flower vinegar is not particularly limited and is contained in an amount of 0.001 to 10% by weight, 0.05 to 5% by weight or 0.1 to 2% by weight based on 100% by weight of the fiber softener composition. be able to. It has a bactericidal action and an effect of removing odor within the above range.
また、本発明による繊維柔軟剤組成物（第１または第２繊維柔軟剤組成物）は、内容物の相安定性のためにエタノールをさらに含むことができる。 In addition, the fiber softener composition according to the present invention (first or second fiber softener composition) may further contain ethanol for the phase stability of the contents.
前記エタノールの含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．１〜１０重量％、０．５〜８重量％または１〜７重量％で含まれることができる。前記範囲内で優れた内容物の相安定性効果を有する。 The content of the ethanol is not particularly limited and may be 0.1 to 10% by weight, 0.5 to 8% by weight or 1 to 7% by weight based on 100% by weight of the fiber softener composition. It has an excellent phase stability effect of the contents within the above range.
また、本発明による繊維柔軟剤組成物（第１または第２繊維柔軟剤組成物）は、香料を追加に使用できる。前記香料は、例えば、フロラール系香料、シトラス系香料等を含むことができるが、その他、繊維柔軟剤として使用できるものであれば、本発明の効果を阻害しない範囲内で制限なしに使用され得る。前記香料の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．０１〜５重量％または０．１〜３重量％で含まれることができる。 In addition, the fiber softener composition according to the present invention (first or second fiber softener composition) can additionally use a fragrance. The fragrance may contain, for example, a floral fragrance, a citrus fragrance, etc., but can be used without limitation as long as it can be used as a fiber softener, as long as it does not impair the effects of the present invention. .. The content of the fragrance is not particularly limited and may be contained in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fiber softener composition.
また、本発明による繊維柔軟剤組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）は、香可溶化剤を追加に使用でき、香可溶化剤は、発酵酢等による酢臭いを緩和させて、繊維柔軟剤の香り満足度を向上させる。その含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．１〜１０重量％または１〜７重量％で含まれることができる。 Further, the fiber softener composition according to the present invention (first fiber softener composition or second fiber softener composition) can additionally use a scent solubilizer, and the scent solubilizer is vinegar made from fermented vinegar or the like. It reduces the odor and improves the scent satisfaction of the fiber softener. The content is not particularly limited and can be contained in an amount of 0.1 to 10% by weight or 1 to 7% by weight based on 100% by weight of the fiber softener composition.
また、本発明による繊維柔軟剤組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）は、酢臭い等の悪臭除去効果を向上させるために、植物抽出物をさらに含むことができる。前記植物抽出物は、柿の葉、緑茶及び陳皮よりなるグループから選択された１つ以上を含むことができる。 In addition, the fiber softener composition according to the present invention (first fiber softener composition or second fiber softener composition) may further contain a plant extract in order to improve the effect of removing malodor such as vinegar odor. it can. The plant extract may contain one or more selected from the group consisting of persimmon leaves, green tea and chenpi.
また、本発明による繊維柔軟剤組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）には、本発明の目的範囲内で少量の添加剤がさらに含まれることができる。前記添加剤としては、抗菌効果をさらに向上させるための抗菌成分であることができ、その他、色素、防腐剤、酸化防止剤、消泡剤等であることができる。添加剤の含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して０．０１〜５重量％または０．１〜３重量％で含まれることができる。 In addition, the fiber softener composition according to the present invention (first fiber softener composition or second fiber softener composition) can further contain a small amount of additives within the scope of the object of the present invention. The additive can be an antibacterial component for further improving the antibacterial effect, and can also be a pigment, a preservative, an antioxidant, an antifoaming agent, or the like. The content of the additive is not particularly limited and may be contained in an amount of 0.01 to 5% by weight or 0.1 to 3% by weight based on 100% by weight of the fiber softener composition.
また、本発明の組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）は、それぞれの剤形に前記記載した成分以外に、一般的に繊維柔軟剤に配合される油分、水、界面活性剤、保湿剤、低級アルコール、増粘剤、キレート剤、色素、防腐剤等を必要に応じて適宜配合して使用できる。その含量は、特に制限されず、繊維柔軟剤組成物１００重量％に対して５５〜９０重量％または６０〜８５重量％で含まれることができる。 Further, the composition of the present invention (first fiber softener composition or second fiber softener composition) is an oil component generally blended in a fiber softener, in addition to the components described above in each dosage form. Water, surfactants, moisturizers, lower alcohols, thickeners, chelating agents, pigments, preservatives and the like can be appropriately blended and used as needed. The content is not particularly limited and can be contained in an amount of 55 to 90% by weight or 60 to 85% by weight based on 100% by weight of the fiber softener composition.
本発明による組成物（第１繊維柔軟剤組成物または第２繊維柔軟剤組成物）は、当業界に公知された方法を利用して、粉末化や顆粒化して使用でき、液体状態で製造して使用できる。 The composition according to the present invention (first fiber softener composition or second fiber softener composition) can be powdered or granulated and used in a liquid state by using a method known in the art. Can be used.
参考例１〜６及び参考例１’〜２’
下記表１の組成及び含量を有する繊維柔軟剤組成物を製造した。
Reference Examples 1 to 6 and Reference Examples 1'to 2'
A fiber softener composition having the composition and content shown in Table 1 below was produced.
まず、精製水に増粘用ポリマーを入れ、完全溶解時まで撹拌した後、これにクエン酸、花発酵酢及び酢を入れた後、３０分間撹拌し、これにエタノール、香料、添加剤をあらかじめ溶解した溶液を投入し、３０分撹拌して製造した。 First, the thickening polymer is added to purified water and stirred until it is completely dissolved, then citric acid, flower fermented vinegar and vinegar are added thereto, and then the mixture is stirred for 30 minutes, to which ethanol, fragrance and additives are added in advance. The dissolved solution was added and stirred for 30 minutes to produce.
前記添加剤として香可溶化剤（５重量％）と消泡剤（０．０５重量％）の混合を使用し、増粘用ポリマーとしては、アクリルコポリマー（ＢＡＳＦ社のＲｈｅｏｖｉｓ ＦＲＣ）を使用し、有機酸としてクエン酸を使用した。 A mixture of a fragrance solubilizer (5% by weight) and an antifoaming agent (0.05% by weight) was used as the additive, and an acrylic copolymer (BASF's Rheovis FRC) was used as the thickening polymer. Citric acid was used as the organic acid.
酢は、醸造酢（天然食品）を使用した。 As the vinegar, brewed vinegar (natural food) was used.
花発酵酢は、ジャスミンの花びらを水洗し、乾燥した後、花びら１重量部に対して酢１５重量部及び糖水１５重量部を前記乾燥した花びらと混合し、約７日間自然発酵過程を経て得たもの使用した。 The flower fermented vinegar is obtained by washing the jasmine petals with water, drying the petals, mixing 15 parts by weight of vinegar and 15 parts by weight of sugar water with the dried petals, and passing through a natural fermentation process for about 7 days. I used vinegar.
洗濯衣類としてＫＳ Ｋ ０９０５に規定された白色標準綿布（１０×１０ｃｍ）３枚を使用し、使用された洗濯洗剤は、ＬＧ生活健康テックを使用した。 Three white standard cotton cloths (10 x 10 cm) specified in KS K 0905 were used as laundry clothes, and LG Household & Health Care Tech was used as the laundry detergent.
実験例１：洗濯後に衣類内に残存する炭酸カルシウムの濃度測定
前記製造された参考例の繊維柔軟剤組成物を使用して洗濯後に衣類内に残存する炭酸カルシウムの濃度を測定した。
Experimental Example 1: Measurement of the concentration of calcium carbonate remaining in clothes after washing The concentration of calcium carbonate remaining in clothes after washing was measured using the fiber softener composition of the above-mentioned reference example.
洗濯実験条件は、韓国環境産業技術院の環境標識認証基準のうちＥＬ３０６（繊維柔軟剤）内の試験方法に準じ、最後のすすぎ時に組成物の使用量は、０．６７ｍＬ／Ｌであった。 The washing experiment conditions conformed to the test method in EL306 (fiber softener) in the environmental label certification standard of the Korea Environmental Industry & Technology Institute, and the amount of the composition used at the final rinse was 0.67 mL / L.
洗濯後に衣類内の炭酸カルシウム残留量に対する分析方法は、前記洗濯試験条件で進行された試験布を０．５ｇ分取して、塩酸／フッ酸／硝酸／ホウ酸の混合液で酸処理した後、２４時間抽出し、ＩＣＰ（高周波誘導結合プラズマ）を利用して分析した。 The method of analyzing the residual amount of calcium carbonate in the clothes after washing is as follows: 0.5 g of the test cloth proceeded under the washing test conditions is taken and acid-treated with a mixed solution of hydrochloric acid / hydrofluoric acid / nitric acid / boric acid. , Extracted for 24 hours and analyzed using ICP (Inductively Coupled Plasma).
前記衣類内の残存炭酸カルシウム濃度測定結果を下記表２に示した。 The results of measuring the residual calcium carbonate concentration in the clothes are shown in Table 2 below.
また、組成物の粘度は、Ｂｒｏｏｋｆｉｅｌｄ回転型粘度計で２５℃、６０ｒｐｍで測定した。 The viscosity of the composition was measured at 25 ° C. and 60 rpm with a Brookfield rotary viscometer.
表２に示されたように、増粘用ポリマー使用含量によって粘度が約２５０ｃＰｓを超過する場合、洗い／すすぎ水内で有効成分の拡散溶解性が劣り、衣類内の残存炭酸カルシウムの除去が容易でないことが分かった。 As shown in Table 2, when the viscosity exceeds about 250 cPs depending on the content of the thickening polymer used, the diffusion solubility of the active ingredient is inferior in washing / rinsing water, and residual calcium carbonate in clothing can be easily removed. It turned out not.
実施例７〜１０
下記表３の組成及び含量を有する繊維柔軟剤組成物を製造した。
Examples 7-10
A fiber softener composition having the composition and content shown in Table 3 below was produced.
まず、精製水に陽イオン性ポリマー、花発酵酢、酢、クエン酸を入れ、３０分間撹拌した後、これにエタノール、香料、香可溶化剤及び消泡剤を溶解した溶液を投入し、３０分間撹拌し、繊維柔軟剤組成物を製造した。 First, a cationic polymer, fermented flower vinegar, vinegar, and citric acid are added to purified water, and the mixture is stirred for 30 minutes. Stirring for 1 minute to produce a fiber softener composition.
また、グルコース系ポリマーは、市中で購入可能なポリクオタニウム「ＤＯＷ Ｃｈｅｍｉｃａｌ社のＰｏｌｙｍｅｒ ＬＲ３０Ｍ」を、アクリル系ポリマーは、市中に販売されるアクリルコポリマー「ＢＡＳＦ社のＲｈｅｏｖｉｓ ＦＲＣ」を使用した。 As the glucose-based polymer, polyquaternium "DOW Chemical's Polymer LR30M" that can be purchased in the market was used, and as the acrylic polymer, the acrylic copolymer "BASF's Rheovis FRC" sold in the market was used.
また、酢は、醸造酢（天然食品）を使用した。 As the vinegar, brewed vinegar (natural food) was used.
また、花発酵酢は、ジャスミンの花びらを水洗して乾燥した後、花びら１重量部に対して酢１５重量部及び糖水１５重量部を前記乾燥した花びらと混合し、約７日間自然発酵過程を経て得たものを使用した。 For the flower fermented vinegar, after washing the jasmine petals with water and drying, 15 parts by weight of vinegar and 15 parts by weight of sugar water are mixed with the dried petals with respect to 1 part by weight of the petals, and the natural fermentation process is carried out for about 7 days. I used the one obtained through the process.
比較例３
繊維柔軟剤組成物の代わりに、指標繊維柔軟剤を使用した。
前記指標繊維柔軟剤組成物は、韓国環境産業技術院の環境標識認証基準のうちＥＬ３０６（繊維柔軟剤）試験方法のうち指標繊維柔軟剤組成物と同一であった。
Comparative Example 3
An index fiber softener was used instead of the fiber softener composition.
The index fiber softener composition was the same as the index fiber softener composition in the EL306 (fiber softener) test method in the environmental label certification standard of the Korea Institute of Environmental Industry Technology.
比較例４
下記表３の組成及び含量を有する繊維柔軟剤組成物を製造した。
まず、精製水に陽イオン界面活性剤を入れ、３０分間撹拌した後、これにエタノール、香料、香可溶化剤及び消泡剤を溶解した溶液を投入し、３０分間撹拌し、繊維柔軟剤組成物を製造した。
Comparative Example 4
A fiber softener composition having the composition and content shown in Table 3 below was produced.
First, a cationic surfactant is added to purified water and stirred for 30 minutes, then a solution in which ethanol, a fragrance, a fragrance solubilizer and an antifoaming agent are dissolved is added thereto, and the mixture is stirred for 30 minutes to compose a fiber softener. Manufactured a thing.
陽イオン界面活性剤は、ＴＥＡ Ｅｓｔｅｒ Ｑｕａｔｅｒｎａｒｙ（ＩＮＣＩ Ｎａｍｅ：ｄｉｈｙｄｒｏｇｅｎａｔｅｄ ｐａｌｍｏｙｌｅｔｈｙｌ ｈｙｄｒｏｘｙｅｔｈｙｌｍｏｎｉｕｍ ｍｅｔｈｏｓｕｌｆａｔｅ、ａｃｔｉｖｅ ９０％）を使用した。 As the cationic surfactant, TEA Ester Quaternary (INCI Name: Quaternary palmolylethyl hydromolymonium method, active 90%) was used.
実験例２：洗濯後の残香強度評価
前記製造された実施例及び比較例の繊維柔軟剤組成物を使用して洗濯後の衣類内の残香強度を評価した。
Experimental Example 2: Evaluation of residual scent intensity after washing The residual scent intensity in clothes after washing was evaluated using the fiber softener compositions of the manufactured Examples and Comparative Examples.
洗濯衣類としてタオル３枚を使用し、洗濯洗剤は、ＬＧ生活健康テックを使用し、洗濯実験条件は、韓国環境産業技術院の環境標識認証基準のうちＥＬ３０６（繊維柔軟剤）内の試験方法に準じ、最後のすすぎ時に組成物試料の使用量は、０．６７ｍＬ／Ｌであり、洗濯後１２時間で２５℃、２０％条件の恒温室で乾燥した。 Three towels are used for laundry clothes, LG Life Health Tech is used for laundry detergent, and the washing experiment conditions are the test method in EL306 (fiber softener) among the environmental label certification standards of the Korea Institute of Environmental Industry Technology. Similarly, the amount of the composition sample used at the time of the final rinse was 0.67 mL / L, and it was dried in a constant temperature room at 25 ° C. and 20% condition 12 hours after washing.
残香強度評価は、専門モニター要員１０人に対して官能評価で進行し、１点が最も残香強度が弱くて、５点が最も残香強度が大きいものと評価した。 The residual scent intensity evaluation proceeded by sensory evaluation for 10 specialized monitor personnel, and 1 point was evaluated as having the weakest residual scent intensity and 5 points as having the highest residual scent intensity.
前記衣類内の残香強度評価結果を下記表４に示した。 The results of evaluating the residual scent intensity in the clothes are shown in Table 4 below.
前記表４に示されたように、繊維柔軟剤組成物に香キャリア役目の陽イオン界面活性剤だけが入っていて、香がない比較例３の指標繊維柔軟剤は、乾燥後に香がほとんどない。 As shown in Table 4, the fiber softener composition contains only the cationic surfactant acting as an incense carrier and has no incense. The index fiber softener of Comparative Example 3 has almost no incense after drying. ..
一般的な繊維柔軟剤（比較例４）には、香キャリアとして陽イオン界面活性剤が使用され、残香強度がある程度維持された。 In a general fiber softener (Comparative Example 4), a cationic surfactant was used as an incense carrier, and the residual aroma strength was maintained to some extent.
しかし、本発明による実施例７〜１０の組成物は、陽イオン界面活性剤を使用せず、陽イオン性ポリマーを使用しても同等以上の残香強度を示し、残香強度に優れていることを確認できた。 However, the compositions of Examples 7 to 10 according to the present invention show the same or higher residual scent strength even when a cationic polymer is used without using a cationic surfactant, and are excellent in residual scent strength. It could be confirmed.
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| KR1020140102206A KR20150100464A (en) | 2014-02-25 | 2014-08-08 | Fabric softener composition |
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