KR101809786B1 - Fabric softener composition - Google Patents

Abstract

The present invention relates to a fabric softener composition, and more particularly, it relates to a fabric softener composition which can effectively remove odor after washing using an organic acid instead of a cationic surfactant.

Description

[0001] Fabric softener composition [0002]

The present invention relates to a fabric softener composition capable of effectively removing a scent that has been changed.

Textile softeners are widely used in households to prevent static electricity generated in clothes and to impart flexibility to fibers, and the amount thereof is gradually increasing. In recent years, there has been an increasing interest in prevention of microbial growth and removal of bad smell in clothing as consumers' desire for hygiene and cleanliness has been increased along with the improvement of living standards and pursuit of a more comfortable lifestyle.

Generally, the cause of the odor generated in the fibers is caused by the mixing of volatile organic compounds such as unsaturated lower fatty acids and ammonia, which are decomposed in the skin of the skin, and organic detergents such as sweat odor, and laundry detergents and residuals in the fabric softener, In particular, it was reported that the drying time was delayed during drying in the rainy season, resulting in more odor generated by the odorant Morxella asloensis .

Conventionally, a fabric softener composition containing an antimicrobial agent has been used to remove such odor, but the antimicrobial agent contained in the conventional fabric softener is harmful to human body. In recent years, the use of synthetic antimicrobial agents has been reported to be harmful to human body. Therefore, the use of such antimicrobial agents is being avoided.

Textile softeners have also been used as cationic surfactants for more than 60 years since they were commercialized worldwide in the 1950s. However, recently, such a cationic surfactant has been found to be toxic to human body, and the desire to avoid it is increasing.

Korean Patent Publication No. 10-2007-0090861

It is an object of the present invention to provide a fabric softener composition capable of removing an odor after washing by adding an organic acid to a conventional fabric softener composition without using a cationic surfactant contained as a softening agent.

In order to achieve the above object, the present invention relates to a process for producing a dyestuff containing an organic acid, which does not contain a cationic surfactant and which has been washed in accordance with the environmental mark EL306 and left for 24 hours under the conditions of a drying temperature of 30 DEG C and a relative humidity of 80% Of a fabric softener composition having a five-point scale sensory evaluation of four or more.

The fabric softener composition according to the present invention can effectively remove the odor generated after washing by using an organic acid without using a cationic surfactant.

Hereinafter, the configuration of the present invention will be described in detail.

The present invention is based on a 5-point scale sensory evaluation of odor, which was prepared by incubation for 24 hours under the conditions of a drying temperature of 30 ° C and a relative humidity of 80% after completion of washing according to the environmental mark EL306 without containing a cationic surfactant, 4 > or more.

The fabric softener composition of the present invention is characterized in that an organic acid is used in place of a cationic surfactant to remove odors after washing.

In the present invention, the organic acid acts to remove the detergent residue, specifically, the calcium carbonate. In addition, the organic acid acts as a softening agent (softens the fabric and improves the feel).

The organic acid may be, for example, citric acid, acetic acid, tartaric acid, succinic acid, malic acid or lactic acid, but is not particularly limited thereto. Preferably, the organic acid may be citric acid. Since the unit cost of the citric acid is low, the production cost of the fabric softener composition can be reduced.

The content of the organic acid is not particularly limited and may be from 1 to 30% by weight, more specifically from 2 to 25% by weight, based on 100% by weight of the fabric softener composition. It is possible to exhibit excellent calcium carbonate removal effect within the above range. Even when the content of the organic acid exceeds 30% by weight, excellent calcium carbonate removal effect is exhibited. However, the higher the content of the organic acid, the lower the pH of the rinse water.

The fabric softener composition of the present invention was evaluated as having a 5-point scent sensory evaluation of odor after being washed in accordance with the environmental mark EL306 by using an organic acid instead of a cationic surfactant, and left at a drying temperature of 30 캜 and a relative humidity of 80% for 24 hours. It is possible to remove the smell that is effectively reproduced. Therefore, it can be easily used as a fabric softening agent.

The fabric softener composition according to the present invention may further comprise a viscosity-adjusting polymer for controlling viscosity in addition to the organic acid.

As the above-mentioned viscosity-enhancing polymer, calcium-carboxymethyl cellulose, methyl cellulose / hydroxypropyl methyl cellulose, hydroxyethyl cellulose, carbopol 934, carbopol 941, xanthan gum, sodium alginate, guar gum , Carrageenan, pectin, acrylic polymer and the like. Preferably, at least one acrylic polymer selected from the group consisting of acrylic acid polymers, acrylic copolymers, and acrylated silicone is preferable.

The content of the viscosity-increasing polymer is not particularly limited and may be 0.01 to 1.2% by weight, more specifically 0.05 to 1% by weight based on 100% by weight of the fabric softener composition.

The fabric softener composition according to the present invention may further comprise vinegar.

Vinegar is a seasoning containing acetic acid as its main ingredient and it has a sweet and bitter taste. It contains dozens of organic acids such as acetic acid, citric acid and various amino acids to activate the metabolism and eliminate the waste materials in the body, It also acts as a powerful disinfectant. In addition, the vinegar can perform the role of removing the detergent residue.

The content of the vinegar is not particularly limited and may be 0.1 to 10% by weight, 0.5 to 5% by weight or 1 to 3% by weight based on 100% by weight of the fabric softener composition. And has the effect of removing the sterilizing effect and the detergent residue within the above range.

The fabric softener composition according to the present invention may further comprise a flower fermented vinegar which plays a role of strong deodorization in addition to the above-mentioned composition components.

The flower fermented vinegar may be one obtained by washing the petal with water, drying it, mixing it with excess vinegar and sugar, and fermenting it for 3 to 7 days.

The vinegar may be a commercial vinegar, and is preferably used in an amount of 5 to 30 parts by weight based on 1 part by weight of the petals.

In addition, the sugar may include various sugars such as glucose, sugar, fructose, oligosaccharide, or syrup. The saccharide may be used to ferment flower extracts to alcohol, and preferably 5 to 30 parts by weight per 1 part by weight of the petals.

Alternatively, the flower fermented vinegar may be sterilized by blending the flower raw material, the flower fermented vinegar may be sterilized by blending the flower raw material, heated at 100 to 150 ° C for 10 to 30 minutes, and then mixed with the herbal extract and sugar Followed by fermentation at 20 to 40 DEG C for 72 to 96 hours.

The above-mentioned herbaceous plant is a plant produced by fermentation of wild-cauliflower bacteria isolated from a traditional vinegar vinegar without any odor and odor, and the herbaceous plant is fermented by a wild-type acetic acid bacteria Acetobacter sp. Any that can be produced can be used. At this time, the amount of the seeds may be added in an amount of 5 to 30% by weight based on 100% by weight of the flower hot-water extract. If the addition amount of the seeds is less than 5 wt%, it is difficult to induce vinegar fermentation of the agar-agaric hot-water extract, and if it exceeds 30 wt%, the efficiency of vinegar fermentation does not increase more than the addition amount.

The sugar may be glucose, sugar, fructose, oligosaccharide, or various sugars such as syrup. The saccharide may be added in an amount of 5 to 30% by weight based on 100% by weight of the flower hot-water extract.

The flower fermented vinegar prepared by the above method may have a pH of 2.70 to 3.30 and an acidity of 3 to 7. [

The kinds of flowers used in the flower fermentation vinegar preparation can be used without limitation. For example, red flowers, apricot flowers, acacia flowers, chamomile flowers, jasmine flowers or lotus flowers can be used.

The content of the flower fermented vinegar is not particularly limited and may be in the range of 0.001 to 10% by weight, more specifically 0.05 to 5% by weight, more specifically 0.1 to 2% by weight based on 100% by weight of the fabric softener composition.

The fabric softener composition according to the present invention may further contain small amounts of additives within the scope of the present invention. The additive may be an antimicrobial component for further improving the antimicrobial effect, or may be a coloring matter, an antiseptic, an antioxidant, a defoaming agent, and the like.

In addition, the composition of the present invention may further comprise, if necessary, appropriate additives such as oil, water, a surfactant, a moisturizer, a lower alcohol, a chelating agent, a coloring agent, Can be used.

The composition according to the present invention may be granulated or powdered using a method known in the art, or may be prepared into a liquid state.

Hereinafter, embodiments of the present invention will be described in detail to facilitate understanding of the present invention. However, the embodiments according to the present invention can be modified into various other forms, and the scope of the present invention should not be construed as being limited to the following embodiments. Embodiments of the invention are provided to more fully describe the present invention to those skilled in the art.

< Example > Example  1 to 5

A fabric softener composition having the composition and contents shown in Table 1 below was prepared.

First, the thickening polymer was added to purified water, stirred until complete dissolution, then citric acid, vinegar and flower fermented vinegar were added thereto, and the mixture was stirred for 30 minutes. Then, a solution prepared by previously dissolving ethanol, .

(5 wt%) and defoamer (0.05 wt%) were used as the additive. Acrylic copolymer (Rheovis FRC, BASF) was used as the thickening polymer and citric acid was used as the organic acid.

Vinegar used was vinegar (natural food).

The flower fermented vinegar was washed with water and dried, and then 15 parts by weight of vinegar and 15 parts by weight of vinegar were mixed with 1 part by weight of the petals and dried for about 7 days.

&Lt; Comparative Example 1 &

Water was used in place of the fabric softener composition.

&Lt; Comparative Example 2 &

An indicator fabric softener was used instead of the fabric softener composition.

The above surface textile softener was manufactured by LG H &H's TEA Ester Quaternary according to EL306 (fabric softener) criteria of environmental label certification standard of Korea Environmental Industry & Technology Institute.

&Lt; Comparative Example 3 &

A fabric softener composition having the composition (wt%) shown in Table 1 below was prepared.

The fabric softener composition was prepared in the same manner as in the above example except that a cationic surfactant was added instead of citric acid.

Polymer LR30M from DOW Chemical was used as a cationic surfactant.

Furtherance(%) Comparative Example
3 Example
One Example
2 Example
3 Example
4 Example
5 Cationic surfactant 5 - - - - - Citric acid - 2 5 20 20 20 A thickening polymer 0.3 0.3 0.3 0.3 0.3 0.3 Spices 0.5 0.5 0.5 0.5 0.5 0.5 ethanol 5 5 5 5 5 5 Fragrance 5 5 5 5 5 5 Defoamer 0.05 0.05 0.05 0.05 0.05 0.05 vinegar - - - - - 1.0 Flower fermented vinegar - - - - 0.5 0.5 Purified water Up to 100% weight Up to 100% weight Up to 100% weight Up to 100% weight Up to 100% weight Up to 100% weight

< Experimental Example  1> Sensory evaluation after washing

Sensory evaluations were carried out after washing using the fabric softener compositions of the above-described Examples and Comparative Examples.

Two standard white cotton cloths (10 × 10 cm) as specified in KS K 0905 were used as laundry clothes, and the used laundry detergent was LG H & H Tech.

The washing test conditions were in accordance with the test method in EL306 (fabric softener) among the environmental label certification standards of Korea Environmental Industrial Technology Institute, and the amount of the composition used was 0.67 mL / L at the last rinsing.

The clothes were allowed to stand for 24 hours at a drying temperature of 30 ° C and a relative humidity of 80% under a constant temperature and humidity condition. The sensory evaluation was carried out on a 5-point scale using 10 professional monitors. There is almost no odor elimination power, and 5 points is the best odor removing power.

Comparative Example / Example Comparative Example 1 Comparative Example 2 Comparative Example 3 Example 1 Example 2 Example 3 Example 4 Example
5 Removed odor elimination (5 points scale) 1.2 1.0 3.0 4.0 4.2 4.8 4.9 5.0

As shown in Table 2, the fabric softener composition containing no softener, a surface fabric softener, or a cationic surfactant had a sensory evaluation value of less than 4 in terms of removing the odor removing ability. However, it is not preferable to use citric acid and / In the composition containing vinegar, the odor removal power of the cooked was superior to the sensory evaluation of 4 or more.

Since the composition containing the cationic surfactant is a composition in which the perfume is used, it is judged that the slightly scented odor is partially masked.

Claims (11)

Organic acid, viscosity-enhancing polymer, and flower fermented vinegar. It does not contain a cationic surfactant. After washing in accordance with the environmental mark EL306, it is left to stand for 24 hours at a drying temperature of 30 ° C and a relative humidity of 80% The point scale sensory evaluation was 4 points or more,
Wherein the organic acid is contained in an amount of 2 to 25% by weight based on 100% by weight of the liquid fiber softener composition, and the flower fermented vinegar is contained in an amount of 0.001 to 10% by weight.
The method according to claim 1,
Wherein the organic acid comprises at least one selected from the group consisting of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid.
delete delete The method according to claim 1,
The thickening polymers include calcium-carboxymethylcellulose, methylcellulose / hydroxypropylmethylcellulose, hydroxyethylcellulose, carbopol 934, carbopol 941, xanthan gum, sodium alginate, guar gum, Carrageenan, pectin, and an acrylic polymer.
The method according to claim 1,
Wherein the viscosity-enhancing polymer is contained in an amount of 0.01 to 1.2% by weight based on 100% by weight of the fabric softener composition.
delete The method according to claim 1,
Wherein the flower fermentation vinegar is obtained by fermenting at least one petal selected from the group consisting of apple flower, apricot flower, acacia flower, chamomile flower, jasmine flower and lotus flower mixed with vinegar and sugar.
delete The method according to claim 1,
Wherein the liquid fabric softener composition further comprises vinegar.
11. The method of claim 10,
Wherein the vinegar is contained in an amount of 0.1 to 10% by weight based on 100% by weight of the liquid fiber softener composition.