CN106029858A - Composition for fabric softener - Google Patents
Composition for fabric softener Download PDFInfo
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- CN106029858A CN106029858A CN201580010357.0A CN201580010357A CN106029858A CN 106029858 A CN106029858 A CN 106029858A CN 201580010357 A CN201580010357 A CN 201580010357A CN 106029858 A CN106029858 A CN 106029858A
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Abstract
The present invention relates to a composition for a fabric softener, and more specifically, which uses an organic acid and a viscosity-increasing polymer, improves loosening of the organic acid by controlling viscosity, and which can effectively remove calcium carbonate remaining in clothes when washing. Also, a composition for a fabric softener for enhancing remaining scent, according to the present invention, can further enhance remaining scent in clothes compared to existing fabric softeners by using a cationic polymer instead of a cationic surfactant, which is harmful to the body.
Description
Technical field
The present invention relates to a kind of fiber softener compositions.
Background technology
In order to prevent from producing on medicated clothing electrostatic, and in order to give the flexibility of fiber, fiber softener exists
It is widely used in family, and its usage amount is the trend gradually increased.Recently, live along with consumer
The raising of level, is also gradually increased the demand of health and cleaning, and more comfortable in order to pursue
Wear the clothes life, to preventing from producing the breeding of the microorganism on medicated clothing, and go to the pass eliminated the unusual smell
Note degree is gradually promoting.
Generally, the moist abnormal smells from the patient produced in fiber, can be by forming the organic of sweat odor etc.
Chemical composition decomposes the volatility such as the unsaturated lower fatty acid generated and ammonia with skin normal flora to be had
Machine compound reacts, or reacts with the residual component of laundry detergents or softener and generate.According to
Know, especially when rainy season, indoor clothing was dried, owing to drying time is delayed, by abnormal flavour bacterium Morxella
The impact of asloensis and be more prone to the abnormal smells from the patient of humidity.
In order to remove the abnormal smells from the patient etc. of this humidity, employed the fiber softener group comprising antibacterial in the past
Compound, but the antibacterial being included in conventional fiber softener is harmful.Recently,
Along with the content using synthetic antibacterial agents harmful is in the news, the use of this antibacterial is popular
Away from.
It addition, since fiber softener in nineteen fifty for since the whole world is universal, more than 60 years as long as
Use cationic surfactant as submissive composition (Korean Patent Publication No. 10-2007-0090861 always
Number).But, the harmfulness of human body is disclosed for by the most this cationic surfactant, it is desirable to remote
Demand from this harmful substance is being gradually increased.
Further, when the viscosity height of fiber softener, the diffusion (dissolving) of organic acid in washings
Slowly, the shortcoming with the effect that cannot give full play to organic acid.
Summary of the invention
The problem that invention is to be solved
It is an object of the invention to, it is provided that one does not uses that to be in the past included in fiber as submissive composition soft
Along the cationic surfactant in agent, but with the addition of organic acid, and use thickening polymer
Improve the dissolubility of organic acid, and for remaining in water-fast one-tenth in intrastitial, laundry detergents
I.e. calcium carbonate is divided to have the fiber softener compositions of outstanding dissolving and removal effect.
It addition, it is an object of the invention to, it is provided that one does not uses and is included in as fragrance carrier in the past
Cationic surfactant in fiber softener, but with the addition of cationic polymer to strengthen lingering fragrance
Fiber softener compositions.
The method solving problem
In order to achieve the above object, the present invention provides a kind of fiber softener compositions, wherein, comprises
Organic acid and thickening polymer, and use rotating cylinder viscometer 25 DEG C, measure under conditions of 60rpm
Viscosity is 1～250cPs.
It addition, the present invention provides a kind of lingering fragrance reinforced fiber softener compositions, wherein, do not comprise
Cationic surfactant, comprises cationic polymer, organic acid and spice.
Invention effect
Fiber softener compositions according to the present invention, employs organic acid, and also employs thickening
With polymer, thus in of short duration washing/rinsing time, improve the dissolubility of organic acid, thus
To remaining in in medicated clothing, laundry detergents the water-fast composition i.e. dissolving of calcium carbonate and removing very
Effectively.
Fiber softener compositions according to the present invention, employs cationic polymer and organic acid,
To replace as fragrance carriers affect lingering fragrance and harmful cationic surfactant, thus not
Only avoid the injury to human body, and submissive with the fiber of conventional use cationic surfactant
Agent is compared, and more strengthens lingering fragrance.
Detailed description of the invention
The present invention relates to a kind of fiber softener compositions, wherein, comprise organic acid and thickening is used
Polymer, and use rotating cylinder viscometer 25 DEG C, the viscosity that measures under conditions of 60rpm be
1～250cPs (hereinafter referred to as " the first fiber softener compositions ").
Viscosity is the highest, and in washings, the diffusion (dissolving) of organic acid is the slowest, and then cannot be abundant
Ground plays effect of organic acid.Fiber softener compositions of the present invention is characterised by, is being added with
Thickening polymer is also added on the basis of machine acid, thus within the short period of washing/rinsing,
Improve the dissolubility of organic acid.
In the present invention, organic acid plays the effect removing laundry detergents residue, specifically, rises
To the effect removing calcium carbonate.It addition, described organic acid play softener itself (make dress material soft,
Improve sense of touch) effect.
As described organic acid, such as can use citric acid, acetic acid, tartaric acid, succinic acid,
More than one in malic acid and lactic acid etc., but it is not limited to this.The most described organic acid is
Citric acid.Owing to the raw-material cost ratio of described citric acid is relatively low, therefore fiber can be saved soft
Production cost along agent compositions.
The content of described organic acid is not particularly limited, relative to fiber softener compositions 100 weight
Amount %, can comprise the organic acid of 5～30 weight %, preferably comprise the organic acid of 10～25 weight %,
More preferably comprise the organic acid of 15～20 weight %.In the range of described, outstanding going can be presented
Effect except calcium carbonate.Even if the content of organic acid is more than 30 weight %, still can present outstanding
The effect removing calcium carbonate, but along with the content of organic acid increases, the pH value of washings can reduce,
It is therefore preferable that usage amount is below 30 weight %.
In order to improve the dissolubility of organic acid, the fiber softener compositions of the present invention comprises scalable
The thickening polymer of viscosity.In the present invention, as described thickening polymer, it is possible to use
Carboxymethylcellulose calcium, methylcellulose/hydroxypropyl methyl cellulose, hydroxyethyl cellulose, card ripple
Nurse 934 (carbopol 934), Carbopol 941 (carbopol 941), xanthan gum, sodium alginate, melon
That glue, carrageenan, pectin (Pectin) and acrylic acid series polymeric compounds etc..It is preferably and is gathered by acrylic acid
The group that compound class and acrylic copolymer, acrylated organosilicon are formed is selected more than one
Acrylic acid series polymeric compounds.
The content of described thickening polymer is not particularly limited, relative to fiber softener compositions
100 weight %, can comprise the thickening polymer of 0.01～1.2 weight %, preferably can comprise 0.05～1
The thickening polymer of weight %.In the range of described, the dissolubility of organic acid is improved, because of
This is outstanding to the removal effect of calcium carbonate.
Further, described thickening polymer is the weight controlling fiber softener composition viscosity of the present invention
Want factor, more specifically, use rotating cylinder viscometer and 25 DEG C, survey under conditions of 60rpm
Regularly, the viscosity of fiber softener compositions of the present invention can be 1～250cPs.When described viscosity surpasses
When crossing 250cPs, organic acid diffusion dissolution in washing/washings can reduce, and then is not easy
The calcium carbonate remained in removing medicated clothing.
The compositions of the present invention by using organic acid and thickening polymer, even if do not comprise sun from
Sub-surface activating agent, the most outstanding to the removal effect of laundry detergents residue, therefore convenient as fiber
Softener uses.
In a specific embodiment, the fiber softener compositions of the present invention is added washing/lingering fragrance
Time in water, the calcium carbonate remained in completely eliminated medicated clothing.
Moreover, it relates to a kind of lingering fragrance reinforced fiber softener compositions, wherein, do not wrap
Compositions comprising cationic surfactants, comprises cationic polymer, organic acid and spice and (below, claims
Make " the second fiber softener compositions ").
In the present invention, cationic polymer plays the effect strengthening lingering fragrance.Described cationic polymerization
One selected in the group that thing can be made up of glucose based polymer and acrylic acid series polymeric compounds
More than Zhong, but, as long as the cationic polymer strengthening lingering fragrance effect can be played, there is no harm in
Hinder and all can use in the range of effect of the present invention, do not limited by any.Described glucose system gathers
The group that compound can be made up of polyquaternary ammonium salt, guar gum, starch and locust bean gum is selected
More than one, but it is not limited to this.Described acrylic acid series polymeric compounds can be by acroleic acid polymerization
The group that thing and acrylic copolymer, acrylated organosilicon are formed is selected more than one, but
It is not limited to this.
The content of described cationic polymer is not particularly limited, relative to fiber softener compositions
100 weight %, can comprise 0.1～3 weight %, 0.2～2 weight % or 0.3～1 weight % sun from
Sub-polymer.In the range of described, play the effect strengthening lingering fragrance, and for viscosity is brought up to
The range of viscosities being suitable for softening agent for fibres is the most effective.
In the present invention, organic acid plays the effect removing laundry detergents residue.Have described in it addition,
The effect of softener (making dress material soft, to improve sense of touch) itself is played in machine acid.These organic acid
Kind is not particularly limited, for example, it is possible to comprise by citric acid, acetic acid, tartaric acid, succinic acid,
The group that malic acid and lactic acid are formed is selected more than one.Particularly because citric acid
Raw-material cost ratio is relatively low, so suitably using as organic acid.
The content of described organic acid is not particularly limited, relative to fiber softener compositions 100 weight
Amount %, can comprise 1～20 weight %, 5～15 weight % or the organic acid of 8～12 weight %.Institute
In the range of stating, for water-fast laundry detergents residue, there is outstanding removal effect.Even if having
When the content of machine acid is more than 20 weight %, still have excellent for water-fast laundry detergents residue
Elegant removal effect.But along with the content of organic acid increases, the pH value of washings can reduce, therefore
The amount of being preferably used is below 20 weight %.
In the present invention, spice such as can comprise fragrant flower (Floral) class spice, Citrus (citrus)
Class spice etc..In addition, as long as the spice that can use as fiber softener, there is no harm in
Hinder and all can use in the range of effect of the present invention, the most any restriction.Containing of described spice
Amount is not particularly limited, and relative to fiber softener compositions 100 weight %, can comprise 0.1～3 weights
Amount %, 0.2～2 weight % or the described spice of 0.3～1 weight %.Beyond described scope, it may appear that
Lingering fragrance crosses the light or problem of overrich.
(the first fiber softener compositions or the second fiber are soft for the fiber softener compositions of the present invention
Along agent compositions) in, it is also possible to add tablet vinegar.
Tablet vinegar be mainly composed of acetic acid, be that it contains with micro-sweetening in a kind of acid
Tens kinds of organic acid such as acetic acid, citric acid and various aminoacid, are possible not only to enhance metabolism,
Assist in removing internal Excreta, also act as the effect of potent preservative and antibacterial.It addition,
Tablet vinegar may also operate as removing the effect of laundry detergents residue.
The content of described tablet vinegar is not particularly limited, relative to fiber softener compositions 100 weight
Amount %, can comprise 0.1～10 weight %, 0.5～5 weight % or the tablet vinegar of 1～3 weight %.?
In the range of described, play sterilization and remove the effect of laundry detergents residue.
Fiber softener compositions (the first fiber softener compositions or the second fibre according to the present invention
Dimension softener compositions), in addition to comprising constituent as above, it is also possible to comprise and play by force
The colored fermented vinegar of effect deodorization.
Described colored fermented vinegar, can by by petal wash and be dried, and with excess tablet vinegar with
And sucrose solution mixing after fermentation 3～7 days and make.
Described tablet vinegar can be commercially available making vinegar, relative to petal 1 weight portion, preferably adds
Add 5～the tablet vinegar of 30 weight portions.It addition, described sucrose solution can comprise glucose, Saccharum Sinensis Roxb., fructose,
The various saccharide such as oligosaccharide or malt sugar.Described sucrose solution plays the effect making flower extract alcohol fermentation.
Relative to petal 1 weight portion, preferably add the sucrose solution of 5～30 weight portions.
Or, after described colored fermented vinegar can be by spending direct sterilization treatment, at 100～150 DEG C
Carry out the hot water extraction of 10～30 minutes, more described hot water extract is mixed with kind vinegar and sucrose solution
After be placed in the environment of 20～40 DEG C, make through the fermentations of 72～96 hours.
Described kind of vinegar refers to, from the free from extraneous odour manufactured by traditional approach, without the making vinegar of foreign odor
In isolate wild vinegar bacterium, and this wild vinegar bacterium is carried out propagation fermentation and the vinegar made.Separately
Outward, as long as can be by the kind vinegar that wild acetic acid bacteria-acetobacter (Acetobacter sp.) is made
Can use.Wherein, relative to flower hot water extract 100 weight %, 5～30 weight can be added
The described kind of vinegar of %.When the addition of described kind of vinegar is less than 5 weight %, it is not easy to induce described ripe
Change the tablet vinegar fermentation of flower hot water extract；During more than 30 weight %, compared with addition, food
Will not sustainable growth again by the efficiency of vinegar fermentation.
Described sucrose solution can comprise the various saccharides such as glucose, Saccharum Sinensis Roxb., fructose, oligosaccharide or malt sugar.
Described sucrose solution plays the effect making flower hot water extract's alcohol fermentation.Relative to flower hot water extract 100
Weight %, can add the described sucrose solution of 5～30 weight %.
The pH value of the colored fermented vinegar made by described method can be 2.70～3.30, and acidity is permissible
Reach 3～7.
Unrestricted for manufacturing the kind of the flower of described colored fermented vinegar.It is, for example possible to use
Flos persicae, Flos Pruni, Flos Sophorae, Flos Chrysanthemi, Flos Jasmini Sambac and Flos Nelumbinis etc..
The content of described colored fermented vinegar is not particularly limited, relative to fiber softener compositions 100
Weight %, can comprise 0.001～10 weight %, 0.05～5 weight % or the described flower of 0.1～2 weight %
Fermented vinegar.In the range of described, there is the effect of sterilization, taste removal.
It addition, according to the fiber softener compositions of the present invention (the first fiber softener compositions or
Second fiber softener compositions), it is also possible to comprise the second of phase stability for keeping content
Alcohol.
The content of described ethanol is not particularly limited, relative to fiber softener compositions 100 weight
%, can comprise 0.1～10 weight %, 0.5～8 weight % or the described ethanol of 1～7 weight %.Institute
In the range of stating, content has outstanding phase stability.
It addition, according to the fiber softener compositions of the present invention (the first fiber softener compositions or
Second fiber softener compositions) in can also add spice.Described spice such as can comprise perfume (or spice)
Flower (Floral) class spice, Citrus (citrus) class spice etc..In addition, as long as can conduct
The spice that fiber softener uses, all can use in the range of effect of the present invention not hindering, and
There is no any restriction.The content of described spice is not particularly limited, relative to fiber softener group
Compound 100 weight %, can comprise 0.01～5 weight % or the described spice of 0.1～3 weight %.
It addition, according to the fiber softener compositions of the present invention (the first fiber softener compositions or
Second fiber softener compositions) in can also add fragrance solubilizing agent, described fragrance solubilizing agent is used
In the acetic acid taste that mitigation is produced by fermented vinegar etc., thus improve the fragrance satisfaction of fiber softener.
Its content is not particularly limited, and relative to fiber softener compositions 100 weight %, can comprise 0.
1～10 weight % or the described fragrance solubilizing agent of 1～7 weight %.
It addition, according to the fiber softener compositions of the present invention (the first fiber softener compositions or
Second fiber softener compositions), it is also possible to comprise for improving the stench effects such as removal acetic acid taste
Plant extract.Described plant extract can comprise by persimmon leaf, green tea and Pericarpium Citri Reticulatae institute
Composition group in select more than one.
It addition, according to the fiber softener compositions of the present invention (the first fiber softener compositions or
Second fiber softener compositions), in the range of the purpose of the present invention, it is also possible to comprise a small amount of
Additive.Described additive can be the sterilization component improving bactericidal effect further, in addition,
Can also is that pigment, preservative, antioxidant and defoamer etc..The content of additive is not by spy
Different limit, relative to fiber softener compositions 100 weight %, can comprise 0.01～5 weight % or
The described additive of 0.1～3 weight %.
It addition, the compositions of the present invention (the first fiber softener compositions or the second fiber softener
Compositions) each dosage form in, except using in addition to composition as above, as required, also may be used
To mate properly into the oil being normally fitted in fiber softener and divide, water, surfactant, moisturizing
Agent, lower alcohol, thickening agent, chelating agen, pigment and preservative etc..Its content is not by special limit
System, relative to fiber softener compositions 100 weight %, can comprise 55～90 weight % or 60
～85 described compositions of weight %.
Furthermore it is possible to by means commonly known in the art, compositions (the first fiber to the present invention
Softener compositions or the second fiber softener compositions) carry out powdered, granulating use,
Liquid can also be made and use.
Specific embodiment
Embodiment 1～6 and comparative example 1～2
It is prepared for having shown in table 1 below and constitutes and the fiber softener compositions of content.
First, thickening polymer is put in Purified Water, be stirred well to be completely dissolved, then to
After wherein putting into citric acid, flower fermented vinegar and tablet vinegar and stirring 30 minutes, it is added to pre-
First it is dissolved with the solution of ethanol, spice and additive, stirs 30 minutes and to be made for fiber submissive
Agent compositions.
As described additive, employ fragrance solubilizing agent (5 weight %) and defoamer (0.05 weight
Amount %) mixture.As thickening polymer, employ acrylic copolymer (BASF AG
Rheovis FRC).As organic acid, employ citric acid.
Tablet vinegar employs making vinegar (wholefood).
It addition, flower fermented vinegar is, by being dried after jasmine petal is washed, then will be relative to petal 1
Weight portion is the tablet vinegar of 15 weight portions and the sucrose solution of 15 weight portions mixes with described dry petal,
And obtain through the natural fermentation of about 7 days.
As washing medicated clothing, employ the white standard cotton (10 × 10cm) of KS K 0905 regulation
3, laundry detergents employ LG life health tech (Trade name).
Table 1
Experimental example 1: the measurement of the calcium carbonate concentration of residual in medicated clothing after washing
The fiber softener compositions made by above-described embodiment and comparative example is used to wash
After washing, rinsing, measure the calcium carbonate concentration of residual in medicated clothing.
It is (fine that wash conditions follows EL306 in the environmental label certification benchmark of Environmental Industry technology institute of Korea S
Dimension softener) experimental technique, and during last rinsing, the usage amount of fiber softener compositions is
0.67mL/L。
After washing rinsing, the calcium carbonate residual quantitative analysis of residual in medicated clothing, is by washing above-mentioned
Under the conditions of washing, the experiment cloth that rinse of washing point takes 0.5g, use hydrochloric acid, fluoric acid, nitric acid with
And after the mixed liquor of boric acid carries out acid treatment to it, carry out the extraction of 24 hours, use ICP (high
Frequently inductively coupled plasma) analyzed.
By the measurement result of the calcium carbonate concentration of residual in above-mentioned medicated clothing, it is shown in table 2 below.
It addition, the viscosity of compositions is to use Brookfield rotating cylinder viscometer and at 25 DEG C, 60rpm
Under conditions of measure.
Table 2
As known from Table 2, when the usage amount viscosity along with thickening polymer is about more than 250cPs,
Owing in washing/washings, the diffusion dissolution of effective ingredient reduces, it is difficult to remain in removing medicated clothing
Calcium carbonate.
Embodiment 7～10
It is prepared for the fiber softener compositions with composition as shown in table 3 below and content.
First, cationic polymer, flower fermented vinegar, tablet vinegar and citric acid are put into Purified Water
After middle stirring 30 minutes, it is added to be dissolved with ethanol, spice, fragrance solubilizing agent and froth breaking
The solution of agent, stirs and is made for fiber softener compositions in 30 minutes.
It addition, as glucose based polymer, employ the polyquaternary amine can being commercially available on the market
The salt Polymer LR30M of company (DOW Chemical)；As acrylic acid series polymeric compounds, make
With commercially available acrylic copolymer (the Rheovis FRC of BASF AG).
It addition, tablet vinegar employs making vinegar (wholefood).
It addition, the colored fermented vinegar used is, by being dried after jasmine petal is washed, then by phase
For the sucrose solution of tablet vinegar that this petal 1 weight portion is 15 weight portions and 15 weight portions with described
After the petal mixing being dried, make through the natural fermentations of about 7 days.
Comparative example 3
Standard fibers softener is used to replace the fiber softener compositions of the present invention.
Described standard fibers softener compositions and the environmental label certification of Environmental Industry technology institute of Korea S
In benchmark, the standard fibers softener compositions of EL306 (fiber softener) experimental technique is identical.
Comparative example 4
It is prepared for the fiber softener compositions with composition as shown in table 3 below and content.
First, cationic surfactant is put into after Purified Water stirs 30 minutes, add wherein
Add and be dissolved with ethanol, spice, fragrance solubilizing agent and the solution of defoamer, stir 30 minutes and make
Become fiber softener compositions.
As cationic surfactant, employ TEA Ester Quaternary (INCI
Name:dehydrogenated palmoylethyl hydroxyethylmonium methosulfate,
Active 90%).
Table 3
Experimental example 2: the evaluation of lingering fragrance intensity after washing
After using the fiber softener cleaning compositions made by above-described embodiment and comparative example,
Lingering fragrance intensity in medicated clothing is evaluated.
As washing medicated clothing, employing 3 towels, laundry detergents employs the tec of LG life health
h(Trade name).Washing experiment condition follows the environment mark of Environmental Industry technology institute of Korea S
The experimental technique of EL306 (fiber softener) in will certification benchmark, and during last rinsing, fiber is soft
It is 0.67mL/L along the usage amount of agent compositions, at temperature 25 DEG C, relative humidity 20% after washing
Thermostatic chamber has been dried 12 hours.
For lingering fragrance intensity, carried out by the sensory evaluation of 10 special supervisors, wherein,
1 point represents that lingering fragrance intensity is the most weak, and 5 points represent that lingering fragrance intensity is the highest.
The evaluation result of lingering fragrance intensity in described medicated clothing is shown in Table 4.
Table 4
As shown in Table 4 above, fiber softener compositions only comprises play fragrance carrier function
Cationic surfactant and there is no the standard fibers softener of the comparative example 3 of spice, after drying
There is no fragrance.
In general fibre softener (comparative example 4), owing to using cationic surfactant conduct
Fragrance carrier, therefore, maintains lingering fragrance intensity to a certain extent.
On the other hand, the compositions of 7～10 according to embodiments of the present invention, even if not using cationic surface
Activating agent, by using cationic polymer, it is thus achieved that above on an equal basis with common softening agent for fibres
Lingering fragrance intensity, can confirm that lingering fragrance excellent.
Claims (18)
1. a fiber softener compositions, wherein, comprises organic acid and thickening polymer, and makes
With rotating cylinder viscometer 25 DEG C, the viscosity that measures under 60rpm be 1～250cPs.
Fiber softener compositions the most according to claim 1, wherein, described organic acid comprises
The group being made up of citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid is selected
More than one.
Fiber softener compositions the most according to claim 1 is wherein, submissive relative to fiber
Agent compositions 100 weight %, comprises the described organic acid of 5～30 weight %.
Fiber softener compositions the most according to claim 1, wherein, described thickening is polymerized
Thing comprises by carboxymethylcellulose calcium, methylcellulose/hydroxypropyl methyl cellulose, hydroxy ethyl fiber
Element, carbomer 934 (carbopol 934), Carbopol 941 (carbopol 941), xanthan gum, alginic acid
The group that sodium, guar gum, carrageenan, pectin (Pectin) and acrylic acid series polymeric compounds are formed is selected
Go out more than one.
Fiber softener compositions the most according to claim 1 is wherein, submissive relative to fiber
Agent compositions 100 weight %, comprises the described thickening polymer of 0.01～1.2 weight %.
6. a fiber softener compositions, wherein, does not comprise cationic surfactant, comprises sun
Ionomer, organic acid and spice.
Fiber softener compositions the most according to claim 6, wherein, described cationic polymerization
The group that thing is made up of glucose based polymer and acrylic acid series polymeric compounds is selected more than one.
Fiber softener compositions the most according to claim 7, wherein, described glucose system gathers
The one selected in the group that compound is made up of polyquaternary ammonium salt, guar gum, starch and locust bean gum with
On.
Fiber softener compositions the most according to claim 7, wherein, described acrylic acid series gathers
The group that compound is made up of acrylate copolymer, acrylic copolymer and acrylated organosilicon
In select more than one.
Fiber softener compositions the most according to claim 6 is wherein, submissive relative to fiber
Agent compositions 100 weight %, comprises the described cationic polymer of 0.1～3 weight %.
11. fiber softener compositionss according to claim 6, wherein, described organic acid be by
One selected in the group that citric acid, acetic acid, tartaric acid, succinic acid, malic acid and lactic acid are formed
More than Zhong.
12. fiber softener compositionss according to claim 6 are wherein, submissive relative to fiber
Agent compositions 100 weight %, comprises the described organic acid of 1～20 weight %.
13. fiber softener compositionss according to claim 6 are wherein, submissive relative to fiber
Agent compositions 100 weight %, comprises the described spice of 0.1～3 weight %.
14. according to the fiber softener compositions described in claim 1 or 6, wherein, also comprises flower and sends out
Ferment vinegar.
15. fiber softener compositionss according to claim 14, wherein, described colored fermented vinegar
It is that the group by being made up of Flos persicae, Flos Pruni, Flos Sophorae, Flos Chrysanthemi, Flos Jasmini Sambac and Flos Nelumbinis is selected
More than one the petal gone out carries out washing and being dried, and with tablet vinegar and sucrose solution mixing after fermentation 3～7
It and obtain.
16. fiber softener compositionss according to claim 14, wherein, soft relative to fiber
Along agent compositions 100 weight %, comprise the described colored fermented vinegar of 0.001～10 weight %.
17. according to the fiber softener compositions described in claim 1 or 6, wherein, also comprises edible
Vinegar.
18. fiber softener compositionss according to claim 17, wherein, soft relative to fiber
Along agent compositions 100 weight %, comprise the described tablet vinegar of 0.1～10 weight %.
Applications Claiming Priority (21)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2014-0021928 | 2014-02-25 | ||
| KR10-2014-0021927 | 2014-02-25 | ||
| KR20140021927 | 2014-02-25 | ||
| KR20140021928 | 2014-02-25 | ||
| KR20140052640 | 2014-04-30 | ||
| KR10-2014-0052637 | 2014-04-30 | ||
| KR20140052637 | 2014-04-30 | ||
| KR10-2014-0052640 | 2014-04-30 | ||
| KR1020140102207A KR20150100465A (en) | 2014-02-25 | 2014-08-08 | Fabric softener composition |
| KR10-2014-0102211 | 2014-08-08 | ||
| KR1020140102214A KR20150125520A (en) | 2014-04-30 | 2014-08-08 | Fabric softener composition |
| KR10-2014-0102214 | 2014-08-08 | ||
| KR1020140102206A KR20150100464A (en) | 2014-02-25 | 2014-08-08 | Fabric softener composition |
| KR1020140102211A KR20150125517A (en) | 2014-04-30 | 2014-08-08 | Fabric softener composition |
| KR10-2014-0102206 | 2014-08-08 | ||
| KR10-2014-0102207 | 2014-08-08 | ||
| KR10-2015-0025438 | 2015-02-23 | ||
| KR10-2015-0025439 | 2015-02-23 | ||
| KR1020150025438A KR102067701B1 (en) | 2014-02-25 | 2015-02-23 | Fabric softener composition |
| KR1020150025439A KR102067702B1 (en) | 2014-02-25 | 2015-02-23 | Fabric softener composition |
| PCT/KR2015/001844 WO2015130088A1 (en) | 2014-02-25 | 2015-02-25 | Composition for fabric softener |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106029858A true CN106029858A (en) | 2016-10-12 |
| CN106029858B CN106029858B (en) | 2021-03-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201580010357.0A Active CN106029858B (en) | 2014-02-25 | 2015-02-25 | Fiber softener composition |
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| JP (2) | JP6817067B2 (en) |
| CN (1) | CN106029858B (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2017509805A (en) | 2017-04-06 |
| JP2019135346A (en) | 2019-08-15 |
| JP6817067B2 (en) | 2021-01-20 |
| JP6833248B2 (en) | 2021-02-24 |
| CN106029858B (en) | 2021-03-02 |
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