CN106566699A - Super concentrated high-efficiency sterilization laundry composition - Google Patents
Super concentrated high-efficiency sterilization laundry composition Download PDFInfo
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- CN106566699A CN106566699A CN201610955430.8A CN201610955430A CN106566699A CN 106566699 A CN106566699 A CN 106566699A CN 201610955430 A CN201610955430 A CN 201610955430A CN 106566699 A CN106566699 A CN 106566699A
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
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- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
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- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
- C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
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- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
The invention relates to a super concentrated high-efficiency sterilization laundry composition composed of the following components in parts by weight: 11-17 parts of a water soluble polyurethane surfactant, 26-37 parts of isooctyl polyoxypropylene ether sodium sulfate, 7-11 parts of lauryl glucoside, 0.2-0.7 part of an enzyme, 1-3 parts of polyethylene glycol oleate, 1-5 parts of clove flower essential oil, 4-9 parts of a longan flower extract product, 12-18 parts of a sea buckthorn seed slag enzymolysis product, and 27-43 parts of a vinegar solid fermentation substrate aqueous extract liquid, wherein the enzyme is a composition of amylase and cellulase, and the weight ratio of the amylase to the cellulase is 1 to 1. The invention aims to provide the super concentrated high-efficiency sterilization laundry composition which not only has the advantages of rich foams, strong detergency and good sterilization effect but also can moisten user hand skin.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, and in particular to a kind of hyperconcetration efficient sterilizing laundry composition.
Background technology
Detergent is one of aily life necessitys.As the liquid detergent of one of detergent, due to its have it is easy to use,
Dissolving is rapid, cold washing effect is good and the advantages of to fabric and gentle skin, is always maintained at surgingly increasing in recent years, market
Volume of production and marketing rises rapidly, so as to become the Main way of detergent development.And Superconcentrated washing liquid is with ordinary liquid laundry detergent
On the basis of advantage, more have concurrently active matter content height, strong detergency, low production cost, carbon emission amount it is few, save packaging material and
The advantages of reducing cost of transportation.Therefore more meet the requirement of the sustainable development of socio-economy, be the main development of following detergent
Trend.
Although Superconcentrated washing liquid has above-mentioned many obvious advantages, hyperconcetration product real on Vehicles Collected from Market
It is rarely found.One of the main reasons is, because formulation actives content is higher, to cause exploitation Related product to have certain technical difficulty,
The problems such as easily occurring bad gel, product low-temperature stability and the bad dispersibility in water when using in production.
In order to overcome above-mentioned technical barrier, qualified Superconcentrated washing liquid product is prepared, prior art mainly passes through
Substantial amounts of solvent, such as ethanol, propane diols, MEA, triethanolamine are added in formula, to improve surfactant and help
The solubility of agent, and promote the compatibility of each component, make system keep dissolubility or the dispersion of stable homogeneous and improving product
Property etc..Such as Chinese patent application CN201110160696.0 disclose a kind of environment-friendly type type hyperconcentration biological enzyme liquid laundry detergent and its
Preparation method, it uses the solvent of 0.5-30 parts.
It can be seen that, substantial amounts of solvent would generally be used in the Superconcentrated washing formula of liquid of prior art, carry such that it is able to reach
The solubility and compatibility of high raw material, and product viscosity can be reduced, the effect for conveniently producing and using.But there is also substantially
Defect, generally these solvents decontamination itself is less, it is impossible to lift washing functions, formulation cost can be but significantly increased, drop
The ratio of performance to price of low product；Also very big smell can be brought to product simultaneously, be there may be when producing and using certain
Potential safety hazard；In addition, last these solvent discharges can also have undesirable effect in environment to environment.
Therefore, in detergent market in the urgent need to a kind of not solvent-laden, safety and environmental protection, foam stability is good, cost performance
Height, the Superconcentrated washing product of strong detergency.
The content of the invention
It is an object of the invention to provide a kind of hyperconcetration efficient sterilizing laundry composition, not only with foaming abundancy, goes
Dirty power is strong, and bactericidal effect is good, and can moisten user's hand skin.
The present invention is a kind of hyperconcetration efficient sterilizing laundry composition by the following technical programs to realize above-mentioned purpose,
It is made up of the component of following parts by weight meter：Soluble polyurethane type surfactant 11-17 parts, isooctanol polyethenoxy ether
Sodium sulphate 26-37 parts, Dodecyl Polyglucosides 7-11 parts, enzyme 0.2-0.7 parts, Polyethylene Glycol Oleate 1-3 parts, lilac
Essential oil 1-5 parts, flos longan extract product 4-9 parts, seed residues of seabuckthorn enzymolysis product 12-18 parts, vinegar unstrained spirits aqueous extract 27-43
Part；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the hyperconcetration efficient sterilizing laundry composition is made up of the component of following percentage by weight meter：Water
Soluble polyurethane type surfactant 13-16 parts, isooctanol polyoxypropylene ether sodium sulfate 29-34 parts, Dodecyl Polyglucosides
8-9 parts, enzyme 0.3-0.5 parts, Polyethylene Glycol Oleate 1-2 parts, cloves flower essential oil 2-3 parts, flos longan extract product 5-8
Part, seed residues of seabuckthorn enzymolysis product 13-15 parts, vinegar unstrained spirits aqueous extract 32-38 parts；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
The preparation method of hyperconcetration efficient sterilizing laundry composition of the present invention, comprises the following steps：Add toward softened water
Soluble polyurethane type surfactant and isooctanol polyoxypropylene ether sodium sulfate, stir, and add oleic acid polyethylene glycol
Ester, Dodecyl Polyglucosides, enzyme, cloves flower essential oil, stir, be eventually adding flos longan extract product, vinegar unstrained spirits aqueous extract,
Seed residues of seabuckthorn enzymolysis product stirs.
Hyperconcetration efficient sterilizing laundry composition of the present invention is highly concentrated liquid detergent, with soluble polyurethane type surface
Activating agent and isooctanol polyoxypropylene ether sodium sulfate are aided with Polyethylene Glycol Oleate as primary surfactant, then coordinate starch
The composition of enzyme and cellulase, quickly can work and by its effective removal with the spot on fabric, while each component is cooperateed with,
Stable system, can extend the shelf-life of product.
In the present invention, vinegar unstrained spirits aqueous extract, flos longan are extracted in product, seed residues of seabuckthorn enzymolysis product and are lived rich in natural biological
Property composition, it is strong to the permeability of skin by these bioactive ingredients by synergistic function, can pass through cuticula and skin
Skin epithelial cell is combined, and participates in and improve the metabolism of Skin Cell, strengthens the collagen activity in skin.It can keep angle
The integrality of matter layer moisture and fibre structure, improves Skin Cell living environment and promotes the metabolism of skin histology, strengthens
Blood circulation, reaches the purpose of skin care, makes hyperconcetration efficient sterilizing laundry composition have functions that skin care.
What the present invention was added in the active ingredient of laundry composition is proposed from natural materials with biologically active
The material of composition, not only with foaming abundancy, strong detergency, and user's hand skin can be moistened.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than the embodiment of whole.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of isooctanol polyoxypropylene ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, oleic acid gather
2 parts of glycol ester, 2 parts of cloves flower essential oil, flos longan extract 7 parts of product, 14 parts of seed residues of seabuckthorn enzymolysis product, vinegar unstrained spirits water extraction
Take 35 parts of liquid；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Embodiment 2
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of isooctanol polyoxypropylene ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.3 part of enzyme, oleic acid
1 part of macrogol ester, 2 parts of cloves flower essential oil, flos longan extract 5 parts of product, 13 parts of seed residues of seabuckthorn enzymolysis product, vinegar unstrained spirits water
32 parts of extract；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Embodiment 3
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of isooctanol polyoxypropylene ether sodium sulfate, 9 parts of Dodecyl Polyglucosides, 0.5 part of enzyme, oleic acid
2 parts of macrogol ester, 3 parts of cloves flower essential oil, flos longan extract 8 parts of product, 15 parts of seed residues of seabuckthorn enzymolysis product, vinegar unstrained spirits water
38 parts of extract；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Embodiment 4
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
13 parts of surfactant, 29 parts of isooctanol polyoxypropylene ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, oleic acid gather
2 parts of glycol ester, 2 parts of cloves flower essential oil, flos longan extract 7 parts of product, 14 parts of seed residues of seabuckthorn enzymolysis product, vinegar unstrained spirits water extraction
Take 35 parts of liquid；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Embodiment 5
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
16 parts of surfactant, 34 parts of isooctanol polyoxypropylene ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, oleic acid gather
2 parts of glycol ester, 2 parts of cloves flower essential oil, flos longan extract 7 parts of product, 14 parts of seed residues of seabuckthorn enzymolysis product, vinegar unstrained spirits water extraction
Take 35 parts of liquid；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Comparative example 1
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Isooctanol polyoxypropylene
32 parts of ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, 2 parts of Polyethylene Glycol Oleate, 2 parts of cloves flower essential oil, dragon
7 parts of product, 14 parts of seed residues of seabuckthorn enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract are extracted in dim eyesight；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Comparative example 2
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, 2 parts of Polyethylene Glycol Oleate, 2 parts of cloves flower essential oil,
Flos longan extracts 7 parts of product, 14 parts of seed residues of seabuckthorn enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Comparative example 3
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of isooctanol polyoxypropylene ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, oleic acid gather
2 parts of glycol ester, 2 parts of cloves flower essential oil, 14 parts of seed residues of seabuckthorn enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the seed residues of seabuckthorn enzymolysis product is：Seed residues of seabuckthorn Jing impurity eliminations, the pretreatment such as blend
Afterwards, with solid-liquid ratio 1: 5（m/V）Add water, soaked overnight, by the way of trypsase and papain mixed enzymolysis, enzymolysis
Condition is：The enzyme concentration of 45 DEG C of temperature, pH 7.5, the .5h of hydrolysis time 2, trypsase and papain is respectively
1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant,
Obtain seed residues of seabuckthorn enzymolysis product through micro-filtration again.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Comparative example 4
A kind of hyperconcetration efficient sterilizing laundry composition, is made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of isooctanol polyoxypropylene ether sodium sulfate, 8 parts of Dodecyl Polyglucosides, 0.4 part of enzyme, oleic acid gather
2 parts of glycol ester, 2 parts of cloves flower essential oil, flos longan extract 7 parts of product, 35 parts of vinegar unstrained spirits aqueous extract；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 under room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio is 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, in proper amount of acetone solution maleic anhydride is added, and is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution reaction simultaneously under conditions of having nitrogen protection；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then after four hours,
Suitable quantity of water is added to seal up for safekeeping in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the flos longan extraction product is：By flos longan clean dry, then flos longan is ground
50 mesh sieves are clayed into power and cross, the flos longan powder after sieving adds 70% ethanol, the quality (g) of flos longan powder
With the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；Dragon
The Jing water-baths backflow extraction again of dim eyesight ethanol, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation
(5000r/min, 15min), rotary evaporation in vacuo reclaims ethanol after filtration, obtains flos longan crude extract；HPD-300 is big
Hole resin soaks 24 h with 95% ethanol, and distilled water is cleaned to after without ethanol flavor and is put into 20 cm × 240 cm macropore trees
The special chromatographic column of fat；Flos longan crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in
On HPD-300 macroreticular resins, upper column quantity is 600 BV；The resin for the having adsorbed distilled water of 800 BV is with 1000 BV
Impurity on the flow velocity eluted resin of/h, then the crude extract being attached on resin is carried out with 60% ethanol of 1200 BV
Wash-out, obtains flos longan and extracts product after wash-out liquid condensing concentration.
Comparative example 5
This comparative example chooses prestige Lay（Guangzhou）The batch of commodity Co., Ltd production is that 20150821 Wei Lushi imitates laundry entirely
Liquid.
Comparative example 6
This comparative example is the laundry composition prepared according to CMC GBs.
Measure of merit
1. dirt-removing power
1.1 detergencies are tested
According to GB ∕ T 13174-2008, the laundry composition prepared in testing example 1-5 and comparative example 1-6 is to three kinds of dirts
Cloth（JB01-carbon black soiled cotton, JB02-albumen soiled cotton and JB03-sebum soiled cotton）Detergency.Tested in 457nm with whiteness instrument
Soiled cotton wash before whiteness value.Four pieces of every kind of soiled cotton（6cm×6cm）, wash at 30 DEG C.Detergency test machine rotating speed is 120rpm, is stirred
Mix 20min.Then, the whiteness value after measurement washing, rinsing and drying.With same method, using standard flour as doing with reference to sample
Identical test.Detergency is expressed from the next：Detergency=（RAW-RBW）/（RAW R-RBW R）；
Wherein, RAWAnd RBWWhiteness value respectively before and after laundry composition washing, RAW RAnd RBW RRespectively before and after standard flour washing
Average whiteness value.
| Test group | JB01 | JB02 | JB03 |
| Embodiment 1 | 1.63 | 1.79 | 1.73 |
| Embodiment 2 | 1.53 | 1.77 | 1.72 |
| Embodiment 3 | 1.60 | 1.81 | 1.76 |
| Embodiment 4 | 1.44 | 1.85 | 1.83 |
| Embodiment 5 | 1.37 | 1.52 | 1.66 |
| Comparative example 1 | 0.41 | 0.57 | 0.42 |
| Comparative example 2 | 0.60 | 0.35 | 0.20 |
| Comparative example 3 | 0.50 | 0.75 | 0.61 |
| Comparative example 4 | 0.61 | 0.65 | 0.52 |
| Comparative example 5 | 1.03 | 1.13 | 0.99 |
| Comparative example 6 | 0.95 | 1.01 | 0.88 |
2. foaming properties
Foaming properties are according to Malaysian palm oil association（MPOB）Internalist methodology is tested.By embodiment 1-5 and comparative example 1-6
Laundry composition prepare 0.2% sample aqueous solution.30 generation foams, note are stirred up and down with a standard piston in graduated cylinder
Foam height when record starting and 5min is foamability, and the change of foam height turns to foam stability.
| Test group | Initial foam height（mm） | Foam height after 5 minutes（mm） |
| Embodiment 1 | 290 | 140 |
| Embodiment 2 | 280 | 135 |
| Embodiment 3 | 275 | 135 |
| Embodiment 4 | 280 | 140 |
| Embodiment 5 | 285 | 130 |
| Comparative example 1 | 195 | 65 |
| Comparative example 2 | 235 | 85 |
| Comparative example 3 | 215 | 60 |
| Comparative example 4 | 245 | 100 |
| Comparative example 5 | 270 | 120 |
| Comparative example 6 | 255 | 130 |
3. moisturizing degree test
The remaining amount of moisture evaporation is moisturizing tolerance in uniform temperature environment, detects the height of its moisture to determine moisturizing degree
Amount, operating procedure is as follows：（1）The laundry composition sample 5.00g of embodiment 1-5 and comparative example 1-6 is weighed respectively, is placed in two
In beaker, 100mL distilled water is added to be sufficiently stirred for being uniformly dissolved, it is standby.（2）Put using the qualitative filter paper of same size quality
Dry to constant weight in 80 DEG C of thermostatic drying chamber, and record the weight of constant weight filter paper.（3）Drawn respectively with quantitative pipette
The each 2mL of the laundry composition sample solution of embodiment 1-5 and comparative example 1-6 is stated, above-mentioned two is added drop-wise to and is dried to constant weight
On filter paper, it is placed in（48±2）DEG C thermostatic drying chamber in be dried after 8h, weigh respectively, calculate volatilization residue after moisture.
| Test group | Moisturizing degree（Relative water content %） |
| Embodiment 1 | 7.02 |
| Embodiment 2 | 6.79 |
| Embodiment 3 | 6.96 |
| Embodiment 4 | 7.00 |
| Embodiment 5 | 6.68 |
| Comparative example 1 | 3.92 |
| Comparative example 2 | 3.77 |
| Comparative example 3 | 2.48 |
| Comparative example 4 | 2.32 |
| Comparative example 5 | 3.38 |
| Comparative example 6 | 4.15 |
4. bacteriostatic test
It is 5.0 × 10 to prepare bacteria concentration respectively5-5.0×106The staphylococcus aureus bacteria suspension of cfu/ml and Escherichia coli
Bacteria suspension, takes 0.1ml bacteria suspensions and is spread evenly across Bacteria Culture primary surface, after its natural drying, places an Oxford cup and exists
Central authorities, light pressure is fixed.Laundry composition in extraction embodiment 1-5 and comparative example 1-6（Concentration is 0.2%）0.2ml is to Oxford
In cup, 37 DEG C are cultivated 24 hours, calculate antibacterial circle diameter size.With the PBS liquid of pH 7.2 as negative control, be not added with it is any
The culture medium of nutrient solution is used as aseptic blank.Every kind of liquid detergent sample is parallel to make 3 flat boards, repeats 2 times.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of the spirit or essential attributes of the present invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask rather than described above is limited, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity those skilled in the art should
Using specification as an entirety, the technical scheme in each embodiment can also Jing it is appropriately combined, form those skilled in the art
Understandable other embodiment.The ins and outs not described in detail in the present invention, can pass through arbitrary in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (6)
1. a kind of hyperconcetration efficient sterilizing laundry composition, it is characterised in that be made up of the component of following parts by weight meter：It is water-soluble
Property polyurethane-type surfactant 11-17 parts, isooctanol polyoxypropylene ether sodium sulfate 26-37 parts, Dodecyl Polyglucosides 7-
11 parts, enzyme 0.2-0.7 parts, Polyethylene Glycol Oleate 1-3 parts, cloves flower essential oil 1-5 parts, flos longan extract product 4-9 parts,
Seed residues of seabuckthorn enzymolysis product 12-18 parts, vinegar unstrained spirits aqueous extract 27-43 parts；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
2. hyperconcetration efficient sterilizing laundry composition according to claim 1, it is characterised in that the hyperconcetration is efficiently killed
Bacterium laundry composition is made up of the component of following percentage by weight meter：It is soluble polyurethane type surfactant 13-16 parts, different
Octanol polyoxypropylene ether sodium sulfate 29-34 parts, Dodecyl Polyglucosides 8-9 parts, enzyme 0.3-0.5 parts, Polyethylene Glycol Oleate
1-2 parts, cloves flower essential oil 2-3 parts, flos longan extract product 5-8 parts, seed residues of seabuckthorn enzymolysis product 13-15 parts, vinegar unstrained spirits water extraction
Take liquid 32-38 parts；
It is 1 that described enzyme is the weight ratio of the composition of amylase and cellulase, the amylase and cellulase:1.
3. hyperconcetration efficient sterilizing laundry composition according to claim 1, it is characterised in that the vinegar unstrained spirits aqueous extract
Preparation method be：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 solid-liquid ratio（g:mL）Distilled water is added, vibration under room temperature is carried
Take and filtered to get filtrate after 3 h, by filtrate again by 0.22 μm of sterilised membrane filter filtration sterilization, obtain vinegar unstrained spirits aqueous extract.
4. hyperconcetration efficient sterilizing laundry composition according to claim 1, it is characterised in that the seed residues of seabuckthorn enzymolysis
The preparation method of product is：Seed residues of seabuckthorn Jing after impurity elimination, the pretreatment such as blending, with solid-liquid ratio 1: 5（m/V）Add water, soaked
At night, by the way of trypsase and papain mixed enzymolysis, enzymatic hydrolysis condition is：45 DEG C of temperature, pH 7.5, hydrolysis
The enzyme concentration of the .5h of time 2, trypsase and papain is respectively 1500 U/g and 1300U/g；The enzyme that goes out after terminating is digested,
By enzymolysis liquid, 5000r/min is centrifuged 10min at 4 DEG C, takes supernatant, then obtains seed residues of seabuckthorn enzymolysis product through micro-filtration.
5. hyperconcetration efficient sterilizing laundry composition according to claim 1, it is characterised in that the soluble polyurethane
The preparation method of type surfactant is：S1, weighs diisocyanate, maleic anhydride and the polyethylene glycol of equivalent, its mass ratio
For 3：8：5；S2, takes polyethylene glycol and appropriate dibutyl tin laurate that S1 is weighed in flask, stirs；S3,
Maleic anhydride is added in proper amount of acetone solution, is stirred；S4, adds in the solid formed to second step under stirring
Enter the 3rd step formation solution, after flask is placed on into 65 DEG C under conditions of react；S5, after four hours, protects there is nitrogen
Under conditions of stir simultaneously and add diisocyanate solution reaction；After S6, then four hours, three appropriate hydroxyls are added in flask
Methylpropane, closes beaker bottleneck；S7, then after four hours, add suitable quantity of water to seal up for safekeeping in flask；S8, half
Taking precipitate is clean in 45 DEG C of acetone soln after month, is drying to obtain soluble polyurethane surfactant.
6. hyperconcetration efficient sterilizing laundry composition according to claim 1, it is characterised in that the flos longan is extracted
The preparation method of product is：By flos longan clean dry, then flos longan grind into powder and 50 mesh sieves are crossed, after sieving
Flos longan powder adds 70% ethanol, and the quality (g) of flos longan powder is with the volume (mL) of ethanol than m: V=1:
13；Supersonic oscillations instrument (40 DEG C, the 450 W) min of assisted extraction 20；The Jing water-baths backflow extraction again of flos longan ethanol,
Extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, and suction filtration centrifugation (5000r/min, 15min) is true after filtration
Empty rotary evaporation reclaims ethanol, obtains flos longan crude extract；HPD-300 macroreticular resins are soaked into 24 h with 95% ethanol, is steamed
Distilled water is cleaned to after without ethanol flavor and is put into the special chromatographic column of 20 cm × 240 cm macroreticular resins；Flos longan crude extract with
400 BV /h( BV:The volume of macroreticular resin) the rate of adsorption be adsorbed on HPD-300 macroreticular resins, upper column quantity is
600 BV；The resin for the having adsorbed distilled water of 800 BV with the impurity on the flow velocity eluted resin of 1000 BV/h, then
The crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, after wash-out liquid condensing concentration longan is obtained
Flower extracts product.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106955369A (en) * | 2017-05-22 | 2017-07-18 | 陶圣香 | A kind of preparation method of contact lens care solution |
| CN108865503A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin washing powder and preparation method thereof |
-
2016
- 2016-11-03 CN CN201610955430.8A patent/CN106566699A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106955369A (en) * | 2017-05-22 | 2017-07-18 | 陶圣香 | A kind of preparation method of contact lens care solution |
| CN108865503A (en) * | 2018-06-29 | 2018-11-23 | 广西浙缘农业科技有限公司 | A kind of Tea Saponin washing powder and preparation method thereof |
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