CN106753839A - A kind of degerming laundry detergent compositions of fixation - Google Patents
A kind of degerming laundry detergent compositions of fixation Download PDFInfo
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- CN106753839A CN106753839A CN201610955432.7A CN201610955432A CN106753839A CN 106753839 A CN106753839 A CN 106753839A CN 201610955432 A CN201610955432 A CN 201610955432A CN 106753839 A CN106753839 A CN 106753839A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
- C11D3/364—Organic compounds containing phosphorus containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38609—Protease or amylase in solid compositions only
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38618—Protease or amylase in liquid compositions only
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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Abstract
It is an object of the invention to provide a kind of degerming laundry detergent compositions of fixation, with natural plant composition as primary raw material, contain abundant bioactive ingredients in extracting product, mangrove bark enzymolysis product, vinegar unstrained spirits aqueous extract by Rosemary Oil, cape jasmine, reach the degerming effect of Synergistic antibacterial, with natural plant fragrance, can go to eliminate the unusual smell, skin care does not stimulate, the COLOR FASTNESS PROBLEM of clothing can be reduced on minimum level.
Description
Technical field
The invention belongs to daily-use chemical industry technical field, and in particular to a kind of degerming laundry detergent compositions of fixation.
Background technology
Laundry detergent common in the market is made up of industrial chemistry material and surfactant, although washing
Convenient, decontamination is quick, but chemical laundry detergent has potential hazard to health.For example, the clothing being dissolved in water is used
Detergent, can be entered in human body by skin absorption, and long term accumulation easily damages liver function, or even carcinogenic.Laundry detergent is
The alkali electroless detergent of sodium alkyl benzene sulfonate, sodium sulphate, toluene sodium iodate, sodium tripolyphosphate and carboxymethyl cellulose synthesis,
Often contact laundry detergent (water), easily makes Keratoderma, is chapped from the cold；Liver function can be influenceed after into human body hemopoietic system.
Enzyme-added laundry detergent adds alkali protease, to hydrolyze the protein on clothing, plays a part of decontamination contaminant releasing, but alkali
The property same decomposable asymmetric choice net skin surface protein of protease, makes one to suffer from allergic dermatitis, eczema etc..
Though also, now laundry detergent on the market with extremely strong dirt-removing power, while decontamination, also easily
So that clothing fades, the quality of clothing and attractive in appearance has been had influence on.As society and consumer increasingly weigh to health, sanitation and hygiene
Depending on development can both reach the purpose of fabric cleaning, can be again a kind of trend with fade-proof laundry detergent.
The content of the invention
It is main with natural plant composition it is an object of the invention to provide a kind of degerming laundry detergent compositions of fixation
Raw material, abundant biology is contained in extracting product, mangrove bark enzymolysis product, vinegar unstrained spirits aqueous extract by Rosemary Oil, cape jasmine
Active component, reaches the degerming effect of Synergistic antibacterial, with natural plant fragrance, can go to eliminate the unusual smell, and skin care does not stimulate,
The COLOR FASTNESS PROBLEM of clothing can be reduced on minimum level.
The present invention is a kind of degerming laundry detergent compositions of fixation by the following technical programs to realize above-mentioned purpose,
It is made up of the component of following parts by weight meter：11-17 parts of soluble polyurethane type surfactant, glycolic cellulose 26-
37 parts, Explotab 7-11 parts, enzyme 0.2-0.7 parts, soybean lecithin 1-3 parts, Rosemary Oil 1-5 parts, cape jasmine carries
Take product 4-9 parts, 12-18 parts of mangrove bark enzymolysis product, 27-43 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the degerming laundry detergent compositions of the fixation are made up of the component of following percentage by weight meter：Water
13-16 parts of soluble polyurethane type surfactant, glycolic cellulose 29-34 parts, Explotab 8-9 parts, enzyme
0.3-0.5 parts, soybean lecithin 1-2 parts, Rosemary Oil 2-3 parts, cape jasmine extract 5-8 parts of product, mangrove bark enzymolysis product
13-15 parts, 32-38 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
The preparation method of the degerming laundry detergent compositions of fixation of the present invention, comprises the following steps：Added toward softened water
Soluble polyurethane type surfactant and glycolic cellulose, stir, and add Polyethylene Glycol Oleate, starch ethanol
Sour sodium, enzyme, Rosemary Oil, stir, and are eventually adding cape jasmine and extract product, vinegar unstrained spirits aqueous extract, mangrove bark enzymolysis product
Stir.
The degerming laundry detergent compositions of fixation of the present invention are with soluble polyurethane type surfactant and cellulosic ethanol
Acid is aided with Polyethylene Glycol Oleate as primary surfactant, then coordinates the composition of amylase and cellulase, can quickly with
Spot on fabric works and by its effective removal, while each component is cooperateed with, stable system can extend the shelf-life of product.
In the present invention, vinegar unstrained spirits aqueous extract, cape jasmine extract product, in mangrove bark enzymolysis product rich in natural bioactive into
Point, by these bioactive ingredients by synergistic function, while cause can be acted on by the Synergistic of each component
The cell membrane and cell film system of germ, destroy directly and rapidly the energetic supersession and cell that depend on membrane structure integrality and thin
The selective permeability to material that born of the same parents' device is depended on for existence, makes nutriment and metabolite to make normally through cell membrane
Microorganism loses nutrition and causes its growth retardation, reaches the purpose of restraining and sterilizing bacteria；Or the breathing by suppressing pathogenic bacteria is made
With making metabolic activity be obstructed, it is impossible to maintain normal dynamic membrane structure, cause the self-dissolving of cell.By in invention activity into
The groups such as the abundant hydroxyl contained in point, easily form hydrogen bond with active site in alcohol, and then cause metabolic system disorderly, enter
And reach the effect of antibiotic and sterilizing.
The present invention is extracted product, mangrove bark and is digested with natural plant composition as primary raw material by Rosemary Oil, cape jasmine
Containing abundant bioactive ingredients in product, vinegar unstrained spirits aqueous extract, the degerming effect of Synergistic antibacterial is reached, with natural
Plant flavour, can be gone to eliminate the unusual smell, and skin care does not stimulate, and the COLOR FASTNESS PROBLEM of clothing can be reduced on minimum level.
Specific embodiment
Technical scheme is clearly and completely described below in conjunction with the embodiment of the present invention, it is clear that retouched
The embodiment stated is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention, this
The every other embodiment that field those of ordinary skill is obtained under the premise of creative work is not made, belongs to the present invention
The scope of protection.
Embodiment 1
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of glycolic cellulose, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, fan change
2 parts of essential oil, cape jasmine extract 7 parts of product, 14 parts of mangrove bark enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Embodiment 2
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of glycolic cellulose, 8 parts of Explotab, 0.3 part of enzyme, 1 part of soybean lecithin, fan
Repeatedly 2 parts of essential oil, cape jasmine extract 5 parts of product, 13 parts of mangrove bark enzymolysis product, 32 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Embodiment 3
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of glycolic cellulose, 9 parts of Explotab, 0.5 part of enzyme, 2 parts of soybean lecithin, fan
Repeatedly 3 parts of essential oil, cape jasmine extract 8 parts of product, 15 parts of mangrove bark enzymolysis product, 38 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Embodiment 4
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
13 parts of surfactant, 29 parts of glycolic cellulose, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, fan change
2 parts of essential oil, cape jasmine extract 7 parts of product, 14 parts of mangrove bark enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Embodiment 5
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
16 parts of surfactant, 34 parts of glycolic cellulose, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, fan change
2 parts of essential oil, cape jasmine extract 7 parts of product, 14 parts of mangrove bark enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Comparative example 1
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Glycolic cellulose 32
Part, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, 2 parts of Rosemary Oil, cape jasmine extract 7 parts of product, awns
14 parts of pericarp enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Comparative example 2
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, 2 parts of Rosemary Oil, cape jasmine carry
Take 7 parts of product, 14 parts of mangrove bark enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Comparative example 3
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of glycolic cellulose, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, fan change
2 parts of essential oil, 14 parts of mangrove bark enzymolysis product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the mangrove bark enzymolysis product is：Mangrove bark after stripping and slicing, the pretreatment such as blending,
With solid-liquid ratio 1: 3（m/V）Add water, soaked overnight by the way of cellulase and papain mixed enzymolysis, digests bar
Part is：The enzyme concentration of 45 DEG C of temperature, pH 6.5, the .5h of hydrolysis time 2, cellulase and papain is respectively 1500
U/g and 1300U/g；The enzyme that gone out after terminating is digested, 5000r/min is centrifuged 10min at 4 DEG C by enzymolysis liquid, takes supernatant, then pass through
Micro-filtration obtains mangrove bark enzymolysis product.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Comparative example 4
A kind of degerming laundry detergent compositions of fixation, are made up of the component of following percentage by weight meter：Soluble polyurethane type
15 parts of surfactant, 32 parts of glycolic cellulose, 8 parts of Explotab, 0.4 part of enzyme, 2 parts of soybean lecithin, fan change
2 parts of essential oil, cape jasmine extract 7 parts of product, 35 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
Further, the preparation method of the vinegar unstrained spirits aqueous extract is：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 material
Liquor ratio（g:mL）Distilled water is added, is filtered to get filtrate after the h of mechanical shaking extraction 3 at room temperature, filtrate is aseptic by 0.22 μm again
Membrane filtration is degerming, obtains vinegar unstrained spirits aqueous extract, is saved backup under the conditions of 4 DEG C.
Further, the preparation method of the soluble polyurethane type surfactant is：S1, weighs two isocyanides of equivalent
Acid esters, maleic anhydride and polyethylene glycol, its mass ratio are 3：8：5；S2, takes polyethylene glycol that S1 weighs and suitable in flask
The dibutyl tin laurate of amount, stirs；S3, maleic anhydride is added in proper amount of acetone solution, is stirred；S4,
The solution for adding the 3rd step to be formed in the solid formed to second step under the stirring, after flask is placed on 65 DEG C of condition
Lower reaction；S5, after four hours, stirs and adds diisocyanate solution to react simultaneously under conditions of having nitrogen to protect；S6,
Again after four hours, appropriate trimethylolpropane is added in flask, close beaker bottleneck；S7, then by after four hours,
Sealed up for safekeeping to suitable quantity of water is added in flask；S8, taking precipitate is clean in 45 DEG C of acetone soln after two weeks, is drying to obtain water
Soluble polyurethane surfactant.
Further, the preparation method of the cape jasmine extraction product is：By cape jasmine clean dry, then cape jasmine is pulverized
50 mesh sieves are simultaneously crossed in end, and the Cape Jasmine Fruit after sieving adds 70% ethanol, the quality (g) of Cape Jasmine Fruit and the body of ethanol
Product (mL) is than m: V=1: 13；Supersonic oscillations instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol is again
Flowed back through water-bath and extracted, extraction temperature is 65 DEG C, extraction 3 times, every time 1.5 h, suction filtration centrifugation (5000r/min,
15min), rotary evaporation in vacuo reclaims ethanol after filtering, obtains cape jasmine crude extract；By 95% second of HPD-300 macroreticular resins
Alcohol soaks 24 h, and distilled water is cleaned to after without ethanol flavor and is put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine
Sub- crude extract is with 400 BV/h (BV:The volume of macroreticular resin) the rate of adsorption be adsorbed in HPD-300 macroreticular resins
On, upper column quantity is 600 BV；The resin for having adsorbed cleans tree with the distilled water of 800 BV with the flow velocity of 1000 BV/h
Impurity on fat, then the crude extract being attached on resin is eluted with 60% ethanol of 1200 BV, elute liquid condensing
Cape jasmine is obtained after concentration and extracts product.
Comparative example 5
This comparative example chooses prestige Lay（Guangzhou）The batch of commodity Co., Ltd production is that 20150821 Wei Lushi imitates laundry entirely
Liquid.
Comparative example 6
This comparative example is the laundry detergent compositions prepared according to CMC GBs.
Measure of merit
1. detergency experiment
According to the laundry detergent compositions pair prepared in GB ∕ T 13174-2008, testing example 1-5 and comparative example 1-6
Three kinds of soiled cottons（JB01-carbon black soiled cotton, JB02-albumen soiled cotton and JB03-sebum soiled cotton）Detergency.Existed with whiteness instrument
The whiteness value that 457nm is tested before soiled cotton is washed.Four pieces of every kind of soiled cotton（6cm×6cm）, washed at 30 DEG C.Detergency test machine rotating speed is
120rpm, stirs 20min.Then, the whiteness value after measurement washing, rinsing and drying.With same method, using standard flour as
Identical test is done with reference to sample.Detergency is expressed from the next：Detergency=（RAW-RBW）/（RAW R-RBW R）；
Wherein, RAWAnd RBWWhiteness value respectively before and after laundry detergent compositions washing, RAW RAnd RBW RRespectively standard flour is washed
Wash front and rear average whiteness value.
| Test group | JB01 | JB02 | JB03 |
| Embodiment 1 | 1.56 | 1.72 | 1.66 |
| Embodiment 2 | 1.47 | 1.70 | 1.65 |
| Embodiment 3 | 1.53 | 1.73 | 1.69 |
| Embodiment 4 | 1.38 | 1.77 | 1.75 |
| Embodiment 5 | 1.31 | 1.46 | 1.59 |
| Comparative example 1 | 0.39 | 0.54 | 0.40 |
| Comparative example 2 | 0.57 | 0.33 | 0.19 |
| Comparative example 3 | 0.47 | 0.71 | 0.58 |
| Comparative example 4 | 0.58 | 0.61 | 0.49 |
| Comparative example 5 | 1.01 | 1.11 | 0.98 |
| Comparative example 6 | 0.94 | 1.00 | 0.87 |
1.2 whiteness keep experiment
The laundry detergent compositions circulation of embodiment 1-5 and comparative example 1-6 is washed 20 times, whiteness of every 10 surveys
Value.Result is as shown in the table.
| Test group | Whiteness decreasing value after washing 10 times | Whiteness decreasing value after washing 20 times |
| Embodiment 1 | 2.52 | 4.18 |
| Embodiment 2 | 2.74 | 4.36 |
| Embodiment 3 | 2.63 | 4.20 |
| Embodiment 4 | 2.54 | 4.42 |
| Embodiment 5 | 2.69 | 4.40 |
| Comparative example 1 | 3.94 | 7.10 |
| Comparative example 2 | 3.27 | 5.02 |
| Comparative example 3 | 4.60 | 8.20 |
| Comparative example 4 | 3.11 | 5.23 |
| Comparative example 5 | 3.24 | 5.26 |
| Comparative example 6 | 3.79 | 5.15 |
2. bacteriostatic test
It is 5.0 × 10 to prepare bacteria concentration respectively5-5.0×106The staphylococcus aureus bacteria suspension of cfu/ml and Escherichia coli
Bacteria suspension, takes 0.1ml bacteria suspensions and is spread evenly across Bacteria Culture primary surface, after after its natural drying, places an Oxford cup and exists
Center, light pressure is fixed.Laundry detergent compositions in extraction embodiment 1-5 and comparative example 1-6（Concentration is 0.2%）0.2ml
Into Oxford cup, 37 DEG C are cultivated 24 hours, calculate antibacterial circle diameter size.With the PBS liquid of pH 7.2 as negative control, no
Plus the culture medium of any nutrient solution is used as aseptic blank.Every kind of liquid detergent sample is parallel to make 3 flat boards, repeats 2 times.
3. fixation experiment
Take 110 laundry items, every group 10, the laundry detergent group being prepared into embodiment 1-5 and comparative example 1-6 respectively
Compound is cleaned, and washes rear visible, clothing clean and bright, the taste for having delicate fragrance, and spot is all cleaned, and fading does not occur in clothing.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, and do not carrying on the back
In the case of spirit or essential attributes of the invention, the present invention can be in other specific forms realized.Therefore, no matter from which
From the point of view of a bit, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention will by appended right
Ask and limited rather than described above, it is intended that all changes that will fall in the implication and scope of the equivalency of claim
Include in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each implementation method is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that for clarity, those skilled in the art should
Specification an as entirety, the technical scheme in each embodiment can also be formed into those skilled in the art through appropriately combined
May be appreciated other embodiment.The ins and outs not described in detail in the present invention, can be by any in this area
Prior art is realized.Particularly, all technical characterstics not described in detail can be realized by any prior art in the present invention.
Claims (6)
1. degerming laundry detergent compositions of a kind of fixation, it is characterised in that be made up of the component of following parts by weight meter：It is water-soluble
11-17 parts of polyurethane-type surfactant of property, glycolic cellulose 26-37 parts, Explotab 7-11 parts, enzyme 0.2-
0.7 part, soybean lecithin 1-3 parts, Rosemary Oil 1-5 parts, cape jasmine extract 4-9 parts of product, mangrove bark enzymolysis product 12-
18 parts, 27-43 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
2. degerming laundry detergent compositions of fixation according to claim 1, it is characterised in that the degerming clothing of fixation is used
Detergent composition is made up of the component of following percentage by weight meter：13-16 parts of soluble polyurethane type surfactant, fibre
Plain 29-34 parts of the glycolic of dimension, Explotab 8-9 parts, enzyme 0.3-0.5 parts, soybean lecithin 1-2 parts, Rosemary Oil
2-3 parts, cape jasmine extract 5-8 parts of product, 13-15 parts of mangrove bark enzymolysis product, 32-38 parts of vinegar unstrained spirits aqueous extract；
Described enzyme is the composition of amylase and cellulase, and the weight ratio of the amylase and cellulase is 1:1.
3. degerming laundry detergent compositions of fixation according to claim 1, it is characterised in that the vinegar unstrained spirits aqueous extract
Preparation method be：The vinegar unstrained spirits after acetic fermentation is taken, by 1:6 solid-liquid ratio（g:mL）Distilled water is added, vibration at room temperature is carried
Filtered to get filtrate after taking 3 h, by filtrate again by 0.22 μm of sterilised membrane filter filtration sterilization, obtain vinegar unstrained spirits aqueous extract, 4
Saved backup under the conditions of DEG C.
4. degerming laundry detergent compositions of fixation according to claim 1, it is characterised in that the mangrove bark enzymolysis is produced
The preparation method of thing is：Mangrove bark after stripping and slicing, the pretreatment such as blending, with solid-liquid ratio 1: 3（m/V）Add water, soaked overnight is adopted
With cellulase and the mode of papain mixed enzymolysis, enzymatic hydrolysis condition is：45 DEG C of temperature, pH 6.5, hydrolysis time 2
.5h, the enzyme concentration of cellulase and papain is respectively 1500 U/g and 1300U/g；The enzyme that gone out after terminating is digested, will be digested
Liquid 5000r/min centrifugations 10min at 4 DEG C, takes supernatant, then obtain mangrove bark enzymolysis product by micro-filtration.
5. degerming laundry detergent compositions of fixation according to claim 1, it is characterised in that the soluble polyurethane
The preparation method of type surfactant is：S1, weighs diisocyanate, maleic anhydride and the polyethylene glycol of equivalent, its mass ratio
It is 3：8：5；S2, takes polyethylene glycol and appropriate dibutyl tin laurate that S1 is weighed in flask, stirs；S3,
Maleic anhydride is added in proper amount of acetone solution, is stirred；S4, adds in the solid formed to second step under stirring
Enter the 3rd step formation solution, after flask is placed on 65 DEG C under conditions of react；S5, after four hours, protects there is nitrogen
Under conditions of simultaneously stir add diisocyanate solution reaction；After S6, then four hours, three appropriate hydroxyls are added in flask
Methylpropane, closes beaker bottleneck；S7, then by after four hours, being sealed up for safekeeping to suitable quantity of water is added in flask；S8, half
Taking precipitate is clean in 45 DEG C of acetone soln after month, is drying to obtain soluble polyurethane surfactant.
6. degerming laundry detergent compositions of fixation according to claim 1, it is characterised in that the cape jasmine extracts product
Preparation method be：By cape jasmine clean dry, then cape jasmine grind into powder and cross 50 mesh sieves, the Cape Jasmine Fruit after sieving
70% ethanol is added, the quality (g) of Cape Jasmine Fruit is with the volume (mL) of ethanol than m: V=1: 13；Supersonic oscillations
Instrument (40 DEG C, 450 W) min of assisted extraction 20；Cape jasmine ethanol flows back through water-bath extract again, and extraction temperature is 65 DEG C,
Extraction 3 times, 1.5 h every time, suction filtration centrifugation (5000r/min, 15min), rotary evaporation in vacuo reclaims second after filtering
Alcohol, obtains cape jasmine crude extract；HPD-300 macroreticular resins are soaked into 24 h with 95% ethanol, distilled water is cleaned to without ethanol flavor
After be put into the 20 cm × 240 special chromatographic columns of cm macroreticular resins；Cape jasmine crude extract is with 400 BV/h (BV:Macropore tree
The volume of fat) the rate of adsorption be adsorbed on HPD-300 macroreticular resins, upper column quantity be 600 BV；The resin for having adsorbed is used
The distilled water of 800 BV with the impurity on the flow velocity eluted resin of 1000 BV/h, then with 60% ethanol of 1200 BV
Crude extract to being attached on resin is eluted, and obtaining cape jasmine after wash-out liquid condensing concentration extracts product.
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| CN201610955432.7A CN106753839A (en) | 2016-11-03 | 2016-11-03 | A kind of degerming laundry detergent compositions of fixation |
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| CN201610955432.7A Pending CN106753839A (en) | 2016-11-03 | 2016-11-03 | A kind of degerming laundry detergent compositions of fixation |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107593896A (en) * | 2017-10-24 | 2018-01-19 | 程志鹏 | A kind of strawberry preservative and preparation method thereof |
| CN107815364A (en) * | 2017-11-14 | 2018-03-20 | 蒙城县存胜家居清洁用品有限公司 | A kind of Chinese herbal medicine detergent |
| CN111171973A (en) * | 2020-01-03 | 2020-05-19 | 上海万华科聚化工科技发展有限公司 | Multifunctional laundry detergent composition with color fixing and antibacterial effects and preparation method and application thereof |
-
2016
- 2016-11-03 CN CN201610955432.7A patent/CN106753839A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107593896A (en) * | 2017-10-24 | 2018-01-19 | 程志鹏 | A kind of strawberry preservative and preparation method thereof |
| CN107815364A (en) * | 2017-11-14 | 2018-03-20 | 蒙城县存胜家居清洁用品有限公司 | A kind of Chinese herbal medicine detergent |
| CN111171973A (en) * | 2020-01-03 | 2020-05-19 | 上海万华科聚化工科技发展有限公司 | Multifunctional laundry detergent composition with color fixing and antibacterial effects and preparation method and application thereof |
| CN111171973B (en) * | 2020-01-03 | 2021-09-07 | 万华化学集团股份有限公司 | Multifunctional laundry detergent composition with color fixing and antibacterial effects and preparation method and application thereof |
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Application publication date: 20170531 |