CN106573795A - 层状锂‑锰‑镍‑钴氧化物材料的制备 - Google Patents

层状锂‑锰‑镍‑钴氧化物材料的制备 Download PDF

Info

Publication number
CN106573795A
CN106573795A CN201580045337.7A CN201580045337A CN106573795A CN 106573795 A CN106573795 A CN 106573795A CN 201580045337 A CN201580045337 A CN 201580045337A CN 106573795 A CN106573795 A CN 106573795A
Authority
CN
China
Prior art keywords
lmnc
layered
mic
lmnca
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201580045337.7A
Other languages
English (en)
Chinese (zh)
Inventor
K·I·奥佐米纳
C·J·贾夫塔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Scientific And Industrial Research Council
Original Assignee
Scientific And Industrial Research Council
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Scientific And Industrial Research Council filed Critical Scientific And Industrial Research Council
Publication of CN106573795A publication Critical patent/CN106573795A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Complex oxides containing nickel and at least one other metal element
    • C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
    • C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/85—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by XPS, EDX or EDAX data
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/03—Particle morphology depicted by an image obtained by SEM
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
CN201580045337.7A 2014-07-03 2015-07-03 层状锂‑锰‑镍‑钴氧化物材料的制备 Pending CN106573795A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ZA201404912 2014-07-03
ZA2014/04912 2014-07-03
PCT/IB2015/055023 WO2016001884A1 (en) 2014-07-03 2015-07-03 Production of a layered lithium-manganese-nickel-cobalt oxide material

Publications (1)

Publication Number Publication Date
CN106573795A true CN106573795A (zh) 2017-04-19

Family

ID=53900863

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201580045337.7A Pending CN106573795A (zh) 2014-07-03 2015-07-03 层状锂‑锰‑镍‑钴氧化物材料的制备

Country Status (12)

Country Link
US (2) US10396357B2 (enExample)
EP (1) EP3164363B1 (enExample)
JP (1) JP6807307B2 (enExample)
KR (1) KR102385307B1 (enExample)
CN (1) CN106573795A (enExample)
AR (1) AR102033A1 (enExample)
BR (1) BR112017000017A2 (enExample)
CA (1) CA2953296A1 (enExample)
DK (1) DK3164363T3 (enExample)
HU (1) HUE052142T2 (enExample)
PL (1) PL3164363T3 (enExample)
WO (1) WO2016001884A1 (enExample)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111479780A (zh) * 2017-12-18 2020-07-31 戴森技术有限公司 化合物
CN114497533A (zh) * 2022-01-27 2022-05-13 西南石油大学 一种原位尖晶石修饰的低钴球形富锂锰基正极材料及其制备方法
US11658296B2 (en) 2017-12-18 2023-05-23 Dyson Technology Limited Use of nickel in a lithium rich cathode material for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material
US11769911B2 (en) 2017-09-14 2023-09-26 Dyson Technology Limited Methods for making magnesium salts
US11817558B2 (en) 2017-09-14 2023-11-14 Dyson Technology Limited Magnesium salts
US11967711B2 (en) 2017-12-18 2024-04-23 Dyson Technology Limited Lithium, nickel, cobalt, manganese oxide compound and electrode comprising the same

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2973802B1 (en) 2013-03-12 2023-08-30 Apple Inc. High voltage, high volumetric energy density li-ion battery using advanced cathode materials
BR112017000017A2 (pt) * 2014-07-03 2018-11-06 Csir produção de material óxido de lítio, manganês, níquel e cobalto, em camadas
US10297821B2 (en) 2015-09-30 2019-05-21 Apple Inc. Cathode-active materials, their precursors, and methods of forming
CN115395008A (zh) 2016-03-14 2022-11-25 苹果公司 用于锂离子电池的阴极活性材料
GB2548361B (en) 2016-03-15 2020-12-02 Dyson Technology Ltd Method of fabricating an energy storage device
CN112158891B (zh) 2016-09-20 2023-03-31 苹果公司 具有改善的颗粒形态的阴极活性材料
KR102223565B1 (ko) 2016-09-21 2021-03-04 애플 인크. 리튬 이온 배터리용 표면 안정화된 캐소드 재료 및 이의 합성 방법
KR102627568B1 (ko) * 2017-11-22 2024-01-23 에이일이삼 시스템즈 엘엘씨 배터리 캐소드 재료의 금속 도핑 방법 및 시스템
GB2569392B (en) * 2017-12-18 2022-01-26 Dyson Technology Ltd Use of aluminium in a cathode material
GB2569387B (en) 2017-12-18 2022-02-02 Dyson Technology Ltd Electrode
US11695108B2 (en) 2018-08-02 2023-07-04 Apple Inc. Oxide mixture and complex oxide coatings for cathode materials
US11749799B2 (en) 2018-08-17 2023-09-05 Apple Inc. Coatings for cathode active materials
JP2022542849A (ja) * 2019-07-19 2022-10-07 エンウェア エネルジ テクノロジレリ アー エス Ｌｉリッチカソード材料の製造方法
US12074321B2 (en) 2019-08-21 2024-08-27 Apple Inc. Cathode active materials for lithium ion batteries
US12206100B2 (en) 2019-08-21 2025-01-21 Apple Inc. Mono-grain cathode materials
US11757096B2 (en) 2019-08-21 2023-09-12 Apple Inc. Aluminum-doped lithium cobalt manganese oxide batteries
CN115715275B (zh) 2020-05-27 2024-06-25 伍斯特理工学院 单晶阴极材料的简易蚀刻
IT202000016966A1 (it) * 2020-07-13 2022-01-13 Fondazione St Italiano Tecnologia Materiale di ossidi di metalli di transizione ricco di litio
CN112875766B (zh) * 2021-01-28 2022-10-14 山东宏匀纳米科技有限公司 一种添加碳源的微波加热溶液法制备三元正极材料的方法
KR102777965B1 (ko) * 2021-12-02 2025-03-11 연세대학교 산학협력단 리튬과잉 이차전지 양극활물질 및 이의 제조방법

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042377C (zh) * 1996-05-10 1999-03-03 中国科学院物理研究所 一种合成锂离子电池中正极材料的方法
CN1610149A (zh) * 2004-10-13 2005-04-27 广州鸿森材料有限公司 锂离子电池正极材料的制备方法及其设备
CN101121508A (zh) * 2006-08-08 2008-02-13 新疆大学 一种微波合成磷酸亚铁锂电池正极材料的方法
CN102054986A (zh) * 2010-11-16 2011-05-11 中国科学院宁波材料技术与工程研究所 微波法制备的超高容量锂离子电池正极材料及其方法
WO2014024075A1 (en) * 2012-08-10 2014-02-13 Csir Production of a spinel material

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08290917A (ja) * 1995-04-18 1996-11-05 Kansai Shin Gijutsu Kenkyusho:Kk 複合酸化物の製造方法
KR101467070B1 (ko) * 2010-03-19 2014-12-01 도요타지도샤가부시키가이샤 리튬 2차 전지 및 상기 리튬 2차 전지용 정극 활물질
BR112017000017A2 (pt) * 2014-07-03 2018-11-06 Csir produção de material óxido de lítio, manganês, níquel e cobalto, em camadas

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1042377C (zh) * 1996-05-10 1999-03-03 中国科学院物理研究所 一种合成锂离子电池中正极材料的方法
CN1610149A (zh) * 2004-10-13 2005-04-27 广州鸿森材料有限公司 锂离子电池正极材料的制备方法及其设备
CN101121508A (zh) * 2006-08-08 2008-02-13 新疆大学 一种微波合成磷酸亚铁锂电池正极材料的方法
CN102054986A (zh) * 2010-11-16 2011-05-11 中国科学院宁波材料技术与工程研究所 微波法制备的超高容量锂离子电池正极材料及其方法
WO2014024075A1 (en) * 2012-08-10 2014-02-13 Csir Production of a spinel material

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
CHARL J.JAFTA ET AL.: "Microwave-Assisted Synthesis of High-Voltage Nanostructured LiMn1.5Ni0.5O4 Spinel: Tuning the Mn3+ Content and Electrochemical Performance", 《ACS APPL. MATER. INTERFACES》 *
YEN-PEI FU ET AL.: "LiMn2−yMyO4 (M =Cr, Co) cathode materials synthesized by the microwave-induced combustion for lithium ion batteries", 《JOURNAL OF ALLOYS AND COMPOUNDS》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11769911B2 (en) 2017-09-14 2023-09-26 Dyson Technology Limited Methods for making magnesium salts
US11817558B2 (en) 2017-09-14 2023-11-14 Dyson Technology Limited Magnesium salts
CN111479780A (zh) * 2017-12-18 2020-07-31 戴森技术有限公司 化合物
US11658296B2 (en) 2017-12-18 2023-05-23 Dyson Technology Limited Use of nickel in a lithium rich cathode material for suppressing gas evolution from the cathode material during a charge cycle and for increasing the charge capacity of the cathode material
US11967711B2 (en) 2017-12-18 2024-04-23 Dyson Technology Limited Lithium, nickel, cobalt, manganese oxide compound and electrode comprising the same
CN114497533A (zh) * 2022-01-27 2022-05-13 西南石油大学 一种原位尖晶石修饰的低钴球形富锂锰基正极材料及其制备方法

Also Published As

Publication number Publication date
BR112017000017A2 (pt) 2018-11-06
US11183692B2 (en) 2021-11-23
US20170133678A1 (en) 2017-05-11
JP2017521848A (ja) 2017-08-03
CA2953296A1 (en) 2016-01-07
EP3164363A1 (en) 2017-05-10
KR102385307B1 (ko) 2022-04-11
AR102033A1 (es) 2017-02-01
JP6807307B2 (ja) 2021-01-06
WO2016001884A1 (en) 2016-01-07
US20190334171A1 (en) 2019-10-31
EP3164363B1 (en) 2020-08-19
HUE052142T2 (hu) 2021-04-28
PL3164363T3 (pl) 2021-05-17
US10396357B2 (en) 2019-08-27
DK3164363T3 (da) 2020-11-23
KR20170080564A (ko) 2017-07-10

Similar Documents

Publication Publication Date Title
US11183692B2 (en) Production of a layered lithium-manganese-nickel-cobalt oxide material
Liao et al. Surface-modified concentration-gradient Ni-rich layered oxide cathodes for high-energy lithium-ion batteries
Yao et al. Synthesis and electrochemical performance of phosphate-coated porous LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion batteries
US8734675B2 (en) Method for preparing Li4NbxTi5−xO12/C nanocomposite as an anode material for li-ion batteries
Liu et al. Structural and electrochemical properties of Co–Mn–Mg multi-doped nickel based cathode materials LiNi0. 9Co0. 1− x [Mn1/2Mg1/2] xO2 for secondary lithium ion batteries
Du et al. Study of effects on LiNi0. 8Co0. 15Al0. 05O2 cathode by LiNi1/3Co1/3Mn1/3O2 coating for lithium ion batteries
CN114420920B (zh) 一种氟离子梯度掺杂富锂锰基正极材料及其制备方法和应用
Qiu et al. Al2O3 coated LiNi1/3Co1/3Mn1/3O2 cathode material by sol–gel method: preparation and characterization
CN111418094A (zh) 掺杂有镁的锰尖晶石、包含其的阴极材料、其制备方法和包含这样的尖晶石的锂离子电池
CN107108260B (zh) 尖晶石材料的制备
Shen et al. A convenient co-precipitation method to prepare high performance LiNi0. 5Mn1. 5O4 cathode for lithium ion batteries
CN104703920A (zh) 尖晶石材料的制造
Jin et al. Improved electrochemical performances of li-and Mn-Rich layered oxides 0.4 Li4/3Mn2/3O2· 0.6 LiNi1/3Co1/3Mn1/3O2 cathode material by Co3O4 coating
Du et al. Synthesis of Lithium vanadium tetroxide anode material via a fast sol-gel method based on spontaneous chemical reactions
Meng et al. Modification of Li [Li0. 2Mn0. 54Ni0. 13Co0. 13] O2 cathode with α-MoO3 via a simple wet chemical coating process
Zhu et al. A layered/spinel heterostructured cathode for Li-ion batteries prepared by ultrafast Joule heating
Kurilenko et al. The effect of synthesis conditions on the morphology, cation disorder and electrochemical performance of Li1+ xNi0. 5Mn0. 5O2
Song et al. Cycling performance of LiNi1− yMyO2 (M= Ni, Ga, Al and/or Ti) synthesized by wet milling and solid-state method
Jayachandran et al. Tailored solution combustion method for enhancing high voltage electrochemical performance Li1. 2Ni0. 1Mn0. 6Co0. 1O2 as cathode material for lithium-ion batteries
CN108565454A (zh) 一种三维沙漠波浪结构的镍锰酸锂正极材料及其制备方法和应用
Balaji et al. A study on the influence of dysprosium cation substitution on the structural, morphological, and electrochemical properties of lithium manganese oxide
Thirunakaran et al. Cerotic acid assisted sol-gel synthesis and electrochemical performance of double doped spinels (LiCrxMgyMn2-x-yO4) as cathode materials for lithium rechargeable batteries
CN108604673B (zh) 尖晶石材料
Mohan et al. Structure and Electrochemical Performances of Co-Substituted LiCo x Li x− y Mn2− x O4 Cathode Materials for the Rechargeable Lithium Ion Batteries
Zainol et al. Investigation on the electrochemical performances of Li4Mn5O12 for battery applications

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170419