CN106565203A - 黄浆陶瓷制品及其制备方法 - Google Patents
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Abstract
本发明属于陶瓷领域,具体为黄浆陶瓷制品,以米黄泥、水洗高岭土、长石、硅灰石、滑石、木节土、碳酸钡、钛白粉、钛黄色料、腐植酸钠、泡化碱为原料进行配料。本发明提供的黄浆陶瓷制品及其制备方法,配料成本低,烧成温度低,烧成后胎体致密,平整光洁,减少坯件施釉烧成后产生的针孔、开裂、变形、坯泡等缺陷,且坯料性能优良,适于机械化流水线生产。
Description
技术领域
本发明属于陶瓷领域,具体为黄浆陶瓷制品及其制备方法。
背景技术
近几年,随着市场大环境的变化,国内陶瓷企业在生产成本日益攀升及当今社会大力倡导低碳经济环境下生存发展非常艰难,而市场对陶瓷产品的颜色、强度、吸水率、规格尺寸要求越来越高。因此,为满足市场需求,目前陶瓷制品一般采用成本较高的瓷土与其他一些原料进行配制,对原材料和烧成要求较高,成本很难控制,不符合当前形势下陶瓷企业发展需求。为了解决企业对成本、资源、能源和环境问题等方面的要求,急需开发出一种适用于现有陶瓷制品的低成本陶瓷坯料及配套的生产工艺。
发明内容
本发明的目的是,为了解决上述问题,提供一种性能高但是成本低的陶瓷制品及其制备方法,选用较低成本的米黄泥,通过合理的陶瓷生产工艺,使得产品具有木材的黄色,更具艺术特色,且坯料性能优良,适于机械化流水线生产,提高了产品质量,降低了生产成本,而且符合低碳环保生产的要求,能满足陶瓷产品大批量的生产,获得广大客户的青睐。
本发明的技术方案如下:
黄浆陶瓷制品,由以下原料按照重量份数配比制成:米黄泥45~55份,水洗高岭土5~10份,长石20~30份,硅灰石0.5~1.5份,钛黄色料1~3份,滑石2~4份,木节土3~6份,碳酸钡0.3~0.8份,钛白粉0.2~0.6份,腐植酸钠0.1~0.2份,泡化碱0.5~1份。
所述的原料按原料:球:水质量比1﹕1.25~1.35﹕1.25~1.35配比,入筒球磨24~30小时,出筒过100目筛,制得陶瓷制品的注浆坯料;
上述注浆坯料采用注浆成型的方法的制得坯体,烘干后坯体经1100~1150℃温度进行烧制,制成为陶瓷制品。
烧成周期为5~5.5小时,烧成曲线为;窑内温度在1~1.5小时内由窑温匀速升至840℃,再在1~1.5小时内匀速升至1150℃,然后再20~30分钟内降至1080℃,再在20分钟内快速降至890℃,然后再1~1.5小时内慢速降至600℃,最后再自然冷却至室温。
所述的原料按原料:球:水质量比优选1﹕1.3﹕1.3的配比,入筒球磨,经28小时球磨,出筒过100目筛,制得陶瓷制品的注浆坯料;
上述注浆坯料采用注浆成型的方法的制得坯体,烘干后坯体施釉,经1100~1150℃温度进行烧制,制成为陶瓷制品。
米黄泥:颜色为青灰色,高温烧制后呈黄色。因这种泥风化程度好,质地较纯,具有比较好的可塑性和结合能力,可以保持日用陶瓷成型性能及干胚强度,且开采成本较低。
水洗高岭土:是一种深加工后的高岭土。高岭土在陶瓷中的作用是引入Al2O3,有利于莫来石的生成,提高其化学稳定性和烧结强度,在烧成中高岭土分解生成莫来石,形成坯体强度的主要框架,可防止制品的变形,使烧成温度变宽,还能使坯体具有一定的白度。同时,高岭土具有一定的可塑性、粘结性、悬浮性和结合能力,赋予瓷泥、瓷釉良好的成形性。
长石:化学成份为不含水的碱金属或碱土金属铝硅酸盐,主要是钾、钠、钙和少量钡的铝硅酸盐,在陶瓷坯料中作为熔剂作用,在釉料中主要作熔剂,是形成玻璃相的主要成分,增加透明度。
钛白粉:学名二氧化钛(TiO2),分子量:79.88,是一种白色无机颜料,具有无毒、最佳的不透明性、最佳白度和光亮度,被认为是目前世界上性能最好的一种白色颜料,广泛应用于涂料、塑料、造纸、印刷油墨、化纤、橡胶、陶瓷、化妆品及食品添加和医药等工业。
钛黄色料:一种陶瓷颜料,在釉料中起到着色作用。
滑石:日用陶瓷工业常用的熔剂原料之一,能降低烧成温度,扩大烧成温度范围,还可以用来调整坯、釉料的热膨胀系数,减少开裂缺陷的产生,提高白度、透明度、力学性质和热稳定性。
木节土:一种富有机质的高可塑性沉积粘土,主要矿物成分为高岭石、多水高岭石和一水铝石,是陶瓷工业主要的结合粘土。
碳酸钡:化学式BaCO3分子量197.35,六角形微细晶体或白色粉末。用于中和游离的硫酸盐,防止产品在烧成过程中产生杂质。
腐植酸钠、泡化碱:属于陶瓷制品注浆成型坯料的添加剂,起解凝作用,加入少量可降低泥浆粘度,用来改善泥浆流动性,使其在低水份的情况下粘度适当,便于浇注。
本发明提供的黄浆陶瓷制品及其制备方法,采用米黄泥作为主要原料,大幅降低了原材料成本,烧成温度低,节能环保,且烧成的陶瓷制品具有强度高、致密性高、吸水率低、尺寸精度高、耐腐蚀、抗渗漏、热稳定性好、不变形、不开裂、釉面平整光洁的优点,并且无针孔、薄釉、缩釉等缺陷,降低次品率,提高生产效率,降低生产成本,同时提升陶瓷制品的外观精美度,适用于高档陶瓷酒瓶等高档陶瓷制品。
坯料中加入碳酸钡,有效防止杂质产生,胎体颜色纯正统一。坯料通过钛白粉、钛黄色料与米黄泥反应发色,烧成后胎体与木材黄色接近,颜色古朴大方,坯料性能优良,适于机械化流水线生产,且适于各种烧成工艺,适用范围广,提高了产品档次,且次品率极低,使其制作成本下降。
具体实施方式
结合实施例说明本发明的具体实施方式。
实施例1
(1)制备坯料,按下列重量百份数配比:
米黄泥45份,水洗高岭土10份,长石30份,硅灰石1份,钛黄色料2份,滑石4份,木节土6份,碳酸钡0.7份,钛白粉0.5份,腐植酸钠0.2份,泡化碱0.6份。
对上述配料按料﹕球﹕水=1﹕1.25﹕1.25的配比,球磨时间为28小时,球磨后过100目过筛即得注浆坯料。
(2)上述注浆坯料采用注浆成型的方法的制得坯体,烘干后坯体经1150℃温度进行烧制,烧成周期为5~5.5小时,烧成曲线为;窑内温度在1~1.5小时内由窑温匀速升至840℃,再在1~1.5小时内匀速升至1150℃,然后再20~30分钟内降至1080℃,再在20分钟内快速降至890℃,然后再1~1.5小时内慢速降至600℃,最后再自然冷却至室温。制成为陶瓷制品,检验合格后就成为合格产品,产品吸水率为0.2%。
实施例2
(1)制备坯料,按下列重量百分比配比:
米黄泥55份,水洗高岭土8份,长石25份,硅灰石0.8份,钛黄色料1.7份,滑石3.5份,木节土5份,碳酸钡0.7份,钛白粉0.4份,腐植酸钠0.2份,泡化碱0.8份。
对上述配料按料﹕球﹕水= 1﹕1.3﹕1.3的配比,球磨时间为24小时,球磨后过100目过筛即得注浆坯料。
(2)上述注浆坯料采用注浆成型的方法的制得坯体,烘干后坯体经1150℃温度进行烧制,烧成周期为5~5.5小时,烧成曲线为;窑内温度在1~1.5小时内由窑温匀速升至840℃,再在1~1.5小时内匀速升至1150℃,然后再20~30分钟内降至1080℃,再在20分钟内快速降至890℃,然后再1~1.5小时内慢速降至600℃,最后再自然冷却至室温。制成为陶瓷制品,检验合格后就成为合格产品,产品吸水率为0.34%。
实施例3
(1)制备坯料,按下列重量百分比配比:
米黄泥50份,水洗高岭土6份,长石29份,硅灰石1.5份,钛黄色料1.5份,滑石3.5份,木节土6份,碳酸钡1份,钛白粉0.7份,腐植酸钠0.1份,泡化碱0.7份。
对上述配料按料﹕球﹕水=1﹕1.35﹕1.35的配比,球磨时间为30小时,球磨后过100目过筛即得注浆坯料。
(2)上述注浆坯料采用注浆成型的方法的制得坯体,烘干后坯体经1140℃温度进行烧制,烧成周期为5~5.5小时,烧成曲线为;窑内温度在1~1.5小时内由窑温匀速升至840℃,再在1~1.5小时内匀速升至1150℃,然后再20~30分钟内降至1080℃,再在20分钟内快速降至890℃,然后再1~1.5小时内慢速降至600℃,最后再自然冷却至室温。制成为陶瓷制品,检验合格后就成为合格产品,产品吸水率为0.43%。
Claims (5)
1.黄浆陶瓷制品,其特征在于,由以下原料按照重量份数配比制成:米黄泥45~55份,水洗高岭土5~10份,长石20~30份,硅灰石0.5~1.5份,钛黄色料1~3份,滑石2~4份,木节土3~6份,碳酸钡0.3~0.8份,钛白粉0.2~0.6份,腐植酸钠0.1~0.2份,泡化碱0.5~1份。
2.根据权利要求1所述的黄浆陶瓷制品,其特征在于,所述的原料按原料:球:水质量比1﹕1.25~1.35﹕1.25~1.35配比,入筒球磨24~30小时,出筒过100目筛,制得陶瓷制品的注浆坯料;
所述注浆坯料采用注浆成型的方法的制得坯体,烘干后坯体经1100~1150℃温度进行烧制,制成为陶瓷制品。
3.根据权利要求1所述的黄浆陶瓷制品,其特征在于,所述的原料按原料:球:水质量比1﹕1.3﹕1.3的配比,入筒球磨,经28小时球磨,出筒过100目筛,制得陶瓷制品的注浆坯料。
4.根据权利要求1所述的黄浆陶瓷制品,其特征在于,所述的原料球磨后制得注浆坯料,采用注浆成型的方法的制得坯体,烘干后坯体施釉,经1100~1150℃温度进行烧制,制成为陶瓷制品。
5.根据权利要求4所述的黄浆陶瓷制品,其特征在于,所述的烧制烧成周期为5~5.5小时,烧成曲线为;窑内温度在1~1.5小时内由窑温匀速升至840℃,再在1~1.5小时内匀速升至1150℃,然后再20~30分钟内降至1080℃,再在20分钟内快速降至890℃,然后再1~1.5小时内慢速降至600℃,最后再自然冷却至室温。
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