CN106564950A - 一种钼酸镁/石墨烯纳米片阵列及其制备方法 - Google Patents
一种钼酸镁/石墨烯纳米片阵列及其制备方法 Download PDFInfo
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- CN106564950A CN106564950A CN201610986194.6A CN201610986194A CN106564950A CN 106564950 A CN106564950 A CN 106564950A CN 201610986194 A CN201610986194 A CN 201610986194A CN 106564950 A CN106564950 A CN 106564950A
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- graphene
- magnesium molybdate
- molybdate
- magnesium
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 37
- MODMKKOKHKJFHJ-UHFFFAOYSA-N magnesium;dioxido(dioxo)molybdenum Chemical compound [Mg+2].[O-][Mo]([O-])(=O)=O MODMKKOKHKJFHJ-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000002135 nanosheet Substances 0.000 title abstract 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000012300 argon atmosphere Substances 0.000 claims abstract description 8
- 238000001027 hydrothermal synthesis Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 32
- 238000003491 array Methods 0.000 claims description 20
- 238000001354 calcination Methods 0.000 claims description 13
- 239000002131 composite material Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 7
- 229910021641 deionized water Inorganic materials 0.000 claims description 7
- 229940050906 magnesium chloride hexahydrate Drugs 0.000 claims description 7
- DHRRIBDTHFBPNG-UHFFFAOYSA-L magnesium dichloride hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[Cl-].[Cl-] DHRRIBDTHFBPNG-UHFFFAOYSA-L 0.000 claims description 7
- RWVGQQGBQSJDQV-UHFFFAOYSA-M sodium;3-[[4-[(e)-[4-(4-ethoxyanilino)phenyl]-[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]-2-methylcyclohexa-2,5-dien-1-ylidene]methyl]-n-ethyl-3-methylanilino]methyl]benzenesulfonate Chemical compound [Na+].C1=CC(OCC)=CC=C1NC1=CC=C(C(=C2C(=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=2C(=CC(=CC=2)N(CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C)C=C1 RWVGQQGBQSJDQV-UHFFFAOYSA-M 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 238000002604 ultrasonography Methods 0.000 claims description 6
- 238000004146 energy storage Methods 0.000 abstract description 2
- 238000012876 topography Methods 0.000 abstract 2
- 238000006555 catalytic reaction Methods 0.000 abstract 1
- 238000003475 lamination Methods 0.000 abstract 1
- 239000002086 nanomaterial Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229940091250 magnesium supplement Drugs 0.000 description 4
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 description 2
- 229910018864 CoMoO4 Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- -1 CuMoO4 Inorganic materials 0.000 description 1
- 229910015142 FeMoO4 Inorganic materials 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- 229910017964 MgMoO4 Inorganic materials 0.000 description 1
- 229910005809 NiMoO4 Inorganic materials 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000009388 chemical precipitation Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000010041 electrostatic spinning Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- 238000004020 luminiscence type Methods 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000004038 photonic crystal Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
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CN201610986194.6A CN106564950B (zh) | 2016-11-09 | 2016-11-09 | 一种钼酸镁/石墨烯纳米片阵列及其制备方法 |
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CN201610986194.6A CN106564950B (zh) | 2016-11-09 | 2016-11-09 | 一种钼酸镁/石墨烯纳米片阵列及其制备方法 |
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CN106564950B CN106564950B (zh) | 2017-12-22 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111302335A (zh) * | 2020-04-21 | 2020-06-19 | 福建永安市永清石墨烯研究院有限公司 | 一种带竖直微孔的超高导热性石墨烯厚膜及其制备方法 |
CN111599989A (zh) * | 2020-05-28 | 2020-08-28 | 湖北亿纬动力有限公司 | 一种硅基负极片及其制备方法和用途 |
CN115286039A (zh) * | 2022-08-24 | 2022-11-04 | 陕西理工大学 | 氧化钼-石墨烯抗菌材料的制备方法 |
CN115806392A (zh) * | 2022-11-30 | 2023-03-17 | 上海理工大学 | 一种在fto透明导电玻璃生长钼酸镍电致变色薄膜的方法 |
Citations (6)
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CN101428857A (zh) * | 2008-12-16 | 2009-05-13 | 上海应用技术学院 | 一种钼酸锌纳米材料的诱导控制合成方法 |
CN103779105A (zh) * | 2014-02-12 | 2014-05-07 | 东华大学 | 一种钼酸镍与石墨烯纳米复合材料的制备方法 |
CN103933967A (zh) * | 2014-04-23 | 2014-07-23 | 河南师范大学 | 一种纳米钼酸铋可见光催化剂的仿生合成方法 |
WO2015112088A2 (en) * | 2014-01-27 | 2015-07-30 | Nanyang Technological University | Graphene-metal chalcogenide porous material |
CN105540669A (zh) * | 2015-12-07 | 2016-05-04 | 陕西科技大学 | 一种钼酸锌的制备方法及钼酸锌在锂离子电池负极材料中的应用 |
CN105967235A (zh) * | 2016-04-27 | 2016-09-28 | 武汉工程大学 | 一种石墨烯-钼酸铋钠纳米复合材料及其制备方法和应用 |
-
2016
- 2016-11-09 CN CN201610986194.6A patent/CN106564950B/zh active Active
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CN101428857A (zh) * | 2008-12-16 | 2009-05-13 | 上海应用技术学院 | 一种钼酸锌纳米材料的诱导控制合成方法 |
WO2015112088A2 (en) * | 2014-01-27 | 2015-07-30 | Nanyang Technological University | Graphene-metal chalcogenide porous material |
CN103779105A (zh) * | 2014-02-12 | 2014-05-07 | 东华大学 | 一种钼酸镍与石墨烯纳米复合材料的制备方法 |
CN103933967A (zh) * | 2014-04-23 | 2014-07-23 | 河南师范大学 | 一种纳米钼酸铋可见光催化剂的仿生合成方法 |
CN105540669A (zh) * | 2015-12-07 | 2016-05-04 | 陕西科技大学 | 一种钼酸锌的制备方法及钼酸锌在锂离子电池负极材料中的应用 |
CN105967235A (zh) * | 2016-04-27 | 2016-09-28 | 武汉工程大学 | 一种石墨烯-钼酸铋钠纳米复合材料及其制备方法和应用 |
Non-Patent Citations (2)
Title |
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M.AMBERG等: "Preparation, Crystal Structure, and Luminescence of Magnesium Molybdate and Tungstate onohydrates, MgMoO4•H2O and MgWO4•H2O", 《JOURNAL OF SOLID STATE CHEMISTRY》 * |
XINZHI YU等: "Super Long-Life Supercapacitors Based on the Construction of Nanohoneycomb-Like Strongly Coupled CoMoO4 Graphene Hybrid Electrodes", 《ADVANCED MATERIALS》 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111302335A (zh) * | 2020-04-21 | 2020-06-19 | 福建永安市永清石墨烯研究院有限公司 | 一种带竖直微孔的超高导热性石墨烯厚膜及其制备方法 |
CN111599989A (zh) * | 2020-05-28 | 2020-08-28 | 湖北亿纬动力有限公司 | 一种硅基负极片及其制备方法和用途 |
CN115286039A (zh) * | 2022-08-24 | 2022-11-04 | 陕西理工大学 | 氧化钼-石墨烯抗菌材料的制备方法 |
CN115806392A (zh) * | 2022-11-30 | 2023-03-17 | 上海理工大学 | 一种在fto透明导电玻璃生长钼酸镍电致变色薄膜的方法 |
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