CN106396890A - Humic acid silicon-calcium type soil conditioning agent and preparation method thereof - Google Patents
Humic acid silicon-calcium type soil conditioning agent and preparation method thereof Download PDFInfo
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- CN106396890A CN106396890A CN201610762150.5A CN201610762150A CN106396890A CN 106396890 A CN106396890 A CN 106396890A CN 201610762150 A CN201610762150 A CN 201610762150A CN 106396890 A CN106396890 A CN 106396890A
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pest Control & Pesticides (AREA)
- Soil Sciences (AREA)
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Abstract
The invention discloses a humic acid silicon-calcium type soil conditioning agent which comprises the following raw materials in parts by weight: 15-20 parts of humic acid, 18-22 parts of desulfurized gypsum, 3-3.5 parts of urea, 45-50 parts of a mineral silicon fertilizer, 0.3-0.5 part of amino acid, 4.5-5 parts of monoammonium phosphate, 3-3.5 parts of potassium chloride, 0.5-1 part of modified tapioca flour, 4-6 parts of attapulgite powder, 0.1-0.8 part of coated trace elements and 2-5 parts of a disintegrating agent. The invention further discloses a preparation method for the humic acid silicon-calcium type soil conditioning agent. By adopting the humic acid silicon-calcium type soil conditioning agent, the physical and chemical properties of saline alkali soil can be remarkably improved, crop growth can be improved, and a remarkable yield increase and quality improvement effect can be achieved.
Description
Technical field
The present invention relates to soil conditioner technical field, more particularly, to a kind of humic acid silico-calcium type soil conditioner and its system
Preparation Method.
Background technology
Arable land is the basis of agricultural development, and good cultivated lands' environment is the premise of agriculture stable development, to social warp
The influence on development of Ji is great.At present, about 34,600,000 hectares of China's salinized soil area, 7,600,000 hectares of tilth salinization, nearly 1/5 ploughs
There is salinization of soil in ground, the salinization of soil not only produces harm to crop growthing development, and so that soil physical property is deteriorated, underground
Water salinity improves, and underground water source can not make full use of.So that tract is lain waste, agriculture plantation reduces, soil Zhong Shui, fertilizer simultaneously
Mutually inharmonious etc. factor, have a strong impact on crop yield and quality.
The appearance of " ten, soil " during " 13 ", Soil Pollution Control campaign is formally unveiled.The 5th of " ten articles of soil "
Emphasize in bar to promote alkaline land soil improvement, the fltting speed of soil remediation repair and the territorial scope of development will enter one
Step increases, and agricultural land is repaired and is expected to take the lead in starting, and the soil remediation market space is huge.Exist in soil conditioner development at present
The problems such as potential risk of pollutant such as product quality and technique unstable, heavy metal.
Siliceous fertilizer is a kind of good quality fertilizer, health care fertilizer and plant modulability fertilizer, is that other chemical fertilizer cannot
A kind of Multifunction fertilizer of analogy.Siliceous fertilizer both can make fertilizer, provides nutrient, can be used as soil conditioner, improved soil again.
Additionally, also having drought resisting, hot-dry wind tolerance, cold-resistant, resistant to lodging, the effect of diseases prevention, insect protected and attenuation concurrently.But the dirt such as its heavy metal at present
Dye thing more, nutritional balance is poor, and available nutrient content is low, and promotion plant growth effect poor, also can not meet demand it would be highly desirable to
Improve.
Content of the invention
Based on background technology exist technical problem, the present invention propose a kind of humic acid silico-calcium type soil conditioner and its
Preparation method, can significantly improve salt affected soil physicochemical character, promote plant growth, increasing yield and improving quality effect is significant.
A kind of humic acid silico-calcium type soil conditioner proposed by the present invention, its raw material includes by weight:Humic acid 15~
20 parts, 18~22 parts of desulfurated plaster, 3~3.5 parts of urea, 45~50 parts of mineral siliceous fertilizer, 0.3~0.5 part of amino acid, MAP
4.5~5 parts, 3~3.5 parts of potassium chloride, 0.5~1 part of modified tapioca starch, 4~6 parts of attapulgite, coating trace element 0.1~
0.8 part, 2~5 parts of disintegrant.
Preferably, coating trace element is using following technique preparation:By egg yolk lecithin, trace element, sucrose-fatty
Sterilization treatment after ester, water mixing, adds Soybean Peptide, glucose, vitamin C to mix, adds sodium carboxymethylcellulose, crystallite
Cellulose, zeolite powder, water mix and blend, homogeneous process, ultrasonically treated, suction filtration, filter cake is vacuum dried, and it is micro that pulverizing obtains coating
Element.
Preferably, coating trace element is using following technique preparation:By egg yolk lecithin, trace element, sucrose-fatty
Sterilization treatment 2~10min after ester, water mixing, adds Soybean Peptide, glucose, vitamin C to mix, adds carboxymethyl cellulose
Plain sodium, microcrystalline cellulose, zeolite powder, water are in 60~70 DEG C of mix and blend 20~40min of temperature, homogeneous process 2~8min, ultrasonic
Process 20~40min, ultrasonic power is 600~700W, suction filtration, and filter cake is vacuum dried, pulverize and obtain coating trace element.
Preferably, coating trace element is using following technique preparation:By weight by 5~15 parts of egg yolk lecithins, 0.1~
0.8 part of trace element, 0.05~0.12 part of sucrose fatty ester, sterilization treatment 2~10min after 5~10 parts of water mixing, add
0.1~0.6 part of Soybean Peptide, 1~3 part of glucose, 0.15~0.25 part of vitamin C mix, and add 20~40 parts of carboxymethyls
Sodium cellulosate, 1~4 part of microcrystalline cellulose, 2~10 parts of zeolite powders, 50~100 parts of water 60~70 DEG C of mix and blends of temperature 20~
40min, homogeneous process 2~8min, ultrasonically treated 20~40min, ultrasonic power is 600~700W, suction filtration, and filter cake vacuum is done
Dry, pulverize and obtain coating trace element.
Preferably, humic acid is monosodium glutamate leftover bits and pieces.
Preferably, amino acid is polyglutamic acid and/or poly-aspartate.
Preferably, mineral siliceous fertilizer is produced by the steel slag that steel plant discard and obtains.
Preferably, humic acid and mineral siliceous fertilizer are 1:3~8.
The preparation method of the above-mentioned humic acid silico-calcium type soil conditioner of the present invention also proposition, comprises the steps:
S1, mineral siliceous fertilizer and humic acid mixing and water adding to moisture content are 6~8wt%, pulverize and obtain material a;
S2, by humic acid, desulfurated plaster, urea, mineral siliceous fertilizer, amino acid, MAP, potassium chloride, modified tapioca starch,
Attapulgite, disintegrant, coating trace element and material a pour cylinder into, mix, then granulation obtain particle diameter be 2.8~
The spheric granules of 4.6mm, is dried to obtain humic acid silico-calcium type soil conditioner.
Gained humic acid silico-calcium type soil conditioner of the present invention contains substantial amounts of humic acid, active group, amino acid, exchange
Property calcium, magnesium, silicon and the easy element sulphur absorbing, while improvement salt affected soil, to crop equilibration provide nitrogen, phosphorus, potassium, silicon and
The nutrients such as calcium, magnesium, sulphur, its available nutrient content is high, and the pollutant such as heavy metal is well below national standard, safe efficient,
The present invention can significantly improve salt affected soil physicochemical character, promotes plant growth, increasing yield and improving quality effect is significant.
The monosodium glutamate leftover bits and pieces that wherein humic acid adopts be with cereal crops for Raw material processing monosodium glutamate after residue, be monosodium glutamate
Auxiliary product, compared with the raw material of other organic fertilizer products, the exceeded problem of content of beary metal has been prevented from source.Pass through
In fermentation feed change, the state of original material is so as to utilization rate improves;Worm in raw material, ovum, virus can be killed.But taste
Smart leftover bits and pieces highly acid, if directly apply can produce certain harm to crop, so needing to carry out certain process;Iron and steel
The mineral siliceous fertilizer of factory is the raw material that a kind of active ingredient is high, security is good.Through high-temperature calcination, cooling, grinding and process and obtain
Powdery siliceous fertilizer raw material, content of beary metal is well below the requirement in national fertilizer standard, and also contains abundant plant growth
The nutrients such as necessary calcium, magnesium.But the most of nutrient in the mineral siliceous fertilizer of steel plant is existed with solubility in citric acid form, is
Improve the nutrients ratio that crop can directly absorb, need to carry out certain process;Therefore pass through by monosodium glutamate leftover bits and pieces with
The mineral siliceous fertilizer mixed processing of steel plant, can not only adjust the acidity of monosodium glutamate leftover bits and pieces moreover it is possible to improve the mineral siliceous fertilizer of steel plant
The nutrients ratio of the direct utilization absorbed by crops of middle energy.On the one hand be conducive to environmental protection, on the other hand make high added value and produce
Product, are conducive to the maximum of resource to utilize.
Polyglutamic acid is plant nutrient accelerator of new generation, has minimizing loss of chemical fertilizer, enrichment nutrient, improves chemical fertilizer utilization
Rate, promotes the function of the synthesis of crop root growth and protein, can promote crop root secretion organic acid, enzyme and nutrition unit
The materials such as plain carrier, are conducive to the absorption of mineral nutrients.Polyglutamic acid has superpower water-absorbing-retaining ability, can be for a long time
Crop mineral nutrients, provide preferable environmental condition.
The coating trace element of the present invention not only particle uniformly, long shelf-life, wherein trace element, Soybean Peptide, tocopherol,
Glucose, vitamin C, egg yolk lecithin coordinate for the required functional mass of plant, under sucrose fatty ester effect, using carboxylic first
Base sodium cellulosate, microcrystalline cellulose, zeolite powder effect, can be coated in one layer of dense film, not only sustained release performance is good, and waterproof
Excellent performance, oxidative resistance is good.
The present invention according to basic soil fertility state and crop alimentary feature, using humic acid, desulfurated plaster, amino acid,
The plurality of raw materials such as mineral siliceous fertilizer, coating trace element, containing element necessary to abundant plant growth.In improvement alkaline soil
The aspects such as earth, balance crop nutrition content, raising chemical fertilizer utilization ratio have remarkable efficacy.
From the point of view of the field experiment being carried out by crops such as paddy rice, corn, vegetables, the effect of increasing production of the present invention is obvious, paddy rice, jade
The cereal crops such as rice are increased production up to more than 10%, and the vegetable increase production such as cucumber, tomato is up to more than 20%, and can be obviously improved agriculture
The quality of product.The content of organic matter >=10.0% of the present invention, total nitrogen >=2.0%, total phosphorus >=2.0%, total potassium >=2.0%, oxidation
Calcium >=22.0%, magnesia >=3.0%, sulphur >=3.0%, silica >=13.0%, moisture≤3.0%, its pH value is 5.0
~6.0.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of humic acid silico-calcium type soil conditioner proposed by the present invention, its raw material includes by weight:15 parts of humic acid,
22 parts of desulfurated plaster, 3 parts of urea, 50 parts of mineral siliceous fertilizer, 0.3 part of amino acid, 5 parts of MAP, 3 parts of potassium chloride, modified cassava
1 part of powder, 4 parts of attapulgite, 0.8 part of coating trace element, 2 parts of disintegrant.
Embodiment 2
A kind of humic acid silico-calcium type soil conditioner proposed by the present invention, its raw material includes by weight:20 parts of humic acid,
18 parts of desulfurated plaster, 3.5 parts of urea, 45 parts of mineral siliceous fertilizer, 0.5 part of amino acid, 4.5 parts of MAP, 3.5 parts of potassium chloride, change
Property 0.5 part of tapioca starch, 6 parts of attapulgite, coating trace element 0.1 part, 5 parts of disintegrant.
Coating trace element is using following technique preparation:Egg yolk lecithin, trace element, sucrose fatty ester, water are mixed
Sterilization treatment after conjunction, adds Soybean Peptide, glucose, vitamin C to mix, add sodium carboxymethylcellulose, microcrystalline cellulose,
Zeolite powder, water mix and blend, homogeneous process, ultrasonically treated, suction filtration, filter cake is vacuum dried, and pulverizes and obtains coating trace element.
The preparation method of the above-mentioned humic acid silico-calcium type soil conditioner of the present invention also proposition, comprises the steps:
S1, mineral siliceous fertilizer and humic acid mixing and water adding to moisture content are 8wt%, pulverize and obtain material a;
S2, by humic acid, desulfurated plaster, urea, mineral siliceous fertilizer, amino acid, MAP, potassium chloride, modified tapioca starch,
Attapulgite, disintegrant, coating trace element and material a pour cylinder into, mix, then granulation obtain particle diameter be 2.8~
The spheric granules of 4.6mm, is dried to obtain humic acid silico-calcium type soil conditioner.
Embodiment 3
A kind of humic acid silico-calcium type soil conditioner proposed by the present invention, its raw material includes by weight:16 parts of humic acid,
21 parts of desulfurated plaster, 3.2 parts of urea, 48 parts of mineral siliceous fertilizer, 0.35 part of amino acid, 4.8 parts of MAP, 3.2 parts of potassium chloride, change
Property 0.9 part of tapioca starch, 4.5 parts of attapulgite, coating trace element 0.6 part, 3 parts of disintegrant.
Coating trace element is using following technique preparation:By weight by 15 parts of egg yolk lecithins, 0.1 part of trace element,
Sterilization treatment 10min after 0.12 part of sucrose fatty ester, 5 parts of water mixing, add 0.1 part of Soybean Peptide, 3 parts of glucose, 0.15 part
Vitamin C mixes, and adds 40 parts of sodium carboxymethylcelluloses, 1 part of microcrystalline cellulose, 10 parts of zeolite powders, 50 parts of water in temperature
70 DEG C of mix and blend 20min, homogeneous process 8min, ultrasonically treated 20min, ultrasonic power is 700W, suction filtration, and filter cake vacuum is done
Dry, pulverize and obtain coating trace element.
The preparation method of the above-mentioned humic acid silico-calcium type soil conditioner of the present invention also proposition, comprises the steps:
S1, mineral siliceous fertilizer and humic acid mixing and water adding to moisture content are 6wt%, pulverize and obtain material a;
S2, by humic acid, desulfurated plaster, urea, mineral siliceous fertilizer, amino acid, MAP, potassium chloride, modified tapioca starch,
Attapulgite, disintegrant, coating trace element and material a pour cylinder into, mix, then granulation obtain particle diameter be 2.8~
The spheric granules of 4.6mm, is dried to obtain humic acid silico-calcium type soil conditioner.
Embodiment 4
A kind of humic acid silico-calcium type soil conditioner proposed by the present invention, its raw material includes by weight:18 parts of humic acid,
19 parts of desulfurated plaster, 3.4 parts of urea, 46 parts of mineral siliceous fertilizer, 0.45 part of polyglutamic acid, 4.6 parts of MAP, 3.4 parts of potassium chloride,
0.7 part of modified tapioca starch, 5.5 parts of attapulgite, 0.2 part of coating trace element, 4 parts of disintegrant.
Coating trace element is using following technique preparation:By weight by 5 parts of egg yolk lecithins, 0.8 part of trace element,
Sterilization treatment 2min after 0.05 part of sucrose fatty ester, 10 parts of water mixing, add 0.6 part of Soybean Peptide, 1 part of glucose, 0.25 part
Vitamin C mixes, and adds 20 parts of sodium carboxymethylcelluloses, 4 parts of microcrystalline celluloses, 2 parts of zeolite powders, 100 parts of water in temperature
60 DEG C of mix and blend 40min, homogeneous process 2min, ultrasonically treated 40min, ultrasonic power is 600W, suction filtration, and filter cake vacuum is done
Dry, pulverize and obtain coating trace element.
Embodiment 5
A kind of humic acid silico-calcium type soil conditioner proposed by the present invention, its raw material includes by weight:17 parts of humic acid,
20 parts of desulfurated plaster, 3.3 parts of urea, 47 parts of mineral siliceous fertilizer, 0.4 part of amino acid, 4.7 parts of MAP, 3.3 parts of potassium chloride, change
Property 0.8 part of tapioca starch, 5 parts of attapulgite, coating trace element 0.4 part, 3.4 parts of disintegrant;Wherein humic acid is got a foothold for monosodium glutamate
Material, mineral siliceous fertilizer is produced by the steel slag that steel plant discard and obtains, and amino acid is polyglutamic acid and poly-aspartate.
Coating trace element is using following technique preparation:Egg yolk lecithin, trace element, sucrose fatty ester, water are mixed
Sterilization treatment 6min after conjunction, adds Soybean Peptide, glucose, vitamin C to mix, and adds sodium carboxymethylcellulose, crystallite fine
Dimension element, zeolite powder, water in 65 DEG C of mix and blend 30min of temperature, homogeneous process 5min, ultrasonically treated 30min, ultrasonic power are
650W, suction filtration, filter cake is vacuum dried, and pulverizes and obtains coating trace element.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (9)
1. a kind of humic acid silico-calcium type soil conditioner is it is characterised in that its raw material includes by weight:Humic acid 15~20
Part, 18~22 parts of desulfurated plaster, 3~3.5 parts of urea, 45~50 parts of mineral siliceous fertilizer, 0.3~0.5 part of amino acid, MAP
4.5~5 parts, 3~3.5 parts of potassium chloride, 0.5~1 part of modified tapioca starch, 4~6 parts of attapulgite, coating trace element 0.1~
0.8 part, 2~5 parts of disintegrant.
2. according to claim 1 humic acid silico-calcium type soil conditioner it is characterised in that coating trace element is using as follows
Prepared by technique:By sterilization treatment after egg yolk lecithin, trace element, sucrose fatty ester, water mixing, add Soybean Peptide, grape
Sugar, vitamin C mix, addition sodium carboxymethylcellulose, microcrystalline cellulose, zeolite powder, water mix and blend, homogeneous process,
Ultrasonically treated, suction filtration, filter cake is vacuum dried, and pulverizes and obtains coating trace element.
3. humic acid silico-calcium type soil conditioner according to claim 1 or claim 2 is it is characterised in that coating trace element adopts
Following technique preparation:By sterilization treatment 2~10min after egg yolk lecithin, trace element, sucrose fatty ester, water mixing, add
Soybean Peptide, glucose, vitamin C mix, and add sodium carboxymethylcellulose, microcrystalline cellulose, zeolite powder, water in temperature 60
~70 DEG C of mix and blend 20~40min, homogeneous process 2~8min, ultrasonically treated 20~40min, ultrasonic power be 600~
700W, suction filtration, filter cake is vacuum dried, and pulverizes and obtains coating trace element.
4. according to any one of claim 1-3 humic acid silico-calcium type soil conditioner it is characterised in that coating is micro-
Using the preparation of following technique:By weight by 5~15 parts of egg yolk lecithins, 0.1~0.8 part of trace element, 0.05~0.12 part
Sterilization treatment 2~10min after sucrose fatty ester, 5~10 parts of water mixing, adds 0.1~0.6 portion of Soybean Peptide, 1~3 portion of grape
Sugar, 0.15~0.25 part of vitamin C mix, add 20~40 parts of sodium carboxymethylcelluloses, 1~4 part of microcrystalline cellulose, 2
~10 parts of zeolite powders, 50~100 parts of water are in 60~70 DEG C of mix and blend 20~40min of temperature, homogeneous process 2~8min, ultrasonic
Process 20~40min, ultrasonic power is 600~700W, suction filtration, and filter cake is vacuum dried, pulverize and obtain coating trace element.
5. according to any one of claim 1-4 humic acid silico-calcium type soil conditioner it is characterised in that humic acid be monosodium glutamate
Leftover bits and pieces.
6. according to any one of claim 1-5 humic acid silico-calcium type soil conditioner it is characterised in that amino acid be poly- paddy
Propylhomoserin and/or poly-aspartate.
7. according to any one of claim 1-6 humic acid silico-calcium type soil conditioner it is characterised in that mineral siliceous fertilizer is by steel
The steel slag that ironworks is discarded produces and obtains.
8. according to any one of claim 1-7 humic acid silico-calcium type soil conditioner it is characterised in that humic acid and mineral
Siliceous fertilizer is 1:3~8.
9. the preparation method of humic acid silico-calcium type soil conditioner described in a kind of any one according to claim 1-8, its feature exists
In comprising the steps:
S1, mineral siliceous fertilizer and humic acid mixing and water adding to moisture content are 6~8wt%, pulverize and obtain material a;
S2, by humic acid, desulfurated plaster, urea, mineral siliceous fertilizer, amino acid, MAP, potassium chloride, modified tapioca starch, concavo-convex
Excellent powder, disintegrant, coating trace element and material a pour cylinder into, mix, and then granulation obtains particle diameter is 2.8~4.6mm
Spheric granules, be dried to obtain humic acid silico-calcium type soil conditioner.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107338055A (en) * | 2017-06-16 | 2017-11-10 | 湖南隆邦生物科技有限公司 | A kind of permeable soil conditioner |
CN108300485A (en) * | 2018-03-13 | 2018-07-20 | 鲁东大学 | It is a kind of to be used to administer the soil conditioner in salt-soda soil and its preparation method and application |
CN111592423A (en) * | 2020-06-06 | 2020-08-28 | 徐州生物工程职业技术学院 | Preparation method of alkaline soil conditioner |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105272760A (en) * | 2015-11-13 | 2016-01-27 | 金正大诺泰尔化学有限公司 | Special alkaline rice fertilizer capable of modifying soil persistently and production process thereof |
-
2016
- 2016-08-29 CN CN201610762150.5A patent/CN106396890A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105272760A (en) * | 2015-11-13 | 2016-01-27 | 金正大诺泰尔化学有限公司 | Special alkaline rice fertilizer capable of modifying soil persistently and production process thereof |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107338055A (en) * | 2017-06-16 | 2017-11-10 | 湖南隆邦生物科技有限公司 | A kind of permeable soil conditioner |
CN108300485A (en) * | 2018-03-13 | 2018-07-20 | 鲁东大学 | It is a kind of to be used to administer the soil conditioner in salt-soda soil and its preparation method and application |
CN111592423A (en) * | 2020-06-06 | 2020-08-28 | 徐州生物工程职业技术学院 | Preparation method of alkaline soil conditioner |
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Application publication date: 20170215 |