CN106245350B - 一种高弹性耐磨球革 - Google Patents

一种高弹性耐磨球革 Download PDF

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CN106245350B
CN106245350B CN201610746216.1A CN201610746216A CN106245350B CN 106245350 B CN106245350 B CN 106245350B CN 201610746216 A CN201610746216 A CN 201610746216A CN 106245350 B CN106245350 B CN 106245350B
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CN106245350A (zh
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刘传庆
刘顺兆
徐蓉
吴丽萍
陈意
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YANGZHOU DERWINS PLASTICS TECHNOLOGY Co Ltd
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Abstract

一种高弹性耐磨球革，包括皮革基层、涂覆在皮革基层上的涂饰剂和止滑增涩膜层，所述皮革基层为经过覆浆处理的无纺布，无纺布为涤纶纤维和尼龙纤维进行混棉，再经梳棉、叠棉、针刺、定型制得；涂饰剂由下述原料制成：酸性粒子元青、蛹酪素、间苯二甲酸二辛酯、柠檬酸乙酯、尼泊金酯、硼砂、氨水、水、炭黑、苯甲酸高碳醇酯、二甲基对氨基苯甲酸辛酯、二烷基二硫代磷酸锌盐、乙烯基三甲氧基硅烷、聚乙烯醇、焦磷酸钠；止滑增涩膜层的由下述原料组成：水性聚氨酯树脂、二甲基甲酰胺、粒径小于10μm的颜料、二氧化钛、聚丙烯酸酯、有机硅弹性体、Al(OH)3、2‑甲基‑5‑硝基咪唑‑1‑乙醇、(1‑萘基)‑N‑甲基氨基甲酸酯。

Description

一种高弹性耐磨球革
技术领域
本发明属于皮革领域，具体地说是一种高弹性耐磨球革。
背景技术
现有技术中球革，在室外使用时，球革表面受到阳光、雨水等侵蚀，表面很容易受损，使得球革支撑的球整体质量较差。球革本身耐磨性能不足，也会影响球革的使用寿命。
发明内容
本发明提供一种高弹性耐磨球革，用以解决现有技术中的缺陷。
本发明通过以下技术方案予以实现：
一种高弹性耐磨球革，包括皮革基层、涂覆在皮革基层上的涂饰剂和止滑增涩膜层，所述皮革基层为经过覆浆处理的无纺布，无纺布为涤纶纤维和尼龙纤维进行混棉，再经梳棉、叠棉、针刺、定型制得，涤纶纤维和尼龙纤维的重量份为：尼龙纤维10-20份、涤纶纤维30-50份；涂饰剂由下述重量份的原料制成：酸性粒子元青20-30份、蛹酪素80-100份、间苯二甲酸二辛酯10-15份、柠檬酸乙酯5-10份、尼泊金酯10-15份、硼砂3-6份、氨水5-8份、水80-150份、炭黑12-30份、苯甲酸高碳醇酯3-5份、二甲基对氨基苯甲酸辛酯4-6份、二烷基二硫代磷酸锌盐0.2-0.5份、乙烯基三甲氧基硅烷0.2-0.5份、聚乙烯醇0.3-0.6份、焦磷酸钠0.2-0.5份；止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂30-60 份、二甲基甲酰胺10-20份、粒径小于10μm的颜料0.2-2.0份、二氧化钛0.2-1.0份、聚丙烯酸酯0.5-1.5份、有机硅弹性体1-4份、Al(OH)3 0.2-0.4份、2-甲基-5-硝基咪唑-1-乙醇0.2-0.5份、(1-萘基)-N-甲基氨基甲酸酯0.2-0.5份。
所述的涂饰剂由下述重量份的原料制成：酸性粒子元青20份、蛹酪素90份、间苯二甲酸二辛酯15份、柠檬酸乙酯5份、尼泊金酯12份、硼砂6份、氨水5份、水120份、炭黑30份、苯甲酸高碳醇酯3份、二甲基对氨基苯甲酸辛酯5份、二烷基二硫代磷酸锌盐0.5份、乙烯基三甲氧基硅烷0.2份、聚乙烯醇0.5份、焦磷酸钠0.5份。
所述的涂饰剂由下述重量份的原料制成：酸性粒子元青25份、蛹酪素100份、间苯二甲酸二辛酯10份、柠檬酸乙酯8份、尼泊金酯15份、硼砂3份、氨水6份、水150份、炭黑12份、苯甲酸高碳醇酯4份、二甲基对氨基苯甲酸辛酯4份、二烷基二硫代磷酸锌盐0.2份、乙烯基三甲氧基硅烷0.4份、聚乙烯醇0.6份、焦磷酸钠0.2份。
所述的涂饰剂由下述重量份的原料制成：酸性粒子元青30份、蛹酪素80份、间苯二甲酸二辛酯12份、柠檬酸乙酯10份、尼泊金酯10份、硼砂4份、氨水8份、水80份、炭黑24份、苯甲酸高碳醇酯5份、二甲基对氨基苯甲酸辛酯6份、二烷基二硫代磷酸锌盐0.3份、乙烯基三甲氧基硅烷0.5份、聚乙烯醇0.3份、焦磷酸钠0.3份。
所述的止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂30 份、二甲基甲酰胺15份、粒径小于10μm的颜料2.0份、二氧化钛0.2份、聚丙烯酸酯1.0份、有机硅弹性体4份、Al(OH)3 0.2份、2-甲基-5-硝基咪唑-1-乙醇0.5份、(1-萘基)-N-甲基氨基甲酸酯0.5份。
所述的止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂40 份、二甲基甲酰胺20份、粒径小于10μm的颜料0.2份、二氧化钛0.7份、聚丙烯酸酯1.5份、有机硅弹性体1份、Al(OH)3 0.3份、2-甲基-5-硝基咪唑-1-乙醇0.3份、(1-萘基)-N-甲基氨基甲酸酯0.2份。
所述的止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂60 份、二甲基甲酰胺10份、粒径小于10μm的颜料1.0份、二氧化钛1.0份、聚丙烯酸酯0.5份、有机硅弹性体3份、Al(OH)3 0.4份、2-甲基-5-硝基咪唑-1-乙醇0.2份、(1-萘基)-N-甲基氨基甲酸酯0.3份。
所述的涂饰剂，由下述步骤的方法制成：①将水分成按照重量比45%、45%和10%分成三份，备用；②将蛹酪素用重量比45%的清水调成糊，升温至60℃，保温搅拌并加入氨水和硼砂，保温搅拌1-2h，在加入重量比45%的清水、尼泊金酯、二烷基二硫代磷酸锌盐、乙烯基三甲氧基硅烷，保温搅拌15min，冷却至室温，用150目筛过滤，得到蛋白浆；③将间苯二甲酸二辛酯、柠檬酸乙酯、炭黑、苯甲酸高碳醇酯、二甲基对氨基苯甲酸辛酯、聚乙烯醇、焦磷酸钠混合均匀，用三辊研磨机研磨均匀，制备得到黑浆料；④用重量比10%的清水溶化酸性粒子元青，加热至45℃，加入步骤③制备的黑浆料和步骤②制备的蛋白浆，搅拌均匀后停止加热，冷却到室温，即得。
本发明的优点是：本发明，通过涂饰剂的各个原料之间的协同作用，在皮革表面形成一层有效的耐磨层，并且涂饰剂能够渗入至基层内部，深层次的提高耐磨效果，具有一定防腐抗酸性，能够适用于弹性球类产品的制造，有效降低生产成本。本发明制造的球革外侧的在止滑增涩膜层增强球革的手感、光泽和质地，有效提高弹性，适用于制作高弹性、对耐磨性能高的球品。本发明还能够减少强光对皮革的损坏，有效抵挡紫外线，提高使用寿命。
具体实施方式
为使本发明实施例的目的、技术方案和优点更加清楚，下面将对本发明实施例中的技术方案进行清楚、完整地描述，显然，所描述的实施例是本发明一部分实施例，而不是全部的实施例。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
一种高弹性耐磨球革，包括皮革基层、涂覆在皮革基层上的涂饰剂和止滑增涩膜层，所述皮革基层为经过覆浆处理的无纺布，无纺布为涤纶纤维和尼龙纤维进行混棉，再经梳棉、叠棉、针刺、定型制得，涤纶纤维和尼龙纤维的重量份为：尼龙纤维10-20份、涤纶纤维30-50份；涂饰剂由下述重量份的原料制成：酸性粒子元青20-30份、蛹酪素80-100份、间苯二甲酸二辛酯10-15份、柠檬酸乙酯5-10份、尼泊金酯10-15份、硼砂3-6份、氨水5-8份、水80-150份、炭黑12-30份、苯甲酸高碳醇酯3-5份、二甲基对氨基苯甲酸辛酯4-6份、二烷基二硫代磷酸锌盐0.2-0.5份、乙烯基三甲氧基硅烷0.2-0.5份、聚乙烯醇0.3-0.6份、焦磷酸钠0.2-0.5份；止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂30-60 份、二甲基甲酰胺10-20份、粒径小于10μm的颜料0.2-2.0份、二氧化钛0.2-1.0份、聚丙烯酸酯0.5-1.5份、有机硅弹性体1-4份、Al(OH)3 0.2-0.4份、2-甲基-5-硝基咪唑-1-乙醇0.2-0.5份、(1-萘基)-N-甲基氨基甲酸酯0.2-0.5份。
所述的涂饰剂由下述实施例的重量份的原料制成：
实施例一：酸性粒子元青20份、蛹酪素90份、间苯二甲酸二辛酯15份、柠檬酸乙酯5份、尼泊金酯12份、硼砂6份、氨水5份、水120份、炭黑30份、苯甲酸高碳醇酯3份、二甲基对氨基苯甲酸辛酯5份、二烷基二硫代磷酸锌盐0.5份、乙烯基三甲氧基硅烷0.2份、聚乙烯醇0.5份、焦磷酸钠0.5份。
实施例二：酸性粒子元青25份、蛹酪素100份、间苯二甲酸二辛酯10份、柠檬酸乙酯8份、尼泊金酯15份、硼砂3份、氨水6份、水150份、炭黑12份、苯甲酸高碳醇酯4份、二甲基对氨基苯甲酸辛酯4份、二烷基二硫代磷酸锌盐0.2份、乙烯基三甲氧基硅烷0.4份、聚乙烯醇0.6份、焦磷酸钠0.2份。
实施例三：酸性粒子元青30份、蛹酪素80份、间苯二甲酸二辛酯12份、柠檬酸乙酯10份、尼泊金酯10份、硼砂4份、氨水8份、水80份、炭黑24份、苯甲酸高碳醇酯5份、二甲基对氨基苯甲酸辛酯6份、二烷基二硫代磷酸锌盐0.3份、乙烯基三甲氧基硅烷0.5份、聚乙烯醇0.3份、焦磷酸钠0.3份。
所述的止滑增涩膜层的由下述实施例的重量份原料组成：
实施例一：水性聚氨酯树脂30 份、二甲基甲酰胺15份、粒径小于10μm的颜料2.0份、二氧化钛0.2份、聚丙烯酸酯1.0份、有机硅弹性体4份、Al(OH)3 0.2份、2-甲基-5-硝基咪唑-1-乙醇0.5份、(1-萘基)-N-甲基氨基甲酸酯0.5份。
实施例二：水性聚氨酯树脂40 份、二甲基甲酰胺20份、粒径小于10μm的颜料0.2份、二氧化钛0.7份、聚丙烯酸酯1.5份、有机硅弹性体1份、Al(OH)3 0.3份、2-甲基-5-硝基咪唑-1-乙醇0.3份、(1-萘基)-N-甲基氨基甲酸酯0.2份。
实施例三：水性聚氨酯树脂60 份、二甲基甲酰胺10份、粒径小于10μm的颜料1.0份、二氧化钛1.0份、聚丙烯酸酯0.5份、有机硅弹性体3份、Al(OH)3 0.4份、2-甲基-5-硝基咪唑-1-乙醇0.2份、(1-萘基)-N-甲基氨基甲酸酯0.3份。
所述的涂饰剂，由下述步骤的方法制成：①将水分成按照重量比45%、45%和10%分成三份，备用；②将蛹酪素用重量比45%的清水调成糊，升温至60℃，保温搅拌并加入氨水和硼砂，保温搅拌1-2h，在加入重量比45%的清水、尼泊金酯、二烷基二硫代磷酸锌盐、乙烯基三甲氧基硅烷，保温搅拌15min，冷却至室温，用150目筛过滤，得到蛋白浆；③将间苯二甲酸二辛酯、柠檬酸乙酯、炭黑、苯甲酸高碳醇酯、二甲基对氨基苯甲酸辛酯、聚乙烯醇、焦磷酸钠混合均匀，用三辊研磨机研磨均匀，制备得到黑浆料；④用重量比10%的清水溶化酸性粒子元青，加热至45℃，加入步骤③制备的黑浆料和步骤②制备的蛋白浆，搅拌均匀后停止加热，冷却到室温，即得。
一种高弹性耐磨球革的制作方法，包括下述步骤
①将无纺布的基布进行打磨拉毛处理，处理后的基布进行进行浸渍处理10-15min，浸渍后使用轧压辊去除基布中的水分；②将步骤①处理后的基布进行覆浆，将覆浆的浆液使用辊筒刀涂机刮凃平整涂覆在基
布上，上浆量为200-500g/ ㎡；③将涂覆后的基布放入烘干定型机进行烘干，烘干温度设定为130℃-150℃，烘干时间设定为5-10min；再均匀涂覆300g/㎡的涂饰剂后自然干燥1天；④将止滑增涩膜层的原料加入至混炼机中混炼，加热至50℃，涂抹在基层表面，涂抹量为100g/㎡,加入烘干机中80℃烘干0.5h，自然晾干后即得。
最后应说明的是：以上实施例仅用以说明本发明的技术方案，而非对其限制；尽管参照前述实施例对本发明进行了详细的说明，本领域的普通技术人员应当理解：其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换；而这些修改或者替换，并不使相应技术方案的本质脱离本发明各实施例技术方案的精神和范围。

Claims (8)

1.一种高弹性耐磨球革，其特征在于：包括皮革基层、涂覆在皮革基层上的涂饰剂和止滑增涩膜层，所述皮革基层为经过覆浆处理的无纺布，无纺布为涤纶纤维和尼龙纤维进行混棉，再经梳棉、叠棉、针刺、定型制得，涤纶纤维和尼龙纤维的重量份为：尼龙纤维10-20份、涤纶纤维30-50份；涂饰剂由下述重量份的原料制成：酸性粒子元青20-30份、蛹酪素80-100份、间苯二甲酸二辛酯10-15份、柠檬酸乙酯5-10份、尼泊金酯10-15份、硼砂3-6份、氨水5-8份、水80-150份、炭黑12-30份、苯甲酸高碳醇酯3-5份、二甲基对氨基苯甲酸辛酯4-6份、二烷基二硫代磷酸锌盐0.2-0.5份、乙烯基三甲氧基硅烷0.2-0.5份、聚乙烯醇0.3-0.6份、焦磷酸钠0.2-0.5份；止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂30-60 份、二甲基甲酰胺10-20份、粒径小于10μm的颜料0.2-2.0份、二氧化钛0.2-1.0份、聚丙烯酸酯0.5-1.5份、有机硅弹性体1-4份、Al(OH)3 0.2-0.4份、2-甲基-5-硝基咪唑-1-乙醇0.2-0.5份、(1-萘基)-N-甲基氨基甲酸酯0.2-0.5份。
2.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的涂饰剂由下述重量份的原料制成：酸性粒子元青20份、蛹酪素90份、间苯二甲酸二辛酯15份、柠檬酸乙酯5份、尼泊金酯12份、硼砂6份、氨水5份、水120份、炭黑30份、苯甲酸高碳醇酯3份、二甲基对氨基苯甲酸辛酯5份、二烷基二硫代磷酸锌盐0.5份、乙烯基三甲氧基硅烷0.2份、聚乙烯醇0.5份、焦磷酸钠0.5份。
3.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的涂饰剂由下述重量份的原料制成：酸性粒子元青25份、蛹酪素100份、间苯二甲酸二辛酯10份、柠檬酸乙酯8份、尼泊金酯15份、硼砂3份、氨水6份、水150份、炭黑12份、苯甲酸高碳醇酯4份、二甲基对氨基苯甲酸辛酯4份、二烷基二硫代磷酸锌盐0.2份、乙烯基三甲氧基硅烷0.4份、聚乙烯醇0.6份、焦磷酸钠0.2份。
4.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的涂饰剂由下述重量份的原料制成：酸性粒子元青30份、蛹酪素80份、间苯二甲酸二辛酯12份、柠檬酸乙酯10份、尼泊金酯10份、硼砂4份、氨水8份、水80份、炭黑24份、苯甲酸高碳醇酯5份、二甲基对氨基苯甲酸辛酯6份、二烷基二硫代磷酸锌盐0.3份、乙烯基三甲氧基硅烷0.5份、聚乙烯醇0.3份、焦磷酸钠0.3份。
5.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂30 份、二甲基甲酰胺15份、粒径小于10μm的颜料2.0份、二氧化钛0.2份、聚丙烯酸酯1.0份、有机硅弹性体4份、Al(OH)3 0.2份、2-甲基-5-硝基咪唑-1-乙醇0.5份、(1-萘基)-N-甲基氨基甲酸酯0.5份。
6.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂40 份、二甲基甲酰胺20份、粒径小于10μm的颜料0.2份、二氧化钛0.7份、聚丙烯酸酯1.5份、有机硅弹性体1份、Al(OH)3 0.3份、2-甲基-5-硝基咪唑-1-乙醇0.3份、(1-萘基)-N-甲基氨基甲酸酯0.2份。
7.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的止滑增涩膜层的由下述重量份原料组成：水性聚氨酯树脂60 份、二甲基甲酰胺10份、粒径小于10μm的颜料1.0份、二氧化钛1.0份、聚丙烯酸酯0.5份、有机硅弹性体3份、Al(OH)3 0.4份、2-甲基-5-硝基咪唑-1-乙醇0.2份、(1-萘基)-N-甲基氨基甲酸酯0.3份。
8.根据权利要求1所述的一种高弹性耐磨球革，其特征在于：所述的涂饰剂，由下述步骤的方法制成：
①将水分成按照重量比45%、45%和10%分成三份，备用；
②将蛹酪素用重量比45%的清水调成糊，升温至60℃，保温搅拌并加入氨水和硼砂，保温搅拌1-2h，在加入重量比45%的清水、尼泊金酯、二烷基二硫代磷酸锌盐、乙烯基三甲氧基硅烷，保温搅拌15min，冷却至室温，用150目筛过滤，得到蛋白浆；
③将间苯二甲酸二辛酯、柠檬酸乙酯、炭黑、苯甲酸高碳醇酯、二甲基对氨基苯甲酸辛酯、聚乙烯醇、焦磷酸钠混合均匀，用三辊研磨机研磨均匀，制备得到黑浆料；
④用重量比10%的清水溶化酸性粒子元青，加热至45℃，加入步骤③制备的黑浆料和步骤②制备的蛋白浆，搅拌均匀后停止加热，冷却到室温，即得。
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