CN106238007A - 一种磁性纳米复合物及其制备方法和应用 - Google Patents
一种磁性纳米复合物及其制备方法和应用 Download PDFInfo
- Publication number
- CN106238007A CN106238007A CN201610600893.2A CN201610600893A CN106238007A CN 106238007 A CN106238007 A CN 106238007A CN 201610600893 A CN201610600893 A CN 201610600893A CN 106238007 A CN106238007 A CN 106238007A
- Authority
- CN
- China
- Prior art keywords
- sio
- magnetic
- pyrroles
- magnetic nanocomposites
- thiophene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000005291 magnetic effect Effects 0.000 title claims abstract description 89
- 239000002114 nanocomposite Substances 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 122
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 90
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 67
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 66
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 66
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 66
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 66
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims abstract description 55
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 36
- 150000003233 pyrroles Chemical class 0.000 claims abstract description 36
- 229930192474 thiophene Natural products 0.000 claims abstract description 34
- 229910052737 gold Inorganic materials 0.000 claims abstract description 26
- 239000010931 gold Substances 0.000 claims abstract description 26
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims abstract description 21
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims abstract description 19
- 239000007864 aqueous solution Substances 0.000 claims abstract description 17
- 229920001577 copolymer Polymers 0.000 claims abstract description 16
- 238000000926 separation method Methods 0.000 claims abstract description 11
- 229920000642 polymer Polymers 0.000 claims abstract description 8
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims description 32
- 239000000243 solution Substances 0.000 claims description 28
- 238000003756 stirring Methods 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 25
- 150000002505 iron Chemical class 0.000 claims description 18
- -1 gold ion Chemical class 0.000 claims description 17
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 17
- 238000006243 chemical reaction Methods 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 13
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000006228 supernatant Substances 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- 230000002378 acidificating effect Effects 0.000 claims description 8
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 8
- 238000001291 vacuum drying Methods 0.000 claims description 8
- FGUUSXIOTUKUDN-IBGZPJMESA-N C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 Chemical compound C1(=CC=CC=C1)N1C2=C(NC([C@H](C1)NC=1OC(=NN=1)C1=CC=CC=C1)=O)C=CC=C2 FGUUSXIOTUKUDN-IBGZPJMESA-N 0.000 claims description 7
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- 241001502050 Acis Species 0.000 claims description 6
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003945 anionic surfactant Substances 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 6
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 6
- 239000000178 monomer Substances 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 229960002089 ferrous chloride Drugs 0.000 claims description 5
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052717 sulfur Inorganic materials 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical group [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 4
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 4
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 4
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 4
- 239000011790 ferrous sulphate Substances 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 229910000358 iron sulfate Inorganic materials 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 4
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- GNFTZDOKVXKIBK-UHFFFAOYSA-N 3-(2-methoxyethoxy)benzohydrazide Chemical compound COCCOC1=CC=CC(C(=O)NN)=C1 GNFTZDOKVXKIBK-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 238000000026 X-ray photoelectron spectrum Methods 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 238000002329 infrared spectrum Methods 0.000 claims description 3
- 230000005389 magnetism Effects 0.000 claims description 3
- JHJUUEHSAZXEEO-UHFFFAOYSA-M sodium;4-dodecylbenzenesulfonate Chemical group [Na+].CCCCCCCCCCCCC1=CC=C(S([O-])(=O)=O)C=C1 JHJUUEHSAZXEEO-UHFFFAOYSA-M 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910002651 NO3 Inorganic materials 0.000 claims description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 2
- 239000011260 aqueous acid Substances 0.000 claims description 2
- 238000009413 insulation Methods 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 15
- 238000010521 absorption reaction Methods 0.000 abstract description 14
- 239000002253 acid Substances 0.000 abstract description 13
- 239000007800 oxidant agent Substances 0.000 abstract description 8
- 230000001590 oxidative effect Effects 0.000 abstract description 7
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 6
- 230000004043 responsiveness Effects 0.000 abstract description 6
- 238000007254 oxidation reaction Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000010189 synthetic method Methods 0.000 abstract description 3
- 239000012429 reaction media Substances 0.000 abstract description 2
- 239000003463 adsorbent Substances 0.000 description 21
- 150000002500 ions Chemical class 0.000 description 11
- 239000002131 composite material Substances 0.000 description 10
- 229920000128 polypyrrole Polymers 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 8
- 238000001179 sorption measurement Methods 0.000 description 8
- 238000004833 X-ray photoelectron spectroscopy Methods 0.000 description 7
- 238000001514 detection method Methods 0.000 description 6
- 238000002414 normal-phase solid-phase extraction Methods 0.000 description 6
- 241000894007 species Species 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 239000002322 conducting polymer Substances 0.000 description 5
- 229920001940 conductive polymer Polymers 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000000634 powder X-ray diffraction Methods 0.000 description 5
- 230000004044 response Effects 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 230000000274 adsorptive effect Effects 0.000 description 4
- 239000012153 distilled water Substances 0.000 description 4
- 239000003302 ferromagnetic material Substances 0.000 description 4
- 239000011259 mixed solution Substances 0.000 description 4
- 229920000123 polythiophene Polymers 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 4
- YMMGRPLNZPTZBS-UHFFFAOYSA-N 2,3-dihydrothieno[2,3-b][1,4]dioxine Chemical compound O1CCOC2=C1C=CS2 YMMGRPLNZPTZBS-UHFFFAOYSA-N 0.000 description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 239000011258 core-shell material Substances 0.000 description 3
- 239000003480 eluent Substances 0.000 description 3
- 230000002452 interceptive effect Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 210000004940 nucleus Anatomy 0.000 description 3
- 239000011368 organic material Substances 0.000 description 3
- 229920000767 polyaniline Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 125000000168 pyrrolyl group Chemical group 0.000 description 3
- WHLUQAYNVOGZST-UHFFFAOYSA-N tifenamil Chemical group C=1C=CC=CC=1C(C(=O)SCCN(CC)CC)C1=CC=CC=C1 WHLUQAYNVOGZST-UHFFFAOYSA-N 0.000 description 3
- 229910016874 Fe(NO3) Inorganic materials 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- HAYXDMNJJFVXCI-UHFFFAOYSA-N arsenic(5+) Chemical compound [As+5] HAYXDMNJJFVXCI-UHFFFAOYSA-N 0.000 description 2
- WLZRMCYVCSSEQC-UHFFFAOYSA-N cadmium(2+) Chemical compound [Cd+2] WLZRMCYVCSSEQC-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000010668 complexation reaction Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 2
- 239000006247 magnetic powder Substances 0.000 description 2
- 230000005415 magnetization Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- GPAAEXYTRXIWHR-UHFFFAOYSA-N (1-methylpiperidin-1-ium-1-yl)methanesulfonate Chemical compound [O-]S(=O)(=O)C[N+]1(C)CCCCC1 GPAAEXYTRXIWHR-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 206010011224 Cough Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- RIVZIMVWRDTIOQ-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co].[Co] RIVZIMVWRDTIOQ-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000010793 electronic waste Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229940056319 ferrosoferric oxide Drugs 0.000 description 1
- CBMIPXHVOVTTTL-UHFFFAOYSA-N gold(3+) Chemical compound [Au+3] CBMIPXHVOVTTTL-UHFFFAOYSA-N 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 238000002173 high-resolution transmission electron microscopy Methods 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 239000010842 industrial wastewater Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 238000000622 liquid--liquid extraction Methods 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 210000000633 nuclear envelope Anatomy 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- XJVIPPHGDPEDJL-UHFFFAOYSA-N thiourea;hydrochloride Chemical compound Cl.NC(N)=S XJVIPPHGDPEDJL-UHFFFAOYSA-N 0.000 description 1
- 229940126680 traditional chinese medicines Drugs 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
- B01J20/264—Synthetic macromolecular compounds derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
- B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
- B01J20/0229—Compounds of Fe
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/06—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/103—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28002—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
- B01J20/28009—Magnetic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28016—Particle form
- B01J20/28019—Spherical, ellipsoidal or cylindrical
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B11/00—Obtaining noble metals
- C22B11/02—Obtaining noble metals by dry processes
- C22B11/021—Recovery of noble metals from waste materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B7/00—Working up raw materials other than ores, e.g. scrap, to produce non-ferrous metals and compounds thereof; Methods of a general interest or applied to the winning of more than two metals
- C22B7/001—Dry processes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/0018—Diamagnetic or paramagnetic materials, i.e. materials with low susceptibility and no hysteresis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
Description
Claims (10)
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610600893.2A CN106238007B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物及其制备方法和应用 |
CN201810323063.9A CN108339538B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物的制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201610600893.2A CN106238007B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物及其制备方法和应用 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810323063.9A Division CN108339538B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物的制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106238007A true CN106238007A (zh) | 2016-12-21 |
CN106238007B CN106238007B (zh) | 2018-09-07 |
Family
ID=57604036
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201610600893.2A Active CN106238007B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物及其制备方法和应用 |
CN201810323063.9A Active CN108339538B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物的制备方法 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810323063.9A Active CN108339538B (zh) | 2016-07-27 | 2016-07-27 | 一种磁性纳米复合物的制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (2) | CN106238007B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107698757A (zh) * | 2017-10-31 | 2018-02-16 | 山西大同大学 | 一种四氧化三铁/二氧化硅/聚吡咯纳米复合粒子及其制备方法 |
CN109331795A (zh) * | 2018-10-31 | 2019-02-15 | 沈阳药科大学 | 一种磁性纳米复合材料及其制备和应用 |
CN110344801A (zh) * | 2018-04-03 | 2019-10-18 | 齐鲁工业大学 | 用于可燃冰开采的压裂作业方法、开采方法和开采系统 |
CN110767437A (zh) * | 2018-07-26 | 2020-02-07 | 香港城市大学深圳研究院 | 二氧化硅包覆四氧化三铁核壳结构磁性纳米颗粒制备方法 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110385116A (zh) * | 2019-06-28 | 2019-10-29 | 沈阳信达泰康医药科技有限公司 | 一种磁性纳米复合材料及其制备和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1090794A (zh) * | 1992-06-08 | 1994-08-17 | 布莱阿姆青年大学 | 用含有结合到固相亲水基质上的吸电子基的含硫复合体从溶液中除去离子的方法 |
CN101708463A (zh) * | 2009-11-23 | 2010-05-19 | 中国科学院宁波材料技术与工程研究所 | 一种高磁性负载导电高分子的重金属离子吸附剂及其制备方法 |
CN102360659A (zh) * | 2011-06-24 | 2012-02-22 | 中国科学院宁波材料技术与工程研究所 | 磁性亚微米复合核壳颗粒及其制备方法和应用 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101070672A (zh) * | 2006-05-12 | 2007-11-14 | 中国科学院化学研究所 | 一种超疏水导电纤维、织物及其制备方法和应用 |
KR20090033940A (ko) * | 2007-10-02 | 2009-04-07 | 재단법인서울대학교산학협력재단 | 중금속 흡착제를 위한 자성 나노입자/고분자 코어-셀구조의 나노복합체의 제조 |
KR101044970B1 (ko) * | 2009-09-15 | 2011-06-29 | 한서대학교 산학협력단 | 메조포러스 고분자 나노중합 합성체 소재 제조방법 |
CN101789299B (zh) * | 2010-01-13 | 2012-05-23 | 西安恒旭科技发展有限公司 | 微米Fe3O4表面包覆纳米SiO2复合粒子的制备方法 |
KR101160156B1 (ko) * | 2010-04-09 | 2012-06-27 | 연세대학교 산학협력단 | 상변이 물질이 전도성 고분자로 둘러싸여 있는 나노캡슐 및 그 제조방법 |
CN102675537B (zh) * | 2012-04-06 | 2014-08-20 | 江苏大学 | 一种脱除油品中二苯并噻吩的磁性材料的制备方法 |
CN103537323A (zh) * | 2013-09-25 | 2014-01-29 | 济南大学 | 一种介孔磁铁矿基类Fenton催化剂的制备方法 |
CN104031244B (zh) * | 2014-01-08 | 2016-11-23 | 上海大学 | 混合溶剂体系中快速制备聚噻吩的方法 |
CN104140642B (zh) * | 2014-07-22 | 2016-06-08 | 中国海洋大学 | 一种聚(吡咯-二氧乙撑噻吩)/Fe3O4复合物及其制备方法 |
CN104324706B (zh) * | 2014-11-05 | 2016-08-17 | 齐鲁工业大学 | 一种用于选择性分离银离子的磁性纳米复合物的制备方法 |
-
2016
- 2016-07-27 CN CN201610600893.2A patent/CN106238007B/zh active Active
- 2016-07-27 CN CN201810323063.9A patent/CN108339538B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1090794A (zh) * | 1992-06-08 | 1994-08-17 | 布莱阿姆青年大学 | 用含有结合到固相亲水基质上的吸电子基的含硫复合体从溶液中除去离子的方法 |
CN101708463A (zh) * | 2009-11-23 | 2010-05-19 | 中国科学院宁波材料技术与工程研究所 | 一种高磁性负载导电高分子的重金属离子吸附剂及其制备方法 |
CN102360659A (zh) * | 2011-06-24 | 2012-02-22 | 中国科学院宁波材料技术与工程研究所 | 磁性亚微米复合核壳颗粒及其制备方法和应用 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107698757A (zh) * | 2017-10-31 | 2018-02-16 | 山西大同大学 | 一种四氧化三铁/二氧化硅/聚吡咯纳米复合粒子及其制备方法 |
CN107698757B (zh) * | 2017-10-31 | 2020-06-02 | 山西大同大学 | 一种四氧化三铁/二氧化硅/聚吡咯纳米复合粒子及其制备方法 |
CN110344801A (zh) * | 2018-04-03 | 2019-10-18 | 齐鲁工业大学 | 用于可燃冰开采的压裂作业方法、开采方法和开采系统 |
CN110767437A (zh) * | 2018-07-26 | 2020-02-07 | 香港城市大学深圳研究院 | 二氧化硅包覆四氧化三铁核壳结构磁性纳米颗粒制备方法 |
CN110767437B (zh) * | 2018-07-26 | 2021-06-25 | 香港城市大学深圳研究院 | 二氧化硅包覆四氧化三铁核壳结构磁性纳米颗粒制备方法 |
CN109331795A (zh) * | 2018-10-31 | 2019-02-15 | 沈阳药科大学 | 一种磁性纳米复合材料及其制备和应用 |
Also Published As
Publication number | Publication date |
---|---|
CN106238007B (zh) | 2018-09-07 |
CN108339538A (zh) | 2018-07-31 |
CN108339538B (zh) | 2020-07-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN106238007B (zh) | 一种磁性纳米复合物及其制备方法和应用 | |
Qin et al. | Enhanced heterogeneous Fenton-like degradation of methylene blue by reduced CuFe 2 O 4 | |
Hu et al. | Combining batch technique with theoretical calculation studies to analyze the highly efficient enrichment of U (VI) and Eu (III) on magnetic MnFe2O4 nanocubes | |
Adegoke et al. | Adsorption of Cr (VI) on synthetic hematite (α-Fe 2 O 3) nanoparticles of different morphologies | |
Qin et al. | Enhanced removal of trace Cr (VI) from neutral and alkaline aqueous solution by FeCo bimetallic nanoparticles | |
CN112316906B (zh) | 一种铁磁性的氨基修饰镧系金属有机骨架材料的制备方法及其吸附除磷的应用 | |
CN107281999B (zh) | 一种铁氧化物/二氧化锰纳米复合材料及其制备方法与应用 | |
Wei et al. | Efficient removal of uranium (vi) from simulated seawater using amidoximated polyacrylonitrile/FeOOH composites | |
CN107913662B (zh) | 一种磁性铁/镧复合除砷吸附材料及其制备方法 | |
CN107973352B (zh) | 一种铁/铜双金属氧化物降解四环素的方法 | |
CN109569548B (zh) | 一种用于海水提铀的磁性纳米功能材料及其制备方法 | |
CN106238006B (zh) | 一种金离子的选择性分离方法 | |
Zhang et al. | From waste to waste treatment: Mesoporous magnetic NiFe2O4/ZnCuCr-layered double hydroxide composite for wastewater treatment | |
Zhang et al. | Polyacrylic acid-functionalized graphene oxide for high-performance adsorption of gallium from aqueous solution | |
Tan et al. | Preparation of magnetic core–shell iron oxide@ silica@ nickel-ethylene glycol microspheres for highly efficient sorption of uranium (VI) | |
CN111266091A (zh) | 一种羧基改性氧化石墨烯@金属有机骨架复合材料及其制备方法和应用 | |
CN112934164A (zh) | 一种磁性除磷吸附剂及其制备方法和应用 | |
Ivanets et al. | Effect of Mg2+ ions on competitive metal ions adsorption/desorption on magnesium ferrite: Mechanism, reusability and stability studies | |
CN113058549B (zh) | 一种碳纳米片复合材料及其制备方法和应用 | |
Wang et al. | Synthesis of yttrium iron garnet using polymer–metal chelate precursor | |
CN108607523A (zh) | 一种选择性分离铟的吸附材料及其制备方法 | |
CN112138634A (zh) | 一种具有双配体的mof及其改性吸附材料和制备方法 | |
CN104324706B (zh) | 一种用于选择性分离银离子的磁性纳米复合物的制备方法 | |
CN112844335B (zh) | 一种耐酸磁性纳米吸附剂及其制备方法 | |
Zhang et al. | Preparation of graphene-based surface ion-imprinted adsorbent for Ga (Ⅲ) selective extraction from acid leaching of fly ash |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20201225 Address after: 246001 e-commerce Industrial Park, NO.48 Renmin Road, Yingjiang District, Anqing City, Anhui Province Patentee after: Wang Zhao Address before: 250353 University Road, Changqing District, Ji'nan, Shandong Province, No. 3501 Patentee before: Qilu University of Technology |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211208 Address after: 314500 Tongxiang, Jiaxing, Zhejiang, Wutong Street East Road (East) 55, Tongxiang chamber of Commerce Building 1 unit 1702, 1703 room -D-405 Patentee after: Jiaxing Ruyun Construction Technology Co.,Ltd. Address before: 246001 e-commerce Industrial Park, NO.48 Renmin Road, Yingjiang District, Anqing City, Anhui Province Patentee before: Wang Zhao |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220420 Address after: 430074 No. 402-269, 4th floor, office building a, No. 777, Guanggu Third Road, Donghu New Technology Development Zone, Wuhan City, Hubei Province Patentee after: Hubei Bailong medical innovation base Co.,Ltd. Address before: 314500 Tongxiang, Jiaxing, Zhejiang, Wutong Street East Road (East) 55, Tongxiang chamber of Commerce Building 1 unit 1702, 1703 room -D-405 Patentee before: Jiaxing Ruyun Construction Technology Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20230310 Address after: Room a-7766, building 3, 20 Yong'an Road, Shilong Economic Development Zone, Mentougou District, Beijing 102300 Patentee after: Beijing Changzhao Medical Instrument Co.,Ltd. Address before: 430074 No. 402-269, 4th floor, office building a, No. 777, Guanggu Third Road, Donghu New Technology Development Zone, Wuhan City, Hubei Province Patentee before: Hubei Bailong medical innovation base Co.,Ltd. |