CN106229515B - 海绵结构陶瓷增强骨架铅负极栅材料及其制备方法 - Google Patents
海绵结构陶瓷增强骨架铅负极栅材料及其制备方法 Download PDFInfo
- Publication number
- CN106229515B CN106229515B CN201610718207.1A CN201610718207A CN106229515B CN 106229515 B CN106229515 B CN 106229515B CN 201610718207 A CN201610718207 A CN 201610718207A CN 106229515 B CN106229515 B CN 106229515B
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- China
- Prior art keywords
- sponge structure
- lead
- skeleton
- ceramics
- preparation
- Prior art date
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- 239000000919 ceramic Substances 0.000 title claims abstract description 68
- 239000000463 material Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 239000004814 polyurethane Substances 0.000 claims abstract description 35
- 229920002635 polyurethane Polymers 0.000 claims abstract description 34
- 230000002708 enhancing effect Effects 0.000 claims abstract description 27
- 239000002253 acid Substances 0.000 claims abstract description 23
- 238000004070 electrodeposition Methods 0.000 claims abstract description 22
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002002 slurry Substances 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 239000008367 deionised water Substances 0.000 claims description 19
- 229910021641 deionized water Inorganic materials 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000725 suspension Substances 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 16
- 238000010438 heat treatment Methods 0.000 claims description 14
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 13
- 229910000281 calcium bentonite Inorganic materials 0.000 claims description 12
- ONCZQWJXONKSMM-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4].[Si+4].[Si+4].[Si+4] ONCZQWJXONKSMM-UHFFFAOYSA-N 0.000 claims description 12
- 229910000280 sodium bentonite Inorganic materials 0.000 claims description 12
- 229940080314 sodium bentonite Drugs 0.000 claims description 12
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 8
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Natural products CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 8
- 235000019441 ethanol Nutrition 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 238000005202 decontamination Methods 0.000 claims description 7
- 230000003588 decontaminative effect Effects 0.000 claims description 7
- YADSGOSSYOOKMP-UHFFFAOYSA-N lead dioxide Inorganic materials O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims description 7
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 claims description 6
- 239000002659 electrodeposit Substances 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 5
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 5
- 238000004321 preservation Methods 0.000 claims description 5
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 238000004506 ultrasonic cleaning Methods 0.000 claims description 4
- 238000010792 warming Methods 0.000 claims description 4
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 238000013007 heat curing Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 2
- 239000002131 composite material Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 13
- 239000002184 metal Substances 0.000 description 13
- 230000006835 compression Effects 0.000 description 5
- 238000007906 compression Methods 0.000 description 5
- 229910045601 alloy Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- XEBCCEFGBHUASY-UHFFFAOYSA-N chlorine lead Chemical compound [Cl].[Pb] XEBCCEFGBHUASY-UHFFFAOYSA-N 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
- H01M4/68—Selection of materials for use in lead-acid accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/73—Grids for lead-acid accumulators, e.g. frame plates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Powder Metallurgy (AREA)
Abstract
Description
质量(g) | 压实强度(MPa) | 抗压强度(MPa) | |
试样1 | 8.54 | 1.32 | - |
试样2 | 5.23 | - | 2.84 |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201610718207.1A CN106229515B (zh) | 2016-08-25 | 2016-08-25 | 海绵结构陶瓷增强骨架铅负极栅材料及其制备方法 |
Applications Claiming Priority (1)
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CN201610718207.1A CN106229515B (zh) | 2016-08-25 | 2016-08-25 | 海绵结构陶瓷增强骨架铅负极栅材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN106229515A CN106229515A (zh) | 2016-12-14 |
CN106229515B true CN106229515B (zh) | 2018-11-13 |
Family
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CN201610718207.1A Active CN106229515B (zh) | 2016-08-25 | 2016-08-25 | 海绵结构陶瓷增强骨架铅负极栅材料及其制备方法 |
Country Status (1)
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CN (1) | CN106229515B (zh) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110256054B (zh) * | 2019-07-03 | 2020-12-29 | 南开大学 | 一种多孔导电陶瓷及其制备方法和应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5800948A (en) * | 1996-12-19 | 1998-09-01 | International Lead Zinc Research Organization, Inc. | Lead-acid battery and separator therefor |
CN1676242A (zh) * | 2005-02-01 | 2005-10-05 | 济南大学 | 网络陶瓷骨架增强金属基复合材料的制备方法及其装置 |
CN105322180A (zh) * | 2014-08-04 | 2016-02-10 | 赵坚强 | 一种新型、环保纯铅铅酸蓄电池 |
-
2016
- 2016-08-25 CN CN201610718207.1A patent/CN106229515B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5800948A (en) * | 1996-12-19 | 1998-09-01 | International Lead Zinc Research Organization, Inc. | Lead-acid battery and separator therefor |
CN1676242A (zh) * | 2005-02-01 | 2005-10-05 | 济南大学 | 网络陶瓷骨架增强金属基复合材料的制备方法及其装置 |
CN105322180A (zh) * | 2014-08-04 | 2016-02-10 | 赵坚强 | 一种新型、环保纯铅铅酸蓄电池 |
Non-Patent Citations (1)
Title |
---|
"铅酸蓄电池镀铅泡沫碳化硅正极集流体的性能";邹智敏 等;《材料研究学报》;20041225;第18卷(第6期);第635-640页 * |
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CN106229515A (zh) | 2016-12-14 |
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SE01 | Entry into force of request for substantive examination | ||
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GR01 | Patent grant | ||
GR01 | Patent grant | ||
CP03 | Change of name, title or address |
Address after: 277200 No. 392, Yinguang Road, economic development zone, Shanting District, Zaozhuang City, Shandong Province Patentee after: SHANDONG QINGDA YINGUANG METAL SPONGE NEW MATERIAL CO.,LTD. Address before: 277200 north of Beijing Road, economic development zone, Shanting District, Zaozhuang City, Shandong Province Patentee before: SHANDONG QINGDA YINGUANG METAL SPONGE NEW MATERIAL CO.,LTD. |
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CP03 | Change of name, title or address | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Sponge structure ceramic reinforced skeleton lead negative grid material and its preparation method Effective date of registration: 20220120 Granted publication date: 20181113 Pledgee: Zaozhuang rural commercial bank Limited by Share Ltd. Shanting branch Pledgor: SHANDONG QINGDA YINGUANG METAL SPONGE NEW MATERIAL CO.,LTD. Registration number: Y2022980000784 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230117 Granted publication date: 20181113 Pledgee: Zaozhuang rural commercial bank Limited by Share Ltd. Shanting branch Pledgor: SHANDONG QINGDA YINGUANG METAL SPONGE NEW MATERIAL CO.,LTD. Registration number: Y2022980000784 |
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PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Sponge structure ceramic reinforced lead cathode grid material and its preparation method Effective date of registration: 20230202 Granted publication date: 20181113 Pledgee: Zaozhuang rural commercial bank Limited by Share Ltd. Shanting branch Pledgor: SHANDONG QINGDA YINGUANG METAL SPONGE NEW MATERIAL CO.,LTD. Registration number: Y2023980031876 |