CN103103592B - 一种(Mn,Co)3O4尖晶石涂层的制备方法 - Google Patents
一种(Mn,Co)3O4尖晶石涂层的制备方法 Download PDFInfo
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- CN103103592B CN103103592B CN201310025622.5A CN201310025622A CN103103592B CN 103103592 B CN103103592 B CN 103103592B CN 201310025622 A CN201310025622 A CN 201310025622A CN 103103592 B CN103103592 B CN 103103592B
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- 239000011248 coating agent Substances 0.000 title claims abstract description 51
- 238000000576 coating method Methods 0.000 title claims abstract description 51
- 238000000034 method Methods 0.000 title claims abstract description 49
- 238000002360 preparation method Methods 0.000 claims abstract description 57
- 239000000843 powder Substances 0.000 claims abstract description 40
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 33
- 229910052596 spinel Inorganic materials 0.000 claims abstract description 33
- 239000011029 spinel Substances 0.000 claims abstract description 33
- 239000000758 substrate Substances 0.000 claims abstract description 29
- 239000000725 suspension Substances 0.000 claims abstract description 14
- 238000001035 drying Methods 0.000 claims abstract description 8
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- 229910045601 alloy Inorganic materials 0.000 claims description 34
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- 238000003756 stirring Methods 0.000 claims description 18
- 230000008021 deposition Effects 0.000 claims description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 239000011812 mixed powder Substances 0.000 claims description 12
- 239000011159 matrix material Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000011068 loading method Methods 0.000 claims description 8
- 229960004756 ethanol Drugs 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 239000012153 distilled water Substances 0.000 claims description 6
- 238000011010 flushing procedure Methods 0.000 claims description 6
- 229910002804 graphite Inorganic materials 0.000 claims description 6
- 239000010439 graphite Substances 0.000 claims description 6
- 239000011259 mixed solution Substances 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 229910000975 Carbon steel Inorganic materials 0.000 claims description 5
- 239000010962 carbon steel Substances 0.000 claims description 5
- 229910000851 Alloy steel Inorganic materials 0.000 claims description 4
- 238000000151 deposition Methods 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000005524 ceramic coating Methods 0.000 abstract description 2
- 238000013019 agitation Methods 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
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- 238000007669 thermal treatment Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 12
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 3
- 230000007774 longterm Effects 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910001220 stainless steel Inorganic materials 0.000 description 3
- 229910000531 Co alloy Inorganic materials 0.000 description 2
- 229910000914 Mn alloy Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
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- 239000000446 fuel Substances 0.000 description 2
- 238000001755 magnetron sputter deposition Methods 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
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- 239000001301 oxygen Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910000846 In alloy Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
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- 239000010935 stainless steel Substances 0.000 description 1
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- -1 this Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
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Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104821406A (zh) * | 2015-04-14 | 2015-08-05 | 中国科学院上海硅酸盐研究所 | 一种固体氧化物燃料电池合金连接体阴极侧涂层的批量制备方法 |
CN106119914B (zh) * | 2016-08-15 | 2018-06-29 | 西安科技大学 | 一种钴锰合金电镀液及其应用 |
CN109267114B (zh) * | 2018-10-22 | 2020-08-21 | 中国科学院金属研究所 | 一种钴锰尖晶石涂层的制备方法 |
CN112322103B (zh) * | 2020-11-11 | 2022-01-25 | 昆明理工大学 | 一种稀土改性(MnCoY)3O4致密涂层的制备方法 |
CN116082022B (zh) * | 2023-04-10 | 2023-06-30 | 矿冶科技集团有限公司 | 一种陶瓷粉末的制备方法及陶瓷粉末 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102653858A (zh) * | 2012-05-28 | 2012-09-05 | 哈尔滨工业大学深圳研究生院 | 磁控溅射与后续氧化制备MnCo尖晶石保护膜的方法 |
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Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102653858A (zh) * | 2012-05-28 | 2012-09-05 | 哈尔滨工业大学深圳研究生院 | 磁控溅射与后续氧化制备MnCo尖晶石保护膜的方法 |
Non-Patent Citations (2)
Title |
---|
Electrophoretic deposition of (Mn,Co)3O4 spinel coating for solid oxide fuel cell interconnects;Hui Zhang等;《Journal of Power Sources》;20110527;第196卷;第二节实验部分和第四节结论部分 * |
Electrophoretic deposition of (Mn,Co)3O4 spinel nano powder on SOFC metallic interconnects;H. Abdoli等;《Materials Letters》;20120424;第80卷;第53-55页 * |
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Application publication date: 20130515 Assignee: Yunnan Tailixin Electromechanical Equipment Co.,Ltd. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023530000059 Denomination of invention: A preparation method of spinel coating for (Mn, Co)3O4 Granted publication date: 20150722 License type: Common License Record date: 20230914 Application publication date: 20130515 Assignee: KMUST ELECTRIC POWER ENGINEERING TECHNOLOGY Co.,Ltd. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023530000056 Denomination of invention: A preparation method of spinel coating for (Mn, Co)3O4 Granted publication date: 20150722 License type: Common License Record date: 20230914 Application publication date: 20130515 Assignee: Yunnan Tusai Engineering Construction Co.,Ltd. Assignor: Kunming University of Technology Design and Research Institute Co.,Ltd. Contract record no.: X2023530000055 Denomination of invention: A preparation method of spinel coating for (Mn, Co)3O4 Granted publication date: 20150722 License type: Common License Record date: 20230914 |