CN106220154B - A kind of crystallite ink-jet polished bricks - Google Patents
A kind of crystallite ink-jet polished bricks Download PDFInfo
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- CN106220154B CN106220154B CN201610572026.2A CN201610572026A CN106220154B CN 106220154 B CN106220154 B CN 106220154B CN 201610572026 A CN201610572026 A CN 201610572026A CN 106220154 B CN106220154 B CN 106220154B
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
- E04F13/142—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of ceramics or clays
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
Abstract
A kind of crystallite ink-jet polished bricks, belong to house decoration material technical field.It is characterized by: being made of sintering integrated upper unburnt brick face and bottom base brick bottom, upper unburnt brick face and bottom base brick bottom are same base-material, it is scattered on upper unburnt brick face somehow agglomerate, somehow the side of agglomerate is surrounded by ink slurry forms colo(u)r streak, wherein the parts by weight composition of base-material includes: 35 ~ 40 parts of albite, 21 ~ 24 parts of potassium feldspar, 26 ~ 28 parts of ball clay, 3 ~ 4 parts of high alumina stone, 2 ~ 2.5 parts of talcum；The parts by weight composition of ink slurry includes: 27 ~ 33 parts of albite, 27 ~ 33 parts of potassium feldspar, 13 ~ 17 parts of ball clay, 8 ~ 12 parts of high alumina stone, 8 ~ 12 parts of pyrophillite, 3 ~ 7 parts of talcum.The textured pattern of the crystallite ink-jet polished bricks has randomness, and each piece of brick all has oneself unique decorative pattern, and decorative pattern is decorative pattern possessed by entire upper green body layer, and brick decorative pattern will not be caused to disappear with friction.
Description
Technical field
A kind of crystallite ink-jet polished bricks, belong to house decoration material technical field.
Background technique
Traditional ceramic tile is the metal oxide and half-metal oxide with fire resisting, via grinding, mixing, compacting, glazing,
Sintering process makes to be formed.Decorative pattern on ceramic tile typically forms glaze layer by glazing step and shows, but this glaze
If the thickness of the glaze layer of face brick is smaller, ceramic tile can be shorter using that will grind glaze layer in the time, so that porcelain
Original decorative pattern hour of brick.And if increasing the thickness of glaze layer, cost can increase considerably, and reduce the market competitiveness.Now
Also the ceramic tile having no longer sets glaze layer, but directly polishes to the green body of ceramic tile, to obtain a kind of ceramic tile of surface-brightening.But
It is that the surfaces of this polished bricks can not form diversified decorative pattern, style is single, does not meet Popular Aesthetics demand.
Summary of the invention
The technical problem to be solved by the present invention is it is various to overcome the deficiencies of the prior art and provide a kind of wear-resisting and pattern
Crystallite ink-jet polished bricks.
The technical solution adopted by the present invention to solve the technical problems is: the crystallite ink-jet polished bricks, it is characterised in that: by
Sintering integrated upper unburnt brick face and bottom base brick bottom composition, upper unburnt brick face and bottom base brick bottom are same base-material, upper unburnt brick face
On be scattered with somehow agglomerate, somehow the side of agglomerate is surrounded by ink slurry forms colo(u)r streak, wherein the parts by weight of the base-material form packet
It includes: 35 ~ 40 parts of albite, 21 ~ 24 parts of potassium feldspar, 26 ~ 28 parts of ball clay, 3 ~ 4 parts of high alumina stone, 2 ~ 2.5 parts of talcum；It is described who
The parts by weight of raw materials composition of dough block includes: 42 ~ 45 parts of albite, and 17 ~ 19 parts of potassium feldspar, 20 ~ 28 parts of ball clay, high alumina stone 3
~ 7 parts, 2 ~ 4 parts of talcum；The parts by weight composition of the ink slurry includes: 27 ~ 33 parts of albite, and 27 ~ 33 parts of potassium feldspar, ball clay 13
~ 17 parts, 8 ~ 12 parts of high alumina stone, 8 ~ 12 parts of pyrophillite, 3 ~ 7 parts of talcum.
This crystallite ink-jet polished bricks are prepared by secondary material distributing mode, and the upper green body and bottom base of secondary material distributing are
Same base-material reduces brick later period rebound deformation caused by mismatching because of bottom surface material, while brick face and brick bottom materials as far as possible
The unified brick body that can also reach is like nature itself effect such as jade.But in order to make brick face form diversified pattern, the present invention
It spreads also on upper unburnt brick face somehow agglomerate, and somehow sketching out colo(u)r streak on the side of agglomerate, this leads to green body and bottom again
Base materials cannot absolutely be unified, in order to thoroughly solve brick later period rebound deformation caused by the disunity bottom surface material of materials mismatches
The problem of, the present invention by base-material, somehow the formula of agglomerate and ink slurry regulates and controls, the color that the main formula by ink slurry is formed
Expansion ratio when firing possessed by line, transition base-material and somehow agglomerate expansion ratio expansion ratio, solve to expect to mismatch because of bottom surface
Caused by brick later period rebound deformation the problem of.The present invention is delineated by unique vivid cloth, colorant, material filling, powder are drilled thoroughly
Unravel silk four big core technology essence castings.Product surface forms the natural textures such as the mountains and rivers vein of the earth, lava agglomerate, valley ground cleave, rubble distribution
Effect.Grand Canyon is risen and fallen be continuous, hundred turns thousand times, dangerously steep elegant natural meteorological perfect inscription rubbing, the terrible axe for restoring the Nature is refreshing
Work.The powder of different colours forms the unbroken mountain range texture that rises and falls after premix squeezes in green body, and lines are free and easy, and freehand brushwork is forced
Very.In order to keep the three-dimensional stronger texture of product finer and smoother, the mill base atomization process cooperation for additionally using ink-jet slurry strikes off step, makes
Ink slurry is uniformly distributed in lava after atomization, around agglomerate, forms brightly painted stone line, deep or shallow, visually
The profile for sketching out lava agglomerate, is rich in three-dimensional sense.Powder of the green body cake after precompressed is pushed aside with pressure tool hand, is formed in length and breadth
Staggered valley topography style and features, then will super material (somehow) filling therebetween so that texture is more life-like, three-dimensional, super material
Use, make product more close to beautiful matter texture.Somehow cooperation of freely trickling down to strike off be somehow the random cloth of powder, deduction are produced
The naturally elegant textured pattern in product surface.The textured pattern of crystallite ink-jet polished bricks made of the technique has randomness, each
Block brick all has oneself unique decorative pattern, and decorative pattern is decorative pattern possessed by entire upper green body layer, will not lead to brick with friction
Decorative pattern disappears.
Preferably, the small green body in irregular shape of longest diagonal line 3cm ~ 10cm is also distributed in the upper unburnt brick face
Block, the spacing between adjacent small blank stock are 2.5cm ~ 15cm.The present invention is by the use of green body raw material twice in upper unburnt brick
It is formed with small blank stock on face, the powder of different colours is subjected to independent assortment collocation, by premixing precompressed, forms face after broken
Color is well arranged, and agglomerate is not of uniform size, and the different lava agglomerate of quantity is randomly distributed on polished bricks surface, more close to original
Stone effect, level are clearly more demarcated.
Preferably, the small blank stock is identical as the composition of base-material, and the dosage of identical component is on the basis of base-material dosage
On increase accordingly or reduce 0.5 ~ 3 parts by weight.While forming color differentiation, guarantee the unification of upper green body and bottom base as far as possible.
Preferably, described somehow agglomerate does not advise the shape that upper unburnt brick face is divided into longest diagonal line 10cm ~ 25cm
Big blank stock then, the spacing between adjacent big blank stock are 0.6 cm ~ 3cm.The ratio of the pattern form more agree with naturally,
It is more beautiful.
Preferably, the parts by weight composition of the base-material are as follows: 38 ~ 39 parts of albite, 22 ~ 23 parts of potassium feldspar, ball clay 26 ~
27 parts, 3 parts of high alumina stone, 2.5 parts of talcum.The optimization formula can reach similar natural jade decorative effect while in turn avoid
The antifouling defect in the bricks such as pin hole pore face.High-quality selection ensures Product Green environmental protection and radiationless pollution.Ball clay when exploitation because being pressed into
It is spherical and gain the name, be constituted and be mixed with by kaolinite the impurity such as a certain number of quartz, micas and organic matter one kind it is plastic glutinous
Soil.High alumina stone is also known as bauxite soil or bauxite, main component are aluminium oxide, is the hydrated alumina containing impurity, is a kind of
Earthy mineral.
Preferably, described somehow the parts by weight of raw materials of agglomerate forms are as follows: 43 ~ 44 parts of albite, 18 ~ 19 parts of potassium feldspar,
24 ~ 26 parts of ball clay, 4 ~ 5 parts of high alumina stone, 3 parts of talcum.Somehow the raw material of agglomerate is adjusted on the basis of base-material, Ke Yigeng
Readily by the transition of ink slurry, matching effect is obtained.
Preferably, the parts by weight composition of the ink slurry are as follows: 28 ~ 30 parts of albite, 29 ~ 31 parts of potassium feldspar, ball clay 15
Part, 10 parts of high alumina stone, 10 parts of pyrophillite, 5 parts of talcum.The ink slurry formula can embody the unexistent exquisiteness of common polished bricks
Texture and rich colors, color development is gorgeous and is completely not in many defects such as delayed crazing, deformation pin hole.
Compared with prior art, beneficial effect possessed by a kind of crystallite ink-jet polished bricks of the invention is: the spray of this crystallite
Black polished bricks, which completely unify brick face and brick bottom by the control of each section compositing formula, can reach jade highest quality effect,
Thoroughly solves the later period rebound deformation of brick simultaneously.Product surface produced by the present invention forms the mountains and rivers vein of the earth, lava agglomerate, valley
The natural texture effects such as ground cleave, rubble distribution.Grand Canyon is risen and fallen be continuous, hundred turns thousand times, dangerously steep elegant natural meteorological perfection
Inscription rubbing restores the superb craftsmanship of the Nature.The textured pattern of crystallite ink-jet polished bricks made of the technique has randomness, each
Block brick all has oneself unique decorative pattern, and decorative pattern is decorative pattern possessed by entire upper green body layer, will not lead to brick with friction
Decorative pattern disappears.
Detailed description of the invention
Fig. 1 is a kind of pattern schematic diagram of crystallite ink-jet polished bricks of the invention.
Fig. 2 is the pattern schematic diagram of another crystallite ink-jet polished bricks of the invention.
Wherein, 1, big blank stock 2, somehow agglomerate 3, small blank stock 4, colo(u)r streak.
Specific embodiment
A kind of crystallite ink-jet polished bricks of the invention are described further combined with specific embodiments below, wherein embodiment
1 is most preferred embodiment.
Embodiment
The parts by weight of base-material form
Somehow the parts by weight of agglomerate raw material form
The parts by weight composition of ink slurry
28 ~ 30 parts of albite, 29 ~ 31 parts of potassium feldspar, 15 parts of ball clay, 10 parts of high alumina stone, 10 parts of pyrophillite, talcum 5
Part.
The crystallite ink-jet polished bricks of each embodiment are made of, upper green body sintering integrated upper unburnt brick face and bottom base brick bottom
Brick face and bottom base brick bottom are same base-material, are scattered on upper unburnt brick face somehow agglomerate 2, is wrapped somehow the side of agglomerate 2 is starched by ink
It encloses to form colo(u)r streak 4, upper unburnt brick EDS maps have the small blank stock 3(embodiment 5 in irregular shape of longest diagonal line 3cm ~ 10cm
Except), the spacing between adjacent small blank stock 3 is 2.5cm ~ 15cm, somehow upper unburnt brick face is divided into longest pair by agglomerate 2
The big blank stock 1 in irregular shape of linea angulata 10cm ~ 25cm, the spacing between adjacent big blank stock 1 are 0.6 cm ~ 3cm.
Embodiment is prepared using following techniques:
1) raw meal powder worn by small blank stock parts by weight composition is pressed into green body item；The blank item is broken into most again
The small blocks in irregular shape of long-diagonal 3cm ~ 10cm, the spacing between adjacent isles body are 2.5cm ~ 15cm；Then after
Spray is by upper behind the continuous unrestrained gap formed between weighing green body raw meal powder filling small blocks made of material milling by base-material parts by weight
State the ink slurry that ink slurry parts by weight composition is modulated into；
2) it after ink-jet slurry carries out that green body cake is made again；
3) green body cake is pushed aside using pressure tool hand, causes the area to be filled of perforation green body cake, pressure tool hand pushs green body cake aside
The agglomerate body in irregular shape for forming longest diagonal line 15cm ~ 25cm afterwards, the spacing between adjacent bulk body be 0.6 cm ~
3cm；
4) it is freely trickled down on the green body cake after Xiang Shangshu is pushed aside above-mentioned somehow what agglomerate raw material claimed to grind after going by weight
Chamotte powder realizes material filling thoroughly；
5) compression moulding is re-started to blank clinker and upper green body is made；
6) it is coated with base-material identical as step 1) on upper green body and forms the bottom base being pressed into, professional etiquette of going forward side by side lattice cut to obtain pre-
Burn part；
7) pre-burning part dry 60min under 200 DEG C of drying temperature；
8) pre-burning part is fired, the thermograph of each temperature of hour record: pre-burning part is fired, furnace
After temperature is preheated to 900 DEG C, pre-burning part carries out into furnace after being gradually heated to 1100 DEG C with 15 DEG C/h ~ 22 DEG C/h heating rate
Primary heat preservation 4h, carries out keeping the temperature for second after being then gradually heated to 1220 DEG C again with 10 DEG C/h ~ 20 DEG C/h heating rate
10h, with 65 DEG C/h ~ 120 DEG C/h rate of temperature fall fast cooling to room temperature after the completion of second of heat preservation；
Thermograph
9) upper green body face is polished after firing to obtain the final product.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint
What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc.
Imitate embodiment.But without departing from the technical solutions of the present invention, according to the technical essence of the invention to above embodiments institute
Any simple modification, equivalent variations and the remodeling made, still fall within the protection scope of technical solution of the present invention.
Claims (6)
1. a kind of crystallite ink-jet polished bricks, it is characterised in that: be made of sintering integrated upper unburnt brick face and bottom base brick bottom, upper base
Body brick face and bottom base brick bottom are same base-material, are scattered with clinker agglomerate (2) on upper unburnt brick face, and the side of clinker agglomerate (2) is logical
It crosses ink slurry encirclement and forms colo(u)r streak (4), wherein the parts by weight composition of the base-material includes: 35 ~ 40 parts of albite, potassium feldspar 21 ~ 24
Part, 26 ~ 28 parts of ball clay, 3 ~ 4 parts of high alumina stone, 2 ~ 2.5 parts of talcum；The parts by weight of raw materials of the clinker agglomerate forms
42 ~ 45 parts of albite, 17 ~ 19 parts of potassium feldspar, 20 ~ 28 parts of ball clay, 3 ~ 7 parts of high alumina stone, 2 ~ 4 parts of talcum；The ink slurry
Parts by weight composition includes: 27 ~ 33 parts of albite, and 27 ~ 33 parts of potassium feldspar, 13 ~ 17 parts of ball clay, 8 ~ 12 parts of high alumina stone, pyrophillite
8 ~ 12 parts, 3 ~ 7 parts of talcum；
Upper unburnt brick face is divided into the big base in irregular shape of longest diagonal line 10cm ~ 25cm by the clinker agglomerate (2)
Body block (1), the spacing between adjacent big blank stock (1) are 0.6 cm ~ 3cm.
2. a kind of crystallite ink-jet polished bricks according to claim 1, it is characterised in that: the upper unburnt brick face is also distributed
There is the small blank stock (3) in irregular shape of longest diagonal line 3cm ~ 10cm, the spacing between adjacent small blank stock (3) is
2.5cm ~15cm。
3. a kind of crystallite ink-jet polished bricks according to claim 2, it is characterised in that: the small blank stock (3) and base
The composition of material is identical, and the dosage of identical component increase accordingly or reduce 0.5 ~ 3 parts by weight on the basis of base-material dosage.
4. a kind of crystallite ink-jet polished bricks according to claim 1, it is characterised in that: the parts by weight of the base-material form
Are as follows: 38 ~ 39 parts of albite, 22 ~ 23 parts of potassium feldspar, 26 ~ 27 parts of ball clay, 3 parts of high alumina stone, 2.5 parts of talcum.
5. a kind of crystallite ink-jet polished bricks according to claim 1, it is characterised in that: the original of the clinker agglomerate (2)
Expect parts by weight composition are as follows: 43 ~ 44 parts of albite, 18 ~ 19 parts of potassium feldspar, 24 ~ 26 parts of ball clay, 4 ~ 5 parts of high alumina stone, talcum 3
Part.
6. a kind of crystallite ink-jet polished bricks according to claim 1, it is characterised in that: the parts by weight composition of the ink slurry
Are as follows: 28 ~ 30 parts of albite, 29 ~ 31 parts of potassium feldspar, 15 parts of ball clay, 10 parts of high alumina stone, 10 parts of pyrophillite, 5 parts of talcum.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610572026.2A CN106220154B (en) | 2016-07-20 | 2016-07-20 | A kind of crystallite ink-jet polished bricks |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610572026.2A CN106220154B (en) | 2016-07-20 | 2016-07-20 | A kind of crystallite ink-jet polished bricks |
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| CN106220154B true CN106220154B (en) | 2019-04-02 |
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| CN107200554A (en) * | 2017-07-20 | 2017-09-26 | 淄博新博陶瓷有限公司 | A kind of preparation technology of antifouling sheen Dali stone ceramic tile |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103159497A (en) * | 2011-12-09 | 2013-06-19 | 辽宁金地阳陶瓷有限公司 | Jinyongdong stone polished tile and production method for same |
| CN104944923A (en) * | 2015-06-23 | 2015-09-30 | 淄博成畅建筑陶瓷有限公司 | Polished tile and making method thereof |
| CN105328782A (en) * | 2015-10-22 | 2016-02-17 | 广东宏陶陶瓷有限公司 | Ceramic polished brick and production method and production line of ceramic polished brick |
-
2016
- 2016-07-20 CN CN201610572026.2A patent/CN106220154B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103159497A (en) * | 2011-12-09 | 2013-06-19 | 辽宁金地阳陶瓷有限公司 | Jinyongdong stone polished tile and production method for same |
| CN104944923A (en) * | 2015-06-23 | 2015-09-30 | 淄博成畅建筑陶瓷有限公司 | Polished tile and making method thereof |
| CN105328782A (en) * | 2015-10-22 | 2016-02-17 | 广东宏陶陶瓷有限公司 | Ceramic polished brick and production method and production line of ceramic polished brick |
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