CN106220154A - A kind of crystallite ink-jet polished bricks - Google Patents

A kind of crystallite ink-jet polished bricks Download PDF

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Publication number
CN106220154A
CN106220154A CN201610572026.2A CN201610572026A CN106220154A CN 106220154 A CN106220154 A CN 106220154A CN 201610572026 A CN201610572026 A CN 201610572026A CN 106220154 A CN106220154 A CN 106220154A
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parts
ink
crystallite
brick
agglomerate
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CN201610572026.2A
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CN106220154B (en
Inventor
王铎
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Zibo Xinbo Ceramic Technology Co Ltd
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Zibo Xinbo Ceramic Technology Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/07Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
    • E04F13/08Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
    • E04F13/14Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
    • E04F13/142Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass with an outer layer of ceramics or clays
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Architecture (AREA)
  • Dispersion Chemistry (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Finishing Walls (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A kind of crystallite ink-jet polished bricks, belongs to house decoration material technical field.It is characterized in that: formed by the bottom of sintering integrated upper unburnt brick face and end base brick, it is same base material at the bottom of upper unburnt brick face and end base brick, it is scattered with somehow agglomerate on upper unburnt brick face, somehow the limit of agglomerate is surrounded by ink slurry forms colo(u)r streak, wherein the weight portion composition of base material includes: albite 35 ~ 40 parts, potassium feldspar 21 ~ 24 parts, ball clay 26 ~ 28 parts, 3 ~ 4 parts of high alumina stone, 2 ~ 2.5 parts of Talcum;The weight portion composition of ink slurry includes: albite 27 ~ 33 parts, potassium feldspar 27 ~ 33 parts, ball clay 13 ~ 17 parts, 8 ~ 12 parts of high alumina stone, pyrophillite 8 ~ 12 parts, 3 ~ 7 parts of Talcum.The textured pattern of this crystallite ink-jet polished bricks has randomness, and each piece of brick all has the decorative pattern of oneself uniqueness, and the decorative pattern that decorative pattern is had by whole upper green body layer, brick decorative pattern will be caused to disappear along with friction.

Description

A kind of crystallite ink-jet polished bricks
Technical field
A kind of crystallite ink-jet polished bricks, belongs to house decoration material technical field.
Background technology
Traditional ceramic tile is with fire-resistant metal-oxide and half-metal oxide, via grinding, mix, suppress, glazing, Sintering process makes and is formed.Decorative pattern on ceramic tile is typically all formed glaze layer by glazing step and shows, but this glaze If the thickness of the glaze layer of face brick is less, then ceramic tile can will grind glaze layer within the shorter use time so that porcelain Original decorative pattern hour of brick.And if increase glaze layer thickness, cost can increase considerably, reduce the market competitiveness.Now Also the ceramic tile having no longer sets glaze layer, but is directly polished, the base substrate of ceramic tile to obtain the ceramic tile of a kind of surface-brightening.But Being that the surface of this polished bricks cannot form diversified decorative pattern, style is single, does not meets Popular Aesthetics demand.
Summary of the invention
The technical problem to be solved in the present invention is: overcome the deficiencies in the prior art, it is provided that a kind of wear-resisting pattern again is various Crystallite ink-jet polished bricks.
The technical solution adopted for the present invention to solve the technical problems is: this crystallite ink-jet polished bricks, it is characterised in that: by Form at the bottom of sintering integrated upper unburnt brick face and end base brick, be same base material at the bottom of upper unburnt brick face and end base brick, upper unburnt brick face On be scattered with somehow agglomerate, somehow the limit of agglomerate is surrounded by ink slurry forms colo(u)r streak, the weight portion composition bag of wherein said base material Include: albite 35 ~ 40 parts, potassium feldspar 21 ~ 24 parts, ball clay 26 ~ 28 parts, 3 ~ 4 parts of high alumina stone, 2 ~ 2.5 parts of Talcum;Described who The parts by weight of raw materials composition of dough block includes: albite 42 ~ 45 parts, potassium feldspar 17 ~ 19 parts, ball clay 20 ~ 28 parts, high alumina stone 3 ~ 7 parts, 2 ~ 4 parts of Talcum;The weight portion composition of described ink slurry includes: albite 27 ~ 33 parts, potassium feldspar 27 ~ 33 parts, ball clay 13 ~ 17 parts, 8 ~ 12 parts of high alumina stone, pyrophillite 8 ~ 12 parts, 3 ~ 7 parts of Talcum.
This crystallite ink-jet polished bricks being prepared from by secondary material distributing mode, upper base substrate and the end base of secondary material distributing are Same base material, decreases because bottom surface material does not mate the brick later stage rebound deformation caused as far as possible, simultaneously materials at the bottom of brick face and brick Unification also can reach brick body highest quality effect as jade.But in order to make brick face form diversified pattern, the present invention Also spread somehow agglomerate on upper unburnt brick face, and somehow sketch out colo(u)r streak on the limit of agglomerate, this causes again base substrate and the end Base materials can not be the most unified, in order to thoroughly solve materials disunity bottom surface expect do not mate the brick later stage rebound deformation caused Problem, the present invention by base material somehow the formula of agglomerate and ink slurry regulates and controls, the color that the main formula starched by ink is formed Expansion ratio when firing that line is had, transition base material, with somehow the expansion ratio expansion ratio of agglomerate, solves because bottom surface material does not mates The problem of the brick later stage rebound deformation caused.The present invention is delineated by unique vivid cloth, colorant, is thoroughly expected that filling, powder are drilled Unravel silk four big core technology essence castings.Product surface forms the natural textures such as the mountains and rivers vein of the earth, lava agglomerate, valley ground cleave, rubble distribution Effect.Grand Canyon is risen and fallen be continuous, hundred turns thousand times, dangerously steep elegant naturally meteorological perfect inscription rubbing, the terrible axe of reduction the Nature is refreshing Work.In base substrate, the powder of different colours is after premix extruding, forms the unbroken mountain range texture that rises and falls, and lines are free and easy, and freehand brushwork is forced Very.In order to make the three-dimensional higher texture of product finer and smoother, the mill base atomization process cooperation additionally using ink-jet slurry strikes off step, makes Ink slurry is distributed in around lava, agglomerate after atomization uniformly, forms brightly painted stone line, deep or shallow, visually Sketch out the profile of lava agglomerate, be rich in third dimension.Base substrate cake powder after precompressed, pushs aside with pressure tool hands, is formed in length and breadth Staggered valley physical features style and features, then will super expect (somehow) filling is therebetween so that texture is more life-like, three-dimensional, super material Use, make product more press close to beautiful matter texture.Somehow freely to trickle down that cooperation strikes off be that deduction is produced somehow powder random cloth The textured pattern that product surface is the most elegant.The textured pattern of the crystallite ink-jet polished bricks that this technique is made has randomness, each Block brick all has the decorative pattern of oneself uniqueness, and the decorative pattern that decorative pattern is had by whole upper green body layer, will not cause brick along with friction Decorative pattern disappears.
Preferably, described upper unburnt brick face is also distributed the in irregular shape little base substrate of long-diagonal 3cm ~ 10cm Block, the spacing between adjacent little blank stock is 2.5cm ~ 15cm.The present invention passes through the use of twice base substrate raw material at upper unburnt brick It is formed with little blank stock on face, the powder of different colours is carried out independent assortment collocation, through premix precompressed, after crushing, form face Color is well arranged, and agglomerate is not of uniform size, the lava agglomerate that quantity differs, and is randomly distributed on polished bricks surface, more presses close to former Stone effect, level is clearly more demarcated.
Preferably, described little blank stock is identical with the composition of base material, and the consumption of identical component is on the basis of base material consumption On 0.5 ~ 3 weight portion is increased or decreased accordingly.While forming color differentiation, ensure upper base substrate and the unification of end base as far as possible.
Preferably, described somehow the shape that upper unburnt brick face is divided into long-diagonal 10cm ~ 25cm is not advised by agglomerate Big blank stock then, the spacing between adjacent big blank stock is 0.6 cm ~ 3cm.The ratio of this pattern form more agrees with nature, More attractive in appearance.
Preferably, the weight portion of described base material consists of: albite 38 ~ 39 parts, potassium feldspar 22 ~ 23 parts, and ball clay 26 ~ 27 parts, 3 parts of high alumina stone, 2.5 parts of Talcum.This optimization formula can reach similar natural jade decorative effect and turn avoid simultaneously The antifouling defects in brick face such as pin hole pore.High-quality selection guarantees Product Green environmental protection and radiationless pollution.It is pressed into when ball clay is because of exploitation Spherical and gain the name, it is that be made up of and be mixed with the one of the impurity such as a number of quartz, Muscovitum and organic matter kaolinite plastic glutinous Soil.High alumina stone is also known as bauxite soil or bauxite, and main component is aluminium oxide, is the hydrated alumina containing impurity, is a kind of Earthy mineral.
Preferably, described somehow the parts by weight of raw materials of agglomerate consists of: albite 43 ~ 44 parts, potassium feldspar 18 ~ 19 parts, Ball clay 24 ~ 26 parts, 4 ~ 5 parts of high alumina stone, 3 parts of Talcum.Somehow the raw material of agglomerate is adjusted on the basis of base material, Ke Yigeng The transition readily starched by ink, obtains matching effect.
Preferably, the weight portion of described ink slurry consists of: albite 28 ~ 30 parts, potassium feldspar 29 ~ 31 parts, ball clay 15 Part, 10 parts of high alumina stone, pyrophillite 10 parts, 5 parts of Talcum.This ink slurry formula can embody the unexistent exquisiteness of common polished bricks Texture and rich colors, color development is gorgeous and does not haves many defects such as delayed crazing, deformation pin hole completely.
Compared with prior art, a kind of crystallite ink-jet polished bricks of the present invention is had the beneficial effect that this crystallite sprays Ink polished bricks makes complete unity at the bottom of brick face and brick can reach jade highest quality effect by the control of each several part compositing formula, Thoroughly solve the later stage rebound deformation of brick simultaneously.The product surface that the present invention prepares forms the mountains and rivers vein of the earth, lava agglomerate, valley The natural texture effects such as ground cleave, rubble distribution.Grand Canyon is risen and fallen be continuous, hundred turns thousand times, dangerously steep elegant naturally meteorological perfection Inscription rubbing, the superb craftsmanship of reduction the Nature.The textured pattern of the crystallite ink-jet polished bricks that this technique is made has randomness, each Block brick all has the decorative pattern of oneself uniqueness, and the decorative pattern that decorative pattern is had by whole upper green body layer, will not cause brick along with friction Decorative pattern disappears.
Accompanying drawing explanation
Fig. 1 is the pattern schematic diagram of a kind of crystallite ink-jet polished bricks of the present invention.
Fig. 2 is the pattern schematic diagram of the another kind of crystallite ink-jet polished bricks of the present invention.
Wherein, 1, big blank stock 2 is somehow agglomerate 3, little blank stock 4, colo(u)r streak.
Detailed description of the invention
Below in conjunction with specific embodiment, a kind of crystallite ink-jet polished bricks of the present invention is described further, wherein embodiment 1 is most preferred embodiment.
Embodiment
The weight portion composition of base material
Somehow the weight portion composition of agglomerate raw material
The weight portion composition of ink slurry
Albite 28 ~ 30 parts, potassium feldspar 29 ~ 31 parts, ball clay 15 parts, 10 parts of high alumina stone, pyrophillite 10 parts, 5 parts of Talcum.
The crystallite ink-jet polished bricks of each embodiment, is formed by the bottom of sintering integrated upper unburnt brick face and end base brick, upper base substrate It is same base material at the bottom of brick face and end base brick, upper unburnt brick face is scattered with somehow agglomerate 2, wraps somehow the limit of agglomerate 2 is starched by ink Enclosing formation colo(u)r streak 4, upper unburnt brick EDS maps has the in irregular shape little blank stock 3(embodiment 5 of long-diagonal 3cm ~ 10cm Except), the spacing between adjacent little blank stock 3 is 2.5cm ~ 15cm, somehow agglomerate 2 upper unburnt brick face is divided into the longest right The in irregular shape big blank stock 1 of linea angulata 10cm ~ 25cm, the spacing between adjacent big blank stock 1 is 0.6 cm ~ 3cm.
Embodiment uses following technique to prepare:
1) raw meal powder worn into by little blank stock weight portion composition is pressed into base substrate bar;It is the longest right to be broken into by this blank bar again The small blocks in irregular shape of linea angulata 3cm ~ 10cm, the spacing between adjacent isles body is 2.5cm ~ 15cm;Then proceed to spill Fall and spray by above-mentioned ink after weighing the space between the base substrate raw meal powder filling small blocks that material pulverizing is made by base material weight portion composition The ink slurry that slurry weight portion composition is modulated into;
2) carry out compacting again after ink-jet slurry and make base substrate cake;
3) utilize pressure tool hands to be pushed aside by base substrate cake, cause the area to be filled of through base substrate cake, pressure tool hands to push base substrate cake aside rear shape Becoming the agglomerate body in irregular shape of long-diagonal 15cm ~ 25cm, the spacing between adjacent bulk body is 0.6 cm ~ 3cm;
4) freely trickle down on the base substrate cake after above-mentioned pushing aside above-mentioned somehow the grog that grinds after claiming by weight of agglomerate raw material Powder realizes thoroughly expecting filling;
5) blank grog is re-started compressing prepared upper base substrate;
6) being coated with base material identical with step 1) on upper base substrate and form the end base being pressed into, the cutting of professional etiquette of going forward side by side lattice obtains pre-burning Part;
7) pre-burning part is dried 60min under the baking temperature of 200 DEG C;
8) pre-burning part is fired, the thermograph of each temperature of hour record: being fired pre-burning part, furnace temperature is pre- After hot to 900 DEG C, pre-burning part enters stove, carries out for the first time after being gradually heating to 1100 DEG C with the heating rate of 15 DEG C/h ~ 22 DEG C/h Insulation 4h, carries out second time and is incubated 10h after being gradually heating to 1220 DEG C with the heating rate of 10 DEG C/h ~ 20 DEG C/h the most again, the Secondary be incubated after with the rate of temperature fall fast cooling of 65 DEG C/h ~ 120 DEG C/h to room temperature;
Thermograph
9) after firing, upper base substrate face is polished and get final product.
The above, be only presently preferred embodiments of the present invention, is not the restriction that the present invention makees other form, appoints What those skilled in the art changed possibly also with the technology contents of the disclosure above or be modified as equivalent variations etc. Effect embodiment.But every without departing from technical solution of the present invention content, the technical spirit of the foundation present invention is to above example institute Any simple modification, equivalent variations and the remodeling made, still falls within the protection domain of technical solution of the present invention.

Claims (7)

1. a crystallite ink-jet polished bricks, it is characterised in that: formed by the bottom of sintering integrated upper unburnt brick face and end base brick, upper base It is same base material at the bottom of body brick face and end base brick, upper unburnt brick face is scattered with somehow agglomerate (2), somehow the limit of agglomerate (2) is passed through Ink slurry surrounds and forms colo(u)r streak (4), and the weight portion composition of wherein said base material includes: albite 35 ~ 40 parts, potassium feldspar 21 ~ 24 Part, ball clay 26 ~ 28 parts, 3 ~ 4 parts of high alumina stone, 2 ~ 2.5 parts of Talcum;Described somehow the parts by weight of raw materials composition of agglomerate includes: sodium Anhydrite 42 ~ 45 parts, potassium feldspar 17 ~ 19 parts, ball clay 20 ~ 28 parts, 3 ~ 7 parts of high alumina stone, 2 ~ 4 parts of Talcum;The weight of described ink slurry Amount part composition includes: albite 27 ~ 33 parts, potassium feldspar 27 ~ 33 parts, ball clay 13 ~ 17 parts, 8 ~ 12 parts of high alumina stone, pyrophillite 8 ~ 12 parts, 3 ~ 7 parts of Talcum.
A kind of crystallite ink-jet polished bricks the most according to claim 1, it is characterised in that: described upper unburnt brick face is also distributed The in irregular shape little blank stock (3) of long-diagonal 3cm ~ 10cm, the spacing between adjacent little blank stock (3) is had to be 2.5cm ~15cm。
A kind of crystallite ink-jet polished bricks the most according to claim 2, it is characterised in that: described little blank stock (3) and base The composition of material is identical, and the consumption of identical component is increased or decreased 0.5 ~ 3 weight portion on the basis of base material consumption accordingly.
A kind of crystallite ink-jet polished bricks the most according to claim 1, it is characterised in that: described somehow agglomerate (2) is by upper Unburnt brick face is divided into the in irregular shape big blank stock (1) of long-diagonal 10cm ~ 25cm, adjacent big blank stock (1) it Between spacing be 0.6 cm ~ 3cm.
A kind of crystallite ink-jet polished bricks the most according to claim 1, it is characterised in that: the weight portion group of described base material Become: albite 38 ~ 39 parts, potassium feldspar 22 ~ 23 parts, ball clay 26 ~ 27 parts, 3 parts of high alumina stone, 2.5 parts of Talcum.
A kind of crystallite ink-jet polished bricks the most according to claim 1, it is characterised in that: described somehow agglomerate (2) former Material weight portion consists of: albite 43 ~ 44 parts, potassium feldspar 18 ~ 19 parts, ball clay 24 ~ 26 parts, 4 ~ 5 parts of high alumina stone, Talcum 3 Part.
A kind of crystallite ink-jet polished bricks the most according to claim 1, it is characterised in that: the weight portion group of described ink slurry Become: albite 28 ~ 30 parts, potassium feldspar 29 ~ 31 parts, ball clay 15 parts, 10 parts of high alumina stone, pyrophillite 10 parts, 5 parts of Talcum.
CN201610572026.2A 2016-07-20 2016-07-20 A kind of crystallite ink-jet polished bricks Active CN106220154B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107200554A (en) * 2017-07-20 2017-09-26 淄博新博陶瓷有限公司 A kind of preparation technology of antifouling sheen Dali stone ceramic tile

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159497A (en) * 2011-12-09 2013-06-19 辽宁金地阳陶瓷有限公司 Jinyongdong stone polished tile and production method for same
CN104944923A (en) * 2015-06-23 2015-09-30 淄博成畅建筑陶瓷有限公司 Polished tile and making method thereof
CN105328782A (en) * 2015-10-22 2016-02-17 广东宏陶陶瓷有限公司 Ceramic polished brick and production method and production line of ceramic polished brick

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103159497A (en) * 2011-12-09 2013-06-19 辽宁金地阳陶瓷有限公司 Jinyongdong stone polished tile and production method for same
CN104944923A (en) * 2015-06-23 2015-09-30 淄博成畅建筑陶瓷有限公司 Polished tile and making method thereof
CN105328782A (en) * 2015-10-22 2016-02-17 广东宏陶陶瓷有限公司 Ceramic polished brick and production method and production line of ceramic polished brick

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107200554A (en) * 2017-07-20 2017-09-26 淄博新博陶瓷有限公司 A kind of preparation technology of antifouling sheen Dali stone ceramic tile

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