CN103497007B - A kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof - Google Patents

A kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof Download PDF

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Publication number
CN103497007B
CN103497007B CN201310426303.5A CN201310426303A CN103497007B CN 103497007 B CN103497007 B CN 103497007B CN 201310426303 A CN201310426303 A CN 201310426303A CN 103497007 B CN103497007 B CN 103497007B
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shimmering powder
glaze
layer
ceramic tile
adobe
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CN103497007A (en
Inventor
刘春梅
宫成伟
黄胜群
何钻华
林典桥
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Guangdong May rose Ceramic Co., Ltd.
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Foshan City Cabbage Pottery Co Ltd
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Abstract

With a ceramic tile for dispersal type shimmering powder, comprise ceramic adobe, color glaze layer, shimmering powder layer and clear frit layer; Described color glaze layer comprises following composition according to mass percent: screen printing glaze, glaze stain, kaolin, methylcellulose gum and tripoly phosphate sodium STPP; Described shimmering powder layer comprises following composition according to mass percent: sheet mica, oiliness stamp-pad ink and described screen printing glaze.Step is followed successively by and makes flower net, allocate color glaze, allocate shimmering powder, push away red ink paste used for seals glaze and shimmering powder, push away and print frit particle, fire and sanding and polishing.Ceramic tile, material is hard, durable attractive in appearance, and the shimmering powder based on sheet mica is suspended in clear frit, and shimmering powder present to a certain degree naturally disperse; Manufacture method simple and fast of the present invention, when not needing to make very large change to existing equipment, still can large batch of mechanization production, operation is very simple, and the ceramic tile for different designs style all can flexible transformation be produced.

Description

A kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof
Technical field
The present invention relates to ceramic fabrication technique field, particularly relate to a kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof.
Background technology
Pottery is the general name of pottery and porcelain, very large in the ceramic demand of China, and the display of the statistic data of Chinese pottery industry, China's architectural pottery output not only accounts for the half of the country of Gross World Product, and grows at top speed with the speed of average annual 16%.But, along with the progress of society and the raising of people's quality of life, people not only rest on the effect of common building materials for the requirement of ceramic tile, also require that it is attractive in appearance, lines Natural, with it, owner are seemed the makings such as noble, generous and higher-grade.
In order to make ceramic tile surface show shimmering powder pattern with default texture, researchist, through research and development for many years and popularization, has invented pottery three degree of firing techniques.Three degree of burnings refer to silk screen printing (red ink paste used for seals, bronze printing, print flash glaze etc.), squeeze the various skill and technique such as glaze, massed glaze and carry out decorating interior wall brick finished product, then through the internal wall brick with certain artistic style that lesser temps (700 ~ 950 DEG C) burns till.Three degree are burnt product major part decoration in toilet and kitchen, after the waist bricks that the internal wall brick wall making color more single is furnished with three degree of different style burnings and ornamental slab for paving the floor, more harmonious with the environment such as sanitary equipment, kitchen range, kitchen tools, ground, curtain, have more artistic appeal.Three degree are burnt the thing that product has become house top grade decoration indispensable some gold.But the shimmering powder effect that this technique is produced only can be used in ceramic tile frit layer surface, through easy fired, and is attached to ceramic tile surface.This easy fired technique, process materials and ceramic tile frit layer cannot merge very well, therefore in use easily soil pick-up, easily peel off by collision, even its shimmering powder feels and also slightly stings sense, and the equal case of the pattern of the shimmering powder of finished product designs distribution in advance, pattern seems inflexible unnatural.
Summary of the invention
The object of the invention is to avoid weak point of the prior art and a kind of ceramic tile with dispersal type shimmering powder provided; shimmering powder pattern mixture is placed under the hard and thoroughly clear frit crystal layer protection of ceramic tile surface, and shimmering powder presents dispersion naturally to a certain degree.Ceramic tile of the present invention is durable wear-resistant elegant in appearance not only, and shimmering powder pattern natural beauty.
Another object of the present invention is to provide a kind of manufacture method of the ceramic tile with dispersal type shimmering powder, and operation is simple, and handiness is strong, and the ceramic tile for different designs style all can flexible transformation be produced.
For achieving the above object, provide following technical scheme.
With a ceramic tile for dispersal type shimmering powder, comprise ceramic adobe, also comprise color glaze layer, shimmering powder layer and clear frit layer; Be followed successively by described clear frit layer, shimmering powder layer, color glaze layer and ceramic adobe from top to bottom;
Described color glaze layer comprises following composition according to mass percent: screen printing glaze 78%-93%, glaze stain 3%-6%, kaolin 0%-10%, methylcellulose gum 0%-3% and tripoly phosphate sodium STPP 0%-3%;
Described shimmering powder layer comprises following composition according to mass percent: sheet mica 3%-15%, clear frit dry granular 30%-50% and described screen printing glaze 20%-50%.
The water-intake rate of described ceramic adobe lower than 3%, the length of described ceramic adobe and the wide length than finished product and wide all many 18mm-20mm.
Described sheet mica was the blanking after 40-60 mesh sieve.
Described clear frit layer thickness is 2.5mm, and described clear frit layer is that clear frit dry granular is fired and formed.
Described ceramic adobe is whiteware adobe; Described sheet mica be white, black and yellow one or more.
With a manufacture method for the ceramic tile of dispersal type shimmering powder, step comprises:
A. make flower net, need by the color of design, produce the colored net of respective color layout;
B. in proportion the composition of described color glaze layer is mixed, and allocate different described glaze stains by the different colours of design, after ball mill grinding, make color glaze;
C. in proportion the composition of described shimmering powder layer is mixed, make shimmering powder;
D. according to the corresponding relation of described colored net and described color glaze layer, in order the pattern that will show is printed on described ceramic batch from level to level with described color glaze, makes color glaze adobe;
E. 30-60 object screen cloth is used to make the silk screen with preset area pattern;
F. described shimmering powder is pushed away by described silk screen and be imprinted in described color glaze adobe, make the adobe of shimmering powder color glaze;
G. being pushed away by 30-60 object screen cloth by described clear frit dry granular is imprinted in the adobe of described shimmering powder color glaze;
H. fire and polishing.
In step b, after described color glaze ball milling, 200 mesh sieves were needed to take off material.
Described small area pattern in step e is dot pattern and/or line image.
The width of described line image is 1-3mm.
In step h firing temperature be 950 DEG C.
The ceramic tile with dispersal type shimmering powder that the present invention obtains, material is hard, durable attractive in appearance, and the shimmering powder based on sheet mica is suspended in clear frit, and shimmering powder presents dispersion naturally to a certain degree; Finished product not only smooth surface is noble, natural beauty, and hard wear resistant.
The manufacture method simple and fast of the ceramic tile with dispersal type shimmering powder of the present invention, when not needing to make very large change to existing equipment, still can large batch of mechanization production, operation is very simple, and the ceramic tile for different designs style all can flexible transformation be produced.
Embodiment
Embodiment 1
The present embodiment is the white shimmering powder pottery of a kind of dark fund glaze, and it comprises:
Be followed successively by from top to bottom described clear frit layer, shimmering powder layer, color glaze layer and water-intake rate lower than 3% whiteware adobe; Wherein color glaze layer comprises the color glaze of black and golden two kinds of colors; Its formula following (mass ratio):
Black color glaze is: the glaze stain 6% of screen printing glaze 78%, black, kaolin 10%, methylcellulose gum 3% and tripoly phosphate sodium STPP 3%;
Golden color glaze is: screen printing glaze 93%, golden glaze stain 3%, methylcellulose gum 3% and tripoly phosphate sodium STPP 1%;
Shimmering powder layer is: take off the white mica sheet 15% of material, clear frit dry granular 50% and described screen printing glaze 35% after crossing 60 mesh sieves.;
Clear frit layer is: clear frit dry granular.
Manufacture method is as follows:
A. press the black of ceramic tile design and golden distribution needs, produce the colored net of respective color layout.
B. in proportion the composition of described color glaze layer is mixed, and allocate different described glaze stains by design black with golden, after ball mill grinding, cross 200 mesh sieves and take off material, make black color glaze and golden color glaze;
C. in proportion the composition of described shimmering powder layer is mixed, make shimmering powder;
D. according to the corresponding relation of described colored net and described color glaze layer, in order the pattern that will show is printed on described ceramic batch from level to level with described color glaze, makes with black and golden color glaze adobe;
E. use 60 object screen cloths to make the silk screen with small area pattern (as dot pattern and/or line image), the width of line image is 1-3mm;
F. described shimmering powder is pushed away by the silk screen in step e and be imprinted in described color glaze adobe, make the adobe of shimmering powder color glaze;
G. being pushed away by 60 object screen cloths by described clear frit dry granular is imprinted in the adobe of described shimmering powder color glaze;
H. the kiln being 950 DEG C through firing temperature is fired, and carries out surface finish after firing.
Described clear frit layer thickness is 2.5mm, and this thickness not only can ensure that clear frit layer can protect shimmering powder layer under it and frit is thoroughly clear.
Sheet mica is made up of phengite, quartz, garnet and rutile etc., has the thermal resistance function having insulation and low loss, or good black matrix.Natural mica sheet is sheet mica through stripping point, fixed thick, cutting, drills or punching forms, have the mica part of certain thickness, definite shape, this product is applicable to televisor, power capacitor, thermo-relay, monitor scope, space flight, aviation, communication, radar, heat-resisting matrix tablet etc. as raw and auxiliary material.Although sheet mica has purposes widely, be used as finishing material or fewer, sheet mica is used for the new try of architectural pottery field application.
Because sheet mica various colors is various, bright in color, can make the sheet mica collocation of different colours use according to the needs of no shimmering powder, the colour-change of shimmering powder is enriched, wherein have employed the sheet mica of white in the present embodiment, contrast black and golden color glaze layer, seem noble generous; And sheet mica is more high temperature resistant, select the sheet mica without color can present the shimmering powder effect of different colours.
Be mixed with screen printing glaze in shimmering powder layer, the sheet mica of solid powdery can be made to become milkiness aqueous, be conducive to printing application.
The kaolin added in color glaze, methylcellulose gum and tripoly phosphate sodium STPP, wherein methylcellulose gum is toughener, methylcellulose gum outward appearance is white or off-white color is fibrous or granulated powders, the aqueous solution is quite stable at normal temperatures, energy gel during high temperature, and this gel can change mutually with solution with the height of temperature, there is excellent wettability, dispersed, cementability, thickening property, emulsifying property, water-retentivity and film-forming properties, and the opacity to grease, methylcellulose gum makes described color glaze become thickness, can the significantly adhesive capacity of described color glaze and heat-drawn wire, tripoly phosphate sodium STPP is dispersion agent, and tripoly phosphate sodium STPP is soluble in water, and its aqueous solution, in alkalescence, for preventing sedimentation and the cohesion of solid particulate in described color glaze, makes it form the stable color glaze suspended.Kaolin has that whiteness is high, matter is soft, easy dispersion suspension in water, good plasticity-and high cohesiveness, make solution become thickness.
Clear frit dry granular is with the addition of in shimmering powder, due to low compared with sheet mica of the fusing point of clear frit dry granular, so when firing, sheet mica has been dissolved in the clear frit dry granular that mixes, and scatter along with its certain mobility, make the distribution natural beauty more of the sheet mica of finished product.
Water-intake rate affects by the composition of raw materials of adobe itself, the press tonnage of pressed compact, sintering process usually, and the adobe that water-intake rate is lower, adobe density is higher, and quality is usually also better.Water-intake rate, lower than 3%, has belonged to the higher standard of Shi porcelain, can ensure that the present invention is stable for the production of practice.
When firing, because the fusing point of clear frit dry granular is lower, and sheet mica is more high temperature resistant, so the sheet mica part in shimmering powder is fused to color glaze layer, a part merges in clear frit layer, and some is fused in the clear frit dry granular in shimmering powder, and the effect that sheet mica is showed is three-dimensional be suspended in ceramic tile surface, because of the light refraction of sheet mica, the formation of reflection characteristic, thus greatly improve the ornamental, ornamental of ceramic tile; Owing to being provided with clear frit layer, make shimmering powder layer obtain protection, and ceramic tile surface seem smooth top grade.
Embodiment 2
The present embodiment is a kind of yellowish-white glaze dark fund shimmering powder pottery, and it comprises:
Be followed successively by described clear frit layer, shimmering powder layer, color glaze layer and whiteware adobe from top to bottom; Wherein color glaze layer comprises color glaze that is yellow and white two kinds of colors; Its formula following (mass ratio):
Yellow color glaze is: screen printing glaze 86%, yellow glaze stain 4%, kaolin 10%;
White color glaze is: screen printing glaze 87%, white glaze stain 5%, kaolin 5%, methylcellulose gum 1.5% and tripoly phosphate sodium STPP 1.5%;
Shimmering powder layer is: cross the black that takes off material after 40 mesh sieves and yellow sheet mica totally 15%, clear frit dry granular 35% and described screen printing glaze 50%;
Clear frit layer is: clear frit dry granular.
Manufacture method is as follows:
A. press yellow and the white distribution needs of ceramic tile design, produce the colored net of respective color layout.
B. in proportion the composition of described color glaze layer is mixed, and by the yellow described glaze stain different with white allotment of design, after ball mill grinding, cross 200 mesh sieves and take off material, make yellow color glaze and white color glaze;
C. in proportion the composition of described shimmering powder layer is mixed, make the shimmering powder that black Huang matches;
D. according to the corresponding relation of described colored net and described color glaze layer, in order the pattern that will show is printed on described ceramic batch from level to level with described color glaze, makes with color glaze adobe that is yellow and white;
E. use 30 object screen cloths to make the silk screen with small area pattern (as dot pattern and/or line image), the width of line image is 1-3mm;
F. described shimmering powder is pushed away by the silk screen in step e and be imprinted in described color glaze adobe, make the adobe of shimmering powder color glaze;
G. being pushed away by 30 object screen cloths by described clear frit dry granular is imprinted in the adobe of described shimmering powder color glaze;
H. the kiln being 950 DEG C through firing temperature is fired, and carries out surface finish after firing.
The shimmering powder of the present embodiment, due under the effect that yellow sheet mica reflects in illumination, shows golden gloss, then is equipped with the phase contrast of black sheet mica, and color seems elegant.
Embodiment 3
The present embodiment is a kind of yellowish-brown glaze dark fund shimmering powder pottery, and it comprises:
Be followed successively by described clear frit layer, shimmering powder layer, color glaze layer and whiteware adobe from top to bottom; Wherein color glaze layer comprises color glaze that is yellow and brown two kinds of colors; Its formula following (mass ratio):
Yellow color glaze is: screen printing glaze 86%, yellow glaze stain 4%, kaolin 10%;
Brown color glaze is: screen printing glaze 80%, brown glaze stain 6%, kaolin 10%, methylcellulose gum 2% and tripoly phosphate sodium STPP 2%;
Shimmering powder layer is: cross the black that takes off material after 50 mesh sieves and yellow sheet mica totally 3%, clear frit dry granular 50% and described screen printing glaze 47%;
Clear frit layer is: clear frit dry granular.
Manufacture method is as follows:
A. press the yellow of ceramic tile design and brown distribution needs, produce the colored net of respective color layout.
B. in proportion the composition of described color glaze layer is mixed, and by the yellow described glaze stain different with brown allotment of design, after ball mill grinding, cross 200 mesh sieves and take off material, make yellow color glaze and brown color glaze;
C. in proportion the composition of described shimmering powder layer is mixed, make the shimmering powder that black Huang matches;
D. according to the corresponding relation of described colored net and described color glaze layer, in order the pattern that will show is printed on described ceramic batch from level to level with described color glaze, makes with yellow and brown color glaze adobe;
E. use 45 object screen cloths to make the silk screen with small area pattern (as dot pattern and/or line image), the width of line image is 1-3mm;
F. described shimmering powder is pushed away by the silk screen in step e and be imprinted in described color glaze adobe, make the adobe of shimmering powder color glaze;
G. being pushed away by 45 object screen cloths by described clear frit dry granular is imprinted in the adobe of described shimmering powder color glaze;
H. the kiln being 950 DEG C through firing temperature is fired, and carries out surface finish after firing.
The shimmering powder of the present embodiment, due under the effect that yellow sheet mica reflects in illumination, shows flavous gloss, then is equipped with the phase contrast of black sheet mica, and color seems elegant.
Finally should be noted that; above embodiment is only for illustration of technical scheme of the present invention but not limiting the scope of the invention; although be explained in detail the present invention with reference to preferred embodiment; those of ordinary skill in the art is to be understood that; can modify to technical scheme of the present invention or equivalent replacement, and not depart from essence and the scope of technical solution of the present invention.

Claims (9)

1. with a ceramic tile for dispersal type shimmering powder, comprise ceramic adobe, it is characterized in that: also comprise color glaze layer, shimmering powder layer and clear frit layer; Be followed successively by described clear frit layer, shimmering powder layer, color glaze layer and ceramic adobe from top to bottom;
Described color glaze layer comprises following composition according to mass percent: screen printing glaze 78%-93%, glaze stain 3%-6%, kaolin 0%-10%, methylcellulose gum 0%-3% and tripoly phosphate sodium STPP 0%-3%;
Described shimmering powder layer comprises following composition according to mass percent: sheet mica 3%-15%, clear frit dry granular 30%-50% and described screen printing glaze 20%-50%;
Manufacture method, step comprises:
A. make flower net, need by the color of design, produce the colored net of respective color layout;
B. in proportion the composition of described color glaze layer is mixed, and allocate different described glaze stains by the different colours of design, after ball mill grinding, make color glaze;
C. in proportion the composition of described shimmering powder layer is mixed, make shimmering powder;
D. according to the corresponding relation of described colored net and described color glaze layer, in order the pattern that will show is printed on described ceramic batch from level to level with described color glaze, makes color glaze adobe;
E. 30-60 object screen cloth is used to make the silk screen with preset area pattern;
F. described shimmering powder is pushed away by described silk screen and be imprinted in described color glaze adobe, make the adobe of shimmering powder color glaze;
G. being pushed away by 30-60 object screen cloth by described clear frit dry granular is imprinted in the adobe of described shimmering powder color glaze;
H. fire and polishing.
2. the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: the water-intake rate of described ceramic adobe lower than 3%, the length of described ceramic adobe and the wide length than finished product and wide all many 18mm-20mm.
3. the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: described sheet mica was the blanking after 40-60 mesh sieve.
4. the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: described clear frit layer thickness is 2.5mm, and described clear frit layer is that clear frit dry granular is fired and formed.
5. the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: described ceramic adobe is whiteware adobe; Described sheet mica be white, black and yellow one or more.
6. the manufacture method of the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: in step b, needs 200 mesh sieves to take off material after described color glaze ball milling.
7. the manufacture method of the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: be provided with small area pattern in step e, described small area pattern is dot pattern and/or line image.
8. the manufacture method of the ceramic tile with dispersal type shimmering powder according to claim 7, is characterized in that: the width of described line image is 1-3mm.
9. the manufacture method of the ceramic tile with dispersal type shimmering powder according to claim 1, is characterized in that: in step h firing temperature be 950 DEG C.
CN201310426303.5A 2013-09-17 2013-09-17 A kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof Active CN103497007B (en)

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CN106396396A (en) * 2016-08-31 2017-02-15 广东金意陶陶瓷有限公司 Color-increasing colored glaze suitable for complementing colors in silk screen printing and ceramic tiles prepared by color-increasing colored glaze
CN106746651B (en) * 2017-01-16 2019-04-30 佛山市道氏科技有限公司 A kind of dry granular glaze with diamond luster effect
CN107778031B (en) * 2017-09-28 2020-12-11 禹州市正玉钧窑有限公司 Glazing method of Jun porcelain glaze
CN108911510A (en) * 2018-09-05 2018-11-30 安徽磐盛新型材料科技有限公司 A kind of the effect glaze and its application method of architectural pottery incrustation
CN110092671A (en) * 2019-05-17 2019-08-06 江西和美陶瓷有限公司 Glazed tile and preparation method with fluorescence gloss

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CN1587144A (en) * 2004-09-15 2005-03-02 黄永平 Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp
CN102653476A (en) * 2012-04-17 2012-09-05 陈满坚 Three-dimensional hierarchical glazed ceramic brick and method for preparing same

Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
CN1587144A (en) * 2004-09-15 2005-03-02 黄永平 Glaze pulp for processing glazed tile and its producing glaze pulp and method for processing glazed tile using glaze pulp
CN102653476A (en) * 2012-04-17 2012-09-05 陈满坚 Three-dimensional hierarchical glazed ceramic brick and method for preparing same

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Address after: 528000 No. 7, Tao Bei Road, Huaxia Ceramic Expo City, Nanzhuang Town, Chancheng District, Foshan, Guangdong, China. 2

Patentee after: Guangdong May rose Ceramic Co., Ltd.

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Patentee before: Foshan City cabbage pottery company limited

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