CN102503386A - Production process of 3D (three-dimensional) digital inkjet ceramic tile - Google Patents

Production process of 3D (three-dimensional) digital inkjet ceramic tile Download PDF

Info

Publication number
CN102503386A
CN102503386A CN2011103427683A CN201110342768A CN102503386A CN 102503386 A CN102503386 A CN 102503386A CN 2011103427683 A CN2011103427683 A CN 2011103427683A CN 201110342768 A CN201110342768 A CN 201110342768A CN 102503386 A CN102503386 A CN 102503386A
Authority
CN
China
Prior art keywords
component
parts
glaze
ceramic tile
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN2011103427683A
Other languages
Chinese (zh)
Other versions
CN102503386B (en
Inventor
王火生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINZHONGYUAN CERAMICS CO Ltd GUANGDONG
Original Assignee
XINZHONGYUAN CERAMICS CO Ltd GUANGDONG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINZHONGYUAN CERAMICS CO Ltd GUANGDONG filed Critical XINZHONGYUAN CERAMICS CO Ltd GUANGDONG
Priority to CN201110342768.3A priority Critical patent/CN102503386B/en
Publication of CN102503386A publication Critical patent/CN102503386A/en
Application granted granted Critical
Publication of CN102503386B publication Critical patent/CN102503386B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Abstract

The invention discloses a production process of a 3D (three-dimensional) digital inkjet ceramic tile. The process comprises the following steps of: (1) preparing a blank, overglaze and fancy glaze; (2) molding the blank in a mold tile to form a blank tile, wherein the blank molding pressure is 2,800-3,400 MPa/cm<2>; (3) sintering and drying the molded blank tile at the sintering temperature of 1,150-1,800 DEG C; (4) sprinkling glaze onto a dry blank, wherein the flowability of glaze slip is 30S/100M1-40S/100M1, the fluctuation is 0S-5S, the specific weight of the glaze slip is 175-190 g/cm<2>, and glaze amount is 0.05-0.15 g/cm<2>; (5) performing inkjet printing, wherein an inkjet printing speed is matched with the rotating speed of a tile feeding belt, and is set as 20-25 m/min; (6) feeding into a kiln for baking at the baking temperature of 1,080-1,125 DEG C; and (7) edging. Due to the adoption of the production process of the 3D digital inkjet ceramic tile, a produced product has high definition, stereo perception and a good mirror face effect, can contribute to making the cleanliness and brightness of an entire space stand out, and has the characteristics of durability, slip prevention, dust prevention, easiness in cleaning, and the like.

Description

A kind of production technique of 3D digital ink-jet ceramic tile
Technical field
The present invention relates to the architectural pottery field, relate in particular to a kind of production technique of 3D digital ink-jet ceramic tile.
Background technology
Along with nation-building conservation-minded society, walk the megatrend of the road of Sustainable development; Under the overall background of ceramic industry industry transfer, ceramic production technology is gone on less energy-consumption, high is concentrated, robotization, technology is simple and clear, product is remarkably productive road become a kind of inevitable.
Along with development, the growth in the living standard of society, people are also increasingly high to the requirement of various home decorations.At first, along with country advocates the propaganda support of environmental protection, people hope to use environmentfriendly products to finishing material also more and more environmental protection, reduce the pollution to nature, and unordered exploitation is demanded, and reduces current pollution level.Secondly, along with development of science and technology, the developing of outlook, people are also increasingly high to the effect of decorating, and do not satisfied the effect that current silk screen and roll printing bring.Part human consumer requires that its textured pattern is more clear, resolving power is higher, naturalness is stronger, and the arbitrary color texture of reduction nature true to nature is unlimited true, is like nature itself.At last, part top-grade consumption person, even can come short run to customize self-designed pattern texture according to the demand of oneself.Therefore, the product of its production of most ceramic enterprise all begins to develop to the new demand of consumption, dominates the market, and makes the aspects such as sharpness, naturalness, gradation sense, environmental protection of its product reach the requirement in market.
The development of inkjet technology divides two stages.Fs is 2000-2006, and ink-jet system has only the solubility ink.In this stage because the low Color Range of employed solubility ink, poor stability and cost are high, big limitations the product various possibilities that can realize, restricted development.Subordinate phase, along with the technical progress of paint ink, qualitative leap has taken place in ink-jet system.Use these paint inks, the conventional color of ink-jet print system on almost can the printing market, and also price is also competitive.The leap of this technology influence even can expand landscape design to, and driven that more new installation producer comes into the market and Production of Ceramics enterprise pours in this field.
But at present, jetting ink has only four looks, and the part color still can't realize, and because of ink is an oiliness, so bring certain difficulty for the upgrading of subsequent product.
Summary of the invention
Technical problem to be solved by this invention is the deficiency that remedies prior art; Purpose is to provide a kind of production technique of 3D digital ink-jet ceramic tile; The product of its production has sharpness, stereoscopic sensation and graceful mirror effect; Can give prominence to the clean and tidy and beautiful of overall space, have characteristics such as durable, anti-skidding, dustproof, easy cleaning again.
For solving above technical problem, technical scheme of the present invention is a kind of production technique of 3D digital ink-jet ceramic tile, comprises the steps:
(1) preparation blank, cover-coat enamel and fancy glaze, wherein,
Said blank comprises following component: SiO2:57.97%-67.97%; Al2O3:11.61%-21.61%; CaO:4.0%-10.0%; MgO:0.12%-0.24%; K2O:1.8%-2.8%; Na2O:0.25%-0.45%; Fe2O3:0.25%-0.45%; Igloss: 5.64%-11.64%; Above component is weight percentage;
Said cover-coat enamel comprises following component: M01:60-80 part; M107:20-40 part; Methyl: 0.03-0.08 part; Trimerization: 0.15-0.35 part water: 50-70 part; Above component by weight;
Said cover-coat enamel comprises following component: 11# frit: 9-15; 18# frit: 15-25 part; Air knife soil: 8-12 part; Calcined kaolin: 15-21 part; Zirconium silicate: 8-12 part; Aluminum oxide: 25-35 part; Methyl: 0.2-0.4 part; Trimerization: 0.03-0.07 part; Water: 25-45 part; Above component by weight;
(2) blank moulding in the mould brick forms the base brick, and the pressure of blank moulding is 2800Mpa/cm 2-3400Mpa/cm 2
(3) the base brick sintering after the moulding is dry, and sintering temperature is 1150 ℃-1800 ℃;
(4) dry body drenches glaze, and the flowability of glaze slip is 30S/100M1-40S/100M1, fluctuates to be that 0S-5S, glaze slip proportion are 175g/cm 2-190g/cm 2, the glaze amount is 0.05g/cm 2-0.15g/cm 2
(5) spray ink Printing, spray ink Printing speed with send the rotating speed of brick belt to be complementary, be set to 20m/min-25m/min;
(6) go into klining, firing temperature is 1080 ℃-1125 ℃;
(7) edging.
More excellent ground, said blank comprises following component:
SiO2:62.97%;
Al2O3:16.61%;
CaO:7.0%;
MgO:0.18%;
K2O:2.3%;
Na2O:0.35%;
Fe2O3:0.35%;
Igloss: 8.64%; Above component is weight percentage.
More excellent ground, said M01 comprises following component: SiO2:40-50 part; Fe2O3:5-7 part; MnO2:6-8 part; Al2O3; 8-12 part; CaO:.08-1.2 part; PO5:6-10 part; NiO:2-4 part; CuO:3-5 part; Na2O:5-7 part; ZrO2:5-7 part; BaO2:0.8-1.2 part; Above component by weight;
More excellent ground, said M01 comprises following component: SiO2:45 part; Fe2O3:6 part; MnO2:7 part; Al2O3; 10 parts; CaO:1.0 part; PO5:8 part; NiO:3 part; CuO:4 part; Na2O:6 part; ZrO2:6 part; BaO2:1 part; Above component by weight.
More excellent ground, said M07 comprises following component: SiO2:44-54 part; Fe2O3:5.5-9.5 part; MnO2:4-6 part; Al2O3; 10-18 part; CaO:1.5-2.5 part; PO5:4-6 part; NiO:1-3 part; CuO:1-3 part; Na2O:4-6 part; ZrO2:2-4 part; BaO2:0.8-1.2 part; Above component by weight.
More excellent ground, said M07 comprises following component: SiO2:49 part; Fe2O3:7.5 part; MnO2:5 part; Al2O3; 14 parts; CaO:2.5 part; PO5:5 part; NiO:2 part; CuO:2 part; Na2O:5 part; ZrO2:3 part; BaO2:1 part; Above component by weight.
More excellent ground, said fancy glaze comprises following component:
11# frit: 20; 18# frit: 40 parts; Air knife soil: 10 parts; Calcined kaolin: 5 parts; Zirconium silicate: 10 parts; Aluminum oxide: 5 parts; Methyl: 0.3 part; Trimerization: 0.05 part; Water: 35 parts; Above component by weight.
More excellent ground, the component of said 11# frit is: 45~56 parts of SiO2,7~13 parts of Al2O3,7~12 parts of CaO; 0.8~8 part of MgO, 0~6 part of BaO, 0~4 part of SrO, 9~17 parts of ZnO; 3~5 parts of K2O, 0.6~3.1 part of Na2O, 0~1.5 part of Li2O; 2~8 parts of B2O3,0~4 part of ZrO2, above component is by weight.
More excellent ground; The component of said 18# frit is: 58.0~66.0 parts of SiO2,10.0~15.0 parts of Al2O3,0~1.0 part of TiO2,0.5~2.0 part of CaO, 0~1.0 part of MgO, 2.0~6.0 parts of K2O; 2.0~6.0 parts of Na2O, 2.0~6.0 parts of Li2O, 1.5~2.5 parts of B2O3, above component by weight.
Compared with prior art; The production technique of 3D digital ink-jet ceramic tile provided by the invention; The product of its production has sharpness, stereoscopic sensation and graceful mirror effect, can give prominence to the clean and tidy and beautiful of overall space, has characteristics such as durable, anti-skidding, dustproof, easy cleaning again.
Embodiment
For those skilled in the art can understand technical scheme provided by the present invention better, set forth below in conjunction with specific embodiment.
The production technique of 3D digital ink-jet ceramic tile provided by the invention comprises the steps:
(1) preparation blank, cover-coat enamel and fancy glaze;
(2) blank moulding in the mould brick forms the base brick, and the pressure of blank moulding is 2800Mpa/cm 2-3400Mpa/cm 2
(3) the base brick sintering after the moulding is dry, and sintering temperature is 1150 ℃-1800 ℃;
(4) dry body drenches glaze, and the flowability of glaze slip is 30S/100M1-40S/100M1, fluctuates to be that 0S-5S, glaze slip proportion are 175g/cm 2-190g/cm 2, the glaze amount is 0.05g/cm 2-0.15g/cm 2
(5) spray ink Printing, spray ink Printing speed with send the rotating speed of brick belt to be complementary, be set to 20m/min-25m/min;
(6) go into klining, firing temperature is 1080 ℃-1125 ℃;
(7) edging.
Blank comprises following component: SiO2:62.97%; Al2O3:16.61%; CaO:7.0%; MgO:0.18%; K2O:2.3%; Na2O:0.35%; Fe2O3:0.35%; Igloss: 8.64%; Above component is weight percentage.
Cover-coat enamel comprises following component: M01:70 part; M107:30 part; Methyl: 0.05 part; Trimerization: 0.25 part of water: 60 parts; Above component by weight;
M01 comprises following component: SiO2:45 part; Fe2O3:6 part; MnO2:7 part; Al2O3; 10 parts; CaO:1.0 part; PO5:8 part; NiO:3 part; CuO:4 part; Na2O:6 part; ZrO2:6 part; BaO2:1 part; Above component by weight.
M07 comprises following component: SiO2:49 part; Fe2O3:7.5 part; MnO2:5 part; Al2O3; 14 parts; CaO:2.5 part; PO5:5 part; NiO:2 part; CuO:2 part; Na2O:5 part; ZrO2:3 part; BaO2:1 part; Above component by weight.
Cover-coat enamel comprises following component: 11# frit: 20; 18# frit: 40 parts; Air knife soil: 10 parts; Calcined kaolin: 5 parts; Zirconium silicate: 10 parts; Aluminum oxide: 5 parts; Methyl: 0.3 part; Trimerization: 0.05 part; Water: 35 parts; Above component by weight.The component of 11# frit is: 50 parts of SiO2, and 10 parts of Al2O3,9 parts of CaO, 5 parts of MgO, 3 parts of BaO, 2 parts of SrO, 13 parts of ZnO, 4 parts of K2O, Na2O2 part, 1 part of Li2O, 5 parts of B2O3,2 parts of ZrO2, above component is by weight.The component of 18# frit is: 63.5 parts of SiO2,12 parts of Al2O3,0.5 part of TiO2,1.5 parts of CaO, 0.5 part of MgO, 4 parts of K2O, and 4 parts of Na2O, 4 parts of Li2O, 20 parts of B2O3, above component is by weight.
The ink that is used for 3D digital ink-jet ceramic tile comprises colorant, AEO, propyl carbinol, octane, ammoniacal liquor and solids, and wherein components contents is:
Colorant: blue (Co-Al-Zn) 6wt%-15wt%;
Red (Fe-Cr-Zn) 8wt%-18wt%;
Yellow (Zr-Si-Pr) 13wt%-35wt%
Pink (Zr-Fe-Si) 15wt%-40wt%;
AEO 12wt%-17wt%;
Propyl carbinol 0.5wt%-5wt%;
Octane 25wt%-35wt%;
Ammoniacal liquor 15wt%-25wt%;
Solids 1wt%-4wt%.
The ink that is used for 3D digital ink-jet ceramic tile also comprises additive 1, the 2-Ucar 35, and said content of additive is: 2wt%-5wt%.
The ink that is used for 3D digital ink-jet ceramic tile also comprises dispersion agent, and the content of said dispersion agent is: 1wt%-3wt%, said dispersion agent are phenylformic acid.
The ink that is used for 3D digital ink-jet ceramic tile also comprises dispersion agent, and the content of said dispersion agent is: 2wt%-4wt%, said dispersion agent are resin.
The production technique of 3D digital ink-jet ceramic tile provided by the invention is innovated aspect following two:
1, strengthened the ratio of plastic material and add and put into softening agent, guaranteed that overglaze is wetting.Aborning because glaze plays powder easily, cause ink attach power excessively a little less than, make the ink color development shallow excessively, it is relatively poor to burn till the pattern effect sharpness, the pink colour color development is not good enough, the glaze surface evenness is general.Comprehensive each side factor research has found that the major cause of powder and the water-intake rate of base substrate have substantial connection, needs the present formula adjustment to base substrate.In blank raw material, add the softening agent Sodium salts humic acids, Sodium salts humic acids is joined ceramic base, can improve plasticity-, slip fluidity and the suspension of pug greatly.And can increase green body strength.Increase the sticking power of glaze and the rate of drying of glaze, reduce the cracking of glaze pore and glazed body.Learn that by test repeatedly Sodium salts humic acids addition in blank raw material is generally 1-3 ‰.If additive is excessive, it is slow excessively to cause base substrate to receive water, causes glaze wet excessively, immiscible with water because ink is an oiliness, the stratified segregation phenomenon of ink and glaze can occur.
2, increase the glaze glossiness, improve the color development of ink.Glaze has very big influence to the color development of color, is superior to other conventional bricks in order to make product glaze effect, and the clear and naturalness of outstanding more image is adjusted to the overglaze effect.The content of some composition in the glaze (like Zr, Ba) plays an important role to the color development of pink colour.In cover-coat enamel, because ink is responsive to the Zr in the glaze, Ba reaction, the content that zirconium white melts piece in the cover-coat enamel has very big influence to the color development of ink; Content is very few; Cover-coat enamel be transparence, the ink color development partially secretly, shallow partially, it is relatively poor to burn till the pattern effect sharpness; The pink colour color development is not good enough, and the glaze surface evenness is general.High more according to specific refractory power; Glossiness is good more, and " this principle is added the oxide compound that an amount of BaO, SnO2, ZrO2 etc. have high refractive index in glaze, find through continuous experimental study; the content of ZrO2 is 6.5-7%; the content of BaO is 1% o'clock, significantly improves the glaze glossiness, and the color development of ink is increased significantly.It is high to burn till the pattern effect sharpness, and the color color development is good, glaze whiteness, brightness height.
To the above-mentioned explanation of the disclosed embodiments, make this area professional and technical personnel can realize or use the present invention.Multiple modification to these embodiment will be conspicuous concerning those skilled in the art, and defined General Principle can realize under the situation that does not break away from the spirit or scope of the present invention in other embodiments among this paper.Therefore, the present invention will can not be restricted to these embodiment shown in this paper, but will meet and principle disclosed herein and features of novelty the wideest corresponding to scope.

Claims (9)

1. the production technique of a 3D digital ink-jet ceramic tile is characterized in that, comprises the steps:
(1) preparation blank, cover-coat enamel and fancy glaze, wherein,
Said blank comprises following component: SiO2:57.97%-67.97%; Al2O3:11.61%-21.61%; CaO:4.0%-10.0%; MgO:0.12%-0.24%; K2O:1.8%-2.8%; Na2O:0.25%-0.45%; Fe2O3:0.25%-0.45%; Igloss: 5.64%-11.64%; Above component is weight percentage;
Said cover-coat enamel comprises following component: M01:60-80 part; M107:20-40 part; Methyl: 0.03-0.08 part; Trimerization: 0.15-0.35 part water: 50-70 part; Above component by weight;
Said fancy glaze comprises following component: 11# frit: 9-15; 18# frit: 15-25 part; Air knife soil: 8-12 part; Calcined kaolin: 15-21 part; Zirconium silicate: 8-12 part; Aluminum oxide: 25-35 part; Methyl: 0.2-0.4 part; Trimerization: 0.03-0.07 part; Water: 25-45 part; Above component by weight;
(2) blank moulding in the mould brick forms the base brick, and the pressure of blank moulding is 2800Mpa/cm 2-3400Mpa/cm 2
(3) the base brick sintering after the moulding is dry, and sintering temperature is 1150 ℃-1800 ℃;
(4) dry body drenches glaze, and the flowability of glaze slip is 30S/100M1-40S/100M1, fluctuates to be that 0S-5S, glaze slip proportion are 175g/cm 2-190g/cm 2, the glaze amount is 0.05g/cm 2-0.15g/cm 2
(5) spray ink Printing, spray ink Printing speed with send the rotating speed of brick belt to be complementary, be set to 20m/min-25m/min;
(6) go into klining, firing temperature is 1080 ℃-1125 ℃;
(7) edging.
2. the production technique of 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, said blank comprises following component:
SiO2:62.97%;
Al2O3:16.61%;
CaO:7.0%;
MgO:0.18%;
K2O:2.3%;
Na2O:0.35%;
Fe2O3:0.35%;
Igloss: 8.64%; Above component is weight percentage.
3. the production technique of 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, said M01 comprises following component: SiO2:40-50 part; Fe2O3:5-7 part; MnO2:6-8 part; Al2O3; 8-12 part; CaO:.08-1.2 part; PO5:6-10 part; NiO:2-4 part; CuO:3-5 part; Na2O:5-7 part; ZrO2:5-7 part; BaO2:0.8-1.2 part; Above component by weight;
4. the production technique of 3D digital ink-jet ceramic tile according to claim 3 is characterized in that, said M01 comprises following component: SiO2:45 part; Fe2O3:6 part; MnO2:7 part; Al2O3; 10 parts; CaO:1.0 part; PO5:8 part; NiO:3 part; CuO:4 part; Na2O:6 part; ZrO2:6 part; BaO2:1 part; Above component by weight.
5. the production technique of 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, said M07 comprises following component: SiO2:44-54 part; Fe2O3:5.5-9.5 part; MnO2:4-6 part; Al2O3; 10-18 part; CaO:1.5-2.5 part; PO5:4-6 part; NiO:1-3 part; CuO:1-3 part; Na2O:4-6 part; ZrO2:2-4 part; BaO2:0.8-1.2 part; Above component by weight.
6. the production technique of 3D digital ink-jet ceramic tile according to claim 5 is characterized in that, said M07 comprises following component: SiO2:49 part; Fe2O3:7.5 part; MnO2:5 part; Al2O3; 14 parts; CaO:2.5 part; PO5:5 part; NiO:2 part; CuO:2 part; Na2O:5 part; ZrO2:3 part; BaO2:1 part; Above component by weight.
7. the production technique of 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, said fancy glaze comprises following component:
11# frit: 20; 18# frit: 40 parts; Air knife soil: 10 parts; Calcined kaolin: 5 parts; Zirconium silicate: 10 parts; Aluminum oxide: 5 parts; Methyl: 0.3 part; Trimerization: 0.05 part; Water: 35 parts; Above component by weight.
8. the production technique of 3D digital ink-jet ceramic tile according to claim 1 is characterized in that, the component of said 11# frit is: 45~56 parts of SiO2,7~13 parts of Al2O3; 7~12 parts of CaO, 0.8~8 part of MgO, 0~6 part of BaO, 0~4 part of SrO; 9~17 parts of ZnO, 3~5 parts of K2O, 0.6~3.1 part of Na2O, 0~1.5 part of Li2O; 2~8 parts of B2O3,0~4 part of ZrO2, above component is by weight.
9. the production technique of 3D digital ink-jet ceramic tile according to claim 1; It is characterized in that; The component of said 18# frit is: 58.0~66.0 parts of SiO2,10.0~15.0 parts of Al2O3, TiO20~1.0 part, 0.5~2.0 part of CaO, 0~1.0 part of MgO, 2.0~6.0 parts of K2O; 2.0~6.0 parts of Na2O, 2.0~6.0 parts of Li2O, 1.5~2.5 parts of B2O3, above component by weight.
CN201110342768.3A 2011-11-02 2011-11-02 Production process of 3D (three-dimensional) digital inkjet ceramic tile Expired - Fee Related CN102503386B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201110342768.3A CN102503386B (en) 2011-11-02 2011-11-02 Production process of 3D (three-dimensional) digital inkjet ceramic tile

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201110342768.3A CN102503386B (en) 2011-11-02 2011-11-02 Production process of 3D (three-dimensional) digital inkjet ceramic tile

Publications (2)

Publication Number Publication Date
CN102503386A true CN102503386A (en) 2012-06-20
CN102503386B CN102503386B (en) 2014-05-07

Family

ID=46215537

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201110342768.3A Expired - Fee Related CN102503386B (en) 2011-11-02 2011-11-02 Production process of 3D (three-dimensional) digital inkjet ceramic tile

Country Status (1)

Country Link
CN (1) CN102503386B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103073335A (en) * 2013-01-29 2013-05-01 福建省晋江市舒适陶瓷有限公司 Production method of inkjet ceramic plate for dry-hanging building curtain wall
CN103086750A (en) * 2013-01-09 2013-05-08 佛山市三水新明珠建陶工业有限公司 Method for manufacturing glazed interior wall bricks with two glazed effects
CN103291039A (en) * 2013-05-29 2013-09-11 佛山市芒果建材有限公司 Ceramic tile with three-dimensional visual effect and manufacturing method thereof
CN104193407A (en) * 2014-08-29 2014-12-10 佛山市东鹏陶瓷有限公司 Method for manufacturing unburnt ceramic tile clay
CN104402531A (en) * 2014-10-29 2015-03-11 万利(中国)有限公司 3D glaze material and preparation method thereof
CN104591687A (en) * 2014-12-31 2015-05-06 江西和美陶瓷有限公司 Wide-color-gamut inkjet glaze decorated ceramic floor tile and production process thereof
CN104788126A (en) * 2015-04-14 2015-07-22 岑溪市新鸿基陶瓷有限公司 Ceramic brick production line
CN107235632A (en) * 2017-07-12 2017-10-10 广东协进陶瓷有限公司 Preparation method with the high digital glaze spraying three-dimensional pattern effect function ceramics bricks of emulation 3D
CN110483104A (en) * 2019-09-03 2019-11-22 广东欧文莱陶瓷有限公司 A kind of ceramic tile production compound dry granular and Ceramic Tiles

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993255A (en) * 2010-09-17 2011-03-30 霍镰泉 Process for producing artificial marble ceramic tiles
CN102029643A (en) * 2010-10-26 2011-04-27 霍镰泉 Process for producing ceramic tile with uneven surface

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101993255A (en) * 2010-09-17 2011-03-30 霍镰泉 Process for producing artificial marble ceramic tiles
CN102029643A (en) * 2010-10-26 2011-04-27 霍镰泉 Process for producing ceramic tile with uneven surface

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103086750A (en) * 2013-01-09 2013-05-08 佛山市三水新明珠建陶工业有限公司 Method for manufacturing glazed interior wall bricks with two glazed effects
CN103086750B (en) * 2013-01-09 2014-06-18 佛山市三水新明珠建陶工业有限公司 Method for manufacturing glazed interior wall bricks with two glazed effects
CN103073335B (en) * 2013-01-29 2014-07-30 福建省晋江市舒适陶瓷有限公司 Production method of inkjet ceramic plate for dry-hanging building curtain wall
CN103073335A (en) * 2013-01-29 2013-05-01 福建省晋江市舒适陶瓷有限公司 Production method of inkjet ceramic plate for dry-hanging building curtain wall
CN103291039A (en) * 2013-05-29 2013-09-11 佛山市芒果建材有限公司 Ceramic tile with three-dimensional visual effect and manufacturing method thereof
CN103291039B (en) * 2013-05-29 2015-07-01 佛山市芒果建材有限公司 Ceramic tile with three-dimensional visual effect and manufacturing method thereof
CN104193407A (en) * 2014-08-29 2014-12-10 佛山市东鹏陶瓷有限公司 Method for manufacturing unburnt ceramic tile clay
CN104193407B (en) * 2014-08-29 2016-11-23 佛山市东鹏陶瓷有限公司 A kind of manufacture method of Ceramic Tiles moulded pottery not yet put in a kiln to bake
CN104402531B (en) * 2014-10-29 2016-04-13 万利(中国)有限公司 A kind of 3D glaze and preparation method thereof
CN104402531A (en) * 2014-10-29 2015-03-11 万利(中国)有限公司 3D glaze material and preparation method thereof
CN104591687A (en) * 2014-12-31 2015-05-06 江西和美陶瓷有限公司 Wide-color-gamut inkjet glaze decorated ceramic floor tile and production process thereof
CN104788126A (en) * 2015-04-14 2015-07-22 岑溪市新鸿基陶瓷有限公司 Ceramic brick production line
CN107235632A (en) * 2017-07-12 2017-10-10 广东协进陶瓷有限公司 Preparation method with the high digital glaze spraying three-dimensional pattern effect function ceramics bricks of emulation 3D
CN107235632B (en) * 2017-07-12 2020-05-15 广东协进陶瓷有限公司 Preparation method of ceramic tile with high-simulation 3D digital glaze spraying three-dimensional pattern effect function
CN110483104A (en) * 2019-09-03 2019-11-22 广东欧文莱陶瓷有限公司 A kind of ceramic tile production compound dry granular and Ceramic Tiles

Also Published As

Publication number Publication date
CN102503386B (en) 2014-05-07

Similar Documents

Publication Publication Date Title
CN102503386B (en) Production process of 3D (three-dimensional) digital inkjet ceramic tile
CN100408516C (en) Press formed dry glaze for ceramic tile adobe and its prepn process
CN106986540B (en) Formula for making sunken and peeled marble glaze
CN103833423A (en) Ceramic tile preparation method and product thereof
CN101898887B (en) Semitransparent ceramic material, imitation jadeite ceramic sheet and preparation method thereof
CN107382377B (en) The preparation method of easy clean Ceramic Tiles
CN102731169A (en) Fully glazed ceramic chip and preparation method thereof
CN102557756B (en) Preparation method of stone-pattern-simulating glazed brick
CN102390931A (en) Method for manufacturing once calcined glass ceramic brick
CN104446344B (en) A kind of slim mirror puts down the preparation method of artistic ceramic board pictures and obtained product thereof
CN102653476A (en) Three-dimensional hierarchical glazed ceramic brick and method for preparing same
CN104311162A (en) Bump texture glazed tile and preparation method thereof
CN206069715U (en) A kind of production line of magic glazed tile
CN104405101A (en) Furnace-transmuted archaized brick and production method thereof
CN103497007B (en) A kind of ceramic tile with dispersal type shimmering powder and manufacture method thereof
CN105218170A (en) A kind of high-hardness, wearable exempts from polishing iron microcrystalline glass in series ceramic clad plate and preparation method thereof
CN109265004A (en) Sea blue double-deck reaction glaze and preparation method thereof
CN109384476A (en) A kind of anti-skid wearable negative ion ceramic ceramic tile and preparation method thereof
CN105367131A (en) Ink-jet penetrated polished semitransparent ceramic sheet, and preparation method thereof
CN106396638B (en) Low temperature lightweight lime gradual change glaze ceramics and its manufacture craft
CN107344814A (en) A kind of sheen brick cover-coat enamel and sheen brick
CN202543089U (en) Glazed ceramic tile with stereoscopic and level impressions
CN103693994A (en) Color-changing glaze tile and production method thereof
CN105541112A (en) A super-flat glaze frit and a method of manufacturing super spar from the same
CN105601127A (en) Coloring method of pyroceram

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140507

Termination date: 20161102