CN110483104A - A kind of ceramic tile production compound dry granular and Ceramic Tiles - Google Patents
A kind of ceramic tile production compound dry granular and Ceramic Tiles Download PDFInfo
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- CN110483104A CN110483104A CN201910829309.4A CN201910829309A CN110483104A CN 110483104 A CN110483104 A CN 110483104A CN 201910829309 A CN201910829309 A CN 201910829309A CN 110483104 A CN110483104 A CN 110483104A
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- Prior art keywords
- dry granular
- ceramic tiles
- ceramic
- pattern
- glue
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- 239000000919 ceramic Substances 0.000 title claims abstract description 58
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 37
- 150000001875 compounds Chemical class 0.000 title claims abstract description 26
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 19
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000007921 spray Substances 0.000 claims abstract description 17
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 16
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 16
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 16
- 229910021543 Nickel dioxide Inorganic materials 0.000 claims abstract description 15
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052593 corundum Inorganic materials 0.000 claims abstract description 15
- 229910001845 yogo sapphire Inorganic materials 0.000 claims abstract description 15
- 239000003292 glue Substances 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 12
- 238000005498 polishing Methods 0.000 claims description 12
- 238000007599 discharging Methods 0.000 claims description 9
- 230000009467 reduction Effects 0.000 claims description 9
- 238000001914 filtration Methods 0.000 claims description 7
- 239000000976 ink Substances 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 13
- 238000005034 decoration Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000035807 sensation Effects 0.000 abstract description 4
- 230000035939 shock Effects 0.000 abstract description 4
- 230000006835 compression Effects 0.000 abstract description 2
- 238000007906 compression Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 12
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 239000011449 brick Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 238000013473 artificial intelligence Methods 0.000 description 2
- 230000000712 assembly Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 238000007641 inkjet printing Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003892 spreading Methods 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000004886 head movement Effects 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 238000003909 pattern recognition Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000010020 roller printing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5053—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials non-oxide ceramics
- C04B41/5055—Fluorides
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The present invention relates to ceramic tile production fields, a kind of ceramic tile production compound dry granular and Ceramic Tiles are provided, for improving the quality of ceramic product.A kind of compound dry granular of ceramic tile production provided by the invention, comprising: SiO245 ~ 52%, Al2O313 ~ 15%, Fe2O30.2 ~ 0.5%, TiO20 ~ 0.02%, CaO 12 ~ 15%, MgO 5 ~ 7%, K2O 0.5 ~ 1.5%, Na2O 1 ~ 1.5%, B2O31 ~ 4%, ZrO23 ~ 5%, BaO 1 ~ 5%, F 1 ~ 4%, NiO23~5%.Many effects may be implemented in dry granular, not only have color, also there is surface tactile sensation.The decoration that product is carried out with dry granular is better than spray special inks effect.Have the characteristics that high hardness and corrosion resistance, resistance to compression, shock resistance, is stained with dirt less, is radiationless.
Description
Technical field
The present invention relates to ceramic tile production fields, and in particular to a kind of ceramic tile production compound dry granular and Ceramic Tiles.
Background technique
Currently, dry granular glaze Ceramic Tiles are generally made using single wire mark dry granular technology, single wire mark dry granular technology is lacked there are following
Point: 1) pattern of every brick chromatography, dullness do not change.2) decoration level is not strong.3) usual a kind of color of glaze of dry granular
Pattern is dull.4) contraposition is inaccurate, is easy to walk, dim pattern is unintelligible.
A kind of ink-jet printer of CN201180043049.X, the figure of the print pattern of the lattice array generated by ink-jet head array
As processing uses vision system, which includes that can be fixed focal length or including focusing automatically and the HD of zoom function is color
Form and aspect machine.Pattern recognition techniques need the pattern of quantity to execute multiple alignment functions for analyze, such as put size, shape and
Integrality；Unidirectionally, the alignment of two-way and step-length；The physical location of ejection assemblies and straight property；The planarization of roller or medium belt；Draw
The bar of guiding systems and the maps defects of track；And it verifies from a jet member pair with reference to jet member to every other ejection assemblies
Homogeneous.From these image analyses, produce for realizing manual or automatic adjustment ink gun physical location, voltage, temperature and spray
Penetrate pulse timing and/or duration；And therefore the print point sprayed from the nozzle in ink gun is positioned in position
Corrected value.CN201410016711.8 discloses a kind of preparation method of Ceramic Tiles, step successively include: mold design, at
Type applies ground coat enamel and forms ground glaze layer, and inkjet printing forms ink-jet decorative layer；Roller printing is carried out in ink-jet decorative layer to decorate to be formed
Printed decor；Layer of transparent glaze is sprayed on printed decor, forms transparent glaze layer；In the enterprising luggage decorations of transparent glaze layer, formed
Glaze layer is decorated, high temperature is fired.Since the stringcourse for using method of the invention to prepare and main brick part are integrally fired, color with
Texture, texture are unified, good decorating effect, and when use not only eliminates cumbersome color separation and the work to plate paving in batches, practical
Property is very strong.
The two is combined with to certain application prospect.
Summary of the invention
Present invention solves the technical problem that providing a kind of ceramic tile production compound dry granular to improve the quality of ceramic product
And Ceramic Tiles.
In order to solve the above technical problem, the present invention provides technical solution are as follows:
A kind of compound dry granular of ceramic tile production, comprising: SiO245 ~ 52%, Al2O313 ~ 15%, Fe2O30.2 ~ 0.5%, TiO2
0 ~ 0.02%, CaO 12 ~ 15%, MgO 5 ~ 7%, K2O 0.5 ~ 1.5%, Na2O 1 ~ 1.5%, B2O31 ~ 4%, ZrO23 ~ 5%, BaO 1 ~
5%, F 1 ~ 4%, NiO2 3~5%。
Dry granular is mixed with pigment etc., different colors may be implemented.
Many effects may be implemented in dry granular, not only have color, also there is surface tactile sensation.The decoration that product is carried out with dry granular, than
It is good to spray special inks effect.Have the characteristics that high hardness and corrosion resistance, resistance to compression, shock resistance, is stained with dirt less, is radiationless.
Preferably, comprising: SiO249.49 ~ 52%, Al2O314 ~ 15%, Fe2O30.3 ~ 0.5%, TiO20.01 ~ 0.02%,
CaO 14 ~ 15%, MgO 6 ~ 7%, K2O 1 ~ 1.5%, Na2O 1.2 ~ 1.5%, B2O32 ~ 4%, ZrO24 ~ 5%, BaO 2 ~ 5%, F 2 ~
4%, NiO2 4~5%。
Preferably, SiO249.49%, Al2O314%, Fe2O30.3%, TiO20.01%, CaO 14%, MgO 6%, K2O
1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%, NiO24%.The ingredient of dry granular is carried out preferably, it can be into one
Step improves the texture of dry granular.
The compound dry granular is applied to manufacture Ceramic Tiles by a kind of Ceramic Tiles.
Preferably, the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. in patterned surfaces sprayed glues；
S14. the dry granular of certain color is sprayed on glue according to the color of the pattern under glue；
S15. it is sintered, obtains Ceramic Tiles after polishing.Using traditional handicraft and the sprayed glues of glaze are drenched in adobe, dry granular shows
Foundry skill is implemented in combination with the application of dry granular, improves the quality of product.
Preferably, the glue is sprayed by ink jet printer.The sprayed glues of ink jet printer are more uniform.
Preferably, the dry granular is sprayed by dry granular machine.Product can effectively be improved by spraying dry granular by dry granular machine
Quality.
Preferably, in the S14 step, further includes:
S141. the pattern under glue is obtained, pattern is handled, the Color feature and shape feature of pattern are obtained；
S142. active path and discharging application are formed in conjunction with the Color feature of pattern and shape feature, by active path and
Discharging application is sent to the control device of dry granular machine machine, and the control device of dry granular machine machine is according to active path and discharging application control
Dry granular machine spray head is mobile and sprays on dry granular to glue.Pattern is handled by way of artificial intelligence, and controls spray head
It is mobile, spray efficiency can be improved.
Preferably, in the S141 step, it is described to pattern carry out processing include gray processing processing, filtering and noise reduction processing and
Normalized it is one of or several.Gray proces are carried out to pattern, filtering and noise reduction is handled, normalized can be improved
The quality of image procossing.
Preferably, the polishing mode is the throwing of DP essence.Different surfaces may be implemented in the throwing of DP essence.
Compared with prior art, the device have the advantages that are as follows: many effects may be implemented in dry granular, not only there is face
Color also has surface tactile sensation.The decoration that product is carried out with dry granular is better than spray special inks effect.With high hardness and corrosion resistance, resist
Pressure, shock resistance, the features such as being stained with dirt less, is radiationless.
The coloured frit dry granular of several different colours also can allow different effects, generate colorful brick.Through throwing
Coloured brick after light has unique artistic effect.
By ink jet printing device, type channel spray is glue, then can be spilt by dry granular machine dry with precise positioning
Grain, to change ink convenient and simple with dry granular ratio is cleaned for replacement.The product of spray drying grain is carried out in conjunction with tradition and modern technique
Production, it is difficult to replicate.
Specific embodiment
Following implementation column is to further explanation of the invention, is not limitation of the present invention.
Embodiment 1
A kind of compound dry granular of ceramic tile production, wherein SiO249.49%, Al2O314%, Fe2O30.3%, TiO20.01%,
CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%, NiO2 4%。
The compound dry granular is applied to manufacture Ceramic Tiles by a kind of Ceramic Tiles, and the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. pass through ink jet printer sprayed glues in patterned surfaces；
S14. the dry granular of certain color is sprayed on glue by dry granular machine according to the color of the pattern under glue；
S15. it is sintered, obtains Ceramic Tiles after polishing.In the S14 step, further includes:
S141. the pattern under glue is obtained, pattern is handled, the Color feature and shape feature of pattern are obtained；
S142. active path and discharging application are formed in conjunction with the Color feature of pattern and shape feature, by active path and
Discharging application is sent to the control device of dry granular machine machine, and the control device of dry granular machine machine is according to active path and discharging application control
Dry granular machine spray head is mobile and sprays on dry granular to glue.It is described that pattern handle including gray processing in the S141 step
Processing, filtering and noise reduction processing and normalized.The polishing mode is the throwing of DP essence.
Dry granular is mixed with pigment etc., different colors may be implemented.Many effects may be implemented in dry granular, not only there is face
Color also has surface tactile sensation.The decoration that product is carried out with dry granular is better than spray special inks effect.With high hardness and corrosion resistance, resist
Pressure, shock resistance, the features such as being stained with dirt less, is radiationless.The ingredient of dry granular is carried out preferably, to can be further improved the texture of dry granular.
It is implemented in combination with the application of dry granular using the modern crafts of the traditional handicraft and sprayed glues, dry granular of drenching glaze in adobe, is improved
The quality of product.The sprayed glues of ink jet printer are more uniform.Product can effectively be improved by spraying dry granular by dry granular machine
Quality.Pattern is handled by way of artificial intelligence, and controls spray head movement, spray efficiency can be improved.To pattern
Carry out gray proces, the quality of image procossing can be improved in filtering and noise reduction processing, normalized.Difference may be implemented in the throwing of DP essence
Surface.
Embodiment 2
A kind of compound dry granular of ceramic tile production, comprising: SiO245.48%, Al2O315%, Fe2O30.5%, TiO20.02%,
CaO 15%, MgO 7%, K2O 1.5%, Na2O 1.5%, B2O34%, ZrO25%, BaO 1%, F 1%, NiO2 3%。
The compound dry granular is applied to manufacture Ceramic Tiles by a kind of Ceramic Tiles, and the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. in patterned surfaces sprayed glues；
S14. the dry granular of certain color is sprayed on glue according to the color of the pattern under glue；
S15. it is sintered, obtains Ceramic Tiles after polishing.The glue is sprayed by ink jet printer.The dry granular is sprayed by dry granular machine
It applies.It is described that pattern handle including gray processing processing, filtering and noise reduction processing in the S141 step.The polishing mode
For the throwing of DP essence.
Embodiment 3
A kind of compound dry granular of ceramic tile production, comprising: SiO250.3%, Al2O313%, Fe2O30.2%, CaO 12%, MgO
5%, K2O 0.5%, Na2O 1%, B2O31%, ZrO23%, BaO 5%, F 4%, NiO2 5%。
The compound dry granular is applied to manufacture Ceramic Tiles by a kind of Ceramic Tiles, and the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. in patterned surfaces sprayed glues；
S14. the dry granular of certain color is sprayed on glue according to the color of the pattern under glue；
S15. it is sintered, obtains Ceramic Tiles after polishing.The glue is sprayed by ink jet printer.It is described right in the S141 step
Pattern carries out the one of which that processing includes gray processing processing, filtering and noise reduction processing and normalized.The polishing mode is
DP essence is thrown.
Embodiment 4
A kind of compound dry granular of ceramic tile production, wherein SiO249.49%, Al2O314%, Fe2O30.3%, TiO20.01%,
CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%, NiO2 4%。
The compound dry granular is applied to manufacture Ceramic Tiles by a kind of Ceramic Tiles, and the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. pass through ink jet printer sprayed glues in patterned surfaces；
S14. the dry granular of certain color is sprayed on glue by ink jet printer according to the color of the pattern under glue；
S15. it is sintered, obtains Ceramic Tiles after polishing.
The ink jet printer is the ink-jet printer of Electronics For Imaging Inc..The ink-jet printer can be sprayed according to figure
Ink printing.
Comparative example 1
A kind of compound dry granular of ceramic tile production, wherein SiO249.49%, Al2O314%, Fe2O30.3%, TiO20.01%,
CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%, NiO2 4%。
The compound dry granular is applied to manufacture Ceramic Tiles by a kind of Ceramic Tiles, and the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. in patterned surfaces spreading glue；
S14. it by dry granular hand spray to glue, fires, polishing.
Comparative example 2
A kind of compound dry granular of ceramic tile production, wherein SiO253.49%, Al2O314%, Fe2O30.3%, TiO20.01%,
CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, BaO 2%, F 2%, NiO2 4%。
Comparative example 3
A kind of compound dry granular of ceramic tile production, wherein SiO2 53.49%, Al2O314%, Fe2O30.3%, TiO20.01%,
CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%.
Comparative example 4
A kind of compound dry granular of ceramic tile production, wherein SiO249.49%, Al2O314%, Fe2O30.3%, TiO20.01%,
CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%, NiO2 4%
Comparative example 5
A kind of compound dry granular of ceramic tile production, wherein SiO263.49%, Fe2O30.3%, TiO20.01%, CaO 14%, MgO
6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO 2%, F 2%, NiO2 4%。
Experimental example
The modulus of rupture of the Ceramic Tiles of method preparation in testing example 1 ~ 4 and comparative example 1 ~ 4.
The performance of 1 Ceramic Tiles of table
As known from Table 1, the modulus of rupture in embodiment 1 ~ 3 has obtained more significant raising.Show containing for reduction boron appropriate
Amount, the content for increasing aluminium oxide deletes the modulus of rupture that plate can be improved in certain degree, and then improves the performance of plate.
Existing ink-jet printer output pattern is directlyed adopt in embodiment 4, also available similar effect.
In comparative example 1 by the way of artificial spreading glue and dry granular, the production time is longer, has led to the quality of product
Decline；Zirconium oxide is free of in comparative example 2, not nickeliferous in comparative example 3, intensity has certain decline, shows zirconium and nickel to raising
The modulus of rupture of product has certain effect；The content of boron is higher in comparative example 4, not salic in comparative example 5, is broken mould
Number is more weaker than comparative example 2 and 3, shows that the content for increasing aluminium, the content for reducing boron have more significant impact to the quality of product.
Meanwhile reducing the content of boron and increasing alumina component, the fusing point of dry granular can be made to be increased to 1050 DEG C or so, in temperature
Before degree rises to fusing point, the moisture in green compact, organic matter has volatilized completely, reduces the high temperature viscosity of frit and relatively slow reduction is molten
Point is conducive to bubble coalescence under high temperature and increases the buoyancy of bubble floating at a large amount of bubbles, thus drain bubble completely as far as possible, into
The quality of one step raising product.
The preparation method of dry granular in the application is to calcine after the oxide of the ingredient or ore are blended, by original
The increase and decrease of material oxide or mineral content controls the content of each substance in final products.
Above-listed detailed description is illustrating for possible embodiments of the present invention, and above embodiments are not to limit this
The scope of the patents of invention, all equivalence enforcements or change without departing from carried out by the present invention, is intended to be limited solely by the scope of the patents of this case.
Claims (10)
1. a kind of compound dry granular of ceramic tile production characterized by comprising SiO245 ~ 52%, Al2O313 ~ 15%, Fe2O3
0.2 ~ 0.5%, TiO20 ~ 0.02%, CaO 12 ~ 15%, MgO 5 ~ 7%, K2O 0.5 ~ 1.5%, Na2O 1 ~ 1.5%, B2O31 ~ 4%,
ZrO23 ~ 5%, BaO 1 ~ 5%, F 1 ~ 4%, NiO2 3~5%。
2. a kind of compound dry granular of ceramic tile production according to claim 1 characterized by comprising SiO2 49.49~
52%, Al2O314 ~ 15%, Fe2O30.3 ~ 0.5%, TiO20.01 ~ 0.02%, CaO 14 ~ 15%, MgO 6 ~ 7%, K2O 1 ~ 1.5%,
Na2O 1.2 ~ 1.5%, B2O32 ~ 4%, ZrO24 ~ 5%, BaO 2 ~ 5%, F 2 ~ 4%, NiO2 4~5%。
3. a kind of compound dry granular of ceramic tile production according to claim 2, which is characterized in that SiO249.49%, Al2O3
14%, Fe2O30.3%, TiO20.01%, CaO 14%, MgO 6%, K2O 1%, Na2O 1.2%, B2O32%, ZrO24%, BaO
2%, F 2%, NiO2 4%。
4. a kind of Ceramic Tiles, which is characterized in that the compound dry granular is applied to manufacture Ceramic Tiles.
5. a kind of Ceramic Tiles according to claim 4, which is characterized in that the method for the manufacture includes:
S11. overglaze is drenched in adobe, obtains glaze；
S12. drawing case is applied in glaze；
S13. in patterned surfaces sprayed glues；
S14. the dry granular of certain color is sprayed on glue according to the color of the pattern under glue；
S15. it is sintered, obtains Ceramic Tiles after polishing.
6. a kind of Ceramic Tiles according to claim 4, which is characterized in that the glue is sprayed by ink jet printer.
7. a kind of Ceramic Tiles according to claim 4, which is characterized in that in the S14 step, further includes:
S141. the pattern under glue is obtained, pattern is handled, the Color feature and shape feature of pattern are obtained；
S142. active path and discharging application are formed in conjunction with the Color feature of pattern and shape feature, by active path and
Discharging application is sent to the control device of dry granular machine machine, and the control device of dry granular machine machine is according to active path and discharging application control
Dry granular machine spray head is mobile and sprays on dry granular to glue.
8. a kind of Ceramic Tiles according to claim 4, which is characterized in that described to be carried out to pattern in the S141 step
Processing includes the one of or several of gray processing processing, filtering and noise reduction processing and normalized.
9. a kind of Ceramic Tiles according to claim 4, which is characterized in that the polishing mode is the throwing of DP essence.
10. a kind of Ceramic Tiles according to claim 4, which is characterized in that the dry granular is sprayed by dry granular machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910829309.4A CN110483104B (en) | 2019-09-03 | 2019-09-03 | Composite dry particles for producing ceramic tile and ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910829309.4A CN110483104B (en) | 2019-09-03 | 2019-09-03 | Composite dry particles for producing ceramic tile and ceramic tile |
Publications (2)
| Publication Number | Publication Date |
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| CN110483104A true CN110483104A (en) | 2019-11-22 |
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| CN111517829A (en) * | 2020-05-27 | 2020-08-11 | 广西欧神诺陶瓷有限公司 | Anti-skid antibacterial ceramic tile and preparation method thereof |
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| CN111517829A (en) * | 2020-05-27 | 2020-08-11 | 广西欧神诺陶瓷有限公司 | Anti-skid antibacterial ceramic tile and preparation method thereof |
| CN111517829B (en) * | 2020-05-27 | 2022-06-03 | 广西欧神诺陶瓷有限公司 | Anti-skid antibacterial ceramic tile and preparation method thereof |
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