CN108658629A - A kind of Ceramic Tiles frit dry granular combination process and Ceramic Tiles - Google Patents

A kind of Ceramic Tiles frit dry granular combination process and Ceramic Tiles Download PDF

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Publication number
CN108658629A
CN108658629A CN201810531350.9A CN201810531350A CN108658629A CN 108658629 A CN108658629 A CN 108658629A CN 201810531350 A CN201810531350 A CN 201810531350A CN 108658629 A CN108658629 A CN 108658629A
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CN
China
Prior art keywords
dry granular
ceramic tiles
frit dry
frit
combination process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810531350.9A
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Chinese (zh)
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CN108658629B (en
Inventor
麦文英
汪加武
叶建明
王礼
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GUANGDONG OVERLAND CERAMICS CO Ltd
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GUANGDONG OVERLAND CERAMICS CO Ltd
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Priority to CN201810531350.9A priority Critical patent/CN108658629B/en
Publication of CN108658629A publication Critical patent/CN108658629A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/52Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/06Frit compositions, i.e. in a powdered or comminuted form containing halogen
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/89Coating or impregnation for obtaining at least two superposed coatings having different compositions

Abstract

The present invention discloses a kind of Ceramic Tiles frit dry granular combination process, which is characterized in that includes the following steps:1) selection adobe, 2) leaching overglaze;3) colored frit dry granular, manufacturing effect pattern are got rid of;4) glue spraying water, cloth clear frit dry granular;5) extra frit dry granular is sopped up;6) it fires, polish.A kind of Ceramic Tiles frit dry granular combination process provided by the invention, using ball frit dry granular, multilayer frit dry granular is combined with each other, achievable change in pattern is up to 10 meters or more, it realizes various different color frit dry granulars while decorating, level is abundant, and texture is true to nature naturally, reproducing the elegant texture of natural rare stone material.Fine grinding tool effect can be realized in conjunction with spray embossment ink, and the embossment position effect shown by each pattern plane changes nature, it appears it is more naturally true to nature, a kind of Ceramic Tiles of great grey sense of touch are formed, strong discrepancy is formed with traditional tile product.The present invention also provides a kind of Ceramic Tiles.

Description

A kind of Ceramic Tiles frit dry granular combination process and Ceramic Tiles
Technical field
The present invention relates to Ceramic Tiles preparing technical field more particularly to a kind of Ceramic Tiles frit dry granular combination process and ceramics Brick.
Background technology
Currently, dry granular glaze Ceramic Tiles are generally made using single wire mark dry granular technology, single wire mark dry granular technology is lacked there are following Point:1) pattern of every brick chromatography, dullness do not change.2) decoration level is not strong.3) usual a kind of color of glaze of dry granular Pattern is dull.4) contraposition is inaccurate, is easy to walk, dim pattern is unintelligible.
Invention content
In view of the deficiencies in the prior art, the purpose of the present invention is to provide a kind of levels to enrich, texture is true to nature certainly Right Ceramic Tiles frit dry granular combination process.
To achieve the above objectives, the present invention adopts the following technical scheme that.
A kind of Ceramic Tiles frit dry granular combination process, which is characterized in that include the following steps:
1) adobe is chosen,
2) overglaze is drenched;
3) colored frit dry granular, manufacturing effect pattern are got rid of;
4) glue spraying water, cloth clear frit dry granular;
5) extra frit dry granular is sopped up;
6) it fires, polish.
As a further illustration of the above scheme, the adobe is the adobe with hole stone effect.
As a further illustration of the above scheme, the overglaze is glaze modelled after an antique.
As a further illustration of the above scheme, the glue spraying water is realized by ink jet printer.
As a further illustration of the above scheme, the cloth clear frit dry granular and described extra frit dry granular is sopped up All realized by dry granular machine.
As a further illustration of the above scheme, in step 6), the Ceramic Tiles baked pass through Elastic abrasive body, brush successively Submodule is polished.
As a further illustration of the above scheme, the colour frit dry granular is by mass percentage, primary chemical forms such as Under:SiO245-52%, Al2O313-15%, Fe2O30.2-0.5%, TiO2< 0.02%, CaO12-14%, MgO 6-8%, K2O 0.5-1.5%, Na2O1-1.5%, Li2O0.08-0.2%, ZnO 4-10%, Cr2O30.2-1.2%, ZrO23-5%, Ba2O34-8%, MnO20.4-1.0%, F 1-4%.
As a further illustration of the above scheme, the clear frit dry granular presses quality proportioning, primary chemical composition is as follows: SiO244-55%, Al2O314-16%, Cao12-15%, MgO 5-7%, K2O 0.5-1.5%, Na2O 1-1.5%, B203 1-4%, ZrO23-5%, Ba2O31-5%, SrO 4-10%.
As a further illustration of the above scheme, before 4) the glue spraying water, cloth clear frit dry granular, it is floating to be additionally provided with spray Carve ink step.
The present invention also provides a kind of Ceramic Tiles, it is characterised in that utilizes Ceramic Tiles frit dry granular combination process as described above It is made.
The beneficial effects of the invention are as follows:
One, multilayer frit dry granular is combined with each other, it can be achieved that change in pattern up to 10 meters or more, realize it is various not homochromy Color frit dry granular is decorated simultaneously, and level is abundant, and texture is true to nature naturally, reproducing the elegant texture of natural rare stone material.
Two, using ink jet printer glue spraying water, cloth frit dry granular, extra frit dry granular is then blown off by dry granular machine, produces work Skill is stablized, and contraposition is accurate, and clear patterns are natural.
Three, technology is thrown using DP essences, makes surface effect more naturally, feel is more comfortable, effect is more true to nature.
Four, fine grinding tool effect, and the embossment position shown by each pattern plane can be realized by spraying embossment ink Effect changes nature, it appears and it is more naturally true to nature, a kind of Ceramic Tiles of great grey sense of touch are formed, are formed with traditional tile product Strong discrepancy.
Specific implementation mode
The specific implementation mode of the present invention is further described below, makes technical scheme of the present invention and its beneficial to effect Fruit is clearer, clear.Embodiment is described below to be exemplary, it is intended to explain the present invention, and should not be understood as to the present invention Limitation.
Embodiment one
A kind of Ceramic Tiles dry granular combination process, includes the following steps:
1) adobe is chosen.
2) overglaze is drenched.
3) colored frit dry granular, manufacturing effect pattern are got rid of.
4) glue spraying water, cloth clear frit dry granular.
5) extra frit dry granular is sopped up into
6) it fires, polish.
Wherein, the adobe is the adobe with hole stone effect.The overglaze is glaze modelled after an antique.The glue spraying water is to pass through spray Black machine is realized.The cloth clear frit dry granular and described sop up extra frit dry granular are realized by dry granular machine 's.The colour frit dry granular and the clear frit dry granular are all ball dry granular.
When polishing, technology is thrown using DP essences, the Ceramic Tiles baked pass through Elastic abrasive body successively, brush module is thrown Light.In the present embodiment, using fine module array technology, by 600 × 8 groups of elastic modules, 400 × 6 groups of elastic modules, 800 × 6 brush modules, module select Italian resin grinding block, processing stone material to be not easy cut stone surface, and essence throws effect according to grinding tool Depth equipment adjust automatically polishing height, realizes the processing of different surfaces, keeps polished surface luminosity uniform.After polishing, then lead to Crossing the antifouling wax water of dozen quick-drying can make surface soiling reach Pyatyi or more.
Preferably, by mass percentage, primary chemical composition is as follows for the colored frit dry granular:SiO245-52%, Al2O313-15%, Fe2O30.2-0.5%, TiO2< 0.02%, CaO12-14%, MgO 6-8%, K2O0.5-1.5%, Na2O1-1.5%, Li2O0.08-0.2%, ZnO 4-10%, Cr2O30.2-1.2%, ZrO23-5%, Ba2O34-8%, MnO20.4-1.0%, F 1-4%.The colour frit dry granular has the characteristics that hardness is high, color development is good.It is dry by color spray frit Many effects may be implemented in grain, not only have color, also there is surface tactile sensation.The decoration of product is carried out with the mode of spray fusing block dry granular, It is got well than spraying special inks.Have the characteristics that high rigidity, corrosion-resistant, resistance to compression, shock resistance, is stained with dirt less, is radiationless.Several difference face The coloured frit dry granular of color, also can allow out different effects, generates colorful brick.Coloured brick after polished has only Special artistic effect.
Preferably, the clear frit dry granular presses quality proportioning, and primary chemical composition is as follows:SiO244-55%, Al2O314-16%, Cao12-15%, MgO 5-7%, K2O 0.5-1.5%, Na2O 1-1.5%, B2031-4%, ZrO2 3- 5%, Ba2O31-5%, SrO 4-10%.The clear frit dry granular forms matt effect.Applicant is preparing transparent dumb light dry granular It was found that the decomposition temperature of barium carbonate higher (1450 degrees Celsius) has more barium carbonate with the glass kind being melt into this way decomposes generation Gas.At the same time, barium monoxide and the CO in furnace atmosphere2Binding ability it is also relatively strong, so containing more barium monoxide at The clarification of the vitreum divided is relatively difficult, in this respect, relatively low (1340 degrees Celsius) strontium oxide strontia of seperated temperature and kiln of strontium carbonate CO in furnace atmosphere2Binding ability it is relatively low, therefore the ratio of the vitreum containing strontium oxide strontia is easier to clarify, so the frit in the present embodiment There is prodigious advantage in terms of dry granular pattern color development stability.By many experiments, the clear frit dry granular that the present embodiment uses is logical It crosses suitable reduction boric acid component and increases alumina component, can make frit that fusing point be made to be increased to 1050 degrees centigrades, in temperature Before degree rises to fusing point, the moisture in green compact, organic matter has volatilized completely, and the dolomite generated in reaction reduces the high temperature of frit Viscosity and relatively slow reduction fusing point, are gathered into a large amount of bubbles conducive to high temperature bubble, increase the buoyancy of bubble floating, to make Bubble drains completely as possible, not soil pick-up after polishing.
A kind of Ceramic Tiles frit dry granular combination process provided in this embodiment, using ball frit dry granular, by multilayer frit Dry granular be combined with each other, it can be achieved that change in pattern up to 10 meters or more, realize various different color frit dry granulars while decorating, layer Secondary abundant, texture is true to nature naturally, reproducing the elegant texture of natural rare stone material.Meanwhile it is dry using ink jet printer glue spraying water, cloth frit Then grain blows extra frit dry granular off by dry granular machine, stable processing technique, contraposition is accurate, and clear patterns are natural.In addition, adopting Technology is thrown with DP essences, makes surface effect more naturally, feel is more comfortable, effect is more true to nature.
Embodiment two
A kind of Ceramic Tiles frit dry granular combination process provided in this embodiment, step and embodiment one are almost the same, area It is not, before 4) the glue spraying water, cloth clear frit dry granular, is additionally provided with spray embossment ink step.
Fine grinding tool effect, and the embossment position effect shown by each pattern plane can be realized by spraying embossment ink Change nature, it appears it is more naturally true to nature, a kind of Ceramic Tiles of great grey sense of touch are formed, are formed strongly with traditional tile product Difference.
Embodiment three
A kind of Ceramic Tiles frit dry granular combination process provided in this embodiment, step and embodiment one are almost the same, area Be not, it is described 2) drench overglaze and it is described 3) get rid of colored frit dry granular, the sequence of manufacturing effect pattern is exchanged.
Example IV
A kind of Ceramic Tiles, it is characterised in that molten using the Ceramic Tiles as described in embodiment one to three kinds of any one of embodiment Block dry granular combination process is made.
From the foregoing description of structures and principles it should be understood by those skilled in the art that, the present invention not office It is limited to above-mentioned specific implementation mode, uses the improvement of techniques well known and replacement to all fall within this hair on the basis of the present invention Bright protection domain, protection scope of the present invention should limit it by each claim and its equivalent.In specific implementation mode The part not illustrated is the prior art or common knowledge.

Claims (10)

1. a kind of Ceramic Tiles frit dry granular combination process, which is characterized in that include the following steps:
1) adobe is chosen,
2) overglaze is drenched;
3) colored frit dry granular, manufacturing effect pattern are got rid of;
4) glue spraying water, cloth clear frit dry granular;
5) extra frit dry granular is sopped up;
6) it fires, polish.
2. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that the adobe be with The adobe of hole stone effect.
3. a kind of preparing ceramic clinker brick dry granular combination process according to claim 1, which is characterized in that the overglaze is modelled after an antique Glaze.
4. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that the glue spraying water is logical Ink jet printer is crossed to realize.
5. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that the cloth clear frit Dry granular and described sop up extra frit dry granular are all realized by dry granular machine.
6. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that in step 6), burn The Ceramic Tiles made pass through Elastic abrasive body successively, brush module is polished.
7. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that the colour frit is dry By mass percentage, primary chemical composition is as follows for grain:SiO245-52%, Al2O313-15%, Fe2O30.2-0.5%, TiO2< 0.02%, CaO12-14%, MgO 6-8%, K2O 0.5-1.5%, Na2O1-1.5%, Li2O0.08-0.2%, ZnO 4- 10%, Cr2O30.2-1.2%, ZrO23-5%, Ba2O34-8%, MnO20.4-1.0%, F 1-4%.
8. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that the clear frit is dry Grain presses quality proportioning, and primary chemical composition is as follows:SiO244-55%, Al2O314-16%, Cao 12-15%, MgO 5-7%, K2O 0.5-1.5%, Na2O 1-1.5%, B2031-4%, ZrO23-5%, Ba2O31-5%, SrO 4-10%.
9. a kind of Ceramic Tiles frit dry granular combination process according to claim 1, which is characterized in that in the 4) glue spraying Before water, cloth clear frit dry granular, it is additionally provided with spray embossment ink step.
10. a kind of Ceramic Tiles, it is characterised in that multiple using the Ceramic Tiles frit dry granular as described in any one of claim 1-9 Technique is closed to be made.
CN201810531350.9A 2018-05-29 2018-05-29 Ceramic tile frit dry particle composite process and ceramic tile Active CN108658629B (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109437977A (en) * 2018-11-09 2019-03-08 蒙娜丽莎集团股份有限公司 A kind of dry granular brick and preparation method thereof with mold concave-convex effect
CN110483104A (en) * 2019-09-03 2019-11-22 广东欧文莱陶瓷有限公司 A kind of ceramic tile production compound dry granular and Ceramic Tiles
CN110498608A (en) * 2019-08-26 2019-11-26 广东萨米特陶瓷有限公司 A kind of low smooth rock beam of high hardness wear-resisting and preparation method thereof
CN113211610A (en) * 2021-07-08 2021-08-06 佛山市东鹏陶瓷有限公司 Glazed tile capable of forming positioning crystallization effect and preparation process thereof
CN113735443A (en) * 2021-10-22 2021-12-03 新明珠集团股份有限公司 Dry bead granules and preparation method thereof
CN113860887A (en) * 2021-10-22 2021-12-31 新明珠集团股份有限公司 Ceramic plate and preparation method thereof
ES2912799A1 (en) * 2020-11-27 2022-05-27 Torrecid Sa Method to produce reliefs in ceramic tiles and ceramic tiles with reliefs manufactured according to the method (Machine-translation by Google Translate, not legally binding)
CN115073215A (en) * 2022-04-27 2022-09-20 广东宏威陶瓷实业有限公司 Ceramic tile with suspended particle decoration effect and preparation method thereof
CN115259666A (en) * 2022-07-29 2022-11-01 新明珠集团股份有限公司 Dry granular glaze, ceramic tile with starlight effect and preparation method thereof
CN115466056A (en) * 2022-10-20 2022-12-13 佛山市东石新型材料有限公司 Colored frit dry particles and ceramic tile decorated by same
CN115947592A (en) * 2023-02-10 2023-04-11 广东天弼陶瓷有限公司 Travertine-imitated ceramic tile with large-opening irregular holes and small-opening holes and preparation method thereof
CN116199529A (en) * 2022-12-30 2023-06-02 广西欧神诺陶瓷有限公司 Fine and smooth matte dry grain glazed ceramic tile and preparation method thereof

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CN107935386A (en) * 2017-11-15 2018-04-20 蒙娜丽莎集团股份有限公司 Graininess dry granular glaze, graininess dry granular glaze cloth ashlar brick and preparation method thereof

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CN107235632A (en) * 2017-07-12 2017-10-10 广东协进陶瓷有限公司 Preparation method with the high digital glaze spraying three-dimensional pattern effect function ceramics bricks of emulation 3D
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CN109437977B (en) * 2018-11-09 2021-08-10 蒙娜丽莎集团股份有限公司 Dry particle brick with concave-convex effect of mold and preparation method thereof
CN109437977A (en) * 2018-11-09 2019-03-08 蒙娜丽莎集团股份有限公司 A kind of dry granular brick and preparation method thereof with mold concave-convex effect
CN110498608A (en) * 2019-08-26 2019-11-26 广东萨米特陶瓷有限公司 A kind of low smooth rock beam of high hardness wear-resisting and preparation method thereof
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ES2912799A1 (en) * 2020-11-27 2022-05-27 Torrecid Sa Method to produce reliefs in ceramic tiles and ceramic tiles with reliefs manufactured according to the method (Machine-translation by Google Translate, not legally binding)
CN113211610A (en) * 2021-07-08 2021-08-06 佛山市东鹏陶瓷有限公司 Glazed tile capable of forming positioning crystallization effect and preparation process thereof
CN113735443A (en) * 2021-10-22 2021-12-03 新明珠集团股份有限公司 Dry bead granules and preparation method thereof
CN113860887A (en) * 2021-10-22 2021-12-31 新明珠集团股份有限公司 Ceramic plate and preparation method thereof
CN115073215A (en) * 2022-04-27 2022-09-20 广东宏威陶瓷实业有限公司 Ceramic tile with suspended particle decoration effect and preparation method thereof
CN115259666A (en) * 2022-07-29 2022-11-01 新明珠集团股份有限公司 Dry granular glaze, ceramic tile with starlight effect and preparation method thereof
CN115259666B (en) * 2022-07-29 2024-03-29 新明珠集团股份有限公司 Dry grain glaze, ceramic tile with starlight effect and preparation method of ceramic tile
CN115466056A (en) * 2022-10-20 2022-12-13 佛山市东石新型材料有限公司 Colored frit dry particles and ceramic tile decorated by same
CN115466056B (en) * 2022-10-20 2023-10-31 佛山市东石新型材料有限公司 Color frit dry particles and ceramic tile decorated by same
CN116199529A (en) * 2022-12-30 2023-06-02 广西欧神诺陶瓷有限公司 Fine and smooth matte dry grain glazed ceramic tile and preparation method thereof
CN115947592A (en) * 2023-02-10 2023-04-11 广东天弼陶瓷有限公司 Travertine-imitated ceramic tile with large-opening irregular holes and small-opening holes and preparation method thereof

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