CN103073335A - Production method of inkjet ceramic plate for dry-hanging building curtain wall - Google Patents
Production method of inkjet ceramic plate for dry-hanging building curtain wall Download PDFInfo
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- CN103073335A CN103073335A CN2013100343577A CN201310034357A CN103073335A CN 103073335 A CN103073335 A CN 103073335A CN 2013100343577 A CN2013100343577 A CN 2013100343577A CN 201310034357 A CN201310034357 A CN 201310034357A CN 103073335 A CN103073335 A CN 103073335A
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Abstract
The invention discloses a production method of an inkjet ceramic plate for a dry-hanging building curtain wall. The production method comprises the following steps of (1) spraying a primary coat absorbing ink easily on a green body, (2) applying a middle coat with a white interface for covering bottom color of the green body on the primary coat, (3) spraying a pattern on the middle coat to form an ink layer, and (4) applying a protection coat on the ink layer, and firing at a high temperature above 1050-1200 DEG C to form the inkjet ceramic plate for the dry-hanging building curtain wall. According to the method, ink can be absorbed quickly, the problems that the ink is dispersed or accumulated, the pattern is blurry easily, and the color and luster are dry during inkjet printing on the ceramic plate are solved, the decorative pattern of the ceramic plate is rich and colorful, the figure is distinct, and the effect is vivid. Compared with the ceramic plate colored wholly, a large number of expensive ceramic pigments are not required to be added to a blank for the inkjet ceramic plate, an inferior clay raw material with high ferrotitanium content can be used, so that the production cost is lowered greatly, and a high-quality pot clay resource is saved.
Description
Technical field
The plate manufacture craft field that the present invention relates to make pottery relates to a kind of cladding building curtain wall in particular with the making method of ink-jet pottery plate.
Background technology
At present existing pottery plate generally is to adopt to add expensive ceramic pigment carry out the painted way of entire body and decorate in base substrate, not only color is simple for it, style is dull, and be difficult to use the reasons such as the high pug of various ferrotitanium foreign matter contents and ceramic pigment price height owing to blank, so that production cost is high.
For above-mentioned reason, research and develop the method for employing spray ink Printing the pottery plate is carried out surface decoration, specifically the imitative high-grade stone material that Computer Design is good, bark, wood grain and various life and art picture directly print on the pottery plate billet surface, after high temperature burns till more than 1050 ℃, make product present colourful decorative effect again.By the formed ink-jet pottery of spray ink Printing plate, have not only that pattern definition is high, effect is true to nature, replacing is simple and the characteristics such as repdocutbility is good, it also has and can the series of advantages such as print at male and fomale(M﹠F), and because base substrate does not need to add colorant, therefore can save cost, owing to can use the high Low-quality clay of ferrotitanium content, also can greatly save high-quality potter's clay resource simultaneously, further reduce cost.
But, because the pottery plate of cladding hollow curtain wall adopts the wet method vacuum extruding form, base substrate has that density is high, ventilation property is poor and the characteristics such as hygroscopic property is low, so when carrying out spray ink Printing, stream becomes a pile because ink fails in time to be adsorbed easily by base substrate, makes dim pattern unclear.In addition, because the sintering temperature of existing ceramic ink self is higher, be painted on after high temperature burns till on the pottery plate often lack of fusion, so that pattern color is dry and astringent unglazed, thereby seriously restricted the application of ink-jet ceramic technology on the pottery panel products is produced.
Summary of the invention
The object of the present invention is to provide a kind of cladding building curtain wall with the making method of ink-jet pottery plate, solved when pottery plate base substrate carries out spray ink Printing base substrate be not easy blotting and high temperature burn till after pattern easily produce dry and astringent unglazed problem.
In order to reach above-mentioned purpose, solution of the present invention is:
A kind of cladding building curtain wall wherein, comprises the steps: with the making method of ink-jet pottery plate
1. spray the ground-coat enamel of the easy blotting of one deck at base substrate;
2. on ground-coat enamel, apply again one deck and have white interface to cover the middle glaze of base substrate background color;
3. carry out the pattern air brushing to form ink lay at middle glaze;
4. impose one deck protection glaze at ink lay, again through the high-temperature firing more than 1050-1200 ℃ to form cladding building curtain wall with the ink-jet plate of making pottery.
Further, the raw material of this ground-coat enamel and weight proportion are: feldspar 20-40%, frit 10-25%, white clay 30-40%, useless porcelain powder 5-20% and silica powder 5-10%.
Further, raw material of glaze and weight proportion are in this: zircon 5-14%, feldspar 30-40%, frit 15-30%, white clay 10-20%, talcum 2-5%, barium carbonate 3-10%, lithium porcelain powder 5-15%.
Further, the raw material of this protection glaze and weight proportion are: feldspar 25-50%, white clay 3-7%, frit 30-50%, dry powder 7-15%, talcum 3-5%.
Further, the glaze volume of this ground-coat enamel is controlled at 250-350g/mm
2, the glaze volume of middle glaze is controlled at 300-450g/mm
2, the glaze volume of protection glaze is controlled at 80-100g/mm
2
Further, the specific gravity control of this ground-coat enamel is between 1.6-1.7, and specific gravity control of glaze is between 1.5-1.6 in this, and the specific gravity control of this protection glaze is between 1.1-1.2.
Further, this ground-coat enamel, middle glaze and protection glaze add respectively the tripoly phosphate sodium STPP of 0.3-0.5% and the carboxymethyl cellulose of 0.15-0.3% again, and then by material: the ratio of water=1: 0.8 adds water polo and is ground to 0.3-0.5% more than the 10000-hole sieve.
After adopting said structure, the present invention relates to a kind of cladding building curtain wall with the making method of ink-jet pottery plate, it is by the mode of the ground-coat enamel that applies easy blotting, the middle glaze of covering the base substrate background color and protection glaze, this ground-coat enamel can adsorb ink, so that ink spreads at depth direction, avoid ink to scatter or accumulation; Should can cover the base substrate background color by middle glaze, and make the color of ink lay purer.
In brief, the present invention can guarantee the quick absorption of printing ink, thereby successfully solved when Tao Banshang carries out spray ink Printing easily wandering or accumulation of ink, pattern easily smudgy and burn after the dry and astringent problem of color and luster, so that the decorative pattern of pottery panel products is rich and varied, figure is clear, and effect is true to nature.
In addition, compare with the pottery plate that present employing entire body is painted, above-mentioned ink-jet pottery plate not only need to not add a large amount of expensive ceramic pigments in blank, and can use the high Low-quality clay raw material of ferrotitanium content, thereby significantly reduces production costs and save high-quality potter's clay resource.
Description of drawings
Fig. 1 the present invention relates to a kind of cladding building curtain wall with the structure sectional view of ink-jet pottery plate.
Among the figure:
Embodiment
In order further to explain technical scheme of the present invention, the present invention will be described in detail below by specific embodiment.
A kind of cladding building curtain wall that the present invention relates to is with the making method of ink-jet pottery plate, and the ink-jet pottery plate structure that it is used to form as shown in Figure 1 comprises the steps:
1. spray the ground-coat enamel 2 of the easy blotting of one deck at base substrate 1;
2. on ground-coat enamel 2, apply again one deck and have white interface to cover the middle glaze 3 of base substrate 1 background color;
3. carry out the pattern air brushing to form ink lay 4 at middle glaze 3;
4. impose one deck protection glaze 5 at ink lay 4, again through the high-temperature firing more than 1050-1200 ℃ to form cladding building curtain wall with the ink-jet plate of making pottery.
Particularly, the weight proportion of this ground-coat enamel 2 is: feldspar 20-40%, frit 10-25%, white clay 30-40%, useless porcelain powder 5-20% and silica powder 5-10%.By above-mentioned weight proportion, so that ground-coat enamel 2 can also be as the transition layer of pottery plate base substrate 1 with middle glaze 3, so that base substrate 1 is good with middle glaze 3 combinations.
Wherein, feldspar plays the effect that reduces the glaze temperature of fusion and improve the ink adsorptive power, if the feldspar consumption is lower than 20%, and then can be so that ground-coat enamel 2 temperature drifts; If consumption is higher than 40%, then ground-coat enamel 2 coefficients of expansion are excessive, are unfavorable for the good combination with base substrate 1.
Frit is the temperature of fusion that plays remarkable reduction ground-coat enamel 2, strengthens the effect of body and glaze associativity; If the frit consumption is lower than 10%, then cooling-down effect is not enough, if be higher than 25% then easily make ground-coat enamel 2 melt temperatures on the low side, all is unfavorable for the combination between base substrate 1 and the ground-coat enamel 2.
White clay mainly is to play the close-burning effect that increases between ground-coat enamel 2 and the base substrate 1, if consumption is lower than 30%, then ground-coat enamel 2 viscosity are not enough, easily peel off; If be higher than 40%, contraction becomes large, easy to crack in the time of then can causing ground-coat enamel 2 dryings and burn till, and has reduced simultaneously the ink absorption ability of ground-coat enamel 2.
Useless porcelain powder then is for the flowability that improves ground-coat enamel 2, strengthens ground-coat enamel 2 ink absorption ability, if its consumption is lower than 5%, the effect of then strengthening ink absorption ability is not obvious, if be higher than 20%, then can significantly improve the maturing temperature of glaze.
The Main Function of silica powder be with ground-coat enamel 2 in other compositions form the silicate glass eutectic when the high temperature, improve physical strength and other mechanical properties of ground-coat enamel 2, increase simultaneously the perviousness of ink; When its consumption is lower than 5% the effect not obvious, if be higher than 10%, then can significantly improve the maturing temperature of glaze.
Particularly, weight proportion of glaze 3 is in this: zircon 5-14%, feldspar 30-40%, frit 15-30%, white clay 10-20%, talcum 2-5%, barium carbonate 3-10%, lithium porcelain powder 5-15%.So can form the white interface of milkiness, to cover the background color of base substrate 1, make ink-jetting pattern not be subjected to the impact of base substrate 1 background color.
Wherein, zircon is most important core component, its role is to make middle glaze 3 to produce white opaque effect, thereby hides base substrate 1 background color, makes ink-jetting pattern color development on white interface, avoids the impact of base substrate 1 background color.Its consumption height is in 5% the time, and opaque effect is with not obvious; And be higher than 14%, then can obviously improve the melt temperature of glaze, the high temperature viscosity of glaze 3 in the increase.
The effect of feldspar is that forming low temperature with frit, talcum, barium carbonate and lithium porcelain powder melts body, the melt temperature of glaze 3 in the reduction altogether.When its consumption was lower than 30%, its cooling effect was not enough; Can make middle glaze 3 coefficient of dilatations excessive if be higher than 40%, be unfavorable for and ground-coat enamel 2 combinations.
The effect of frit is that forming low temperature with feldspar, talcum, barium carbonate and lithium porcelain powder melts body, the melt temperature of glaze 3 in the reduction altogether.When its consumption was lower than 15%, its cooling effect was not enough; Can make middle glaze 3 material melt temperatures excessively low if be higher than 30%.
The adhesive power of glaze 3 during the effect of white clay is to improve can make the glaze adhesivity not enough when being lower than 10%, be higher than 20% melt temperature that can significantly improve middle glaze 3, strengthens simultaneously glaze and shrinks.
The effect of talcum is to form low temperature and melt altogether body with feldspar and frit, barium carbonate, lithium porcelain powder, and the melt temperature of glaze 3 in the reduction, consumption are lower than 2% cooling effect deficiency, is higher than 5% the glaze temperature is raise, and glaze is unglazed.
The effect of barium carbonate is to form low temperature and melt altogether body with feldspar and frit, lithium porcelain powder, talcum, and the melt temperature of glaze 3 in the reduction, consumption are lower than 3% cooling effect deficiency, is higher than 10% clear crystalline substance can make glaze high temperature the time, causes glaze unglazed.
The effect of lithium porcelain powder is to form low temperature and melt altogether body with feldspar and frit, barium carbonate, talcum, and the melt temperature of glaze 3 in the reduction, consumption are lower than 5% cooling effect deficiency, and being higher than 15%, can to make glaze begin to melt temperature excessively low, causes glaze to bubble.
Particularly, the weight proportion of this protection glaze 5 is: feldspar 25-50%, white clay 3-7%, frit 30-50%, dry powder 7-15%, talcum 3-5%.So this protection glaze 5 can also play the temperature of fusion that reduces ink except playing the effect that prevents that pattern from being scratched, and increases the glossiness of pattern and the effect of degree bright in luster.
Wherein, the feldspar Main Function is to form low temperature with frit, dry powder and talcum to melt altogether body, and when its consumption was lower than 25%, this glaze melt temperature was too high; Then can make the too high and possibility that causes glaze to split of glaze coefficient of dilatation when being higher than 50%.
The effect of white clay is the adhesive power that increases glaze, and when its consumption was lower than 3%, the glaze suspension was not enough, easily precipitation; If be higher than 7%, the transparency of glaze is reduced, be unfavorable for the demonstration of ink-jetting pattern.
The effect of frit is to reduce the melt temperature of glaze, improves the transparency of glaze layer.When consumption was lower than 30%, its cooling effect was not enough; To melt temperature excessively low if be higher than 50% beginning, easily causes glaze to bubble.
The effect of dry powder is to reduce the melt temperature of glaze, improves glossiness and the transparency of glaze; When its consumption is lower than 7% the effect not obvious, be higher than 15% and easily cause the clear crystalline substance of glaze high temperature, glaze is unglazed.
The effect of talcum is that forming low temperature with frit, feldspar and dry powder melts body altogether, reduces the glaze melt temperature; When consumption was lower than 3%, its effect was not obvious; Easily improve the glaze melt temperature if be higher than 5%.
Like this, the present invention relates to a kind of cladding building curtain wall with the making method of ink-jet pottery plate, it is by the mode of the ground-coat enamel 2 that applies easy blotting, the middle glaze 3 of covering base substrate 1 background color and protection glaze 5, and this ground-coat enamel 2 can adsorb ink, so that ink spreads at depth direction, avoid ink to scatter or accumulation; Should can cover base substrate 1 background color by middle glaze 3, and make the color of ink lay 4 purer.
Embodiment:
Used raw material and ground-coat enamel among the present invention, middle glaze, the weight proportion of protection glaze is shown in table 1 embodiment.
Table 1:
Above-mentioned numerical value all refers to weight percent wt%.
Each embodiment of ground-coat enamel, middle glaze and protection glaze can be carried out arbitrary combination, implementation step is as follows:
1. at first prepare respectively ground-coat enamel, middle glaze and protection glaze by the prescription among each embodiment in the table one; add respectively again the tripoly phosphate sodium STPP of 0.3-0.5% and the carboxymethyl cellulose of 0.15-0.3%; then in material: the ratio of water=1: 0.8 adds water polo and is ground to suitable fineness, usually is controlled at the remaining 0.3-0.5% of 10000-hole sieve.
2. the pottery plate base substrate that will prepare is executed one deck ground-coat enamel, and the specific gravity control of ground-coat enamel is between 1.6-1.7, and glaze volume is controlled at 250-350g/mm
2, and then execute middle glaze, and the specific gravity control of middle glaze is between 1.5-1.6, and glaze volume is controlled at 300-450g/mm
2, then carry out the pattern air brushing by ink-jet printer, spray again at last one deck protection glaze.The specific gravity control of protection glaze is between 1.1-1.2, and glaze volume is controlled at 80-100g/mm
2
3. will send into roller kiln through the pottery plate base substrate of above-mentioned steps, the high temperature between 1050-1150 ℃ burns till.
In sum, the present invention can guarantee the quick absorption of printing ink, thereby successfully solved when Tao Banshang carries out spray ink Printing easily wandering or accumulation of ink, pattern easily smudgy and burn after the dry and astringent problem of color and luster, so that the decorative pattern of pottery panel products is rich and varied, figure is clear, and effect is true to nature.In addition, compare with the pottery plate that present employing entire body is painted, above-mentioned ink-jet pottery plate not only need to not add a large amount of expensive ceramic pigments in blank, and can use the high Low-quality clay raw material of ferrotitanium content, thereby significantly reduces production costs and save high-quality potter's clay resource.
Above-described embodiment and graphic and non-limiting product form of the present invention and style, any person of an ordinary skill in the technical field all should be considered as not breaking away from patent category of the present invention to its suitable variation or modification of doing.
Claims (7)
1. a cladding building curtain wall is characterized in that with the making method of ink-jet pottery plate, comprises the steps:
1. spray the ground-coat enamel of the easy blotting of one deck at base substrate;
2. on ground-coat enamel, apply again one deck and have white interface to cover the middle glaze of base substrate background color;
3. carry out the pattern air brushing to form ink lay at middle glaze;
4. impose one deck protection glaze at ink lay, again through the high-temperature firing more than 1050-1200 ℃ to form cladding building curtain wall with the ink-jet plate of making pottery.
2. a kind of cladding building curtain wall as claimed in claim 1 is with the making method of ink-jet pottery plate, it is characterized in that, the raw material of this ground-coat enamel and weight proportion are: feldspar 20-40%, frit 10-25%, white clay 30-40%, useless porcelain powder 5-20% and silica powder 5-10%.
3. a kind of cladding building curtain wall as claimed in claim 1 is characterized in that with the making method of ink-jet pottery plate, and raw material of glaze and weight proportion are in this: zircon 5-14%, feldspar 30-40%, frit 15-30%, white clay 10-20%, talcum 2-5%, barium carbonate 3-10%, lithium porcelain powder 5-15%.
4. a kind of cladding building curtain wall as claimed in claim 1 is characterized in that with the making method of ink-jet pottery plate, and the raw material of this protection glaze and weight proportion are: feldspar 25-50%, white clay 3-7%, frit 30-50%, dry powder 7-15%, talcum 3-5%.
5. a kind of cladding building curtain wall as claimed in claim 1 is characterized in that with the making method of ink-jet pottery plate, and the glaze volume of this ground-coat enamel is controlled at 250-350g/mm
2, the glaze volume of middle glaze is controlled at 300-450g/mm
2, the glaze volume of protection glaze is controlled at 80-100g/mm
2
6. a kind of cladding building curtain wall as claimed in claim 5 is with the making method of ink-jet pottery plate; it is characterized in that; the specific gravity control of this ground-coat enamel is between 1.6-1.7, and specific gravity control of glaze is between 1.5-1.6 in this, and the specific gravity control of this protection glaze is between 1.1-1.2.
7. a kind of cladding building curtain wall as claimed in claim 1 is with the making method of ink-jet pottery plate; it is characterized in that; this ground-coat enamel, middle glaze and protection glaze add respectively the tripoly phosphate sodium STPP of 0.3-0.5% and the carboxymethyl cellulose of 0.15-0.3% again, and then by material: the ratio of water=1: 0.8 adds water polo and is ground to 0.3-0.5% more than the 10000-hole sieve.
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| CN107199628A (en) * | 2016-03-16 | 2017-09-26 | 上海悦心健康集团股份有限公司 | The ceramic tile manufacture system and manufacturing process of parian texture, granite granules |
| CN106396607A (en) * | 2016-09-09 | 2017-02-15 | 广西梧州市远方陶瓷有限公司 | Really-through ceramic tile preparation method |
| CN106396621A (en) * | 2016-09-09 | 2017-02-15 | 广西梧州市远方陶瓷有限公司 | Manufacturing method for manufacturing artistic porcelain exterior wall tile |
| CN106396626A (en) * | 2016-09-09 | 2017-02-15 | 广西梧州市远方陶瓷有限公司 | Preparation method of full-body ceramic external wall tile |
| CN106431198A (en) * | 2016-09-09 | 2017-02-22 | 广西梧州市远方陶瓷有限公司 | Manufacturing method of glazed ceramic exterior wall tile |
| CN106431006A (en) * | 2016-09-10 | 2017-02-22 | 许志军 | Glass-based ceramic and production technology |
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