CN103497006A - Ice-crack-shaped polished crystal tile and manufacturing method thereof - Google Patents
Ice-crack-shaped polished crystal tile and manufacturing method thereof Download PDFInfo
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- CN103497006A CN103497006A CN201310426301.6A CN201310426301A CN103497006A CN 103497006 A CN103497006 A CN 103497006A CN 201310426301 A CN201310426301 A CN 201310426301A CN 103497006 A CN103497006 A CN 103497006A
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Abstract
The invention discloses an ice-crack-shaped polished crystal tile comprising a ceramic tile blank, a coloured glaze layer, an ice crack layer and a transparent frit layer, wherein the coloured glaze layer comprises the following components in percentage by mass: printing glaze, glaze pigment, kaolin, methylcellulose and sodium tripolyphosphate; the ice crack layer is made of ice flower crystals with crystal glaze as the main material. The ice-crack-shaped polished crystal tile is manufactured sequentially through the steps: manufacturing a flower net; blending coloured glaze; pushing-printing the coloured glaze and ice flower crystal powder; pushing-printing frit particles; firing; and polishing. According to the invention, a crystal effect liked by people is integrated into the transparent frit layer of the polished crystal tile to form a snowflake-like natural, clean and varied embedded crystal effect, so that the tile with the novel technology has stronger decorative performance; the manufacturing method of the ice-crack-shaped polished crystal tile is simple and rapid, capable of realizing large-batch mechanical production under the condition of no great change of the original equipment, extremely simple in operation and capable of realizing flexible production for tiles with different deigned styles.
Description
Technical field
The present invention relates to the ceramic fabrication technique field, particularly relate to the brilliant brick of a kind of throwing with the ice crack shape and manufacture method thereof.
Background technology
Pottery is the hard material of a kind of densification with the moulding of various material high-temperature firing.Pottery as a kind of material of construction on metope and ground, plays the effect of protection originally.Due to the raising of living standards of the people, a lot of variations have all occurred in the structure and function of pottery gradually.But change in any case, in the situation that do not damage ceramic function and appearance reduces production costs as far as possible, adopting various technical schemes to change characteristic and the manifestation of pottery itself, to scheme to attract human consumer's sight, is the eternal constant two principal themes of evolution of technology of ceramics factory.Under the guide of this power, the polished tile that ceramic tile is burnt till by common material develops multiple different ceramic tile.Wherein a kind of the throwing on the surface that brilliant brick is exactly the ceramic tile of burning till at common material applies the colorful glaze of one deck, then fire for the first time, then by frit cloth on the glazed layer of the biscuit of firing for the first time formation, through burning till as throwing brilliant brick for the second time.On the one hand, glaze has colorful pattern, and the mode that it can adopt roll printing, block printing or ink jet printing just looks like the pigment using glaze as oil painting, draw out a lifelike oil painting at ceramic brick surface, expanded the performing content of ceramic tile.On the other hand, frit cloth, on glaze layer, is formed to vitreous transparent layer after frit melts, by the glaze layer protection in the inner, be equivalent to oil painting mount sealer, the protection pattern is not damaged by the external world.But the pattern of the brilliant brick product of current throwing only shows by glaze layer, and manifestation is too single, and the stereoscopic sensation shown between frit layer and glaze layer is poor, can not meet the modern to requirement attractive in appearance.And the product needed of moulding fires through twice on the basis of biscuit, consume the more energy, increased widely the cost of making.
Summary of the invention
The brilliant brick of the throwing with the ice crack shape that the object of the invention is to avoid weak point of the prior art and provide, the mixture with ice crack pattern is placed in to be thrown under the hard and saturating clear frit crystal layer protection in brilliant brick surface, not only elegant in appearance, and durable wear-resisting.
Another object of the present invention is to provide the manufacture method of the brilliant brick of a kind of throwing with the ice crack shape, and operation is simple, and handiness is strong, but for the equal flexible transformation production of the ceramic tile of different designs style.
For achieving the above object, provide following technical scheme.
The brilliant brick of a kind of throwing with the ice crack shape, comprise ceramic adobe, also comprises color glaze layer, ice crack layer and clear frit layer; Be followed successively by from top to bottom described clear frit layer, ice crack layer, color glaze layer and ceramic adobe;
Described color glaze layer comprises following composition according to mass percent: screen printing glaze 78%-93%, glaze stain 3%-6%, kaolin 0%-10%, methylcellulose gum 0%-3% and tripoly phosphate sodium STPP 0%-3%;
Described ice crack layer is 30-80 purpose frost flower crystal.
The water-intake rate of described ceramic adobe is lower than 3%, the length of described ceramic adobe and wide than the length of finished product and wide all many 18mm-20mm; Described ceramic adobe is the whiteware adobe.
Described clear frit layer thickness is 2.5mm, and described clear frit layer is that the clear frit dry granular is fired and formed.
Described frost flower crystal comprises following chemical composition according to mass percent:
Three silicon oxide 79%-85%;
Alchlor 7%-9%;
Magnesium oxide 0.1%-0.7%;
Calcium oxide 1.5%-3%;
Titanium trioxide 0.01%-0.1%;
Potassium oxide 0.1%-1%;
Sodium oxide 5%-7%;
Ferric oxide 0%-0.2%
Described ferric oxide is less than 0.12%
With the manufacture method of the brilliant brick of the throwing of ice crack shape, step comprises:
A. make the flower net, need by the color designed, produce the colored net of respective color layout;
B. in proportion the composition of described color glaze layer is mixed, and allocate different described glaze stains by the different colours of design, after ball mill grinding, make color glaze;
C. described frost flower crystal is made to 30-80 purpose frost flower crystal powder;
D. according to the corresponding relation of described colored net and described color glaze layer, with described color glaze, in order the pattern that will show is printed on described ceramic batch from level to level, makes the color glaze adobe;
E. according to the position of pre-designed appearance ice crack shape, use 30-60 purpose screen cloth to make the silk screen with respective area pattern;
F. described frost flower crystal powder is pushed away and is imprinted in described color glaze adobe by described silk screen, make the adobe of ice crack color glaze;
G. described clear frit dry granular is pushed away and is imprinted in the adobe of described ice crack color glaze by 30-60 purpose screen cloth;
H. fire and polishing.
In step b, after described color glaze ball milling, needed 200 mesh sieves to take off material.
Described silk screen in step e is the all-pass silk screen.
In step h firing temperature be 950 ℃.
The brilliant brick of the throwing with the ice crack shape that the present invention obtains, material is hard, durable attractive in appearance, and the ice crack layer that the frost flower crystal of take is the master is suspended in clear frit, and finished product not only smooth surface is attractive in appearance, and hard wear resistant.
The manufacture method simple and fast of the brilliant brick of the throwing with the ice crack shape of the present invention, in the situation that do not need existing equipment is made to very large change, still can large batch of mechanization production, operate very simple, but for all flexible transformation production of ceramic tile of different designs style.
Embodiment
Embodiment 1
The present embodiment is that a kind of dark fund glaze ice crack is thrown brilliant brick, and it comprises:
Be followed successively by from top to bottom described clear frit layer, ice crack layer, color glaze layer and water-intake rate lower than 3% whiteware adobe; Wherein the color glaze layer comprises the color glaze of black and golden two kinds of colors; Its formula following (mass ratio):
Black color glaze is: the glaze stain 6% of screen printing glaze 78%, black, kaolin 10%, methylcellulose gum 3% and tripoly phosphate sodium STPP 3%;
Golden color glaze is: glaze stain 3%, methylcellulose gum 3% and the tripoly phosphate sodium STPP 1% of screen printing glaze 93%, gold;
The ice crack layer is frost flower crystal, comprises following chemical composition: three silicon oxide 79%; Alchlor 9%; Magnesium oxide 0.7%; Calcium oxide 3%; Titanium trioxide 0.1%; Potassium oxide 1%; Sodium oxide 7%; Ferric oxide 0.2%.
The clear frit layer is: the clear frit dry granular.
Manufacture method is as follows:
A. press black and the golden needs that distribute of ceramic tile design, produce the colored net of respective color layout.
B. in proportion the composition of described color glaze layer is mixed, and, by design black and the different described glaze stain of golden allotment, after ball mill grinding, cross 200 mesh sieves and take off material, make black color glaze and golden color glaze;
C. by the 80 purpose frost flower crystal powders of making of described frost flower crystal;
D. according to the corresponding relation of described colored net and described color glaze layer, with described color glaze, in order the pattern that will show is printed on described ceramic batch from level to level, makes with black and golden color glaze adobe;
E. according to the position of pre-designed appearance ice crack shape, use 60 purpose screen cloths to make the all-pass silk screen with respective area pattern;
F. described frost flower crystal powder is pushed away and is imprinted in described color glaze adobe by described silk screen, make the adobe of ice crack color glaze;
G. described clear frit dry granular is pushed away and is imprinted in the adobe of described ice crack color glaze by 60 purpose screen cloths;
H. the kiln that is 950 ℃ through firing temperature is fired, and carries out surface finish after firing.
Described clear frit layer thickness is 2.5mm, and this thickness not only can guarantee that the clear frit layer can protect shimmering powder layer and frit under it thoroughly clear.
The main raw of frost flower crystal is the crystal clinker.
The kaolin added in color glaze, methylcellulose gum and tripoly phosphate sodium STPP, wherein methylcellulose gum is toughener, the methylcellulose gum outward appearance is white or off-white color is fibrous or granulated powders, the aqueous solution is quite stable at normal temperatures, energy gel during high temperature, and this gel can change mutually with solution with the height of temperature, there is good wettability, dispersed, cementability, thickening property, emulsifying property, water-retentivity and film-forming properties, and to the opacity of grease, methylcellulose gum makes the described color glaze thickness that becomes, the significantly adhesive capacity of described color glaze and heat-drawn wire, tripoly phosphate sodium STPP is dispersion agent, and tripoly phosphate sodium STPP is soluble in water, and its aqueous solution is alkalescence, can prevent sedimentation and the cohesion of solid particulate for described color glaze, makes it form the stable color glaze suspended.Kaolin has that whiteness is high, matter is soft, easy dispersion suspension in water, good plasticity-and high cohesiveness, make the solution thickness that becomes.
Water-intake rate is affected by composition of raw materials, the press tonnage of pressed compact, the sintering process of adobe itself usually, the adobe that water-intake rate is lower, and the adobe density is higher, and quality is usually also just better.Water-intake rate, lower than 3%, has belonged to the higher standard of Shi porcelain, can guarantee that the present invention is stable for the production of practice.
When firing, because the fusing point of clear frit dry granular is lower, and take frost flower crystal that crystalline glaze is main component through firing the state that presents ice crack, part clear frit dry granular merges in the ice crack layer, the effect that makes the ice crack layer show is the three-dimensional ceramic tile surface that is suspended in, and forms the snowflake general nature clean and the abundant embedded Aero Glass changed arranged; Owing to being provided with the clear frit layer, make the ice crack layer obtain protection, and the ceramic tile surface smooth top grade that seems.
The advantage of this is: within the Aero Glass that people are liked is dissolved into the clear frit layer of ceramic tile, form the snowflake general nature clean and the abundant embedded Aero Glass changed is arranged, thereby order is used the ceramic tile of this new technology to have stronger decorate properties.And this product only need to reduce the number of times of firing through once firing of biscuit be can be made into to finished product, greatly reduce production cost.
Embodiment 2
The present embodiment is that a kind of yellowish-white glaze ice crack is thrown brilliant brick, and it comprises:
Be followed successively by from top to bottom described clear frit layer, ice crack layer, color glaze layer and whiteware adobe; Wherein the color glaze layer comprises color glaze yellow and two kinds of colors of white; Its formula following (mass ratio):
Yellow color glaze is: glaze stain 4%, the kaolin 10% of screen printing glaze 86%, yellow;
White color glaze is: glaze stain 5%, kaolin 5%, methylcellulose gum 1.5% and the tripoly phosphate sodium STPP 1.5% of screen printing glaze 87%, white;
The ice crack layer is frost flower crystal, comprises following chemical composition: three silicon oxide 85%; Alchlor 7%; Magnesium oxide 0.1%; Calcium oxide 1.5%; Titanium trioxide 0.01%; Potassium oxide 0.1%; Sodium oxide 6.29%;
The clear frit layer is: the clear frit dry granular.
Manufacture method is as follows:
A. press yellow and the white distribution needs of ceramic tile design, produce the colored net of respective color layout.
B. in proportion the composition of described color glaze layer is mixed, and, by design yellow and the different described glaze stain of white allotment, after ball mill grinding, cross 200 mesh sieves and take off material, make yellow color glaze and white color glaze;
C. by the 30 purpose frost flower crystal powders of making of described frost flower crystal;
D. according to the corresponding relation of described colored net and described color glaze layer, with described color glaze, in order the pattern that will show is printed on described ceramic batch from level to level, makes with yellow and white color glaze adobe;
E. according to the position of pre-designed appearance ice crack shape, use 30 purpose screen cloths to make the all-pass silk screen with respective area pattern;
F. described frost flower crystal powder is pushed away and is imprinted in described color glaze adobe by described silk screen, make the adobe of ice crack color glaze;
G. described clear frit dry granular is pushed away and is imprinted in the adobe of described ice crack color glaze by 30 purpose screen cloths;
H. the kiln that is 950 ℃ through firing temperature is fired, and carries out surface finish after firing.
The present embodiment throw brilliant brick for yellowish-white glaze ice crack, match and add the ice crack layer in the clear frit layer with white due to yellow, form the snowflake general nature clean and the abundant embedded Aero Glass changed, the pattern elegant that seems arranged.
Embodiment 3
The present embodiment is that a kind of yellowish-brown glaze ice crack is thrown brilliant brick, and it comprises:
Be followed successively by from top to bottom described clear frit layer, ice crack layer, color glaze layer and whiteware adobe; Wherein the color glaze layer comprises the color glaze of yellow and brown two kinds of colors; Its formula following (mass ratio):
Yellow color glaze is: glaze stain 4%, the kaolin 10% of screen printing glaze 86%, yellow;
Brown color glaze is: screen printing glaze 80%, brown glaze stain 6%, kaolin 10%, methylcellulose gum 2% and tripoly phosphate sodium STPP 2%;
The ice crack layer is frost flower crystal, comprises following chemical composition: three silicon oxide 81.47%; Alchlor 8.76%; Magnesium oxide 0.27%; Calcium oxide 2.68%; Titanium trioxide 0.06%; Potassium oxide 0.87%; Sodium oxide 5.88%; Ferric oxide 0.01%;
The clear frit layer is: the clear frit dry granular.
Manufacture method is as follows:
A. press yellow and the brown distribution needs of ceramic tile design, produce the colored net of respective color layout.
B. in proportion the composition of described color glaze layer is mixed, and, by the yellow described glaze stain different with brown allotment of design, after ball mill grinding, cross 200 mesh sieves and take off material, make yellow color glaze and brown color glaze;
C. by the 45 purpose frost flower crystal powders of making of described frost flower crystal;
D. according to the corresponding relation of described colored net and described color glaze layer, with described color glaze, in order the pattern that will show is printed on described ceramic batch from level to level, makes with yellow and brown color glaze adobe;
E. according to the position of pre-designed appearance ice crack shape, use 50 purpose screen cloths to make the all-pass silk screen with respective area pattern;
F. described frost flower crystal powder is pushed away and is imprinted in described color glaze adobe by described silk screen, make the adobe of ice crack color glaze;
G. described clear frit dry granular is pushed away and is imprinted in the adobe of described ice crack color glaze by 45 purpose screen cloths;
H. the kiln that is 950 ℃ through firing temperature is fired, and carries out surface finish after firing.
The present embodiment throw brilliant brick for yellowish-brown glaze ice crack, add the ice crack layer in the clear frit layer due to yellow with brown matching, form the snowflake general nature clean and the abundant embedded Aero Glass changed, the pattern elegant that seems arranged.
Finally should be noted that; above embodiment is only for illustrating technical scheme of the present invention but not limiting the scope of the invention; although with reference to preferred embodiment, the present invention is explained in detail; those of ordinary skill in the art is to be understood that; can modify or be equal to replacement technical scheme of the present invention, and not break away from essence and the scope of technical solution of the present invention.
Claims (9)
1. the brilliant brick of the throwing with the ice crack shape, comprise ceramic adobe, it is characterized in that: also comprise color glaze layer, ice crack layer and clear frit layer; Be followed successively by from top to bottom described clear frit layer, ice crack layer, color glaze layer and ceramic adobe;
Described color glaze layer comprises following composition according to mass percent: screen printing glaze 78%-93%, glaze stain 3%-6%, kaolin 0%-10%, methylcellulose gum 0%-3% and tripoly phosphate sodium STPP 0%-3%;
Described ice crack layer is 30-80 purpose frost flower crystal.
2. the brilliant brick of the throwing with the ice crack shape according to claim 1 is characterized in that: the water-intake rate of described ceramic adobe is lower than 3%, the length of described ceramic adobe and wide than the length of finished product and wide all many 18mm-20mm; Described ceramic adobe is the whiteware adobe.
3. the brilliant brick of the throwing with the ice crack shape according to claim 1, it is characterized in that: described clear frit layer thickness is 2.5mm, described clear frit layer is that the clear frit dry granular is fired and formed.
4. the brilliant brick of the throwing with the ice crack shape according to claim 1, it is characterized in that: described frost flower crystal comprises following chemical composition according to mass percent:
Three silicon oxide 79%-85%;
Alchlor 7%-9%;
Magnesium oxide 0.1%-0.7%;
Calcium oxide 1.5%-3%;
Titanium trioxide 0.01%-0.1%;
Potassium oxide 0.1%-1%;
Sodium oxide 5%-7%;
Ferric oxide 0%-0.2%.
5. the brilliant brick of the throwing with the ice crack shape according to claim 4, it is characterized in that: described ferric oxide is less than 0.12%.
6. the manufacture method of the brilliant brick of as described as the claim 1-5 any one throwing with the ice crack shape, it is characterized in that: step comprises:
A. make the flower net, need by the color designed, produce the colored net of respective color layout;
B. in proportion the composition of described color glaze layer is mixed, and allocate different described glaze stains by the different colours of design, after ball mill grinding, make color glaze;
C. described frost flower crystal is made to 30-80 purpose frost flower crystal powder;
D. according to the corresponding relation of described colored net and described color glaze layer, with described color glaze, in order the pattern that will show is printed on described ceramic batch from level to level, makes the color glaze adobe;
E. according to the position of pre-designed appearance ice crack shape, use 30-60 purpose screen cloth to make the silk screen with respective area pattern;
F. described frost flower crystal powder is pushed away and is imprinted in described color glaze adobe by described silk screen, make the adobe of ice crack color glaze;
G. described clear frit dry granular is pushed away and is imprinted in the adobe of described ice crack color glaze by 30-60 purpose screen cloth;
H. fire and polishing.
7. the manufacture method of the brilliant brick of the throwing with the ice crack shape according to claim 6, is characterized in that: in step b, after described color glaze ball milling, needed 200 mesh sieves to take off material.
8. the manufacture method of the brilliant brick of the throwing with the ice crack shape according to claim 6, it is characterized in that: the described silk screen in step e is the all-pass silk screen.
9. the manufacture method of the brilliant brick of the throwing with the ice crack shape according to claim 6 is characterized in that: in step h firing temperature be 950 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310426301.6A CN103497006B (en) | 2013-09-17 | 2013-09-17 | A kind of Polished crystal tile with ice crack shape and manufacture method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310426301.6A CN103497006B (en) | 2013-09-17 | 2013-09-17 | A kind of Polished crystal tile with ice crack shape and manufacture method thereof |
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| CN103497006A true CN103497006A (en) | 2014-01-08 |
| CN103497006B CN103497006B (en) | 2016-08-31 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108129029A (en) * | 2018-01-05 | 2018-06-08 | 九牧厨卫股份有限公司 | Snowflake glaze preparation method and relevant glaze, glaze preparation method for material, enamel frit makeing material composition knead dough glaze formula method of adjustment |
| CN110776256A (en) * | 2019-11-27 | 2020-02-11 | 蒙娜丽莎集团股份有限公司 | White radial crystal flower dry grain glaze, light-transmitting ceramic tile and preparation method thereof |
| CN110818264A (en) * | 2019-12-18 | 2020-02-21 | 湖南华联瓷业股份有限公司 | High-temperature all-ceramic crack glaze and preparation method thereof |
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| CN1715229A (en) * | 2004-07-03 | 2006-01-04 | 陈根 | Longquan celadon frostwork glaze and its producing method for product |
| CN202248704U (en) * | 2011-09-30 | 2012-05-30 | 佛山石湾鹰牌陶瓷有限公司 | Once-fired devitrified glass compound tile |
| CN203160611U (en) * | 2013-03-15 | 2013-08-28 | 余建平 | Ceramic decorative tile coated with transparent crackle glaze |
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2013
- 2013-09-17 CN CN201310426301.6A patent/CN103497006B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1715229A (en) * | 2004-07-03 | 2006-01-04 | 陈根 | Longquan celadon frostwork glaze and its producing method for product |
| CN202248704U (en) * | 2011-09-30 | 2012-05-30 | 佛山石湾鹰牌陶瓷有限公司 | Once-fired devitrified glass compound tile |
| CN203160611U (en) * | 2013-03-15 | 2013-08-28 | 余建平 | Ceramic decorative tile coated with transparent crackle glaze |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108129029A (en) * | 2018-01-05 | 2018-06-08 | 九牧厨卫股份有限公司 | Snowflake glaze preparation method and relevant glaze, glaze preparation method for material, enamel frit makeing material composition knead dough glaze formula method of adjustment |
| CN108129029B (en) * | 2018-01-05 | 2020-10-27 | 九牧厨卫股份有限公司 | Snowflake glaze material and related preparation method and overglaze formula adjustment method |
| CN110776256A (en) * | 2019-11-27 | 2020-02-11 | 蒙娜丽莎集团股份有限公司 | White radial crystal flower dry grain glaze, light-transmitting ceramic tile and preparation method thereof |
| CN110776256B (en) * | 2019-11-27 | 2021-10-22 | 蒙娜丽莎集团股份有限公司 | White radial crystal flower dry grain glaze, light-transmitting ceramic tile and preparation method thereof |
| CN110818264A (en) * | 2019-12-18 | 2020-02-21 | 湖南华联瓷业股份有限公司 | High-temperature all-ceramic crack glaze and preparation method thereof |
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|---|---|
| CN103497006B (en) | 2016-08-31 |
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Address after: 528000 No. 7, Tao Bei Road, Huaxia Ceramic Expo City, Nanzhuang Town, Chancheng District, Foshan, Guangdong, China. 2 Patentee after: Guangdong May rose Ceramic Co., Ltd. Address before: 528000 No. 7, Tao Bei Road, Huaxia Ceramic Expo City, Nanzhuang Town, Chancheng District, Foshan, Guangdong, China. 2 Patentee before: Foshan City cabbage pottery company limited |
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